DE19681320C2 - Verfahren zur überkritischen katalytischen Vergasung von nasser Biomasse - Google Patents

Verfahren zur überkritischen katalytischen Vergasung von nasser Biomasse

Info

Publication number
DE19681320C2
DE19681320C2 DE19681320T DE19681320T DE19681320C2 DE 19681320 C2 DE19681320 C2 DE 19681320C2 DE 19681320 T DE19681320 T DE 19681320T DE 19681320 T DE19681320 T DE 19681320T DE 19681320 C2 DE19681320 C2 DE 19681320C2
Authority
DE
Germany
Prior art keywords
catalyst
organic matter
feed
water
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE19681320T
Other languages
German (de)
English (en)
Other versions
DE19681320T1 (de
Inventor
Jun Michael J Antal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Hawaii
Original Assignee
University of Hawaii
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Hawaii filed Critical University of Hawaii
Publication of DE19681320T1 publication Critical patent/DE19681320T1/de
Application granted granted Critical
Publication of DE19681320C2 publication Critical patent/DE19681320C2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/008Processes carried out under supercritical conditions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/06Catalysts as integral part of gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0916Biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0946Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • C10J2300/0979Water as supercritical steam
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983Additives
    • C10J2300/0986Catalysts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/1269Heating the gasifier by radiating device, e.g. radiant tubes
    • C10J2300/1276Heating the gasifier by radiating device, e.g. radiant tubes by electricity, e.g. resistor heating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/54Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE19681320T 1995-03-31 1996-03-28 Verfahren zur überkritischen katalytischen Vergasung von nasser Biomasse Expired - Fee Related DE19681320C2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US41452395A 1995-03-31 1995-03-31
PCT/US1996/004439 WO1996030464A1 (en) 1995-03-31 1996-03-28 Catalytic supercritical gasification of wet biomass

Publications (2)

Publication Number Publication Date
DE19681320T1 DE19681320T1 (de) 1998-03-19
DE19681320C2 true DE19681320C2 (de) 2000-06-29

Family

ID=23641824

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19681320T Expired - Fee Related DE19681320C2 (de) 1995-03-31 1996-03-28 Verfahren zur überkritischen katalytischen Vergasung von nasser Biomasse

Country Status (7)

Country Link
EP (1) EP0820497A4 (sv)
JP (1) JPH11502891A (sv)
KR (1) KR19980703309A (sv)
AU (1) AU5381796A (sv)
DE (1) DE19681320C2 (sv)
SE (1) SE9703448L (sv)
WO (1) WO1996030464A1 (sv)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10259928A1 (de) * 2002-12-20 2004-07-22 Forschungszentrum Karlsruhe Gmbh Verfahren zur Behandlung von Biomasse
DE102004038491A1 (de) * 2004-08-07 2006-03-16 Forschungszentrum Karlsruhe Gmbh Verfahren zur Umsetzung von Biomasse in gasförmige Produkte
EP1772202A1 (de) * 2005-10-04 2007-04-11 Paul Scherrer Institut Verfahren zur Erzeugung von Methan und/oder Methanhydrat aus Biomasse

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2979149B1 (ja) * 1998-11-11 1999-11-15 財団法人石炭利用総合センター 熱化学的分解による水素の製造方法
DE19955150B4 (de) * 1999-11-17 2010-08-05 Karlsruher Institut für Technologie Verfahren zur Erzeugung von Wasserstoff
DE10015620A1 (de) * 2000-03-29 2001-10-04 Abb Patent Gmbh Verfahren und Vorrichtung zum Erzeugen von Wärme
KR100569120B1 (ko) * 2004-08-05 2006-04-10 한국에너지기술연구원 바이오메스 정제연료의 저온 촉매가스화 장치 및가스제조방법
JP2006169329A (ja) * 2004-12-14 2006-06-29 Hiroshima Univ 有機物のガス化方法
KR100780910B1 (ko) * 2007-01-24 2007-11-30 한국에너지기술연구원 니켈/활성탄 촉매 제조방법 및 니켈/활성탄 촉매를 이용한유기물질의 초임계수 기화에 의한 수소제조시스템 및 그운전방법
JP5305426B2 (ja) * 2007-07-31 2013-10-02 国立大学法人広島大学 リン酸塩回収方法
US8608981B2 (en) 2008-01-31 2013-12-17 Battelle Memorial Institute Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass
US8241605B2 (en) 2008-01-31 2012-08-14 Battelle Memorial Institute Methods and apparatus for catalytic hydrothermal gasification of biomass
FR2931477B1 (fr) * 2008-05-21 2012-08-17 Arkema France Acide cyanhydrique derive de matiere premiere renouvable
DE102008049778A1 (de) 2008-09-30 2010-04-01 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Gewinnung von gasförmigen Kohlenwasserstoffen aus biogenen Rohstoffen
FI122817B (sv) * 2008-12-19 2012-07-13 Upm Kymmene Corp Förfarande, system och användning för värmeväxling
DE102009018350A1 (de) * 2009-04-23 2010-10-28 Aimes Gmbh Umwandlungsvorrichtung zum Umwandeln von Biomasse in Kohlenwasserstoffverbindungen, Verfahren zum wenigstens teilweisen Umwandeln von Biomasse in Kohlenwasserstoffverbindungen, Nutzgas und Feststoff, sowie Verfahren zum wenigstens teilweisen Umwandeln von kontaminierten Stoffen in CO2
CN101928616B (zh) * 2009-06-24 2013-04-17 新奥科技发展有限公司 一种由煤制备富甲烷气体的方法
US8487148B2 (en) 2010-12-13 2013-07-16 Exxonmobil Research And Engineering Company Hydrothermal treatment of biomass with heterogeneous catalyst
US8624070B2 (en) 2010-12-13 2014-01-07 Exxonmobil Research And Engineering Company Phosphorus recovery from hydrothermal treatment of biomass
US8704020B2 (en) 2010-12-13 2014-04-22 Exxonmobil Research And Engineering Company Catalytic hydrothermal treatment of biomass
US8704019B2 (en) * 2010-12-13 2014-04-22 Exxonmobil Research And Engineering Company Catalyst recovery in hydrothermal treatment of biomass
ITTO20110772A1 (it) * 2011-08-23 2013-02-24 Welt Company Srl Procedimento ed impianto per lo smaltimento di rifiuti di origine algale
CN102584528A (zh) * 2011-12-15 2012-07-18 北京金骄生物质化工有限公司 一种利用废弃生物质制备燃料乙醇的方法
ITRM20120548A1 (it) * 2012-11-09 2014-05-10 En E Lo Sviluppo Economico Sostenibile L "processo di trattamento di acque di vegetazione di frantoi oleari mediante reazioni di reforming, e relativo impianto"
JP6338080B2 (ja) * 2013-03-26 2018-06-06 中国電力株式会社 超臨界水によるバイオマスガス化システム
WO2017115019A1 (en) 2015-12-30 2017-07-06 Forestgas Oy Arrangement and method for preparing a gas

