DE3607929A1 - Verfahren zur herstellung von desulfurierenden und denitrierenden mitteln - Google Patents
Verfahren zur herstellung von desulfurierenden und denitrierenden mittelnInfo
- Publication number
- DE3607929A1 DE3607929A1 DE19863607929 DE3607929A DE3607929A1 DE 3607929 A1 DE3607929 A1 DE 3607929A1 DE 19863607929 DE19863607929 DE 19863607929 DE 3607929 A DE3607929 A DE 3607929A DE 3607929 A1 DE3607929 A1 DE 3607929A1
- Authority
- DE
- Germany
- Prior art keywords
- materials
- starting
- starting materials
- starting material
- desulfurization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 39
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000007858 starting material Substances 0.000 claims description 44
- 239000000463 material Substances 0.000 claims description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 37
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 32
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 26
- 239000000292 calcium oxide Substances 0.000 claims description 23
- 230000032683 aging Effects 0.000 claims description 18
- 230000003009 desulfurizing effect Effects 0.000 claims description 16
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000006477 desulfuration reaction Methods 0.000 description 27
- 230000023556 desulfurization Effects 0.000 description 27
- 235000012255 calcium oxide Nutrition 0.000 description 21
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 16
- 239000002585 base Substances 0.000 description 14
- 239000007789 gas Substances 0.000 description 14
- 235000011132 calcium sulphate Nutrition 0.000 description 10
- 239000010883 coal ash Substances 0.000 description 10
- 239000004571 lime Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 9
- 235000011941 Tilia x europaea Nutrition 0.000 description 9
- 238000011056 performance test Methods 0.000 description 9
- 229910004298 SiO 2 Inorganic materials 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000005259 measurement Methods 0.000 description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 239000002956 ash Substances 0.000 description 6
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 6
- 239000000920 calcium hydroxide Substances 0.000 description 6
- 235000011116 calcium hydroxide Nutrition 0.000 description 6
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 239000000741 silica gel Substances 0.000 description 5
- 229910002027 silica gel Inorganic materials 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000004568 cement Substances 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000010459 dolomite Substances 0.000 description 4
- 229910000514 dolomite Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000011398 Portland cement Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000000378 calcium silicate Substances 0.000 description 3
- 229910052918 calcium silicate Inorganic materials 0.000 description 3
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 3
- 150000004683 dihydrates Chemical class 0.000 description 3
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 230000036962 time dependent Effects 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229940037003 alum Drugs 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 229940043430 calcium compound Drugs 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- -1 CaSO. Inorganic materials 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000356114 Trachytes Species 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- COOGPNLGKIHLSK-UHFFFAOYSA-N aluminium sulfide Chemical compound [Al+3].[Al+3].[S-2].[S-2].[S-2] COOGPNLGKIHLSK-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 150000001674 calcium compounds Chemical class 0.000 description 1
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229910001653 ettringite Inorganic materials 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000011426 gypsum mortar Substances 0.000 description 1
- 239000004572 hydraulic lime Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000005648 named reaction Methods 0.000 description 1
- 239000010742 number 1 fuel oil Substances 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/508—Sulfur oxides by treating the gases with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/60—Simultaneously removing sulfur oxides and nitrogen oxides
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60051247A JPS61209038A (ja) | 1985-03-13 | 1985-03-13 | 脱硫、脱硝用吸収剤 |
| JP60237195A JPS6297640A (ja) | 1985-10-25 | 1985-10-25 | 脱硫脱硝剤の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3607929A1 true DE3607929A1 (de) | 1986-09-18 |
| DE3607929C2 DE3607929C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1990-02-08 |
Family
ID=26391777
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19863607929 Granted DE3607929A1 (de) | 1985-03-13 | 1986-03-11 | Verfahren zur herstellung von desulfurierenden und denitrierenden mitteln |
Country Status (6)
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3735245A1 (de) * | 1987-04-23 | 1989-05-03 | Hoelter Heinz | Trockene gasreinigung von sauren schadstoffen wie so(pfeil abwaerts)3(pfeil abwaerts), so(pfeil abwaerts)2(pfeil abwaerts), hf, hcl und no(pfeil abwaerts)x(pfeil abwaerts) durch mit alkalien getraenkte kalk-aluminium-zementsilikate als sorptionsmittel |
| DE3915934A1 (de) * | 1988-05-16 | 1989-11-30 | Fichtel Roland | Mittel und verfahren zur reinigung von gasen und abgasen und ein verfahren zur herstellung dieser mittel |
| DE3826971A1 (de) * | 1988-08-09 | 1990-02-15 | Ftu Gmbh | Verfahren zur herstellung modifizierter calciumhydroxide fuer die gas- und abgasreinigung unter verwendung von wirkstoffkonzentraten |
| DE3844217A1 (de) * | 1988-12-29 | 1990-07-05 | Ftu Gmbh | Verfahren zur herstellung von calciumhydroxiden |
| DE8816866U1 (de) * | 1987-05-18 | 1991-02-28 | FTU GmbH, 82319 Starnberg | Feinpulvriges Calciumhydroxid zur Gas- und Abgasreinigung |
| DE3939214A1 (de) * | 1989-11-28 | 1991-06-13 | Ftu Gmbh | Verfahren zur reinigung von abgasen |
| DE4401166A1 (de) * | 1994-01-17 | 1995-07-20 | Krupp Polysius Ag | Verfahren zur Reinigung von Rauchgasen |
| DE102014018799A1 (de) * | 2014-12-19 | 2016-06-23 | Bayerisches Zentrum für Angewandte Energieforschung e.V. | Feuchtespeicherndes Stoffgemisch und Bauplatte daraus |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5401481A (en) * | 1986-11-10 | 1995-03-28 | Board Of Regents, The University Of Texas System | Processes for removing acid components from gas streams |
| EP0454885A1 (de) * | 1990-05-02 | 1991-11-06 | Ftu Gmbh | Verfahren zur Reinigung von Gasen und Abgasen von Schadstoffen |
| CN1054078C (zh) * | 1995-11-02 | 2000-07-05 | 国家建筑材料工业局南京水泥工业设计研究院 | 去除工业窑炉废气中一氧化氮和二氧化氮混合物的方法 |
| CN1280030C (zh) * | 1999-11-04 | 2006-10-18 | 出光兴产株式会社 | 煤燃烧灰的处理方法及脱硫方法 |
| JP3409285B2 (ja) * | 2000-04-04 | 2003-05-26 | 北海道電力株式会社 | 排煙処理剤の製造方法 |
| US8124036B1 (en) | 2005-10-27 | 2012-02-28 | ADA-ES, Inc. | Additives for mercury oxidation in coal-fired power plants |
| US8574324B2 (en) | 2004-06-28 | 2013-11-05 | Nox Ii, Ltd. | Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels |
| JP2008533432A (ja) | 2005-03-17 | 2008-08-21 | ノックス・ツー・インターナショナル・リミテッド | 石炭の燃焼からの水銀放出の低減 |
| PL3424585T3 (pl) | 2005-03-17 | 2022-10-03 | Nox Ii International, Ltd. | Redukcja emisji rtęci i siarki ze spalania węgla |
| US20070163476A1 (en) * | 2006-01-18 | 2007-07-19 | Comrie Douglas C | Apparatus for delivery of sorbent to a furnace during combustion |
| US8150776B2 (en) | 2006-01-18 | 2012-04-03 | Nox Ii, Ltd. | Methods of operating a coal burning facility |
| US8496894B2 (en) | 2010-02-04 | 2013-07-30 | ADA-ES, Inc. | Method and system for controlling mercury emissions from coal-fired thermal processes |
| US8951487B2 (en) | 2010-10-25 | 2015-02-10 | ADA-ES, Inc. | Hot-side method and system |
| CN107866141A (zh) | 2010-02-04 | 2018-04-03 | Ada-Es股份有限公司 | 控制从烧煤的热工艺释放汞的方法和系统 |
| US8524179B2 (en) | 2010-10-25 | 2013-09-03 | ADA-ES, Inc. | Hot-side method and system |
| US8784757B2 (en) | 2010-03-10 | 2014-07-22 | ADA-ES, Inc. | Air treatment process for dilute phase injection of dry alkaline materials |
| EP2545334B8 (en) | 2010-03-10 | 2018-09-19 | ADA-ES, Inc. | Process for dilute phase injection of dry alkaline materials into a gas |
| US8845986B2 (en) | 2011-05-13 | 2014-09-30 | ADA-ES, Inc. | Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers |
| US9017452B2 (en) | 2011-11-14 | 2015-04-28 | ADA-ES, Inc. | System and method for dense phase sorbent injection |
| US8883099B2 (en) | 2012-04-11 | 2014-11-11 | ADA-ES, Inc. | Control of wet scrubber oxidation inhibitor and byproduct recovery |
| US8974756B2 (en) | 2012-07-25 | 2015-03-10 | ADA-ES, Inc. | Process to enhance mixing of dry sorbents and flue gas for air pollution control |
