DE2145055A1 - Verfahren zur Herstellung von Polymeren oder Copolymeren von Vinylchlorid - Google Patents
Verfahren zur Herstellung von Polymeren oder Copolymeren von VinylchloridInfo
- Publication number
- DE2145055A1 DE2145055A1 DE19712145055 DE2145055A DE2145055A1 DE 2145055 A1 DE2145055 A1 DE 2145055A1 DE 19712145055 DE19712145055 DE 19712145055 DE 2145055 A DE2145055 A DE 2145055A DE 2145055 A1 DE2145055 A1 DE 2145055A1
- Authority
- DE
- Germany
- Prior art keywords
- vinyl chloride
- peroxide
- bis
- polymerization
- initiator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 23
- 238000000034 method Methods 0.000 title claims description 9
- 229920001577 copolymer Polymers 0.000 title claims description 7
- 229920000642 polymer Polymers 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 32
- 239000000178 monomer Substances 0.000 claims description 20
- 239000003999 initiator Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 18
- 238000006116 polymerization reaction Methods 0.000 description 17
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 11
- 238000007334 copolymerization reaction Methods 0.000 description 5
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 2
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- UKDKWYQGLUUPBF-UHFFFAOYSA-N 1-ethenoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOC=C UKDKWYQGLUUPBF-UHFFFAOYSA-N 0.000 description 1
- RPBWMJBZQXCSFW-UHFFFAOYSA-N 2-methylpropanoyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(=O)C(C)C RPBWMJBZQXCSFW-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical class C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- CWINGZLCRSDKCL-UHFFFAOYSA-N ethoxycarbonyloxy ethyl carbonate Chemical compound CCOC(=O)OOC(=O)OCC CWINGZLCRSDKCL-UHFFFAOYSA-N 0.000 description 1
- -1 ethylene, propylene Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7014141A NL7014141A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1970-09-25 | 1970-09-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2145055A1 true DE2145055A1 (de) | 1972-03-30 |
Family
ID=19811161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712145055 Ceased DE2145055A1 (de) | 1970-09-25 | 1971-09-09 | Verfahren zur Herstellung von Polymeren oder Copolymeren von Vinylchlorid |
Country Status (12)
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3464245D1 (de) * | 1983-08-05 | 1987-07-23 | Nippon Oils & Fats Co Ltd | Diacyl peroxide composition |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2419347A (en) * | 1944-03-13 | 1947-04-22 | Goodrich Co B F | Polymerization catalysts |
| US2658057A (en) * | 1952-10-24 | 1953-11-03 | Monsanto Chemicals | Mass polymerization with mixture of 4, 4-dihydroxy benzoyl peroxide and adipoyl peroxide |
| US3222327A (en) * | 1961-07-27 | 1965-12-07 | Eastman Kodak Co | Peroxide catalysts and polymerization processes employing the same |
| NL126755C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1966-05-06 | |||
| NL136301C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1967-10-24 | |||
| NL136294C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1968-04-24 |
-
1970
- 1970-09-25 NL NL7014141A patent/NL7014141A/xx unknown
-
1971
- 1971-08-31 GB GB4059271A patent/GB1354185A/en not_active Expired
- 1971-09-09 DE DE19712145055 patent/DE2145055A1/de not_active Ceased
- 1971-09-15 CH CH1348371A patent/CH552022A/xx not_active IP Right Cessation
- 1971-09-15 CA CA122914A patent/CA1034699A/en not_active Expired
- 1971-09-15 US US05/180,716 patent/US3959241A/en not_active Expired - Lifetime
- 1971-09-22 FR FR7134053A patent/FR2112976A5/fr not_active Expired
- 1971-09-24 NO NO3540/71A patent/NO137239C/no unknown
- 1971-09-24 DK DK465971AA patent/DK133013B/da unknown
- 1971-09-24 BE BE773020A patent/BE773020A/nl not_active IP Right Cessation
- 1971-09-24 AT AT828871A patent/AT307736B/de not_active IP Right Cessation
- 1971-09-24 ES ES395399A patent/ES395399A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1354185A (en) | 1974-06-05 |
| AT307736B (de) | 1973-06-12 |
| US3959241A (en) | 1976-05-25 |
| FR2112976A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-06-23 |
| BE773020A (nl) | 1972-01-17 |
| NO137239B (no) | 1977-10-17 |
| NO137239C (no) | 1978-01-25 |
| NL7014141A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-03-28 |
| CH552022A (de) | 1974-07-31 |
| DK133013B (da) | 1976-03-08 |
| CA1034699A (en) | 1978-07-11 |
| ES395399A1 (es) | 1973-12-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| OGA | New person/name/address of the applicant | ||
| 8131 | Rejection |