NL7700554A - Hydroformylation of olefinic cpd. - on catalyst with porous carrier impregnated with soln. of metal complex in ligand - Google Patents

Hydroformylation of olefinic cpd. - on catalyst with porous carrier impregnated with soln. of metal complex in ligand

Info

Publication number
NL7700554A
NL7700554A NL7700554A NL7700554A NL7700554A NL 7700554 A NL7700554 A NL 7700554A NL 7700554 A NL7700554 A NL 7700554A NL 7700554 A NL7700554 A NL 7700554A NL 7700554 A NL7700554 A NL 7700554A
Authority
NL
Netherlands
Prior art keywords
catalyst
soln
ligand
cpd
metal complex
Prior art date
Application number
NL7700554A
Other languages
Dutch (nl)
Original Assignee
Nl Org Zuiver Wetenschapp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nl Org Zuiver Wetenschapp filed Critical Nl Org Zuiver Wetenschapp
Priority to NL7700554A priority Critical patent/NL7700554A/en
Priority to BE184336A priority patent/BE862926A/en
Priority to AT31778A priority patent/AT356639B/en
Priority to FR7801353A priority patent/FR2377990A1/en
Priority to US05/870,582 priority patent/US4193942A/en
Priority to IT47690/78A priority patent/IT1103255B/en
Priority to ES466145A priority patent/ES466145A1/en
Priority to CA295,291A priority patent/CA1133455A/en
Priority to DE19782802276 priority patent/DE2802276A1/en
Priority to GB2413/78A priority patent/GB1551601A/en
Priority to JP514678A priority patent/JPS5463010A/en
Publication of NL7700554A publication Critical patent/NL7700554A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof

Abstract

Olefinically unsatd. organic cpds. are reacted with H2 and/or CO, at 20-300 degrees C and 1-100 bar, in presence of a catalyst consisting of (a) a solid porous carrier carrying in the pores (b) a catalytically active metal complex in soln. in (c) is not 1 ligand-forming cpd. with vapour pressure under the reaction conditions of 15 mbar. Complexes of Ru, Co, Rh or Ir, dissolved in an organo P ligand, are pref. The carrier is esp. macroporous, with pores 100 angstroms and pores >100 angstroms (>1000 angstroms). The organic cpd. is esp. an olefin or unsatd. aldehyde or corresp. acetal. The catalysts have good activity, selectivity and stability. Reaction may be at a temp. below the m. pt. of the soln. of (b) in (c) i.e. on a supported solid phase catalyst. The sensitivity of the catalyst to O2 is low.
NL7700554A 1977-01-20 1977-01-20 Hydroformylation of olefinic cpd. - on catalyst with porous carrier impregnated with soln. of metal complex in ligand NL7700554A (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
NL7700554A NL7700554A (en) 1977-01-20 1977-01-20 Hydroformylation of olefinic cpd. - on catalyst with porous carrier impregnated with soln. of metal complex in ligand
BE184336A BE862926A (en) 1977-01-20 1978-01-16 PROCEDURE FOR THE CATALYTIC CONVERSION OF OLEFINICALLY UNSATURATED COMPOUNDS WITH HYDROGEN AND / OR CARBON MONOXIDE
AT31778A AT356639B (en) 1977-01-20 1978-01-17 METHOD FOR CATALYTICALLY IMPLEMENTING OLEFINICALLY UNSATURATED COMPOUNDS WITH HYDROGEN AND CARBON MONOXIDE
FR7801353A FR2377990A1 (en) 1977-01-20 1978-01-18 PROCESS FOR THE CATALYTIC CONVERSION OF COMPOUNDS WITH OLEFINIC INSATURATION BY HYDROGEN AND / OR OXYGEN
US05/870,582 US4193942A (en) 1977-01-20 1978-01-18 Process for catalytic conversion of olefinically unsaturated compounds with hydrogen and/or carbon monoxide
IT47690/78A IT1103255B (en) 1977-01-20 1978-01-18 PROCEDURE FOR THE CATALYTIC CONVERSION OF NON-SATURATION COMPOUNDS OF THE OLEFINIC TYPE
ES466145A ES466145A1 (en) 1977-01-20 1978-01-19 Process for catalytic conversion of olefinically unsaturated compounds with hydrogen and/or carbon monoxide
CA295,291A CA1133455A (en) 1977-01-20 1978-01-19 Process for catalytic conversion of olefinically unsaturated compounds with hydrogen and/or carbon monoxide
DE19782802276 DE2802276A1 (en) 1977-01-20 1978-01-19 PROCESS FOR THE CATALYTIC REPRODUCTION OF OLEFINIC UNSATURIZED COMPOUNDS WITH HYDROGEN AND / OR CARBON MONOXIDE
GB2413/78A GB1551601A (en) 1977-01-20 1978-01-20 Process for catalytic conversion of olefinically unsaturated compounds with hydrogen and/ or carbon monoxide
JP514678A JPS5463010A (en) 1977-01-20 1978-01-20 Catalytic conversion of olefinic unsaturated compounds by using hydrogen and*or carbon monoxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7700554A NL7700554A (en) 1977-01-20 1977-01-20 Hydroformylation of olefinic cpd. - on catalyst with porous carrier impregnated with soln. of metal complex in ligand

Publications (1)

Publication Number Publication Date
NL7700554A true NL7700554A (en) 1978-07-24

Family

ID=19827809

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7700554A NL7700554A (en) 1977-01-20 1977-01-20 Hydroformylation of olefinic cpd. - on catalyst with porous carrier impregnated with soln. of metal complex in ligand

Country Status (2)

Country Link
BE (1) BE862926A (en)
NL (1) NL7700554A (en)

Also Published As

Publication number Publication date
BE862926A (en) 1978-07-17

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Legal Events

Date Code Title Description
BC A request for examination has been filed
A85 Still pending on 85-01-01
BV The patent application has lapsed