DE1193971B - Thermographisches Kopierpapier - Google Patents
Thermographisches KopierpapierInfo
- Publication number
- DE1193971B DE1193971B DEM34572A DEM0034572A DE1193971B DE 1193971 B DE1193971 B DE 1193971B DE M34572 A DEM34572 A DE M34572A DE M0034572 A DEM0034572 A DE M0034572A DE 1193971 B DE1193971 B DE 1193971B
- Authority
- DE
- Germany
- Prior art keywords
- acid
- heat
- sensitive
- reagents
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010410 layer Substances 0.000 claims description 26
- 239000003638 chemical reducing agent Substances 0.000 claims description 12
- 239000003153 chemical reaction reagent Substances 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 10
- 150000007524 organic acids Chemical class 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910000510 noble metal Inorganic materials 0.000 claims description 5
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 239000002356 single layer Substances 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 claims 1
- 238000006731 degradation reaction Methods 0.000 claims 1
- 229910021645 metal ion Inorganic materials 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 12
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 10
- 229910052709 silver Inorganic materials 0.000 description 10
- 239000004332 silver Substances 0.000 description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 9
- 230000008859 change Effects 0.000 description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 229940116226 behenic acid Drugs 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 229920005990 polystyrene resin Polymers 0.000 description 7
- 238000007639 printing Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 7
- YQUVCSBJEUQKSH-UHFFFAOYSA-N 3,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(O)=C1 YQUVCSBJEUQKSH-UHFFFAOYSA-N 0.000 description 6
- 235000021357 Behenic acid Nutrition 0.000 description 6
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 230000002035 prolonged effect Effects 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- GLDQAMYCGOIJDV-UHFFFAOYSA-N 2,3-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(O)=C1O GLDQAMYCGOIJDV-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- FBSFWRHWHYMIOG-UHFFFAOYSA-N methyl 3,4,5-trihydroxybenzoate Chemical compound COC(=O)C1=CC(O)=C(O)C(O)=C1 FBSFWRHWHYMIOG-UHFFFAOYSA-N 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- -1 undecylene Chemical group 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 230000033458 reproduction Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LBUJPTNKIBCYBY-UHFFFAOYSA-N 1,2,3,4-tetrahydroquinoline Chemical compound C1=CC=C2CCCNC2=C1 LBUJPTNKIBCYBY-UHFFFAOYSA-N 0.000 description 2
- 229940082044 2,3-dihydroxybenzoic acid Drugs 0.000 description 2
- WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 2
- CFFZDZCDUFSOFZ-UHFFFAOYSA-N 3,4-Dihydroxy-phenylacetic acid Chemical compound OC(=O)CC1=CC=C(O)C(O)=C1 CFFZDZCDUFSOFZ-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- GHKJXEICAPOWQS-UHFFFAOYSA-K [Au+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O Chemical compound [Au+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O GHKJXEICAPOWQS-UHFFFAOYSA-K 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 239000003613 bile acid Substances 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- KBPUBCVJHFXPOC-UHFFFAOYSA-N ethyl 3,4-dihydroxybenzoate Chemical compound CCOC(=O)C1=CC=C(O)C(O)=C1 KBPUBCVJHFXPOC-UHFFFAOYSA-N 0.000 description 2
- VFPFQHQNJCMNBZ-UHFFFAOYSA-N ethyl gallate Chemical compound CCOC(=O)C1=CC(O)=C(O)C(O)=C1 VFPFQHQNJCMNBZ-UHFFFAOYSA-N 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- IBKQQKPQRYUGBJ-UHFFFAOYSA-N methyl gallate Natural products CC(=O)C1=CC(O)=C(O)C(O)=C1 IBKQQKPQRYUGBJ-UHFFFAOYSA-N 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 150000003378 silver Chemical class 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- CVYDEWKUJFCYJO-UHFFFAOYSA-M sodium;docosanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O CVYDEWKUJFCYJO-UHFFFAOYSA-M 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- HSINOMROUCMIEA-FGVHQWLLSA-N (2s,4r)-4-[(3r,5s,6r,7r,8s,9s,10s,13r,14s,17r)-6-ethyl-3,7-dihydroxy-10,13-dimethyl-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1h-cyclopenta[a]phenanthren-17-yl]-2-methylpentanoic acid Chemical compound C([C@@]12C)C[C@@H](O)C[C@H]1[C@@H](CC)[C@@H](O)[C@@H]1[C@@H]2CC[C@]2(C)[C@@H]([C@H](C)C[C@H](C)C(O)=O)CC[C@H]21 HSINOMROUCMIEA-FGVHQWLLSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- XIROXSOOOAZHLL-UHFFFAOYSA-N 2',3',4'-Trihydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C(O)=C1O XIROXSOOOAZHLL-UHFFFAOYSA-N 0.000 description 1
- ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 description 1
- YRNWIFYIFSBPAU-UHFFFAOYSA-N 4-[4-(dimethylamino)phenyl]-n,n-dimethylaniline Chemical compound C1=CC(N(C)C)=CC=C1C1=CC=C(N(C)C)C=C1 YRNWIFYIFSBPAU-UHFFFAOYSA-N 0.000 description 1
- KVOJTUXGYQVLAJ-UHFFFAOYSA-N 6,7-dihydroxy-4-methylcoumarin Chemical compound C1=C(O)C(O)=CC2=C1OC(=O)C=C2C KVOJTUXGYQVLAJ-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 241000251730 Chondrichthyes Species 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- RPWFJAMTCNSJKK-UHFFFAOYSA-N Dodecyl gallate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 RPWFJAMTCNSJKK-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000004262 Ethyl gallate Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229940088990 ammonium stearate Drugs 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 1
- UQTCSFPVHNDUOG-UHFFFAOYSA-N azanium 4-carboxy-2,6-dihydroxyphenolate Chemical compound [NH4+].OC(=O)C1=CC(O)=C([O-])C(O)=C1 UQTCSFPVHNDUOG-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 1
- 210000000941 bile Anatomy 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- XOPOEBVTQYAOSV-UHFFFAOYSA-N butyl 3,4,5-trihydroxybenzoate Chemical compound CCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 XOPOEBVTQYAOSV-UHFFFAOYSA-N 0.000 description 1
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
- 239000000555 dodecyl gallate Substances 0.000 description 1
- 235000010386 dodecyl gallate Nutrition 0.000 description 1
- 229940080643 dodecyl gallate Drugs 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 235000019277 ethyl gallate Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- JYGYEBCBALMPDC-UHFFFAOYSA-N heptane;propan-2-one Chemical compound CC(C)=O.CCCCCCC JYGYEBCBALMPDC-UHFFFAOYSA-N 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 229910001721 mellite Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical group C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- JRNGUTKWMSBIBF-UHFFFAOYSA-N naphthalene-2,3-diol Chemical compound C1=CC=C2C=C(O)C(O)=CC2=C1 JRNGUTKWMSBIBF-UHFFFAOYSA-N 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- TXGSOSAONMOPDL-UHFFFAOYSA-N propan-2-yl 3,4,5-trihydroxybenzoate Chemical compound CC(C)OC(=O)C1=CC(O)=C(O)C(O)=C1 TXGSOSAONMOPDL-UHFFFAOYSA-N 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- MMLCSDNEYQRUDM-UHFFFAOYSA-M silver;docosanoate;docosanoic acid Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O MMLCSDNEYQRUDM-UHFFFAOYSA-M 0.000 description 1
- ORYURPRSXLUCSS-UHFFFAOYSA-M silver;octadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCC([O-])=O ORYURPRSXLUCSS-UHFFFAOYSA-M 0.000 description 1
- FZHLWVUAICIIPW-UHFFFAOYSA-M sodium gallate Chemical compound [Na+].OC1=CC(C([O-])=O)=CC(O)=C1O FZHLWVUAICIIPW-UHFFFAOYSA-M 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000007651 thermal printing Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
- G03C1/4989—Photothermographic systems, e.g. dry silver characterised by a thermal imaging step, with or without exposure to light, e.g. with a thermal head, using a laser
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/913—Material designed to be responsive to temperature, light, moisture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/165—Thermal imaging composition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
- Y10T428/31884—Regenerated or modified cellulose
- Y10T428/31888—Addition polymer of hydrocarbon[s] only
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Color Printing (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US594540A US2910377A (en) | 1956-06-28 | 1956-06-28 | Heat-sensitive copying-paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1193971B true DE1193971B (de) | 1965-06-03 |
Family
ID=24379309
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEM34572A Pending DE1193971B (de) | 1956-06-28 | 1957-06-27 | Thermographisches Kopierpapier |
| DEM58359A Pending DE1232991B (de) | 1956-06-28 | 1957-06-27 | Thermographisches Kopierpapier |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEM58359A Pending DE1232991B (de) | 1956-06-28 | 1957-06-27 | Thermographisches Kopierpapier |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US2910377A (enrdf_load_stackoverflow) |
| BE (1) | BE558766A (enrdf_load_stackoverflow) |
| CH (1) | CH364800A (enrdf_load_stackoverflow) |
| DE (2) | DE1193971B (enrdf_load_stackoverflow) |
| FR (1) | FR1200724A (enrdf_load_stackoverflow) |
| GB (1) | GB866076A (enrdf_load_stackoverflow) |
| NL (2) | NL106780C (enrdf_load_stackoverflow) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3028255A (en) * | 1956-06-28 | 1962-04-03 | Minnesota Mining & Mfg | Heat-sensitive copy-sheet |
| NL241300A (enrdf_load_stackoverflow) * | 1958-07-15 | |||
| DE1109712B (de) * | 1958-08-09 | 1961-06-29 | Kalle Ag | Kopierschichten zur Herstellung von Bildern durch Waerme |
| FR1238083A (fr) * | 1958-10-20 | 1960-08-05 | Minnesota Mining & Mfg | Feuille copiante pour thermographie |
| US3103881A (en) * | 1958-10-20 | 1963-09-17 | Minnesota Mining & Mfg | Method of copying |
| US3088028A (en) * | 1959-02-06 | 1963-04-30 | Columbia Ribbon & Carbon | Duplication with heat-meltable solvent for hectographic coloring material |
| BE588328A (enrdf_load_stackoverflow) * | 1959-04-21 | |||
| NL252087A (enrdf_load_stackoverflow) * | 1959-05-28 | |||
| US3073953A (en) * | 1959-07-29 | 1963-01-15 | Du Pont | Process for producing images |
| US3028254A (en) * | 1959-09-21 | 1962-04-03 | Minnesota Mining & Mfg | Stabilized chemically reactive heatsensitive copy-sheet |
| US3074809A (en) * | 1959-10-26 | 1963-01-22 | Minnesota Mining & Mfg | Heat-sensitive copying-paper |
| US3108896A (en) * | 1959-10-26 | 1963-10-29 | Minnesota Mining & Mfg | Heat-sensitive copying-paper |
| US3080254A (en) * | 1959-10-26 | 1963-03-05 | Minnesota Mining & Mfg | Heat-sensitive copying-paper |
| US3031329A (en) * | 1959-10-26 | 1962-04-24 | Minnesota Mining & Mfg | Heat-sensitive copy-sheet and composition therefor |
| US3109748A (en) * | 1960-04-28 | 1963-11-05 | Columbia Ribbon & Carbon | Thermographic reproduction composite wherein a calcium carbonate layer is effected by a transferred heat-sensitive material |
| US3111423A (en) * | 1960-05-16 | 1963-11-19 | Minnesota Mining & Mfg | Heat-sensitive copy-sheet |
| US3315598A (en) * | 1960-07-28 | 1967-04-25 | Minnesota Mining & Mfg | Copying of graphic originals |
| NL273128A (enrdf_load_stackoverflow) * | 1961-01-03 | |||
| BE612241A (enrdf_load_stackoverflow) * | 1961-01-03 | 1900-01-01 | ||
| US3090697A (en) * | 1961-02-13 | 1963-05-21 | Nashua Corp | Heat sensitive marking papers and methods for making same |
| US3241997A (en) * | 1961-12-23 | 1966-03-22 | Schutzner Walter | Heat-sensitive copying material |
| US3161770A (en) * | 1962-03-20 | 1964-12-15 | Dietzgen Co Eugene | Thermographic reproduction paper and method of using |
| US3162763A (en) * | 1962-04-05 | 1964-12-22 | Dietzgen Co Eugene | Thermographic reproduction paper, method of making and method of using |
| US3167651A (en) * | 1962-05-15 | 1965-01-26 | Dietzgen Co Eugene | Thermographic reproduction paper and method of making and using |
| US3174038A (en) * | 1962-06-18 | 1965-03-16 | Dietzgen Co Eugene | Thermographic reproduction paper and method of using |
| DE1250842B (de) * | 1962-11-23 | 1967-09-28 | Minnesota Mining and Manufacturing Company, Saint Paul, Minn. (V. St. A.) | Wärmeempfindliches Kopiermaterial |
| US3394042A (en) * | 1963-09-13 | 1968-07-23 | Minnesota Mining & Mfg | Heat-sensitive copy-sheet |
| DE1249295B (de) * | 1964-07-17 | 1967-09-07 | General Company Limited, Osakashi (Japan) | Thermokopierblatt |
| GB1124756A (en) * | 1964-11-28 | 1968-08-21 | Kodak Ltd | Photographic reproduction |
| US3446648A (en) * | 1965-09-27 | 1969-05-27 | Minnesota Mining & Mfg | Reactive copying sheet and method of using |
| US3460946A (en) * | 1966-02-03 | 1969-08-12 | Minnesota Mining & Mfg | Image receptor sheets containing organic silver salts and metal ion image |
| US3632377A (en) * | 1969-01-06 | 1972-01-04 | Minnesota Mining & Mfg | Image transfer sheet and method |
| GB1330984A (en) * | 1970-09-28 | 1973-09-19 | Fuji Photo Film Co Ltd | Colour-developer compositions |
| US3934070A (en) * | 1970-10-23 | 1976-01-20 | Fuji Photo Film Co., Ltd. | Recording sheet and color developer therefor |
| DE2440678C2 (de) * | 1974-08-24 | 1983-10-20 | Agfa-Gevaert Ag, 5090 Leverkusen | Thermophotographisches Aufzeichnungsmmaterial |
| US4232083A (en) * | 1975-07-22 | 1980-11-04 | Minnesota Mining And Manufacturing Company | Imaging compositions and methods |
| US4109937A (en) * | 1976-01-30 | 1978-08-29 | Trans World Technology Laboratories, Inc. (Twt Labs Inc.) | Donor sheet for thermographic imaging process |
| JPS5323635A (en) * | 1976-08-18 | 1978-03-04 | Fuji Photo Film Co Ltd | Conductive formation material an d its conductive picture recording method |
| US4379835A (en) * | 1980-12-22 | 1983-04-12 | Minnesota Mining And Manufacturing Company | Black image from a thermographic imaging system |
| US4461496A (en) * | 1982-08-17 | 1984-07-24 | Minnesota Mining And Manufacturing Company | Soap having improved carbonless imaging properties |
| US4604635A (en) * | 1984-11-08 | 1986-08-05 | Intermec Corporation | Thermal paper and method for making thermal paper with silicone resin protective layer |
| JPS61173987A (ja) * | 1985-01-30 | 1986-08-05 | Sugai Kagaku Kogyo Kk | 熱転写記録体 |
| US4741992A (en) * | 1986-09-22 | 1988-05-03 | Eastman Kodak Company | Thermally processable element comprising an overcoat layer containing poly(silicic acid) |
| US5210245A (en) * | 1990-12-10 | 1993-05-11 | Mooney Chemicals, Inc. | Gold carboxylates and process for preparing the same |
| US5275932A (en) * | 1992-03-16 | 1994-01-04 | Minnesota Mining And Manufacturing Company | Thermal development accelerators for thermographic materials |
| DE69427635T2 (de) * | 1994-03-10 | 2002-05-08 | Agfa-Gevaert N.V., Mortsel | Thermotransferbilderzeugungsverfahren |
| EP0713133B1 (en) * | 1994-10-14 | 2001-05-16 | Agfa-Gevaert N.V. | Receiving element for use in thermal transfer printing |
| DE69520927T2 (de) * | 1994-10-14 | 2001-11-15 | Agfa-Gevaert N.V., Mortsel | Empfangselement für die thermische Farbstoffübertragung |
| US5578548A (en) * | 1995-10-16 | 1996-11-26 | Minnesota Mining & Manufacturing Company | Thermographic element with improved anti-stick coating |
| US6093529A (en) * | 1997-04-16 | 2000-07-25 | Fuji Photo Film Co., Ltd. | Imaging materials |
| EP0903628B1 (en) * | 1997-09-17 | 2004-07-07 | Agfa-Gevaert | Thermographic recording material with improved stability |
| JP4043663B2 (ja) | 1999-09-17 | 2008-02-06 | 富士フイルム株式会社 | 熱現像感光材料 |
| US6682878B2 (en) | 2000-12-05 | 2004-01-27 | Fuji Photo Film Co., Ltd. | Thermal development photosensitive material |
| JP2002287293A (ja) | 2001-03-23 | 2002-10-03 | Fuji Photo Film Co Ltd | 熱現像感光材料 |
| US7211373B2 (en) * | 2001-03-23 | 2007-05-01 | Fujifilm Corporation | Photothermographic material |
| US20030235795A1 (en) * | 2001-08-22 | 2003-12-25 | Fuji Photo Film Co., Ltd. | Photothermographic material |
| JP3930290B2 (ja) * | 2001-09-12 | 2007-06-13 | 富士フイルム株式会社 | 熱現像感光材料及びそれを用いた熱現像方法 |
| JP3922904B2 (ja) | 2001-10-05 | 2007-05-30 | 富士フイルム株式会社 | 熱現像感光材料 |
| JP2003121961A (ja) | 2001-10-19 | 2003-04-23 | Fuji Photo Film Co Ltd | 熱現像感光材料 |
| JP2004064704A (ja) * | 2002-07-31 | 2004-02-26 | Fuji Photo Film Co Ltd | 熱現像記録装置のシェーディング補正方法及び熱現像記録装置 |
| AU2003283560A1 (en) * | 2002-11-12 | 2004-06-03 | Sherwood Technology Limited | Use of transition metal compounds in imageable coatings |
| JP2005063838A (ja) * | 2003-08-13 | 2005-03-10 | Toshiba Matsushita Display Technology Co Ltd | 光学デバイス及び有機ｅｌ表示装置 |
| US20050231585A1 (en) * | 2004-03-02 | 2005-10-20 | Mudigonda Dhurjati S | Method and system for laser imaging utilizing low power lasers |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA552750A (en) * | 1947-05-10 | 1958-02-04 | Minnesota Mining And Manufacturing Company | Heat-sensitive copying-paper |
| CA535267A (en) * | 1952-05-15 | 1957-01-01 | Minnesota Mining And Manufacturing Company | Physical-mixture heat-sensitive copying-paper |
| US2663656A (en) * | 1952-05-15 | 1953-12-22 | Minnesota Mining & Mfg | Heat-sensitive copying paper |
| US2749253A (en) * | 1952-05-20 | 1956-06-05 | Dick Co Ab | Method of making a copy sheet and resultant article |
-
0
- BE BE558766D patent/BE558766A/xx unknown
- NL NL218538D patent/NL218538A/xx unknown
- NL NL106780D patent/NL106780C/xx active
-
1956
- 1956-06-28 US US594540A patent/US2910377A/en not_active Expired - Lifetime
-
1957
- 1957-06-27 DE DEM34572A patent/DE1193971B/de active Pending
- 1957-06-27 CH CH4775757A patent/CH364800A/de unknown
- 1957-06-27 DE DEM58359A patent/DE1232991B/de active Pending
- 1957-06-28 FR FR1200724D patent/FR1200724A/fr not_active Expired
- 1957-06-28 GB GB20589/57A patent/GB866076A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1200724A (fr) | 1959-12-23 |
| NL106780C (enrdf_load_stackoverflow) | 1900-01-01 |
| DE1232991B (de) | 1967-01-26 |
| CH364800A (de) | 1962-10-15 |
| GB866076A (en) | 1961-04-26 |
| NL218538A (enrdf_load_stackoverflow) | 1900-01-01 |
| US2910377A (en) | 1959-10-27 |
| BE558766A (enrdf_load_stackoverflow) | 1900-01-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1193971B (de) | Thermographisches Kopierpapier | |
| DE1200846B (de) | Thermographisches Kopiermaterial und Verfahren zur Herstellung waermebestaendiger Kopien hiermit | |
| US3080254A (en) | Heat-sensitive copying-paper | |
| DE1572203C3 (de) | Verfahren zur Herstellung eines wärmeentwickelbaren Blattmaterials mit einem strahlungsempfindlichen Überzug | |
| DE1234243B (de) | Waermeempfindliche Kopierblaetter | |
| DE1250842B (de) | Wärmeempfindliches Kopiermaterial | |
| DE1146078B (de) | Thermographisches Kopierblatt | |
| DE1200845B (de) | Waermeempfindliches Kopierblatt | |
| DE1249295B (de) | Thermokopierblatt | |
| DE1927412A1 (de) | Transparente lichtempfindliche durch Waerme entwickelbare Blattmaterialien mit durch Waerme transparent werdenden Antihaloschichten | |
| DE1109712B (de) | Kopierschichten zur Herstellung von Bildern durch Waerme | |
| DE1421471B2 (de) | Thermokopieverfahren | |
| DE1149730B (de) | Waermeempfindliches Kopierpapier | |
| US3108896A (en) | Heat-sensitive copying-paper | |
| DE2628103C3 (de) | Stromempfindliches Aufzeichnungsblatt und Verfahren zu seiner Herstellung | |
| DE2021432B2 (de) | Thermographisch farbentwickelbare zusammensetzung | |
| DE1572209C3 (de) | Bildempfangsblatt für Wärmeübertragungsverfahren | |
| DE2927094C2 (de) | Verfahren zum Beschichten von glatten Oberflächen mit einer thermochromen Schicht und Verwendung des Verfahrens | |
| DE1244205B (de) | Waermeempfindliches blattfoermiges Kopiermaterial und Verfahren zu dessen Herstellung | |
| DE1249891B (de) | Warmekopierverfahren | |
| DE2030868B2 (de) | Blattmaterial zur thermographischen herstellung von farb projektionsdurchsichtbildern | |
| DE1908758A1 (de) | Lichtempfindliches,in der Waerme entwickelbares Blatt- oder,Bahnenmaterial fuer Positiv-Verfahren | |
| DE1240097B (de) | Waermeempfindliches Kopierblatt | |
| DE2703378C2 (de) | Säurehaltiges Donorblatt für thermographische Aufzeichnungsverfahren und seine Verwendung zur Herstellung von Durchsichtsbildern | |
| DE1267961B (de) | Durch Druckeinwirkung aktivierbares, selbst bildlieferndes Papier oder sonstiges Bahnenmaterial |