DE1542529A1 - Verfahren zur Herstellung von Katalysatoren zur stereospezifischen Polymerisation konjungierter Diolefine - Google Patents
Verfahren zur Herstellung von Katalysatoren zur stereospezifischen Polymerisation konjungierter DiolefineInfo
- Publication number
- DE1542529A1 DE1542529A1 DE19641542529 DE1542529A DE1542529A1 DE 1542529 A1 DE1542529 A1 DE 1542529A1 DE 19641542529 DE19641542529 DE 19641542529 DE 1542529 A DE1542529 A DE 1542529A DE 1542529 A1 DE1542529 A1 DE 1542529A1
- Authority
- DE
- Germany
- Prior art keywords
- cerium
- catalyst
- aluminum
- iii
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/37—Lanthanum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/38—Lanthanides other than lanthanum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US261875A US3297667A (en) | 1963-02-28 | 1963-02-28 | Production of cis-1, 4-polydienes by polymerization of 1, 3-dienes |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1542529A1 true DE1542529A1 (de) | 1970-07-23 |
Family
ID=22995253
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19641542529 Pending DE1542529A1 (de) | 1963-02-28 | 1964-02-26 | Verfahren zur Herstellung von Katalysatoren zur stereospezifischen Polymerisation konjungierter Diolefine |
DE19641302264D Pending DE1302264B (US20110009641A1-20110113-C00116.png) | 1963-02-28 | 1964-02-26 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19641302264D Pending DE1302264B (US20110009641A1-20110113-C00116.png) | 1963-02-28 | 1964-02-26 |
Country Status (6)
Families Citing this family (72)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1030932A (en) * | 1963-10-30 | 1966-05-25 | Mitsui Chemical Ind Co Ltd | Method for polymerizing conjugated diolefines |
IT1085663B (it) * | 1977-08-01 | 1985-05-28 | Snam Progetti | Procedimento per la polimerizzazione e copolimerizzazione di diolefine e mezzi adatti allo scopo |
DE2848964A1 (de) * | 1978-11-11 | 1980-05-22 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
IT1151542B (it) * | 1982-04-15 | 1986-12-24 | Anic Spa | Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo |
US4544718A (en) * | 1984-09-13 | 1985-10-01 | Phillips Petroleum Company | Olefin polymerization |
US4556647A (en) * | 1984-09-13 | 1985-12-03 | Phillips Petroleum Company | Olefin polymerization |
US4575538A (en) * | 1984-12-20 | 1986-03-11 | Phillips Petroleum Company | Olefin polymerization |
DE4334045A1 (de) * | 1993-10-06 | 1995-04-13 | Bayer Ag | Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen |
DE19512116A1 (de) * | 1995-04-04 | 1996-10-10 | Bayer Ag | Gasphasenpolymerisation von konjugierten Dienen in Gegenwart von Allylverbindungen der seltenen Erden |
US6001478A (en) * | 1997-08-08 | 1999-12-14 | Union Carbide Chemicals & Plastics Technology Corporation | Resin particle produced by diene polymerization with rare earth and transition metal catalysts |
DE19806931A1 (de) * | 1998-02-19 | 1999-08-26 | Bayer Ag | Verfahren zur Herstellung von Polydienen mit geregelter Mooney-Viskosität |
WO2000059955A1 (fr) * | 1999-04-06 | 2000-10-12 | Mitsui Chemicals, Incorporated | Catalyseur de polymerisation, nouveau compose de metaux de transition, procede de polymerisation et copolymere dans lequel ils sont utilises |
US6977281B1 (en) * | 1999-11-12 | 2005-12-20 | Bridgestone Corporation | Modified polymers prepared with lanthanide-based catalysts |
CA2424815C (en) * | 1999-11-12 | 2009-12-29 | Bridgestone Corporation | Modified polymers prepared with lanthanide-based catalysts |
WO2002038615A1 (en) | 2000-11-10 | 2002-05-16 | Bridgestone Corporation | Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents |
DE10135314A1 (de) * | 2001-07-19 | 2003-01-30 | Bayer Ag | Aufarbeitung von Polymersyntheselösungen |
US9226876B2 (en) | 2001-10-19 | 2016-01-05 | The Goodyear Tire & Rubber Company | Rubber for baby bottle nipples, pacifiers, and syringe plungers |
