DE19738051A1 - Spritzgieß-Artikel aus Metallocen-Polypropylen - Google Patents
Spritzgieß-Artikel aus Metallocen-PolypropylenInfo
- Publication number
- DE19738051A1 DE19738051A1 DE19738051A DE19738051A DE19738051A1 DE 19738051 A1 DE19738051 A1 DE 19738051A1 DE 19738051 A DE19738051 A DE 19738051A DE 19738051 A DE19738051 A DE 19738051A DE 19738051 A1 DE19738051 A1 DE 19738051A1
- Authority
- DE
- Germany
- Prior art keywords
- propylene
- homopolymers
- injection molded
- copolymers
- alk
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001155 polypropylene Polymers 0.000 title claims description 13
- 238000002347 injection Methods 0.000 title claims description 10
- 239000007924 injection Substances 0.000 title claims description 10
- -1 polypropylene Polymers 0.000 title description 4
- 239000004743 Polypropylene Substances 0.000 title description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 28
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 28
- 229920001519 homopolymer Polymers 0.000 claims abstract description 16
- 239000000178 monomer Substances 0.000 claims abstract description 11
- 239000012968 metallocene catalyst Substances 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 238000004806 packaging method and process Methods 0.000 claims description 13
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 9
- 230000000379 polymerizing effect Effects 0.000 claims description 7
- 238000003860 storage Methods 0.000 claims description 4
- 235000013365 dairy product Nutrition 0.000 claims description 2
- 230000035622 drinking Effects 0.000 claims description 2
- 235000013305 food Nutrition 0.000 claims description 2
- 235000013618 yogurt Nutrition 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 abstract description 12
- 238000001746 injection moulding Methods 0.000 abstract description 5
- 238000000465 moulding Methods 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 229920001384 propylene homopolymer Polymers 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000012766 organic filler Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920006301 statistical copolymer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- OJVWBQRZCJLURF-UHFFFAOYSA-L C1=CC=C2C(C3=CC=CC4=C3C=C(C)C4[Zr](Cl)(Cl)(C3C4=C(C(=CC=C4)C=4C5=CC=CC=C5C=CC=4)C=C3C)=[Si](C)C)=CC=CC2=C1 Chemical compound C1=CC=C2C(C3=CC=CC4=C3C=C(C)C4[Zr](Cl)(Cl)(C3C4=C(C(=CC=C4)C=4C5=CC=CC=C5C=CC=4)C=C3C)=[Si](C)C)=CC=CC2=C1 OJVWBQRZCJLURF-UHFFFAOYSA-L 0.000 description 1
- CZPSTFVUNSZYCA-UHFFFAOYSA-L CC(C)c1cc2C(C(C)=Cc2c(c1)C(C)C)[Zr](Cl)(Cl)(C1C(C)=Cc2c1cc(cc2C(C)C)C(C)C)=[Si](C)C Chemical compound CC(C)c1cc2C(C(C)=Cc2c(c1)C(C)C)[Zr](Cl)(Cl)(C1C(C)=Cc2c1cc(cc2C(C)C)C(C)C)=[Si](C)C CZPSTFVUNSZYCA-UHFFFAOYSA-L 0.000 description 1
- FLFNHHSXSLXYQB-UHFFFAOYSA-L CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 FLFNHHSXSLXYQB-UHFFFAOYSA-L 0.000 description 1
- ZQVDTPHKVJVFGG-UHFFFAOYSA-L CCC1=Cc2c(cccc2-c2ccccc2)C1[Zr](Cl)(Cl)(C1C(CC)=Cc2c1cccc2-c1ccccc1)=[Si](C)C Chemical compound CCC1=Cc2c(cccc2-c2ccccc2)C1[Zr](Cl)(Cl)(C1C(CC)=Cc2c1cccc2-c1ccccc1)=[Si](C)C ZQVDTPHKVJVFGG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920008712 Copo Polymers 0.000 description 1
- 206010013911 Dysgeusia Diseases 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001777 Tupperware Polymers 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- FGLAWIXRCXRZJX-UHFFFAOYSA-L [Cl-].[Cl-].CC(C)c1cc2C(C(C)=Cc2c(c1)C(C)C)[Zr++]1(CC1)C1C(C)=Cc2c1cc(cc2C(C)C)C(C)C Chemical compound [Cl-].[Cl-].CC(C)c1cc2C(C(C)=Cc2c(c1)C(C)C)[Zr++]1(CC1)C1C(C)=Cc2c1cc(cc2C(C)C)C(C)C FGLAWIXRCXRZJX-UHFFFAOYSA-L 0.000 description 1
- KBOAIUOMHXNSGH-UHFFFAOYSA-L [Cl-].[Cl-].CC(C)c1cccc2[C@H](C(C)=Cc12)[Zr++]([C@@H]1C(C)=Cc2c1cccc2C(C)C)=[Si](C)C Chemical compound [Cl-].[Cl-].CC(C)c1cccc2[C@H](C(C)=Cc12)[Zr++]([C@@H]1C(C)=Cc2c1cccc2C(C)C)=[Si](C)C KBOAIUOMHXNSGH-UHFFFAOYSA-L 0.000 description 1
- WIZSMGXHZDJBTO-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2c(C1[Zr++]1(CC1)C1C(C)=Cc3c1c(C)ccc3C)c(C)ccc2C Chemical compound [Cl-].[Cl-].CC1=Cc2c(C1[Zr++]1(CC1)C1C(C)=Cc3c1c(C)ccc3C)c(C)ccc2C WIZSMGXHZDJBTO-UHFFFAOYSA-L 0.000 description 1
- UVVHOKMKYKTWHC-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2c([C@H]1[Zr++]([C@@H]1C(C)=Cc3c1c(C)ccc3C)=[Si](C)C)c(C)ccc2C Chemical compound [Cl-].[Cl-].CC1=Cc2c([C@H]1[Zr++]([C@@H]1C(C)=Cc3c1c(C)ccc3C)=[Si](C)C)c(C)ccc2C UVVHOKMKYKTWHC-UHFFFAOYSA-L 0.000 description 1
- BOMWQXOILQOKHL-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2c(ccc3ccccc23)C1[Zr++](C1C(C)=Cc2c1ccc1ccccc21)=[Si](C)C Chemical compound [Cl-].[Cl-].CC1=Cc2c(ccc3ccccc23)C1[Zr++](C1C(C)=Cc2c1ccc1ccccc21)=[Si](C)C BOMWQXOILQOKHL-UHFFFAOYSA-L 0.000 description 1
- KOECLOYQFLBOJD-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2c(ccc3ccccc23)C1[Zr++]1(CC1)C1C(C)=Cc2c1ccc1ccccc21 Chemical compound [Cl-].[Cl-].CC1=Cc2c(ccc3ccccc23)C1[Zr++]1(CC1)C1C(C)=Cc2c1ccc1ccccc21 KOECLOYQFLBOJD-UHFFFAOYSA-L 0.000 description 1
- MSOOKQOLPYTDQN-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2c(cccc2-c2cccc3ccccc23)C1[Zr++]1(CC1)C1C(C)=Cc2c1cccc2-c1cccc2ccccc12 Chemical compound [Cl-].[Cl-].CC1=Cc2c(cccc2-c2cccc3ccccc23)C1[Zr++]1(CC1)C1C(C)=Cc2c1cccc2-c1cccc2ccccc12 MSOOKQOLPYTDQN-UHFFFAOYSA-L 0.000 description 1
- UDPQUWPUPHBEKR-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2c(cccc2-c2ccccc2)C1[Zr++]1(CC1)C1C(C)=Cc2c1cccc2-c1ccccc1 Chemical compound [Cl-].[Cl-].CC1=Cc2c(cccc2-c2ccccc2)C1[Zr++]1(CC1)C1C(C)=Cc2c1cccc2-c1ccccc1 UDPQUWPUPHBEKR-UHFFFAOYSA-L 0.000 description 1
- PNRJUCXJBYLCRR-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2cccc(C)c2C1[Zr++](C1C(C)=Cc2cccc(C)c12)=[Si](C)C Chemical compound [Cl-].[Cl-].CC1=Cc2cccc(C)c2C1[Zr++](C1C(C)=Cc2cccc(C)c12)=[Si](C)C PNRJUCXJBYLCRR-UHFFFAOYSA-L 0.000 description 1
- XHPOYMKSOQMYAX-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2cccc(C)c2C1[Zr++]1(CC1)C1C(C)=Cc2cccc(C)c12 Chemical compound [Cl-].[Cl-].CC1=Cc2cccc(C)c2C1[Zr++]1(CC1)C1C(C)=Cc2cccc(C)c12 XHPOYMKSOQMYAX-UHFFFAOYSA-L 0.000 description 1
- CGELJBSWQTYCIY-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2ccccc2[C@H]1[Zr++]([C@@H]1C(C)=Cc2ccccc12)=[Si](C)C Chemical compound [Cl-].[Cl-].CC1=Cc2ccccc2[C@H]1[Zr++]([C@@H]1C(C)=Cc2ccccc12)=[Si](C)C CGELJBSWQTYCIY-UHFFFAOYSA-L 0.000 description 1
- XHVLAWXDMTYYJZ-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2ccccc2[C@H]1[Zr++]1(CC1)[C@@H]1C(C)=Cc2ccccc12 Chemical compound [Cl-].[Cl-].CC1=Cc2ccccc2[C@H]1[Zr++]1(CC1)[C@@H]1C(C)=Cc2ccccc12 XHVLAWXDMTYYJZ-UHFFFAOYSA-L 0.000 description 1
- GIQOXDNIOMQZDO-UHFFFAOYSA-L [Cl-].[Cl-].CCC1=Cc2c(ccc3ccccc23)C1[Zr++](C1C(CC)=Cc2c1ccc1ccccc21)=[Si](C)C Chemical compound [Cl-].[Cl-].CCC1=Cc2c(ccc3ccccc23)C1[Zr++](C1C(CC)=Cc2c1ccc1ccccc21)=[Si](C)C GIQOXDNIOMQZDO-UHFFFAOYSA-L 0.000 description 1
- LFYDRNUYVGKKGY-UHFFFAOYSA-L [Cl-].[Cl-].CCC1=Cc2c(cccc2-c2ccccc2)C1[Zr++]1(CC1)C1C(CC)=Cc2c1cccc2-c1ccccc1 Chemical compound [Cl-].[Cl-].CCC1=Cc2c(cccc2-c2ccccc2)C1[Zr++]1(CC1)C1C(CC)=Cc2c1cccc2-c1ccccc1 LFYDRNUYVGKKGY-UHFFFAOYSA-L 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000004159 blood analysis Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 235000021185 dessert Nutrition 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000009512 pharmaceutical packaging Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/178—Syringes
- A61M5/31—Details
- A61M5/3129—Syringe barrels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B3/00—Recording by mechanical cutting, deforming or pressing, e.g. of grooves or pits; Reproducing by mechanical sensing; Record carriers therefor
- G11B3/68—Record carriers
- G11B3/70—Record carriers characterised by the selection of material or structure; Processes or apparatus specially adapted for manufacturing record carriers
- G11B3/705—Record carriers characterised by the selection of material or structure; Processes or apparatus specially adapted for manufacturing record carriers characterised by the selection of the material only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/06—Walls
- F25D23/065—Details
- F25D23/066—Liners
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B23/00—Record carriers not specific to the method of recording or reproducing; Accessories, e.g. containers, specially adapted for co-operation with the recording or reproducing apparatus ; Intermediate mediums; Apparatus or processes specially adapted for their manufacture
- G11B23/02—Containers; Storing means both adapted to cooperate with the recording or reproducing means
- G11B23/023—Containers for magazines or cassettes
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B33/00—Constructional parts, details or accessories not provided for in the other groups of this subclass
- G11B33/02—Cabinets; Cases; Stands; Disposition of apparatus therein or thereon
- G11B33/04—Cabinets; Cases; Stands; Disposition of apparatus therein or thereon modified to store record carriers
- G11B33/0405—Cabinets; Cases; Stands; Disposition of apparatus therein or thereon modified to store record carriers for storing discs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Heart & Thoracic Surgery (AREA)
- Biomedical Technology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hematology (AREA)
- Animal Behavior & Ethology (AREA)
- Anesthesiology (AREA)
- Vascular Medicine (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19738051A DE19738051A1 (de) | 1997-09-01 | 1997-09-01 | Spritzgieß-Artikel aus Metallocen-Polypropylen |
| AU95330/98A AU9533098A (en) | 1997-09-01 | 1998-08-21 | Injection moulding articles made of metallocene and polypropylene |
| JP2000508713A JP2001514310A (ja) | 1997-09-01 | 1998-08-21 | メタロセンプロピレンから形成される射出成形体製品 |
| US09/486,634 US6537478B1 (en) | 1997-09-01 | 1998-08-21 | Injection moulding articles made of metallocene polypropylene |
| ES98948856T ES2196606T3 (es) | 1997-09-01 | 1998-08-21 | Articulos de moldeo por inyeccion hechos a partir de metaloceno-popipropileno. |
| EP98948856A EP1017730B1 (de) | 1997-09-01 | 1998-08-21 | Spritzgiessartikel aus metallocen-polypropylen |
| DE59807669T DE59807669D1 (de) | 1997-09-01 | 1998-08-21 | Spritzgiessartikel aus metallocen-polypropylen |
| PCT/EP1998/005334 WO1999011678A2 (de) | 1997-09-01 | 1998-08-21 | Spritzgiessartikel aus metallocen-polypropylen |
| TW087114084A TW426607B (en) | 1997-09-01 | 1998-08-26 | Injection-molded articles made of metallocene polypropylene |
| ZA9807895A ZA987895B (en) | 1997-09-01 | 1998-08-31 | Injection-molded articles made of metallocene polypropylene. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19738051A DE19738051A1 (de) | 1997-09-01 | 1997-09-01 | Spritzgieß-Artikel aus Metallocen-Polypropylen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19738051A1 true DE19738051A1 (de) | 1999-03-04 |
Family
ID=7840782
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19738051A Withdrawn DE19738051A1 (de) | 1997-09-01 | 1997-09-01 | Spritzgieß-Artikel aus Metallocen-Polypropylen |
| DE59807669T Expired - Lifetime DE59807669D1 (de) | 1997-09-01 | 1998-08-21 | Spritzgiessartikel aus metallocen-polypropylen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59807669T Expired - Lifetime DE59807669D1 (de) | 1997-09-01 | 1998-08-21 | Spritzgiessartikel aus metallocen-polypropylen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6537478B1 (https=) |
| EP (1) | EP1017730B1 (https=) |
| JP (1) | JP2001514310A (https=) |
| AU (1) | AU9533098A (https=) |
| DE (2) | DE19738051A1 (https=) |
| ES (1) | ES2196606T3 (https=) |
| TW (1) | TW426607B (https=) |
| WO (1) | WO1999011678A2 (https=) |
| ZA (1) | ZA987895B (https=) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003052791A (ja) * | 2001-06-07 | 2003-02-25 | Q P Corp | 複室容器 |
| ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| CA2540887C (en) * | 2003-10-07 | 2012-07-10 | Dow Global Technologies Inc. | Polypropylene composition for air quenched blown films |
| JP2008508123A (ja) * | 2004-07-29 | 2008-03-21 | ビーエフエス デバーシファイド プロダクツ エルエルシー | 組立用積層体 |
