DE102012022976A1 - Einsatz leitfähiger Polymere in Batterie-Elektroden - Google Patents

Einsatz leitfähiger Polymere in Batterie-Elektroden Download PDF

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Publication number
DE102012022976A1
DE102012022976A1 DE102012022976.3A DE102012022976A DE102012022976A1 DE 102012022976 A1 DE102012022976 A1 DE 102012022976A1 DE 102012022976 A DE102012022976 A DE 102012022976A DE 102012022976 A1 DE102012022976 A1 DE 102012022976A1
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DE
Germany
Prior art keywords
composition
complexes
polythiophene
lithium
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE102012022976.3A
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German (de)
English (en)
Inventor
Wilfried Lövenich
Lidiya Komsiyska
Eva-Maria Hammer
Daniela Ledwoch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ewe-Forschungszentrum fur Energietechnologie De
Heraeus Deutschland GmbH and Co KG
Original Assignee
Ewe-Forschungszentrum fur Energietechnologie E V
Heraeus Precious Metals GmbH and Co KG
EWE FORSCHUNGSZENTRUM fur ENERGIETECHNOLOGIE EV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ewe-Forschungszentrum fur Energietechnologie E V, Heraeus Precious Metals GmbH and Co KG, EWE FORSCHUNGSZENTRUM fur ENERGIETECHNOLOGIE EV filed Critical Ewe-Forschungszentrum fur Energietechnologie E V
Priority to DE102012022976.3A priority Critical patent/DE102012022976A1/de
Priority to US14/646,905 priority patent/US9722249B2/en
Priority to EP13802237.1A priority patent/EP2923401B1/en
Priority to KR1020157016034A priority patent/KR20150109336A/ko
Priority to CN201380061414.9A priority patent/CN104956523B/zh
Priority to JP2015543340A priority patent/JP6338590B2/ja
Priority to PCT/EP2013/003533 priority patent/WO2014079581A1/en
Priority to TW102142760A priority patent/TWI610489B/zh
Publication of DE102012022976A1 publication Critical patent/DE102012022976A1/de
Ceased legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/60Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602Polymers
    • H01M4/606Polymers containing aromatic main chain polymers
    • H01M4/608Polymers containing aromatic main chain polymers containing heterocyclic rings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/049Manufacturing of an active layer by chemical means
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/137Electrodes based on electro-active polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1397Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1399Processes of manufacture of electrodes based on electro-active polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Conductive Materials (AREA)
DE102012022976.3A 2012-11-26 2012-11-26 Einsatz leitfähiger Polymere in Batterie-Elektroden Ceased DE102012022976A1 (de)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE102012022976.3A DE102012022976A1 (de) 2012-11-26 2012-11-26 Einsatz leitfähiger Polymere in Batterie-Elektroden
US14/646,905 US9722249B2 (en) 2012-11-26 2013-11-22 Use of conductive polymers in battery electrodes
EP13802237.1A EP2923401B1 (en) 2012-11-26 2013-11-22 Electrode compositions comprising conductive polymers and method for their production
KR1020157016034A KR20150109336A (ko) 2012-11-26 2013-11-22 배터리 전극에서 전도성 고분자의 사용
CN201380061414.9A CN104956523B (zh) 2012-11-26 2013-11-22 导电聚合物在电池组电极中的用途
JP2015543340A JP6338590B2 (ja) 2012-11-26 2013-11-22 電池電極における導電性ポリマーの使用
PCT/EP2013/003533 WO2014079581A1 (en) 2012-11-26 2013-11-22 Use of conductive polymers in battery electrodes
TW102142760A TWI610489B (zh) 2012-11-26 2013-11-25 導電聚合物於電池電極的用途

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102012022976.3A DE102012022976A1 (de) 2012-11-26 2012-11-26 Einsatz leitfähiger Polymere in Batterie-Elektroden

Publications (1)

Publication Number Publication Date
DE102012022976A1 true DE102012022976A1 (de) 2014-05-28

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DE102012022976.3A Ceased DE102012022976A1 (de) 2012-11-26 2012-11-26 Einsatz leitfähiger Polymere in Batterie-Elektroden

Country Status (8)

Country Link
US (1) US9722249B2 (zh)
EP (1) EP2923401B1 (zh)
JP (1) JP6338590B2 (zh)
KR (1) KR20150109336A (zh)
CN (1) CN104956523B (zh)
DE (1) DE102012022976A1 (zh)
TW (1) TWI610489B (zh)
WO (1) WO2014079581A1 (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105355819A (zh) * 2015-10-13 2016-02-24 深圳宏泰电池科技有限公司 一种富锂锰基的高能量密度锂离子电池及其制备方法
WO2016079696A3 (en) * 2014-11-19 2016-07-21 Biotectix, LLC Conductive polymer coatings for three dimensional substrates
WO2024057187A1 (en) 2022-09-15 2024-03-21 Dyson Technology Limited Electrode precursor composition
WO2024057185A1 (en) 2022-09-15 2024-03-21 Dyson Technology Limited Electrode precursor composition

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EP2997581A4 (en) 2013-05-17 2017-05-03 Biotectix LLC Impregnation of a non-conductive material with an intrinsically conductive polymer
EP3216072B1 (en) * 2014-11-07 2020-05-13 Silver H-Plus Technology Co., Ltd. Artificial sei cathode material and lithium secondary battery comprising the same
EP3037497A1 (en) * 2014-12-23 2016-06-29 Heraeus Deutschland GmbH & Co. KG Process for producing functionalized polythiophenes
CN105161718B (zh) * 2015-08-03 2018-04-10 山东威能环保电源科技股份有限公司 一种锂电池正极材料磷酸锰锂的制备方法
CN105390678B (zh) * 2015-11-03 2018-05-01 宁德新能源科技有限公司 负极材料以及包括该负极材料的锂离子电池
US11302924B2 (en) 2016-10-17 2022-04-12 Massachusetts Institute Of Technology Dual electron-ion conductive polymer composite
CN106803574B (zh) * 2016-12-26 2019-09-13 宁波中车新能源科技有限公司 锂离子电池正极材料及其制备方法和应用
CN109119180A (zh) * 2017-06-22 2019-01-01 宁德时代新能源科技股份有限公司 导电材料、电极片及电化学储能装置
CN109390566B (zh) * 2017-08-11 2021-01-15 宁德时代新能源科技股份有限公司 电极活性材料、电极片及电化学储能装置
KR102315399B1 (ko) * 2017-09-28 2021-10-20 주식회사 엘지화학 리튬 이차전지용 고분자 재료 및 그 제조방법
JP7071695B2 (ja) * 2018-05-01 2022-05-19 トヨタ自動車株式会社 電池組立体および非水電解液二次電池の製造方法
US11180867B2 (en) 2019-03-20 2021-11-23 University Of Kentucky Research Foundation Continuous wet-spinning process for the fabrication of PEDOT:PSS fibers with high electrical conductivity, thermal conductivity and Young's modulus

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JP2004158286A (ja) 2002-11-06 2004-06-03 Nichirin Co Ltd ポリ(3,4−エチレンジオキシチオフェン)を含有する正極材料複合体および該複合体からなる正極を有するリチウム二次電池
JP2011100594A (ja) 2009-11-05 2011-05-19 Tayca Corp リチウムイオン電池用導電助剤組成物、その製造方法、リチウムイオン電池用電極合剤組成物、その製造方法およびリチウムイオン電池
WO2012038628A1 (fr) * 2010-09-22 2012-03-29 Commissariat A L'energie Atomique Et Aux Energies Alternatives Encre aqueuse pour l'impression d'electrodes pour batteries au lithium

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GB0428444D0 (en) * 2004-12-29 2005-02-02 Cambridge Display Tech Ltd Conductive polymer compositions in opto-electrical devices
JP2011001391A (ja) * 2008-03-19 2011-01-06 Univ Of Yamanashi 導電性高分子材料、導電性高分子フィルム及びこれを用いた導電性高分子アクチュエータ
JP5324866B2 (ja) * 2008-08-29 2013-10-23 富山薬品工業株式会社 3,4−エチレンジオキシチオフェンの重合用酸化剤
JP2010135310A (ja) * 2008-10-29 2010-06-17 Sanyo Chem Ind Ltd リチウム二次電池正極用結着剤及び正極材料
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JP2010257954A (ja) * 2009-04-02 2010-11-11 Sanyo Chem Ind Ltd リチウムイオン二次電池正極用結着剤及び正極材料
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016079696A3 (en) * 2014-11-19 2016-07-21 Biotectix, LLC Conductive polymer coatings for three dimensional substrates
EP3553138A1 (en) * 2014-11-19 2019-10-16 Biotectix LLC Conductive polymer coatings for three dimensional substrates
CN105355819A (zh) * 2015-10-13 2016-02-24 深圳宏泰电池科技有限公司 一种富锂锰基的高能量密度锂离子电池及其制备方法
WO2024057187A1 (en) 2022-09-15 2024-03-21 Dyson Technology Limited Electrode precursor composition
WO2024057185A1 (en) 2022-09-15 2024-03-21 Dyson Technology Limited Electrode precursor composition

Also Published As

Publication number Publication date
TW201434195A (zh) 2014-09-01
EP2923401B1 (en) 2018-03-28
CN104956523B (zh) 2018-02-16
CN104956523A (zh) 2015-09-30
US9722249B2 (en) 2017-08-01
US20150303477A1 (en) 2015-10-22
JP6338590B2 (ja) 2018-06-06
EP2923401A1 (en) 2015-09-30
TWI610489B (zh) 2018-01-01
KR20150109336A (ko) 2015-10-01
JP2016504434A (ja) 2016-02-12
WO2014079581A1 (en) 2014-05-30

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