US6871751B2 (en) * | 2001-10-19 | 2005-03-29 | The Goodyear Tire & Rubber Company | Rubber for baby bottle nipples, pacifiers, & syringe plungers |
US6699813B2 (en) | 2001-11-07 | 2004-03-02 | Bridgestone Corporation | Lanthanide-based catalyst composition for the manufacture of polydienes |
US6780948B2 (en) | 2002-03-28 | 2004-08-24 | The Goodyear Tire & Rubber Company | Synthesis of polyisoprene with neodymium catalyst |
US7008899B2 (en) * | 2003-08-11 | 2006-03-07 | Bridgestone Corporation | Lanthanide-based catalyst composition for producing cis-1,4-polydienes |
US7094849B2 (en) * | 2003-12-15 | 2006-08-22 | Bridgestone Corporation | Bulk polymerization process for producing polydienes |
US7091150B2 (en) * | 2003-12-19 | 2006-08-15 | The Goodyear Tire & Rubber Company | Synthetic polyisoprene rubber |
JP5111101B2 (ja) | 2004-03-02 | 2012-12-26 | 株式会社ブリヂストン | バルク重合プロセス |
DE102004022676A1 (de) * | 2004-05-07 | 2005-12-15 | Bayer Ag | Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen |
JP4294011B2 (ja) * | 2004-07-21 | 2009-07-08 | 日信工業株式会社 | 炭素系材料及びその製造方法、複合材料の製造方法 |
JP4279220B2 (ja) * | 2004-09-09 | 2009-06-17 | 日信工業株式会社 | 複合材料及びその製造方法、複合金属材料及びその製造方法 |
US7879952B2 (en) * | 2005-12-28 | 2011-02-01 | Bridgestone Corporation | Functionalized polymers |
US7671138B2 (en) * | 2006-05-26 | 2010-03-02 | Bridgestone Corporation | Polymers functionized with hydrobenzamides |
US20080006833A1 (en) * | 2006-06-02 | 2008-01-10 | Semiconductor Energy Laboratory Co., Ltd. | Lighting device and liquid crystal display device |
JP2007323544A (ja) * | 2006-06-05 | 2007-12-13 | Sony Corp | 情報処理システム、情報処理装置、および方法、並びにコンピュータ・プログラム |
US7795354B2 (en) | 2006-06-16 | 2010-09-14 | Georgia-Pacific Chemicals Llc | Formaldehyde free binder |
US7732534B2 (en) * | 2006-08-28 | 2010-06-08 | Bridgestone Corporation | Polymers functionalized with nitro compounds |
US8088868B2 (en) | 2006-12-19 | 2012-01-03 | Bridgestone Corporation | Polymers functionalized with protected oxime compounds |
US7879958B2 (en) * | 2007-08-07 | 2011-02-01 | Bridgestone Corporation | Polyhydroxy compounds as polymerization quenching agents |
US7741418B2 (en) * | 2007-12-31 | 2010-06-22 | Bridgestone Corporation | Process for producing polydienes |
US8268933B2 (en) * | 2007-12-31 | 2012-09-18 | Bridgestone Corporation | Polymers functionalized with polyimine compounds |
US7825201B2 (en) * | 2007-12-31 | 2010-11-02 | Bridgestone Corporation | Process for producing polydienes |
JP5345835B2 (ja) * | 2007-12-31 | 2013-11-20 | 株式会社ブリヂストン | ポリジエンの製造のためのバルク重合法 |
US7807763B2 (en) * | 2008-04-07 | 2010-10-05 | Bridgestone Corporation | Method for bulk polymerization |
US7906592B2 (en) * | 2008-07-03 | 2011-03-15 | Bridgestone Corporation | Polymers functionalized with imide compounds containing a protected amino group |
US8188195B2 (en) | 2008-12-31 | 2012-05-29 | Bridgestone Corporation | Polymers functionalized with nitroso compounds |
KR101682733B1 (ko) | 2009-01-23 | 2016-12-05 | 가부시키가이샤 브리지스톤 | 보호된 아미노기를 함유하는 니트릴 화합물로 관능화된 중합체 |
RU2543165C2 (ru) | 2009-01-23 | 2015-02-27 | Бриджстоун Корпорейшн | Полимеры, функционализированные полицианосоединениями |
US7902309B2 (en) | 2009-02-23 | 2011-03-08 | Bridgestone Corporation | Process and catalyst system for polydiene production |
FR2944800B1 (fr) * | 2009-04-28 | 2012-10-26 | Michelin Soc Tech | Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues |
US8623975B2 (en) | 2009-06-24 | 2014-01-07 | Bridgestone Corporation | Process for producing polydienes |
KR101762461B1 (ko) | 2009-10-14 | 2017-07-27 | 가부시키가이샤 브리지스톤 | 환식 비환식 디엔 공중합체의 제조 방법 및 고무 조성물 |
US8338544B2 (en) * | 2009-12-21 | 2012-12-25 | Bridgestone Corporation | Polymers functionalized with polyoxime compounds and methods for their manufacture |
RU2692101C2 (ru) | 2010-09-23 | 2019-06-21 | Бриджстоун Корпорейшн | Способ получения полидиенов |
US8748531B2 (en) | 2010-12-10 | 2014-06-10 | Bridgestone Corporation | Polymers functionalized with oxime compounds containing an acyl group |