| US20060102496A1 (en) * | 2004-11-12 | 2006-05-18 | Bruce Christy | Contact lens case having a lid with soft gripping surface |
| US20070202285A1 (en) | 2004-12-15 | 2007-08-30 | Fina Technology, Inc. | Articles having improved clarity, prepared from propylene-ethylene copolymers |
| US7416766B2 (en) * | 2005-08-16 | 2008-08-26 | S.C. Johnson & Son, Inc. | Bottles made from metallocene polypropylene for delivery of fragrances |
| CN101291986B (zh) * | 2005-10-21 | 2011-12-14 | 巴塞尔聚烯烃股份有限公司 | 用于注射模塑的聚丙烯 |
| WO2019166918A1 (en) * | 2018-02-27 | 2019-09-06 | 3M Innovative Properties Company | Pop-up sheet dispenser |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5126986A (en) * | 1974-08-29 | 1976-03-05 | Furukawa Electric Co Ltd | Kuuraayokezara no seizohoho |
| US4637222A (en) * | 1984-06-08 | 1987-01-20 | Nippondenso Co., Ltd. | Refrigerator for vehicle |
| DE4005947A1 (de) * | 1990-02-26 | 1991-08-29 | Basf Ag | Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
| TW318184B (https=) | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
| JPH05295184A (ja) * | 1992-04-21 | 1993-11-09 | Asahi Chem Ind Co Ltd | 表面外観に優れた樹脂組成物 |
| TW294669B (https=) | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| EP0582194B1 (de) | 1992-08-03 | 1998-05-06 | TARGOR GmbH | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
| TW272985B (https=) * | 1992-09-11 | 1996-03-21 | Hoechst Ag | |
| AU682008B2 (en) * | 1992-09-25 | 1997-09-18 | Ciba Specialty Chemicals Holding Inc. | Process for the stabilization of and stabilizer mixtures forsingle-material recycled plastics |
| EP0596379A1 (de) * | 1992-10-31 | 1994-05-11 | Hoechst Aktiengesellschaft | Kunststoff-Formmasse zur Herstellung von Formteilen mit farblich abstimmbarem Dekoreffekt |
| US5377825A (en) * | 1993-01-04 | 1995-01-03 | Sykes; Philip K. | Compact disc storage case |
| CA2120315C (en) * | 1993-04-30 | 2001-05-15 | Joel L. Williams | Medical articles and process therefor |
| DE4333128A1 (de) * | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
| CA2164461C (en) * | 1994-12-06 | 2000-08-08 | Tatsuya Tanizaki | Polypropylene composition and uses thereof |
| WO1996032441A1 (en) * | 1995-04-13 | 1996-10-17 | Exxon Chemical Patents Inc. | Improved processability of metallocene-catalyzed polyolefins |
| JPH08325327A (ja) * | 1995-06-02 | 1996-12-10 | Chisso Corp | 高立体規則性ポリプロピレン |
| EP0751215A3 (en) * | 1995-06-29 | 1997-03-05 | Becton Dickinson Co | Culture container for use with culture plates |
| JPH0948040A (ja) * | 1995-08-04 | 1997-02-18 | Chisso Corp | 射出成形品 |
| JPH0948820A (ja) * | 1995-08-04 | 1997-02-18 | Chisso Corp | ポリプロピレン成形品 |
| JPH0952331A (ja) * | 1995-08-17 | 1997-02-25 | Showa Denko Kk | 積層体 |
| ES2144264T3 (es) * | 1995-08-29 | 2000-06-01 | Exxon Chemical Patents Inc | Polipropileno tolerante a la radiacion y sus articulos utiles. |
| US5741563A (en) * | 1995-09-18 | 1998-04-21 | Exxon Chemical Patents Inc. | Shrink films from propylene polymers |
| JPH0986582A (ja) * | 1995-09-25 | 1997-03-31 | Victor Co Of Japan Ltd | コンパクトディスク用ケース |
