DE2802276C2 - - Google Patents

Info

Publication number
DE2802276C2
DE2802276C2 DE2802276A DE2802276A DE2802276C2 DE 2802276 C2 DE2802276 C2 DE 2802276C2 DE 2802276 A DE2802276 A DE 2802276A DE 2802276 A DE2802276 A DE 2802276A DE 2802276 C2 DE2802276 C2 DE 2802276C2
Authority
DE
Germany
Prior art keywords
ligand
catalyst
activity
pores
metal complex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE2802276A
Other languages
German (de)
English (en)
Other versions
DE2802276A1 (de
Inventor
Leendert Arie Hendrik Ido Ambacht Nl Gerritsen
Joseph Johannes Franciscus Sittard Nl Scholten
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DSM BV
Original Assignee
Stamicarbon BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from NL7700554A external-priority patent/NL7700554A/xx
Priority claimed from NL7712648A external-priority patent/NL7712648A/xx
Application filed by Stamicarbon BV filed Critical Stamicarbon BV
Publication of DE2802276A1 publication Critical patent/DE2802276A1/de
Application granted granted Critical
Publication of DE2802276C2 publication Critical patent/DE2802276C2/de
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE19782802276 1977-01-20 1978-01-19 Verfahren zur katalytischen umsetzung olefinisch ungesaettigter verbindungen mit wasserstoff und/oder kohlenmonoxid Granted DE2802276A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL7700554A NL7700554A (en) 1977-01-20 1977-01-20 Hydroformylation of olefinic cpd. - on catalyst with porous carrier impregnated with soln. of metal complex in ligand
NL7712648A NL7712648A (en) 1977-11-17 1977-11-17 Hydroformylation of olefinic cpd. - on catalyst with porous carrier impregnated with soln. of metal complex in ligand

Publications (2)

Publication Number Publication Date
DE2802276A1 DE2802276A1 (de) 1978-07-27
DE2802276C2 true DE2802276C2 (enExample) 1993-05-06

Family

ID=26645281

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19782802276 Granted DE2802276A1 (de) 1977-01-20 1978-01-19 Verfahren zur katalytischen umsetzung olefinisch ungesaettigter verbindungen mit wasserstoff und/oder kohlenmonoxid

Country Status (9)

Country Link
US (1) US4193942A (enExample)
JP (1) JPS5463010A (enExample)
AT (1) AT356639B (enExample)
CA (1) CA1133455A (enExample)
DE (1) DE2802276A1 (enExample)
ES (1) ES466145A1 (enExample)
FR (1) FR2377990A1 (enExample)
GB (1) GB1551601A (enExample)
IT (1) IT1103255B (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7902964A (nl) * 1979-04-14 1980-10-16 Nl Org Zuiver Wetenschapp Heterogene katalysator op basis van een metaal- organisch complex.
CA1123859A (en) * 1979-06-18 1982-05-18 Celanese Corporation Hydroformylation process improved by choice of reaction solvent and control of product stripping parameters
NL8002342A (nl) * 1980-04-23 1981-11-16 Stamicarbon Bereiding van 2-hydroxytetrahydrofuraan.
US4605780A (en) * 1980-09-24 1986-08-12 Union Carbide Corporation Reactivation of rhodium complex hydroformylation catalysts
US4504684A (en) * 1982-01-06 1985-03-12 The Standard Oil Company Metal coordination polymers as hydroformylation and hydrogenation catalysts
US4594463A (en) * 1985-01-28 1986-06-10 Union Carbide Corporation Synthesis of aldehydes from alcohols
US4947003A (en) * 1988-11-28 1990-08-07 Virginia Tech Intellectual Properties, Inc. Process for the hydroformulation of olefinically unsaturated organic reactants using a supported aqueous phase catalyst
US4994427A (en) * 1988-11-28 1991-02-19 Virginia Tech Intellectual Properties, Inc. Supported aqueous phase organometallic catalyst useful for hydroformylation and other reactions, and a method for its preparation
US5135901A (en) * 1989-06-29 1992-08-04 Eastman Chemical Company A catalyst composition comprising rhodium, ruthenium,and a promoter
US5100851A (en) * 1990-09-04 1992-03-31 Exxon Research And Engineering Company Stationary aqueous acid phase transition metal catalysts for reduction of aromatics
KR930003648B1 (ko) * 1990-10-05 1993-05-08 재단법인 한국화학연구소 에틸리덴 디 아세테이트 제조용 무기체 담지 촉매, 그 제조방법 및 이에 의한 에틸리덴 디 아세테이트의 제조방법
KR930003650B1 (ko) * 1990-10-08 1993-05-08 재단법인 한국화학연구소 에틸리덴 디 아세테이트 제조용 유기체 담지 촉매 및 이를 이용한 에틸리덴 디 아세테이트의 제조방법
US6881445B1 (en) * 2001-10-29 2005-04-19 Innovation Chemical Technologies, Ltd. Forming thin films on substrates using a porous carrier
US7048971B2 (en) * 2002-05-01 2006-05-23 Innovation Chemical Technologies, Ltd. Making invisible logos using hydrophobic and hydrophilic coatings
JP7462756B2 (ja) * 2020-07-07 2024-04-05 株式会社巴川コーポレーション 触媒粒子