US9000107B2 (en) | 2011-01-31 | 2015-04-07 | Bridgestone Corporation | Process for producing polydienes |
US8962766B2 (en) | 2011-09-15 | 2015-02-24 | Bridgestone Corporation | Polymers functionalized with polyhydrazone compounds |
EP2780381B1 (en) | 2011-11-17 | 2015-10-07 | Bridgestone Corporation | Process for producing polydienes |
EP2820054B1 (en) | 2012-02-27 | 2017-04-05 | Bridgestone Corporation | Processes for the preparation of high-cis polydienes |
US9694629B1 (en) | 2012-02-29 | 2017-07-04 | Carolyn Dry | Self-repairing inflatable articles incorporating an integrated self-repair system |
US8685513B1 (en) | 2012-02-29 | 2014-04-01 | Carolyn M. Dry | Inflatable articles comprising a self-repairing laminate |
EP2825574B1 (en) | 2012-03-14 | 2016-02-24 | Bridgestone Corporation | Process for producing polydienes |
JP6069044B2 (ja) * | 2013-03-12 | 2017-01-25 | 住友ゴム工業株式会社 | ベーストレッド用ゴム組成物及び空気入りタイヤ |
CN105814132A (zh) | 2013-12-03 | 2016-07-27 | 株式会社普利司通 | 用于制备顺式-1,4-聚丁二烯和间同立构1,2-聚丁二烯的共混物的方法 |
TWI522378B (zh) | 2013-12-13 | 2016-02-21 | 奇美實業股份有限公司 | 改質的高順式丁二烯-異戊二烯系共聚物、其製造方法及含有前述聚合物的輪胎 |
TWI508979B (zh) | 2013-12-18 | 2015-11-21 | Chi Mei Corp | 改質的高順式異戊二烯聚合物、其製造方法及含有前述聚合物的輪胎 |
CN107001522A (zh) | 2014-10-10 | 2017-08-01 | 株式会社普利司通 | 聚合催化剂组合物及采用聚合催化剂组合物的方法 |
CN104557994B (zh) * | 2014-12-15 | 2017-02-22 | 黑龙江大学 | 单分子磁体[Dy2(saph)2(NO3)2(CH3OH)4]的制备方法 |
EP3237526B1 (en) | 2014-12-23 | 2022-05-18 | Bridgestone Americas Tire Operations, LLC | Tire comprising an oil-containing rubber composition |
US10202474B2 (en) | 2015-09-11 | 2019-02-12 | Bridgestone Corporation | Process for producing polydienes |
US10730985B2 (en) | 2016-12-19 | 2020-08-04 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
EP3724244B1 (en) | 2017-12-15 | 2024-02-21 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
WO2019133633A1 (en) | 2017-12-30 | 2019-07-04 | Bridgestone Corporation | Composition including multiple terminally functionalized polymers |
US11767388B1 (en) | 2019-09-18 | 2023-09-26 | The Goodyear Tire & Rubber Company | Silicon-functionalized rubber |
EP3838932B1 (en) | 2019-12-20 | 2022-08-10 | The Goodyear Tire & Rubber Company | Synthesis of isoprene-butadiene copolymer rubbers |
US11584808B2 (en) | 2019-12-30 | 2023-02-21 | Bridgestone Corporation | Polymerization catalyst composition and method of employing same |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3094514A (en) * | 1958-02-13 | 1963-06-18 | Goodrich Gulf Chem Inc | Polymerization process for aliphatic, conjugated dienes |
BE549910A (US20110009641A1-20110113-C00116.png) * | 1955-07-29 | 1900-01-01 | ||
GB865248A (en) * | 1956-12-28 | 1961-04-12 | Hoechst Ag | Process for the polymerisation of olefines |
AT213051B (de) * | 1958-04-24 | 1961-01-25 | Montedison Spa | Verfahren zum Polymerisieren von Diolefinen mit wenigstens einer Vinyldoppelbindung |
NL257560A (US20110009641A1-20110113-C00116.png) * | 1959-11-18 | |||
FR1281516A (fr) * | 1959-12-31 | 1962-01-12 | Bridgestone Tire Co Ltd | Procédé de préparation de cis-1, 4 polybutadiène et catalyseur pour sa mise en oeuvre et produits obtenus |
-
1963
- 1963-02-28 US US261875A patent/US3297667A/en not_active Expired - Lifetime
-
1964
- 1964-02-11 GB GB5595/64A patent/GB1061002A/en not_active Expired
- 1964-02-25 BE BE644291D patent/BE644291A/xx unknown
- 1964-02-26 DE DE19641542529 patent/DE1542529A1/de active Pending
- 1964-02-26 FR FR965269A patent/FR1390509A/fr not_active Expired
- 1964-02-26 DE DE19641302264D patent/DE1302264B/de active Pending
- 1964-02-28 NL NL6401996A patent/NL6401996A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
GB1061002A (en) | 1967-03-08 |
FR1390509A (fr) | 1965-02-26 |
BE644291A (US20110009641A1-20110113-C00116.png) | 1964-06-15 |
US3297667A (en) | 1967-01-10 |
NL6401996A (US20110009641A1-20110113-C00116.png) | 1964-08-31 |
DE1302264B (US20110009641A1-20110113-C00116.png) | 1970-11-12 |
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