DE2320222C2 - Verfahren zur Aktivierung eines Isomerisierungskatalysators auf der Basis eines H-Mordenits - Google Patents
Verfahren zur Aktivierung eines Isomerisierungskatalysators auf der Basis eines H-MordenitsInfo
- Publication number
- DE2320222C2 DE2320222C2 DE2320222A DE2320222A DE2320222C2 DE 2320222 C2 DE2320222 C2 DE 2320222C2 DE 2320222 A DE2320222 A DE 2320222A DE 2320222 A DE2320222 A DE 2320222A DE 2320222 C2 DE2320222 C2 DE 2320222C2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- water content
- weight
- gas
- isomerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 91
- 238000006317 isomerization reaction Methods 0.000 title claims description 30
- 229910052680 mordenite Inorganic materials 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 9
- 230000008569 process Effects 0.000 title claims description 5
- 230000003213 activating effect Effects 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 84
- 230000018044 dehydration Effects 0.000 claims description 22
- 238000006297 dehydration reaction Methods 0.000 claims description 22
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 230000036571 hydration Effects 0.000 claims description 10
- 238000006703 hydration reaction Methods 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 9
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- 239000010457 zeolite Substances 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 24
- 208000005156 Dehydration Diseases 0.000 description 21
- 239000001257 hydrogen Substances 0.000 description 21
- 229910052739 hydrogen Inorganic materials 0.000 description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000002474 experimental method Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 8
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 6
- 238000001354 calcination Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- -1 C 5 hydrocarbons Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000694408 Isomeris Species 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
- B01J29/22—Noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
- C07C5/2724—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/8995—Catalyst and recycle considerations
- Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NLAANVRAGE7205564,A NL171331C (nl) | 1972-04-25 | 1972-04-25 | Werkwijze voor het activeren van katalysatoren die geschikt zijn voor het isomeriseren van alifatische verzadigde koolwaterstoffen. |
Publications (2)
Publication Number | Publication Date |
---|---|
DE2320222A1 DE2320222A1 (de) | 1973-11-08 |
DE2320222C2 true DE2320222C2 (de) | 1982-03-11 |
Family
ID=19815913
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2320222A Expired DE2320222C2 (de) | 1972-04-25 | 1973-04-19 | Verfahren zur Aktivierung eines Isomerisierungskatalysators auf der Basis eines H-Mordenits |
Country Status (16)
Country | Link |
---|---|
US (1) | US3842114A (en, 2012) |
JP (1) | JPS5548861B2 (en, 2012) |
AT (1) | AT335409B (en, 2012) |
AU (1) | AU468094B2 (en, 2012) |
BE (1) | BE798254A (en, 2012) |
CA (1) | CA1002507A (en, 2012) |
CH (1) | CH582543A5 (en, 2012) |
DE (1) | DE2320222C2 (en, 2012) |
DK (1) | DK141317B (en, 2012) |
ES (1) | ES413933A1 (en, 2012) |
FR (1) | FR2181931B1 (en, 2012) |
GB (1) | GB1429884A (en, 2012) |
IT (1) | IT980304B (en, 2012) |
NL (1) | NL171331C (en, 2012) |
SE (1) | SE383688B (en, 2012) |
ZA (1) | ZA732703B (en, 2012) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2241539C1 (ru) * | 2003-07-02 | 2004-12-10 | Общество с ограниченной ответственностью "Еврохим-СПб-Трейдинг" | Способ приготовления катализатора и способ изомеризации парафиновых углеводородов с4-с7 |
RU2306979C2 (ru) * | 2005-10-26 | 2007-09-27 | ГОУ ВПО Иркутский государственный университет | Катализатор изомеризации парафиновых углеводородов (варианты) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4002575A (en) * | 1975-08-14 | 1977-01-11 | Union Oil Company Of California | Rejuvenation of supported group VIII metal catalysts |