| US9957454B2 (en) | 2012-08-10 | 2018-05-01 | ADA-ES, Inc. | Method and additive for controlling nitrogen oxide emissions |
| CN104353348B (zh) * | 2014-10-16 | 2017-02-15 | 信丰县包钢新利稀土有限责任公司 | 一种含有稀土的干法脱硫剂 |
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| DE3428502A1 (de) * | 1983-08-16 | 1985-03-07 | Gernot Prof. Dipl.-Ing. Dr. Graz Staudinger | Verfahren und einrichtung zum trockenen entschwefeln von abgasen |
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| GB1115482A (en) * | 1964-04-07 | 1968-05-29 | Bayer Ag | Modified satin white |
| NL7307675A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1972-06-16 | 1973-12-18 | ||
| US4011299A (en) * | 1975-10-01 | 1977-03-08 | Monsanto Company | Process for removing sulfur dioxide and nitrogen oxides from gases |
| US4177158A (en) * | 1978-02-13 | 1979-12-04 | Chevron Research Company | Method for producing an attrition-resistant adsorbent for sulfur dioxide, the resulting composition and a process using same |
| US4316813A (en) * | 1980-08-04 | 1982-02-23 | Engelhard Minerals & Chemicals Corp. | Limestone-based sorbent agglomerates for removal of sulfur compounds in hot gases and method of making |
| JPS58166932A (ja) * | 1982-03-26 | 1983-10-03 | Onoda Cement Co Ltd | 排ガス中の酸性物質除去剤 |
| GB2138793B (en) * | 1983-04-26 | 1986-09-03 | Mitsubishi Heavy Ind Ltd | Method of control for a wet lime-gypsum process desulfurization plant |
| GB2146977B (en) * | 1983-09-26 | 1987-02-18 | Onoda Cement Co Ltd | Desulfurizing agent |
| GB2152487A (en) * | 1984-01-07 | 1985-08-07 | Kloeckner Humboldt Deutz Ag | Method of desulphurising flue gas |
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- 1986-03-06 GB GB8605506A patent/GB2172277B/en not_active Expired
- 1986-03-11 DE DE19863607929 patent/DE3607929A1/de active Granted
- 1986-03-12 CA CA000503931A patent/CA1258059A/en not_active Expired
- 1986-03-12 CN CN86101607A patent/CN86101607B/zh not_active Expired
- 1986-03-12 US US06/838,662 patent/US4629721A/en not_active Expired - Lifetime
- 1986-03-13 FR FR868603594A patent/FR2578753B1/fr not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3428502A1 (de) * | 1983-08-16 | 1985-03-07 | Gernot Prof. Dipl.-Ing. Dr. Graz Staudinger | Verfahren und einrichtung zum trockenen entschwefeln von abgasen |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3735245A1 (de) * | 1987-04-23 | 1989-05-03 | Hoelter Heinz | Trockene gasreinigung von sauren schadstoffen wie so(pfeil abwaerts)3(pfeil abwaerts), so(pfeil abwaerts)2(pfeil abwaerts), hf, hcl und no(pfeil abwaerts)x(pfeil abwaerts) durch mit alkalien getraenkte kalk-aluminium-zementsilikate als sorptionsmittel |
| DE8816866U1 (de) * | 1987-05-18 | 1991-02-28 | FTU GmbH, 82319 Starnberg | Feinpulvriges Calciumhydroxid zur Gas- und Abgasreinigung |
| DE3915934A1 (de) * | 1988-05-16 | 1989-11-30 | Fichtel Roland | Mittel und verfahren zur reinigung von gasen und abgasen und ein verfahren zur herstellung dieser mittel |
| DE3915934C2 (de) * | 1988-05-16 | 1999-08-12 | Ftu Gmbh | Mittel und Verfahren zur Reinigung von Gasen und Abgasen und ein Verfahren zur Herstellung dieser Mittel |
| DE3826971A1 (de) * | 1988-08-09 | 1990-02-15 | Ftu Gmbh | Verfahren zur herstellung modifizierter calciumhydroxide fuer die gas- und abgasreinigung unter verwendung von wirkstoffkonzentraten |
| DE3844217A1 (de) * | 1988-12-29 | 1990-07-05 | Ftu Gmbh | Verfahren zur herstellung von calciumhydroxiden |
| DE3939214A1 (de) * | 1989-11-28 | 1991-06-13 | Ftu Gmbh | Verfahren zur reinigung von abgasen |
| DE4401166A1 (de) * | 1994-01-17 | 1995-07-20 | Krupp Polysius Ag | Verfahren zur Reinigung von Rauchgasen |
| DE102014018799A1 (de) * | 2014-12-19 | 2016-06-23 | Bayerisches Zentrum für Angewandte Energieforschung e.V. | Feuchtespeicherndes Stoffgemisch und Bauplatte daraus |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2172277B (en) | 1989-06-21 |
| DE3607929C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1990-02-08 |
| CA1258059A (en) | 1989-08-01 |
| CN86101607B (zh) | 1988-09-14 |
| GB8605506D0 (en) | 1986-04-09 |
| CN86101607A (zh) | 1986-10-22 |
| US4629721A (en) | 1986-12-16 |
| FR2578753B1 (fr) | 1990-02-16 |
| FR2578753A1 (fr) | 1986-09-19 |
| GB2172277A (en) | 1986-09-17 |
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