DE1263768B - Vorrichtung zur Durchfuehrung elektrochemischer Reaktionen organischer Verbindungen mit stroemendem Elektrolyten - Google Patents
Vorrichtung zur Durchfuehrung elektrochemischer Reaktionen organischer Verbindungen mit stroemendem ElektrolytenInfo
- Publication number
- DE1263768B DE1263768B DEB82757A DEB0082757A DE1263768B DE 1263768 B DE1263768 B DE 1263768B DE B82757 A DEB82757 A DE B82757A DE B0082757 A DEB0082757 A DE B0082757A DE 1263768 B DE1263768 B DE 1263768B
- Authority
- DE
- Germany
- Prior art keywords
- electrodes
- electrolyte
- electrolysis
- electrochemical reactions
- organic compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003792 electrolyte Substances 0.000 title claims description 25
- 238000003487 electrochemical reaction Methods 0.000 title claims description 10
- 150000002894 organic compounds Chemical class 0.000 title claims description 6
- 239000007788 liquid Substances 0.000 claims 1
- 238000005868 electrolysis reaction Methods 0.000 description 19
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 description 15
- 239000011541 reaction mixture Substances 0.000 description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- 229940116351 sebacate Drugs 0.000 description 5
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010349 cathodic reaction Methods 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 239000011133 lead Substances 0.000 description 3
- HWLDNSXPUQTBOD-UHFFFAOYSA-N platinum-iridium alloy Chemical compound [Ir].[Pt] HWLDNSXPUQTBOD-UHFFFAOYSA-N 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- ALOUNLDAKADEEB-UHFFFAOYSA-N dimethyl sebacate Chemical compound COC(=O)CCCCCCCCC(=O)OC ALOUNLDAKADEEB-UHFFFAOYSA-N 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010626 work up procedure Methods 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 238000006612 Kolbe reaction Methods 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229910000978 Pb alloy Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910001007 Tl alloy Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- LJPPDESLSQOQIO-UHFFFAOYSA-N [Hg].[Pb] Chemical compound [Hg].[Pb] LJPPDESLSQOQIO-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 150000008365 aromatic ketones Chemical class 0.000 description 1
- 125000003118 aryl group Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000003857 carboxamides Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 229940014772 dimethyl sebacate Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010411 electrocatalyst Substances 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- HCWMUANODLPMEO-UHFFFAOYSA-M ethyl sulfate;tetraethylazanium Chemical compound CCOS([O-])(=O)=O.CC[N+](CC)(CC)CC HCWMUANODLPMEO-UHFFFAOYSA-M 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- JGJWEFUHPCKRIJ-UHFFFAOYSA-M methyl sulfate;tetramethylazanium Chemical compound C[N+](C)(C)C.COS([O-])(=O)=O JGJWEFUHPCKRIJ-UHFFFAOYSA-M 0.000 description 1
- UOBSVARXACCLLH-UHFFFAOYSA-N monomethyl adipate Chemical compound COC(=O)CCCCC(O)=O UOBSVARXACCLLH-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- IAHFWCOBPZCAEA-UHFFFAOYSA-N succinonitrile Chemical compound N#CCCC#N IAHFWCOBPZCAEA-UHFFFAOYSA-N 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- OACODUCFPHHCIH-SANMLTNESA-N tert-butyl (2s)-2-[[4-amino-3-[2-(4-hydroxyphenyl)ethyl]benzoyl]amino]-4-phenylbutanoate Chemical compound C([C@@H](C(=O)OC(C)(C)C)NC(=O)C=1C=C(CCC=2C=CC(O)=CC=2)C(N)=CC=1)CC1=CC=CC=C1 OACODUCFPHHCIH-SANMLTNESA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/30—Cells comprising movable electrodes, e.g. rotary electrodes; Assemblies of constructional parts thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/06—Detection or inhibition of short circuits in the cell