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1171390A (fr) * 1956-01-11 1959-01-26 Exxon Research Engineering Co Réaction de synthèse par carbonylation
GB1185453A (en) * 1967-02-20 1970-03-25 Monsanto Co Multiphase Catalysis.
US3855307A (en) * 1967-02-20 1974-12-17 Monsanto Co Catalysis
US3733362A (en) * 1968-03-19 1973-05-15 Union Oil Co Vapor phase carbonylation
US4012450A (en) * 1969-10-01 1977-03-15 Johnson Matthey & Co., Limited Catalytic reactions
BE758802A (enExample) * 1969-11-14 1971-04-16 Johnson Matthey & Cy Ltd
US3937742A (en) * 1970-03-06 1976-02-10 Atlantic Richfield Company Hydroformylation process using catalyst comprising platinum group metal on support having separate alumina phase
US3940447A (en) * 1970-04-27 1976-02-24 Atlantic Richfield Company Process for hydroformylation of olefin hydrocarbons
US3989759A (en) * 1970-07-01 1976-11-02 Atlantic Richfield Company Hydroformylation process over catalyst having silica alumina support with separate alumina phase and noble metal and cobalt or nickel
JPS516124A (en) * 1974-07-05 1976-01-19 Hitachi Chemical Co Ltd Kikinzoku oyobi ryusandono kaishuhoho
JPS5976034A (ja) * 1982-10-21 1984-04-28 Mitsubishi Chem Ind Ltd ヒドロホルミル化法

Also Published As

Publication number Publication date
CA1133455A (en) 1982-10-12
GB1551601A (en) 1979-08-30
ES466145A1 (es) 1979-02-16
FR2377990B1 (enExample) 1984-08-24
FR2377990A1 (fr) 1978-08-18
IT1103255B (it) 1985-10-14
JPS5463010A (en) 1979-05-21
US4193942A (en) 1980-03-18
AT356639B (de) 1980-05-12
ATA31778A (de) 1979-10-15
DE2802276A1 (de) 1978-07-27
IT7847690A0 (it) 1978-01-18

Similar Documents

Publication Publication Date Title
DE69804776T3 (de) Verfahren zum carbonylieren von aethylen
DE69820635T2 (de) Geträgerte diole
DE69915878T2 (de) Verfahren zur herstellung von 2,3-dihalogenpropanolen
DE2802276A1 (de) Verfahren zur katalytischen umsetzung olefinisch ungesaettigter verbindungen mit wasserstoff und/oder kohlenmonoxid
DE60124878T2 (de) Carbonylierungskatalysator auf einen träger aus einen karbunisiert persulfoniert styrol-divinylbenzolcopolymer
EP3750865A1 (de) Verfahren zur herstellung von carbonsäuren oder deren salzen aus kohlenwasserstoffen
DE60319263T2 (de) Herstellungsverfahren von Laktat Ester- oder Säure
DE1667200A1 (de) Mehrphasenkatalysator und Verfahren zur Herstellung desselben
DE1767151A1 (de) Verfahren zur Herstellung von organischen Saeuren und Estern und Katalysator hierfuer
DD154483A5 (de) Verfahren zur herstellung von aethanol aus methanol
DE3151495C2 (de) Verfahren zur Herstellung von Carbonsäuren
EP3377554A1 (de) Herstellung von estern der 3-hydroxypropionsäure und acrylsäure
DE3725870A1 (de) Verfahren zur herstellung eines lactons
DE2117255B2 (de) Verfahren zur katalytischen Dis proportiomerung von Olefinen
DE3045946A1 (de) Verfahren zur herstellung von nicht-polymeren disproportionierungsprodukten aus olefinen
DE2401958A1 (de) Fester katalysator fuer heterogene reaktionen
DE60008118T2 (de) Dampfphasencarbonylierungsverfahren unter verwendung von aktivierten iridium-katalysatoren
DE19919495A1 (de) Verfahren zur Herstellung von Aldehyden
DE10243446B4 (de) Verfahren zur Herstellung von Aldehyden
DE2055539A1 (de) Verfahren zur Hydroformylierung oder Carbonylierung einer organischen Verbin dung
DE3917894A1 (de) Verfahren zur herstellung von c(pfeil abwaerts)2(pfeil abwaerts)+ alkanolen
DE69419491T2 (de) Verfahren zur Herstellung eines in einer organischen flüssigen Phase löslichen Hydrierungskatalysators
DE60207853T2 (de) Einstufige herstellung von 1,3-propandiol aus ethylenoxid und syngas mit einem katalysator mit einem phospholanoalkanliganden
DE4233235C2 (de) Verfahren zur Herstellung von Octadienolen und Palladiumkomplex
DE69011237T2 (de) Verfahren zur Herstellung von alpha-(4-Isobutylphenyl)propionsäure oder deren Vorläufer.

Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
8125 Change of the main classification

Ipc: B01J 31/18

8125 Change of the main classification

Ipc: C07C 45/50

D2 Grant after examination
8327 Change in the person/name/address of the patent owner

Owner name: DSM N.V., HEERLEN, NL

8328 Change in the person/name/address of the agent

Free format text: ZUMSTEIN, F., DIPL.-CHEM. DR.RER.NAT. KLINGSEISEN, F., DIPL.-ING., PAT.-ANWAELTE, 8000 MUENCHEN

8380 Miscellaneous part iii

Free format text: DER PATENTINHABER LAUTET RICHTIG: DSM N.V., HEERLEN, NL

8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee