DE2730374C2 - Poly-(oxypropylen-oxyäthylen)-polyole, Verfahren zu deren Herstellung sowie Verfahren zur Herstellung von Polymer/Polyolen - Google Patents
Poly-(oxypropylen-oxyäthylen)-polyole, Verfahren zu deren Herstellung sowie Verfahren zur Herstellung von Polymer/PolyolenInfo
- Publication number
- DE2730374C2 DE2730374C2 DE2730374A DE2730374A DE2730374C2 DE 2730374 C2 DE2730374 C2 DE 2730374C2 DE 2730374 A DE2730374 A DE 2730374A DE 2730374 A DE2730374 A DE 2730374A DE 2730374 C2 DE2730374 C2 DE 2730374C2
- Authority
- DE
- Germany
- Prior art keywords
- polyol
- polyols
- ethylene oxide
- oxyethylene
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003077 polyols Chemical class 0.000 title claims description 123
- 229920005862 polyol Polymers 0.000 title claims description 120
- 229920000642 polymer Polymers 0.000 title claims description 42
- -1 Poly (oxypropylene-oxyethylene) Polymers 0.000 title claims description 39
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 14
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 61
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 32
- 239000000178 monomer Substances 0.000 claims description 16
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 9
- 238000009826 distribution Methods 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 230000003068 static effect Effects 0.000 claims description 2
- 125000006353 oxyethylene group Chemical group 0.000 claims 7
- 239000007788 liquid Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 57
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 30
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 21
- 239000004970 Chain extender Substances 0.000 description 19
- 229920001451 polypropylene glycol Polymers 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
- 239000002253 acid Substances 0.000 description 17
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 14
- 229920001971 elastomer Polymers 0.000 description 13
- 239000000806 elastomer Substances 0.000 description 13
- 235000011187 glycerol Nutrition 0.000 description 13
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 9
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 9
- 150000002009 diols Chemical class 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 230000003301 hydrolyzing effect Effects 0.000 description 4
- 238000005191 phase separation Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- MNZAKDODWSQONA-UHFFFAOYSA-N 1-dibutylphosphorylbutane Chemical compound CCCCP(=O)(CCCC)CCCC MNZAKDODWSQONA-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- 229920003225 polyurethane elastomer Polymers 0.000 description 3
- ZVQXQPNJHRNGID-UHFFFAOYSA-N tetramethylsuccinonitrile Chemical compound N#CC(C)(C)C(C)(C)C#N ZVQXQPNJHRNGID-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- CBFHOPPJBYHALQ-RLWMBFFFSA-N 3-(Butyl sulfinyl)-alanine Chemical compound CCCCS(=O)C[C@H](N)C(O)=O CBFHOPPJBYHALQ-RLWMBFFFSA-N 0.000 description 1
- CBFHOPPJBYHALQ-PWCHPLFNSA-N Butiin Natural products CCCC[S@@](=O)C[C@H]([NH3+])C([O-])=O CBFHOPPJBYHALQ-PWCHPLFNSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
- C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyethers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/703,022 US4125505A (en) | 1976-07-06 | 1976-07-06 | Polymer/polyols from high ethylene oxide content polyols |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2730374A1 DE2730374A1 (de) | 1978-01-12 |
| DE2730374C2 true DE2730374C2 (de) | 1982-12-23 |
Family
ID=24823631
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2730374A Expired DE2730374C2 (de) | 1976-07-06 | 1977-07-05 | Poly-(oxypropylen-oxyäthylen)-polyole, Verfahren zu deren Herstellung sowie Verfahren zur Herstellung von Polymer/Polyolen |
| DE2759334A Expired DE2759334C2 (de) | 1976-07-06 | 1977-07-05 | Verfahren zur Herstellung von Elastomeren, gegebenenfalls verschäumten Polyurethanen und Polyolmischung zur Durchführung derselben |
| DE2759398A Withdrawn DE2759398B1 (de) | 1976-07-06 | 1977-07-05 | Polyol-Kettenverlaengerungsmittel-Mischung |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2759334A Expired DE2759334C2 (de) | 1976-07-06 | 1977-07-05 | Verfahren zur Herstellung von Elastomeren, gegebenenfalls verschäumten Polyurethanen und Polyolmischung zur Durchführung derselben |
| DE2759398A Withdrawn DE2759398B1 (de) | 1976-07-06 | 1977-07-05 | Polyol-Kettenverlaengerungsmittel-Mischung |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4125505A (enExample) |
| JP (2) | JPS5313700A (enExample) |
| AU (1) | AU509111B2 (enExample) |
| BE (1) | BE856486A (enExample) |
| BR (1) | BR7704381A (enExample) |
| CA (1) | CA1105182A (enExample) |
| DE (3) | DE2730374C2 (enExample) |
| ES (2) | ES460407A1 (enExample) |
| FR (1) | FR2357592A1 (enExample) |
| GB (1) | GB1579640A (enExample) |
| IT (1) | IT1081512B (enExample) |
| MX (1) | MX146808A (enExample) |
| NL (1) | NL7707438A (enExample) |
| SE (2) | SE434646B (enExample) |
Families Citing this family (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4312973A (en) * | 1978-08-10 | 1982-01-26 | Union Carbide Corporation | Polyurethane elastomers prepared from polyol or polymer/polyol-chain extender mixtures |
| US4242476A (en) * | 1978-11-17 | 1980-12-30 | Union Carbide Corporation | Polymer/polyol compositions containing vinylidene chloride |
| FR2446298A1 (fr) * | 1979-01-15 | 1980-08-08 | Inst Sint Smol | Procede continu de preparation de polyethers |
| DE2915610A1 (de) * | 1979-04-18 | 1980-10-30 | Bayer Ag | Verfahren zur herstellung von modifizierten polyetherpolyolen und deren verwendung in verfahren zur herstellung von polyurethankunststoffen |
| US4243760A (en) * | 1979-05-23 | 1981-01-06 | Texaco Development Corporation | Reaction injection molded polyurethane |
| JPS5831093B2 (ja) * | 1980-09-11 | 1983-07-04 | テキサコ・デイベロップメント・コ−ポレ−ション | 反応射出成形ポリウレタンエラストマ−の製造方法 |
| JPS57209920A (en) * | 1981-06-18 | 1982-12-23 | Sanyo Chem Ind Ltd | Production of polyurethane |
| DE3126517A1 (de) * | 1981-07-04 | 1983-01-20 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von gegebenenfalls zellhaltigen polyurethan-elastomeren |
| DE3137132A1 (de) * | 1981-09-18 | 1983-04-07 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von elastischen polyurethan-weichschaumstoffen |
| DE3219759A1 (de) * | 1982-05-26 | 1983-12-01 | Bayer Ag, 5090 Leverkusen | Einphasig lagerstabile polyolkompositionen mit hohem ethylenglykol-anteil und ihre verwendung zur herstellung von polyurethanen |
| DE3219822A1 (de) | 1982-05-26 | 1983-12-01 | Bayer Ag, 5090 Leverkusen | Einphasig lagerstabile, salzhaltige polyolkompositionen mit hohem ethylenglykol- oder butandiol-anteil und ihre verwendung zur herstellung von polyurethanen |
| JPS58208335A (ja) * | 1982-05-29 | 1983-12-05 | Nippon Polyurethan Kogyo Kk | ゴム配合組成物 |
| JPS59187019A (ja) * | 1983-04-08 | 1984-10-24 | Asahi Glass Co Ltd | ポリウレタン系エラストマ−の製造方法 |
| US4521548A (en) * | 1983-04-12 | 1985-06-04 | The Dow Chemical Company | Preparation of polyether polyols |
| JPS59227921A (ja) * | 1983-06-10 | 1984-12-21 | Asahi Glass Co Ltd | ポリウレタン系エラストマ−の製造方法 |
| US4448903A (en) * | 1983-07-25 | 1984-05-15 | Mobay Chemical Corporation | Novel system for the production of polyurethanes |
| US4539378A (en) * | 1984-09-27 | 1985-09-03 | Texaco Inc. | Vinyl polymer polyols made using epoxy resin-modified polyols |
| US4539339A (en) * | 1984-09-27 | 1985-09-03 | Texaco Inc. | Polyurethane foams made from vinyl polymer polyols |
| US4731416A (en) * | 1984-10-01 | 1988-03-15 | The Dow Chemical Company | Polyurethane-type adhesives containing nonaqueous solutions of acrylate polymers |
| US4622361A (en) * | 1985-03-29 | 1986-11-11 | Union Carbide Corporation | Flame retarded high modulus polyurethane elastomers and method of making same |
| US4785127A (en) * | 1985-08-05 | 1988-11-15 | Arco Chemical Company | Vinyl polymer polyols made using partially alkoxylated polyoxyalkyleneamines |
| US4686240A (en) | 1985-10-25 | 1987-08-11 | Union Carbide Corporation | Process for producing polyurethane foams using foam modifiers |
| JPS62288623A (ja) * | 1986-06-05 | 1987-12-15 | M D Kasei Kk | ウレタン発泡体の製造方法 |
| GB2199504A (en) * | 1987-01-06 | 1988-07-13 | Peter Egan | Directional dice |
| US4883825A (en) * | 1987-12-30 | 1989-11-28 | Union Carbide Chemicals And Plastics Company Inc. | Process for the manufacture of low density, flexible polyurethane foams |
| US5011908A (en) * | 1988-07-12 | 1991-04-30 | Arco Chemical Technology, Inc. | Polymer polyol compositions and their use in the preparation of polyurethane foams |
| US5171759A (en) * | 1988-07-12 | 1992-12-15 | Arco Chemical Technology, L.P. | Polymer polyol compositions and their use in the preparation of polyurethane foams |
| DE68919555T2 (de) * | 1988-07-12 | 1995-04-13 | Arco Chem Tech | Polymerpolyol-Zusammensetzungen sowie deren Anwendung zur Herstellung von Polyurethan-Schaumstoffen. |
| US5145602A (en) * | 1989-02-01 | 1992-09-08 | Union Oil Company Of California | Sol/gels containing nonionic surfactants and preparation methods |
| JPH02206643A (ja) * | 1989-02-03 | 1990-08-16 | Asahi Glass Co Ltd | ポリマー分散ポリオール，およびその用途 |
| US5122548A (en) * | 1990-03-23 | 1992-06-16 | The Dow Chemical Company | Elastomeric polyisocyanate-based polymers from polyoxyalkylene polyols containing internal polyoxyethylene blocks |
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| DE2341294A1 (de) | 1973-08-16 | 1975-02-27 | Bayer Ag | Polyolgemische |
| DE2521000A1 (de) | 1974-05-15 | 1975-11-20 | Mccord Corp | Thermoplastisches polyurethan in spritzgussqualitaet |
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| GB1120223A (en) * | 1964-06-23 | 1968-07-17 | Lankro Chem Ltd | Improvements in or relating to polyethers and polyurethanes derived therefrom |
| GB1321697A (en) * | 1970-11-16 | 1973-06-27 | Sangamo Weston | Optical attachments for exposure meters |
| BE788115A (fr) | 1971-08-30 | 1973-02-28 | Union Carbide Corp | Compositions a base d'un polymere et d'un polyol convenant pourla fabrication des mousses de polyurethane |
| GB1355227A (en) * | 1971-12-10 | 1974-06-05 | Shell Int Research | Mixtures for the preparation of polyurethane foams |
| DE2220338C3 (de) | 1972-04-26 | 1978-08-17 | Bayer Ag, 5090 Leverkusen | Verwendung von Äthylenoxid/Propylenoxid-Mischpolymerisaten als wasserlösliche Schmiermittel, Metallbearbeitungsmittel und Hydraulikflüssigkeiten |
| US3823201A (en) * | 1972-12-04 | 1974-07-09 | Basf Wyandotte Corp | Highly-stable graft copolymer dispersions in polyols containing unsaturation and polyurethanes prepared therefrom |
| JPS533438B2 (enExample) * | 1973-05-02 | 1978-02-06 | ||
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| DE2607380C3 (de) * | 1976-02-24 | 1981-07-23 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von warmformbaren Polyisocyanuratschaumstoffen |
-
1976
- 1976-07-06 US US05/703,022 patent/US4125505A/en not_active Expired - Lifetime
-
1977
- 1977-06-23 CA CA281,240A patent/CA1105182A/en not_active Expired
- 1977-07-04 AU AU26708/77A patent/AU509111B2/en not_active Expired
- 1977-07-05 GB GB28050/77A patent/GB1579640A/en not_active Expired
- 1977-07-05 NL NL7707438A patent/NL7707438A/xx not_active Application Discontinuation
- 1977-07-05 BE BE179088A patent/BE856486A/xx not_active IP Right Cessation
- 1977-07-05 DE DE2730374A patent/DE2730374C2/de not_active Expired
- 1977-07-05 SE SE7707850A patent/SE434646B/xx unknown
- 1977-07-05 IT IT25422/77A patent/IT1081512B/it active
- 1977-07-05 ES ES460407A patent/ES460407A1/es not_active Expired
- 1977-07-05 DE DE2759334A patent/DE2759334C2/de not_active Expired
- 1977-07-05 BR BR7704381A patent/BR7704381A/pt unknown
- 1977-07-05 DE DE2759398A patent/DE2759398B1/de not_active Withdrawn
- 1977-07-05 JP JP7957477A patent/JPS5313700A/ja active Granted
- 1977-07-05 MX MX169734A patent/MX146808A/es unknown
- 1977-07-06 FR FR7720797A patent/FR2357592A1/fr active Granted
- 1977-11-23 ES ES464399A patent/ES464399A1/es not_active Expired
-
1981
- 1981-02-04 JP JP1450781A patent/JPS56127627A/ja active Granted
-
1983
- 1983-06-20 SE SE8303533A patent/SE8303533L/sv not_active Application Discontinuation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2341294A1 (de) | 1973-08-16 | 1975-02-27 | Bayer Ag | Polyolgemische |
| DE2521000A1 (de) | 1974-05-15 | 1975-11-20 | Mccord Corp | Thermoplastisches polyurethan in spritzgussqualitaet |
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2670877A (en) | 1979-01-11 |
| JPS576471B2 (enExample) | 1982-02-04 |
| SE8303533D0 (sv) | 1983-06-20 |
| SE434646B (sv) | 1984-08-06 |
| FR2357592B1 (enExample) | 1980-04-25 |
| DE2759334C2 (de) | 1984-07-19 |
| DE2759398B1 (de) | 1980-07-17 |
| IT1081512B (it) | 1985-05-21 |
| CA1105182A (en) | 1981-07-14 |
| NL7707438A (nl) | 1978-01-10 |
| FR2357592A1 (fr) | 1978-02-03 |
| SE7707850L (sv) | 1978-01-07 |
| MX146808A (es) | 1982-08-24 |
| BE856486A (fr) | 1978-01-05 |
| JPS56127627A (en) | 1981-10-06 |
| US4125505A (en) | 1978-11-14 |
| JPS5313700A (en) | 1978-02-07 |
| GB1579640A (en) | 1980-11-19 |
| JPS6239609B2 (enExample) | 1987-08-24 |
| AU509111B2 (en) | 1980-04-17 |
| ES464399A1 (es) | 1978-09-01 |
| BR7704381A (pt) | 1978-04-04 |
| ES460407A1 (es) | 1978-05-01 |
| SE8303533L (sv) | 1983-06-20 |
| DE2730374A1 (de) | 1978-01-12 |
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