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/29—Coupling reactions
- C25B3/295—Coupling reactions hydrodimerisation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Hybrid Cells (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB82757A DE1263768B (de) | 1965-07-09 | 1965-07-09 | Vorrichtung zur Durchfuehrung elektrochemischer Reaktionen organischer Verbindungen mit stroemendem Elektrolyten |
| DEB85386A DE1298087B (de) | 1965-07-09 | 1966-01-13 | Vorrichtung zur Durchfuehrung elektrochemischer Reaktionen |
| LU51508A LU51508A1 (enExample) | 1965-07-09 | 1966-07-07 | |
| NL6609554A NL6609554A (enExample) | 1965-07-09 | 1966-07-07 | |
| CH993266A CH475031A (de) | 1965-07-09 | 1966-07-08 | Vorrichtung zur Durchführung elektrochemischer Reaktionen |
| US563794A US3511765A (en) | 1965-07-09 | 1966-07-08 | Carrying out electrochemical reactions |
| GB30712/66A GB1145539A (en) | 1965-07-09 | 1966-07-08 | Carrying out electrochemical reactions |
| AT656966A AT274748B (de) | 1965-07-09 | 1966-07-08 | Vorrichtung zur Durchführung elektrochemischer Reaktionen und Verwendung derselben für die elektrochemische Hydrodimerisierung von Acrylnitril |
| FR68877A FR1486561A (fr) | 1965-07-09 | 1966-07-09 | Dispositif et procédé pour la mise en oeuvre des réactions électrochimiques |
| ES0328915A ES328915A1 (es) | 1965-07-09 | 1966-07-09 | Dispositivo para la realizacion de reacciones electroquimicas. |
| BE683934D BE683934A (enExample) | 1965-07-09 | 1966-07-11 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB82757A DE1263768B (de) | 1965-07-09 | 1965-07-09 | Vorrichtung zur Durchfuehrung elektrochemischer Reaktionen organischer Verbindungen mit stroemendem Elektrolyten |
| DEB85386A DE1298087B (de) | 1965-07-09 | 1966-01-13 | Vorrichtung zur Durchfuehrung elektrochemischer Reaktionen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1263768B true DE1263768B (de) | 1968-03-21 |
Family
ID=25967600
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB82757A Pending DE1263768B (de) | 1965-07-09 | 1965-07-09 | Vorrichtung zur Durchfuehrung elektrochemischer Reaktionen organischer Verbindungen mit stroemendem Elektrolyten |
| DEB85386A Pending DE1298087B (de) | 1965-07-09 | 1966-01-13 | Vorrichtung zur Durchfuehrung elektrochemischer Reaktionen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB85386A Pending DE1298087B (de) | 1965-07-09 | 1966-01-13 | Vorrichtung zur Durchfuehrung elektrochemischer Reaktionen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3511765A (enExample) |
| AT (1) | AT274748B (enExample) |
| BE (1) | BE683934A (enExample) |
| CH (1) | CH475031A (enExample) |
| DE (2) | DE1263768B (enExample) |
| ES (1) | ES328915A1 (enExample) |
| FR (1) | FR1486561A (enExample) |
| GB (1) | GB1145539A (enExample) |
| LU (1) | LU51508A1 (enExample) |
| NL (1) | NL6609554A (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3887442A (en) * | 1970-11-23 | 1975-06-03 | Scm Corp | Polymerization process |
| US3844911A (en) * | 1972-07-27 | 1974-10-29 | Phillips Petroleum Co | Method for producing adiponitrile |