| JPH09111058A (ja) * | 1995-10-23 | 1997-04-28 | Mitsubishi Chem Corp | 結晶性オレフィン系樹脂組成物 |
| DE19544709A1 (de) * | 1995-11-30 | 1997-06-05 | Basf Ag | Biaxial orientierte Polypropylenfolie aus Metallocen-Polypropylen |
| EP0863943A1 (en) * | 1995-11-30 | 1998-09-16 | Exxon Chemical Patents Inc. | Articles made from polypropylene, higher alpha-olefin copolymers |
| US5590768A (en) * | 1996-01-11 | 1997-01-07 | Compliant Solutions, Lc | Storage case for disk-shaped media having a bi-stable ejection mechanism utilizing compliant device technology |
| GB9601568D0 (en) * | 1996-01-26 | 1996-03-27 | Headway Cms Ltd | Case for data carrying discs |
| US5786291A (en) * | 1996-02-23 | 1998-07-28 | Exxon Chemical Patents, Inc. | Engineered catalyst systems and methods for their production and use |
| DE29603840U1 (de) * | 1996-03-01 | 1997-06-26 | AEG Hausgeräte GmbH, 90429 Nürnberg | Kältegerät |
| US5775491A (en) * | 1996-05-15 | 1998-07-07 | Atlanta Precision Molding Company | Compact disk tray and cover therefor |
| AU718385B2 (en) * | 1996-06-11 | 2000-04-13 | Basf Aktiengesellschaft | Mettallocene catalyst systems with inorganic oxides as supports |
| US5782348A (en) * | 1996-06-19 | 1998-07-21 | Alpha Enterprises, Inc. | Multiple disc storage case |
| JP3311931B2 (ja) * | 1996-06-25 | 2002-08-05 | 三菱化学株式会社 | ポリプロピレン樹脂及びその製造法 |
| DE29700263U1 (de) * | 1997-01-09 | 1997-03-20 | Geissen, Robert, 37235 Hessisch Lichtenau | Auf einen Gegenstand, z.B. eine Zeitschrift, aufklebbare Sichthülle für Compact-Discs (CDs) |
| JPH10251463A (ja) * | 1997-03-13 | 1998-09-22 | Nippon Porikemu Kk | プロピレン系樹脂組成物 |
| DE59812014D1 (de) * | 1997-05-14 | 2004-11-04 | Borealis Gmbh Schwechat Mannsw | Polyolefinfasern und Polyolefingarne und daraus hergestellte textile Flächengebilde |
-
1997
- 1997-09-01 DE DE19738051A patent/DE19738051A1/de not_active Withdrawn
-
1998
- 1998-08-21 AU AU95330/98A patent/AU9533098A/en not_active Abandoned
- 1998-08-21 EP EP98948856A patent/EP1017730B1/de not_active Expired - Lifetime
- 1998-08-21 US US09/486,634 patent/US6537478B1/en not_active Expired - Lifetime
- 1998-08-21 ES ES98948856T patent/ES2196606T3/es not_active Expired - Lifetime
- 1998-08-21 WO PCT/EP1998/005334 patent/WO1999011678A2/de not_active Ceased
- 1998-08-21 JP JP2000508713A patent/JP2001514310A/ja active Pending
- 1998-08-21 DE DE59807669T patent/DE59807669D1/de not_active Expired - Lifetime
- 1998-08-26 TW TW087114084A patent/TW426607B/zh not_active IP Right Cessation
- 1998-08-31 ZA ZA9807895A patent/ZA987895B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA987895B (en) | 2000-02-29 |
| EP1017730B1 (de) | 2003-03-26 |
| WO1999011678A2 (de) | 1999-03-11 |
| EP1017730A2 (de) | 2000-07-12 |
| ES2196606T3 (es) | 2003-12-16 |
| TW426607B (en) | 2001-03-21 |
| AU9533098A (en) | 1999-03-22 |
| WO1999011678A3 (de) | 1999-05-27 |
| US6537478B1 (en) | 2003-03-25 |
| DE59807669D1 (de) | 2003-04-30 |
| JP2001514310A (ja) | 2001-09-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |