DE2236459A1 - Thiadiazolderivate als wirkstoffe in schaedlingsbekaempfungsmitteln - Google Patents
Thiadiazolderivate als wirkstoffe in schaedlingsbekaempfungsmittelnInfo
- Publication number
- DE2236459A1 DE2236459A1 DE2236459A DE2236459A DE2236459A1 DE 2236459 A1 DE2236459 A1 DE 2236459A1 DE 2236459 A DE2236459 A DE 2236459A DE 2236459 A DE2236459 A DE 2236459A DE 2236459 A1 DE2236459 A1 DE 2236459A1
- Authority
- DE
- Germany
- Prior art keywords
- group
- alkyl
- thiadiazole
- phosphorylated
- thiadiazole derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000004867 thiadiazoles Chemical class 0.000 title description 2
- 239000013543 active substance Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 239000004480 active ingredient Substances 0.000 claims description 11
- 125000003545 alkoxy group Chemical group 0.000 claims description 8
- YGTAZGSLCXNBQL-UHFFFAOYSA-N 1,2,4-thiadiazole Chemical class C=1N=CSN=1 YGTAZGSLCXNBQL-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 239000000575 pesticide Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002366 halogen compounds Chemical class 0.000 claims description 2
- 150000002367 halogens Chemical group 0.000 claims description 2
- OGVWWGVZVJUPHF-UHFFFAOYSA-N 1,2,4-thiadiazol-3-one Chemical class O=C1N=CSN1 OGVWWGVZVJUPHF-UHFFFAOYSA-N 0.000 claims 1
- 125000003282 alkyl amino group Chemical group 0.000 claims 1
- NOIJEDJHAHUJCB-UHFFFAOYSA-N dimethoxy-[(5-phenyl-1,2,4-thiadiazol-3-yl)oxy]-sulfanylidene-lambda5-phosphane Chemical compound COP(=S)(OC1=NSC(=N1)C1=CC=CC=C1)OC NOIJEDJHAHUJCB-UHFFFAOYSA-N 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- -1 methoxy, ethoxy Chemical group 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 241001608567 Phaedon cochleariae Species 0.000 description 4
- 241000255969 Pieris brassicae Species 0.000 description 4
- 241000500437 Plutella xylostella Species 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 241000256118 Aedes aegypti Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- 241000171293 Megoura viciae Species 0.000 description 3
- 244000046052 Phaseolus vulgaris Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000000895 acaricidal effect Effects 0.000 description 3
- 239000000642 acaricide Substances 0.000 description 3
- 238000004587 chromatography analysis Methods 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 241000239290 Araneae Species 0.000 description 2
- 235000016068 Berberis vulgaris Nutrition 0.000 description 2
- 241000335053 Beta vulgaris Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 241000255925 Diptera Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 244000141359 Malus pumila Species 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 241001454293 Tetranychus urticae Species 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 125000004663 dialkyl amino group Chemical group 0.000 description 2
- 239000004495 emulsifiable concentrate Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- RDYMFSUJUZBWLH-UHFFFAOYSA-N endosulfan Chemical compound C12COS(=O)OCC2C2(Cl)C(Cl)=C(Cl)C1(Cl)C2(Cl)Cl RDYMFSUJUZBWLH-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004546 suspension concentrate Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 125000004172 4-methoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C([H])C([H])=C1* 0.000 description 1
- LAKQZMOFHIMETE-UHFFFAOYSA-N 5-(4-chlorophenyl)-1,2,4-thiadiazol-3-one Chemical compound C1=CC(Cl)=CC=C1C1=NC(=O)NS1 LAKQZMOFHIMETE-UHFFFAOYSA-N 0.000 description 1
- XWNLOUXOTUBXEA-UHFFFAOYSA-N 5-phenyl-1,2,4-thiadiazol-3-one Chemical compound S1NC(=O)N=C1C1=CC=CC=C1 XWNLOUXOTUBXEA-UHFFFAOYSA-N 0.000 description 1
- LQIITQSGYNMPGU-UHFFFAOYSA-N 5-phenyl-1,2,4-thiadiazole Chemical compound C1=NSC(C=2C=CC=CC=2)=N1 LQIITQSGYNMPGU-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 241000256113 Culicidae Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 241000257159 Musca domestica Species 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 241001454295 Tetranychidae Species 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LGTLXDJOAJDFLR-UHFFFAOYSA-N diethyl chlorophosphate Chemical compound CCOP(Cl)(=O)OCC LGTLXDJOAJDFLR-UHFFFAOYSA-N 0.000 description 1
- 239000012259 ether extract Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 229920002113 octoxynol Polymers 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 125000005425 toluyl group Chemical group 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6536—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and sulfur atoms with or without oxygen atoms, as the only ring hetero atoms
- C07F9/6539—Five-membered rings
- C07F9/65392—Five-membered rings containing two nitrogen atoms
- C07F9/65397—Five-membered rings containing two nitrogen atoms having the two nitrogen atoms in positions 1 and 3
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
- Plural Heterocyclic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3521471 | 1971-07-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2236459A1 true DE2236459A1 (de) | 1973-02-08 |
Family
ID=10375167
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2236459A Pending DE2236459A1 (de) | 1971-07-27 | 1972-07-25 | Thiadiazolderivate als wirkstoffe in schaedlingsbekaempfungsmitteln |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3801586A (OSRAM) |
| AU (1) | AU461861B2 (OSRAM) |
| CH (1) | CH574213A5 (OSRAM) |
| DE (1) | DE2236459A1 (OSRAM) |
| FR (1) | FR2147168A1 (OSRAM) |
| GB (1) | GB1334418A (OSRAM) |
| HU (1) | HU166010B (OSRAM) |
| IT (1) | IT963263B (OSRAM) |
| NL (1) | NL7210216A (OSRAM) |
| PL (1) | PL90347B1 (OSRAM) |
| SU (1) | SU521843A3 (OSRAM) |
| ZA (1) | ZA725147B (OSRAM) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7403327A (OSRAM) * | 1973-04-19 | 1974-10-22 | ||
| US4069319A (en) * | 1973-10-26 | 1978-01-17 | Roussel Uclaf | Novel thiadiazoles |
-
1971
- 1971-07-27 GB GB3521471A patent/GB1334418A/en not_active Expired
-
1972
- 1972-07-06 US US00269342A patent/US3801586A/en not_active Expired - Lifetime
- 1972-07-21 IT IT27299/72A patent/IT963263B/it active
- 1972-07-25 PL PL1972156909A patent/PL90347B1/pl unknown
- 1972-07-25 DE DE2236459A patent/DE2236459A1/de active Pending
- 1972-07-25 ZA ZA725147A patent/ZA725147B/xx unknown
- 1972-07-25 CH CH1108872A patent/CH574213A5/xx not_active IP Right Cessation
- 1972-07-25 FR FR7226723A patent/FR2147168A1/fr not_active Withdrawn
- 1972-07-25 NL NL7210216A patent/NL7210216A/xx not_active Application Discontinuation
- 1972-07-25 SU SU1816228A patent/SU521843A3/ru active
- 1972-07-25 AU AU44950/72A patent/AU461861B2/en not_active Expired
- 1972-07-27 HU HUSE1636A patent/HU166010B/hu unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL7210216A (OSRAM) | 1973-01-30 |
| PL90347B1 (OSRAM) | 1977-01-31 |
| SU521843A3 (ru) | 1976-07-15 |
| IT963263B (it) | 1974-01-10 |
| GB1334418A (en) | 1973-10-17 |
| CH574213A5 (OSRAM) | 1976-04-15 |
| ZA725147B (en) | 1973-04-25 |
| HU166010B (OSRAM) | 1974-12-28 |
| AU461861B2 (en) | 1975-06-05 |
| FR2147168A1 (OSRAM) | 1973-03-09 |
| AU4495072A (en) | 1974-01-31 |
| US3801586A (en) | 1974-04-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1803084A1 (de) | Schaedlingsbekaempfungsmittel | |
| CH485736A (de) | Verfahren zur Herstellung halogensubstituierter Imidazol-Derivate | |
| DE2149312C3 (de) | Thiophosphorsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung als Nematicide und Bodeninsektizide | |
| DE2514402A1 (de) | Insektizide mittel | |
| DD150841A5 (de) | Insektizide mittel enthaltend salze von thiazolyliden-oxo-propionitrilen | |
| DE1811409A1 (de) | Mittel zur Bekaempfung von Insekten,Milben,Hasenartigen und Nagetieren | |
| EP0014734A1 (de) | 1-N,N-Dimethylcarbamoyl-3(5)-alkyl-5(3)-alkylthioalkylthio-1,2,4-triazole, Verfahren zu ihrer Herstellung, diese Verbindungen enthaltende Mittel und ihre Verwendung zur Bekämpfung von Schädlingen sowie ihre Ausgangsprodukte und deren Herstellung | |
| EP0010754A2 (de) | 1-Posphorylierte 2-(Phenoxy-alkyl)-2-imidazolinderivate, Verfahren zu ihrer Herstellung, Mittel welche diese Derivate enthalten und ihre Verwendung zur Bekämpfung von Schädlingen | |
| DE2447735A1 (de) | Spiro-cyclopropane, verfahren zu ihrer herstellung und ihre verwendung zur schaedlingsbekaempfung | |
| DE2236459A1 (de) | Thiadiazolderivate als wirkstoffe in schaedlingsbekaempfungsmitteln | |
| DE2247109A1 (de) | Benzylcyclopropancarboxylat-derivate und verfahren zu ihrer herstellung | |
| DE2524578A1 (de) | Barbitursaeurederivate, verfahren zu ihrer herstellung und ihre verwendung als herbizide | |
| DE2813281A1 (de) | Symmetrische, n-substituierte bis- carbamoyloximinodisulfidverbindungen mit pestizider wirkung | |
| DE2434378A1 (de) | Sich vom pyrazolin ableitende phosphorsaeureester, deren herstellung und diese enthaltende zusammensetzungen | |
| DE1813194A1 (de) | Trichlorthiophen-2-carbonsaeureamide | |
| DE2937334A1 (de) | Neue, als ovicide mittel brauchbare cyanomethyltrithiocarbonatverbindungen | |
| DE2211706A1 (de) | Thiazol-Derivate | |
| DE1806120A1 (de) | Neue Carbamoyloxime,Verfahren zu ihrer Herstellung und ihre Verwendung zur Bekaempfung von Schaedlingen | |
| DE2101687C3 (de) | Organische Phosphorsäureester, Ver-, fahren zu deren Herstellung und deren Verwendung zur Bekämpfung von Insekten und Pilzen | |
| DE2926408A1 (de) | Benzyloxim-aether-derivate | |
| AT324045B (de) | Insektizide und akarizide zusammensetzungen | |
| DE2034478C3 (de) | O-Alkyl-O-Phenyl-S-Alkoxyäthylphosphorthiolate mit insektizider und fungizider Wirkung | |
| AT262696B (de) | Schädlingsbekämpfungsmittel | |
| DE1917922A1 (de) | Schaedlingsbekaempfungsmittel | |
| AT257268B (de) | Mischungen zur Schädlingsbekämpfung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| OHN | Withdrawal |