| FR2208876B2 (enExample) * | 1972-12-01 | 1976-06-04 | Rhone Poulenc Ind | |
| US3897318A (en) * | 1973-08-06 | 1975-07-29 | Monsanto Co | Single-compartment electrolytic hydrodimerization process |
| DE2343054C2 (de) * | 1973-08-25 | 1975-10-09 | Basf Ag, 6700 Ludwigshafen | Verfahren zur elektrochemischen Herstellung von Pinacolen |
| US3960679A (en) * | 1974-08-15 | 1976-06-01 | Monsanto Company | Process for hydrodimerizing olefinic compounds |
| DE2711005C3 (de) * | 1977-03-14 | 1979-09-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur direkten und elektrolytischen Herstellung von metallfreien Phthalocyaninen |
| GB2098238B (en) * | 1981-05-07 | 1984-10-24 | Electricity Council | An electrochemical cell |
| EP0252172B1 (de) * | 1986-07-07 | 1989-02-08 | Deutsche Carbone AG | Elektrolyseverfahren |
| DE102013226357A1 (de) * | 2013-12-18 | 2015-06-18 | Siemens Aktiengesellschaft | Pulsierende Elektrolytzufuhr in den Reaktionsraum einer Elektrolysezelle mit gasentwickelnden Elektroden |
| DE102024200397A1 (de) | 2024-01-17 | 2025-07-17 | Robert Bosch Gesellschaft mit beschränkter Haftung | Betriebsverfahren zum Betreiben eines Elektrolysesystems und Elektrolysesystem |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA730231A (en) * | 1966-03-15 | Laurent Jean-Francois | Fuel cells | |
| US1225052A (en) * | 1915-12-31 | 1917-05-08 | Chem Ind Basel | Process of treating organic compounds by electrolysis. |
| NL18772C (enExample) * | 1925-06-17 | |||
| US2071260A (en) * | 1935-04-13 | 1937-02-16 | Holden Charles Revell | Apparatus for the separation of solids in liquid suspension |
| DE895761C (de) * | 1938-04-12 | 1953-11-05 | Rudolf Kuerth | Verfahren zur Elektrolyse, Elektroosmose oder Elektrophorese unter Schwingungserzeugung |
| US2816067A (en) * | 1955-05-03 | 1957-12-10 | Du Pont | Electrolytic drying method |
| US2919235A (en) * | 1956-11-06 | 1959-12-29 | Paul S Roller | Electrolytic method and apparatus for the production of metal hydroxide |
| US3342718A (en) * | 1964-01-21 | 1967-09-19 | William M Adams | Apparatus for the recovery of silver from used photographic fixing solutions by electrolysis |
| US3379634A (en) * | 1965-05-24 | 1968-04-23 | Air Force Usa | Zero gravity electrolysis apparatus |
-
1965
- 1965-07-09 DE DEB82757A patent/DE1263768B/de active Pending
-
1966
- 1966-01-13 DE DEB85386A patent/DE1298087B/de active Pending
- 1966-07-07 NL NL6609554A patent/NL6609554A/xx unknown
- 1966-07-07 LU LU51508A patent/LU51508A1/xx unknown
- 1966-07-08 AT AT656966A patent/AT274748B/de active
- 1966-07-08 CH CH993266A patent/CH475031A/de not_active IP Right Cessation
- 1966-07-08 GB GB30712/66A patent/GB1145539A/en not_active Expired
- 1966-07-08 US US563794A patent/US3511765A/en not_active Expired - Lifetime
- 1966-07-09 FR FR68877A patent/FR1486561A/fr not_active Expired
- 1966-07-09 ES ES0328915A patent/ES328915A1/es not_active Expired
- 1966-07-11 BE BE683934D patent/BE683934A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH475031A (de) | 1969-07-15 |
| NL6609554A (enExample) | 1967-01-10 |
| DE1298087B (de) | 1969-06-26 |
| GB1145539A (en) | 1969-03-19 |
| AT274748B (de) | 1969-09-25 |
| BE683934A (enExample) | 1967-01-11 |
| US3511765A (en) | 1970-05-12 |
| ES328915A1 (es) | 1967-04-16 |
| LU51508A1 (enExample) | 1966-09-07 |
| FR1486561A (fr) | 1967-06-30 |
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