NL7601663A (nl) * | 1976-02-19 | 1977-08-23 | Shell Int Research | Werkwijze ter verhoging van het octaangetal van een lichte benzinefractie. |
US4232181A (en) * | 1979-06-28 | 1980-11-04 | Norton Company | Hydroisomerization of pentane utilizing Pd exchanged mordenite |
FR2593084B1 (fr) * | 1986-01-22 | 1990-09-28 | Inst Francais Du Petrole | Catalyseur contenant une mordenite, sa preparation et son application a l'isomerisation de coupes riches en paraffines normales. |
US4709117A (en) * | 1986-04-07 | 1987-11-24 | Union Carbide Corporation | Total isomerization process and apparatus |
FR2602784B1 (fr) * | 1986-04-16 | 1988-11-04 | Inst Francais Du Petrole | Procede combine d'hydroreformage et d'hydroisomerisation |
US4778944A (en) * | 1986-10-10 | 1988-10-18 | Union Carbide Corporation | Catalytic isomerization of sulfur-containing feedstocks |
US5256277A (en) * | 1991-07-24 | 1993-10-26 | Mobil Oil Corporation | Paraffin isomerization process utilizing a catalyst comprising a mesoporous crystalline material |
KR101156299B1 (ko) * | 2004-02-09 | 2012-06-13 | 알베마를 네덜란드 비.브이. | 고체 산 및 수소화 금속을 포함하는 촉매를 사용한 알킬화방법 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3367885A (en) * | 1966-02-21 | 1968-02-06 | Union Carbide Corp | Hydrocarbon conversion catalysts |
-
1972
- 1972-04-25 NL NLAANVRAGE7205564,A patent/NL171331C/xx not_active IP Right Cessation
-
1973
- 1973-03-05 US US00338111A patent/US3842114A/en not_active Expired - Lifetime
- 1973-03-27 CA CA167,136A patent/CA1002507A/en not_active Expired
- 1973-04-16 BE BE1004967A patent/BE798254A/xx not_active IP Right Cessation
- 1973-04-18 DK DK215173AA patent/DK141317B/da not_active IP Right Cessation
- 1973-04-19 DE DE2320222A patent/DE2320222C2/de not_active Expired
- 1973-04-19 SE SE7305630A patent/SE383688B/xx unknown
- 1973-04-19 CH CH566373A patent/CH582543A5/xx not_active IP Right Cessation
- 1973-04-19 ZA ZA732703A patent/ZA732703B/xx unknown
- 1973-04-19 ES ES0413933A patent/ES413933A1/es not_active Expired
- 1973-04-19 FR FR7314398A patent/FR2181931B1/fr not_active Expired
- 1973-04-19 AU AU54714/73A patent/AU468094B2/en not_active Expired
- 1973-04-19 JP JP4371673A patent/JPS5548861B2/ja not_active Expired
- 1973-04-19 GB GB1888773A patent/GB1429884A/en not_active Expired
- 1973-04-19 IT IT49581/73A patent/IT980304B/it active
- 1973-04-19 AT AT353373A patent/AT335409B/de not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2241539C1 (ru) * | 2003-07-02 | 2004-12-10 | Общество с ограниченной ответственностью "Еврохим-СПб-Трейдинг" | Способ приготовления катализатора и способ изомеризации парафиновых углеводородов с4-с7 |
RU2306979C2 (ru) * | 2005-10-26 | 2007-09-27 | ГОУ ВПО Иркутский государственный университет | Катализатор изомеризации парафиновых углеводородов (варианты) |
Also Published As
Publication number | Publication date |
---|---|
AU468094B2 (en) | 1975-12-18 |
DK141317B (da) | 1980-02-25 |
DK141317C (en, 2012) | 1980-08-18 |
SE383688B (sv) | 1976-03-29 |
NL7205564A (en, 2012) | 1973-10-29 |
FR2181931B1 (en, 2012) | 1976-09-10 |
CA1002507A (en) | 1976-12-28 |
ATA353373A (de) | 1976-07-15 |
JPS5548861B2 (en, 2012) | 1980-12-09 |
IT980304B (it) | 1974-09-30 |
AU5471473A (en) | 1974-10-24 |
GB1429884A (en) | 1976-03-31 |
AT335409B (de) | 1977-03-10 |
BE798254A (nl) | 1973-10-16 |
FR2181931A1 (en, 2012) | 1973-12-07 |
NL171331C (nl) | 1983-03-16 |
JPS4922394A (en, 2012) | 1974-02-27 |
DE2320222A1 (de) | 1973-11-08 |
ZA732703B (en) | 1974-06-26 |
ES413933A1 (es) | 1976-02-01 |
NL171331B (nl) | 1982-10-18 |
US3842114A (en) | 1974-10-15 |
CH582543A5 (en, 2012) | 1976-12-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
OD | Request for examination | ||
D2 | Grant after examination | ||
8339 | Ceased/non-payment of the annual fee |