DE2222222C3 - Verfahren zur Polymerisation von α-Olefinen mit 4 bis 10 Kohlenstoffatomen - Google Patents
Verfahren zur Polymerisation von α-Olefinen mit 4 bis 10 KohlenstoffatomenInfo
- Publication number
- DE2222222C3 DE2222222C3 DE19722222222 DE2222222A DE2222222C3 DE 2222222 C3 DE2222222 C3 DE 2222222C3 DE 19722222222 DE19722222222 DE 19722222222 DE 2222222 A DE2222222 A DE 2222222A DE 2222222 C3 DE2222222 C3 DE 2222222C3
- Authority
- DE
- Germany
- Prior art keywords
- component
- aluminum
- mol percent
- polymerization
- olefins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 title claims description 4
- 238000006116 polymerization reaction Methods 0.000 title description 12
- 239000004711 α-olefin Substances 0.000 title description 2
- 229920000642 polymer Polymers 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 claims description 7
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000012071 phase Substances 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000000306 component Substances 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 7
- CECABOMBVQNBEC-UHFFFAOYSA-K aluminium iodide Chemical compound I[Al](I)I CECABOMBVQNBEC-UHFFFAOYSA-K 0.000 description 4
- 235000005911 diet Nutrition 0.000 description 4
- 230000000378 dietary effect Effects 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 3
- -1 butene- (I) Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- SUWJESCICIOQHO-UHFFFAOYSA-N 4-methylhex-1-ene Chemical compound CCC(C)CC=C SUWJESCICIOQHO-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14202771A | 1971-05-10 | 1971-05-10 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2222222A1 DE2222222A1 (de) | 1972-11-23 |
| DE2222222B2 DE2222222B2 (de) | 1981-04-02 |
| DE2222222C3 true DE2222222C3 (de) | 1981-11-26 |
Family
ID=22498269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722222222 Expired DE2222222C3 (de) | 1971-05-10 | 1972-05-05 | Verfahren zur Polymerisation von α-Olefinen mit 4 bis 10 Kohlenstoffatomen |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5436598B1 (enExample) |
| BE (1) | BE783124A (enExample) |
| CA (1) | CA976945A (enExample) |
| DE (1) | DE2222222C3 (enExample) |
| FR (1) | FR2137630B1 (enExample) |
| GB (1) | GB1337925A (enExample) |
| IT (1) | IT955346B (enExample) |
| NL (1) | NL173961C (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2944018C2 (de) * | 1979-10-31 | 1983-08-04 | Nikolaj Petrovič Grosnyj Šestak | Verfahren zur Herstellung von Polypropylen |
| FR2629703A2 (fr) * | 1987-10-16 | 1989-10-13 | Courty Claude | Barbecue compact |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2909511A (en) * | 1958-11-20 | 1959-10-20 | Hercules Powder Co Ltd | Olefin polymerization process |
| FR1290798A (fr) * | 1960-06-10 | 1962-04-13 | Montedison Spa | Procédé de polymérisation d'alpha-oléfines |
| GB1051680A (enExample) * | 1964-06-15 |
-
1972
- 1972-04-13 CA CA139,599A patent/CA976945A/en not_active Expired
- 1972-04-20 GB GB1825972A patent/GB1337925A/en not_active Expired
- 1972-05-05 BE BE783124A patent/BE783124A/xx not_active IP Right Cessation
- 1972-05-05 DE DE19722222222 patent/DE2222222C3/de not_active Expired
- 1972-05-08 FR FR7216384A patent/FR2137630B1/fr not_active Expired
- 1972-05-09 IT IT2412172A patent/IT955346B/it active
- 1972-05-09 JP JP4508272A patent/JPS5436598B1/ja active Pending
- 1972-05-09 NL NL7206282A patent/NL173961C/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA976945A (en) | 1975-10-28 |
| DE2222222B2 (de) | 1981-04-02 |
| FR2137630B1 (enExample) | 1978-03-03 |
| FR2137630A1 (enExample) | 1972-12-29 |
| DE2222222A1 (de) | 1972-11-23 |
| BE783124A (fr) | 1972-11-06 |
| NL7206282A (enExample) | 1972-11-14 |
| JPS5436598B1 (enExample) | 1979-11-09 |
| AU4203872A (en) | 1973-11-15 |
| NL173961B (nl) | 1983-11-01 |
| IT955346B (it) | 1973-09-29 |
| GB1337925A (en) | 1973-11-21 |
| NL173961C (nl) | 1984-04-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| C3 | Grant after two publication steps (3rd publication) | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: KOHLER, M., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 8000 MUENCHEN |
|
| 8339 | Ceased/non-payment of the annual fee |