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3989480A (en) * 1974-09-05 1976-11-02 The United States Of America As Represented By The United States Energy Research And Development Administration Decomposition of carbohydrate wastes
WO1993025639A1 (en) * 1992-06-05 1993-12-23 Battelle Memorial Institute Method for the catalytic conversion of organic materials into a product gas

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US2592603A (en) * 1950-11-01 1952-04-15 Sinclair Refining Co Re-forming naphtha stocks
US2880167A (en) * 1954-06-01 1959-03-31 Exxon Research Engineering Co Production and utilization of activated carbon catalyst
DE1063590B (de) * 1956-05-16 1959-08-20 Metallgesellschaft Ag Verfahren zur Herstellung von Methan aus festen Brennstoffen durch Einwirkung von Wasserdampf
US4113446A (en) * 1975-07-22 1978-09-12 Massachusetts Institute Of Technology Gasification process
US4425256A (en) * 1979-12-28 1984-01-10 Marcoal Chemical Industries Conversion of cellulose into activated charcoal
US4558027A (en) * 1984-05-25 1985-12-10 The United States Of America As Represented By The United States Department Of Energy Catalysts for carbon and coal gasification
US5460792A (en) * 1992-12-23 1995-10-24 Rohm And Haas Company Removal and destruction of halogenated organic and hydrocarbon compounds with porous carbonaceous materials
US5444031A (en) * 1993-01-21 1995-08-22 Calgon Carbon Corporation Process for making catalytic carbon

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3989480A (en) * 1974-09-05 1976-11-02 The United States Of America As Represented By The United States Energy Research And Development Administration Decomposition of carbohydrate wastes
WO1993025639A1 (en) * 1992-06-05 1993-12-23 Battelle Memorial Institute Method for the catalytic conversion of organic materials into a product gas

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10259928A1 (de) * 2002-12-20 2004-07-22 Forschungszentrum Karlsruhe Gmbh Verfahren zur Behandlung von Biomasse
DE10259928B4 (de) * 2002-12-20 2006-05-24 Forschungszentrum Karlsruhe Gmbh Verfahren zur Behandlung von Biomasse
DE102004038491A1 (de) * 2004-08-07 2006-03-16 Forschungszentrum Karlsruhe Gmbh Verfahren zur Umsetzung von Biomasse in gasförmige Produkte
DE102004038491B4 (de) * 2004-08-07 2010-07-22 Karlsruher Institut für Technologie Verfahren zur Umsetzung von Biomasse in gasförmige Produkte
EP1772202A1 (de) * 2005-10-04 2007-04-11 Paul Scherrer Institut Verfahren zur Erzeugung von Methan und/oder Methanhydrat aus Biomasse

Also Published As

Publication number Publication date
KR19980703309A (ko) 1998-10-15
SE9703448L (sv) 1997-11-25
AU5381796A (en) 1996-10-16
JPH11502891A (ja) 1999-03-09
DE19681320T1 (de) 1998-03-19
WO1996030464A1 (en) 1996-10-03
SE9703448D0 (sv) 1997-09-24
EP0820497A4 (en) 1998-12-16
EP0820497A1 (en) 1998-01-28

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Legal Events

Date Code Title Description
OP8 Request for examination as to paragraph 44 patent law
8607 Notification of search results after publication
D2 Grant after examination
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee