DE1113212B - Verfahren zur Herstellung von festem, kristallinem Natrium-Ammonium-Salz der Caro'schen Saeure - Google Patents
Verfahren zur Herstellung von festem, kristallinem Natrium-Ammonium-Salz der Caro'schen SaeureInfo
- Publication number
- DE1113212B DE1113212B DED30861A DED0030861A DE1113212B DE 1113212 B DE1113212 B DE 1113212B DE D30861 A DED30861 A DE D30861A DE D0030861 A DED0030861 A DE D0030861A DE 1113212 B DE1113212 B DE 1113212B
- Authority
- DE
- Germany
- Prior art keywords
- sodium
- ammonium
- acid
- caro
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical compound OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 title claims description 15
- 239000007787 solid Substances 0.000 title claims description 7
- UPDATVKGFTVGQJ-UHFFFAOYSA-N sodium;azane Chemical compound N.[Na+] UPDATVKGFTVGQJ-UHFFFAOYSA-N 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims 10
- 238000004519 manufacturing process Methods 0.000 title description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 7
- 150000003388 sodium compounds Chemical class 0.000 claims description 7
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 5
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 5
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 4
- 239000004160 Ammonium persulphate Substances 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000001099 ammonium carbonate Substances 0.000 claims description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 4
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 3
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 238000001816 cooling Methods 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/06—Peroxyhydrates; Peroxyacids or salts thereof containing sulfur
- C01B15/08—Peroxysulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED30861A DE1113212B (de) | 1959-06-13 | 1959-06-13 | Verfahren zur Herstellung von festem, kristallinem Natrium-Ammonium-Salz der Caro'schen Saeure |
| CH1414765A CH438240A (de) | 1959-06-13 | 1960-05-13 | Verfahren zur Herstellung von festem, kristallinem Natrium-Ammonium-Salz der Caroschen Säure im Gemisch mit Natrium- und Ammoniumsulfat und Natrium- und Ammoniumbisulfat |
| CH552060A CH408880A (de) | 1959-06-13 | 1960-05-13 | Verfahren zur Herstellung von festem, kristallinem Natrium-Ammonium-Salz der Caro'schen Säure |
| NL252054A NL121167C (enrdf_load_stackoverflow) | 1959-06-13 | 1960-05-27 | |
| BE591685A BE591685A (fr) | 1959-06-13 | 1960-06-08 | Sel cristallin solide sodico-ammonique de l'acide monopersulfurique et procédé pour sa fabrication |
| FR829418A FR1266670A (fr) | 1959-06-13 | 1960-06-08 | Sel cristallin solide ammonio-sodé de l'acide de <caro> et son procédé de fabrication |
| GB2071360A GB940772A (en) | 1959-06-13 | 1960-06-13 | Solid crystalline sodium-ammonium salt of caro's acid and process for its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED30861A DE1113212B (de) | 1959-06-13 | 1959-06-13 | Verfahren zur Herstellung von festem, kristallinem Natrium-Ammonium-Salz der Caro'schen Saeure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1113212B true DE1113212B (de) | 1961-08-31 |
Family
ID=7040676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DED30861A Pending DE1113212B (de) | 1959-06-13 | 1959-06-13 | Verfahren zur Herstellung von festem, kristallinem Natrium-Ammonium-Salz der Caro'schen Saeure |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE591685A (enrdf_load_stackoverflow) |
| CH (2) | CH438240A (enrdf_load_stackoverflow) |
| DE (1) | DE1113212B (enrdf_load_stackoverflow) |
| FR (1) | FR1266670A (enrdf_load_stackoverflow) |
| GB (1) | GB940772A (enrdf_load_stackoverflow) |
| NL (1) | NL121167C (enrdf_load_stackoverflow) |
-
1959
- 1959-06-13 DE DED30861A patent/DE1113212B/de active Pending
-
1960
- 1960-05-13 CH CH1414765A patent/CH438240A/de unknown
- 1960-05-13 CH CH552060A patent/CH408880A/de unknown
- 1960-05-27 NL NL252054A patent/NL121167C/xx active
- 1960-06-08 BE BE591685A patent/BE591685A/fr unknown
- 1960-06-08 FR FR829418A patent/FR1266670A/fr not_active Expired
- 1960-06-13 GB GB2071360A patent/GB940772A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE591685A (fr) | 1960-10-03 |
| GB940772A (en) | 1963-11-06 |
| NL252054A (enrdf_load_stackoverflow) | 1964-02-25 |
| CH408880A (de) | 1966-03-15 |
| CH438240A (de) | 1967-06-30 |
| FR1266670A (fr) | 1961-07-17 |
| NL121167C (enrdf_load_stackoverflow) | 1966-09-15 |
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