DE102007047434A1 - Sinterstabiler Katalysator für die Hydrierung und Dehydrierungen und Verfahren zu dessen Herstellung - Google Patents

Sinterstabiler Katalysator für die Hydrierung und Dehydrierungen und Verfahren zu dessen Herstellung Download PDF

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Publication number
DE102007047434A1
DE102007047434A1 DE102007047434A DE102007047434A DE102007047434A1 DE 102007047434 A1 DE102007047434 A1 DE 102007047434A1 DE 102007047434 A DE102007047434 A DE 102007047434A DE 102007047434 A DE102007047434 A DE 102007047434A DE 102007047434 A1 DE102007047434 A1 DE 102007047434A1
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Germany
Prior art keywords
catalyst
palladium
sio
chain
long
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DE102007047434A
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German (de)
English (en)
Inventor
Aurel Dr. Wolf
Leslaw Prof. Dr. Mleczko
Jens Dr. Assmann
Frank Dr. Rauscher
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Bayer AG
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Bayer Technology Services GmbH
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Priority to DE102007047434A priority Critical patent/DE102007047434A1/de
Priority to US12/677,157 priority patent/US20100204518A1/en
Priority to BRPI0817590-0A priority patent/BRPI0817590A2/pt
Priority to RU2010116815/04A priority patent/RU2480278C2/ru
Priority to EP08802454A priority patent/EP2200739A2/de
Priority to CN200880110149A priority patent/CN101815575A/zh
Priority to PCT/EP2008/007954 priority patent/WO2009043496A2/de
Priority to JP2010527353A priority patent/JP5415425B2/ja
Publication of DE102007047434A1 publication Critical patent/DE102007047434A1/de
Priority to US13/625,972 priority patent/US20130035511A1/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/05—Metallic powder characterised by the size or surface area of the particles
    • B22F1/054—Nanosized particles
    • B22F1/056—Submicron particles having a size above 100 nm up to 300 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/16—Metallic particles coated with a non-metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10—Processes characterised by the sequence of their steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE102007047434A 2007-10-04 2007-10-04 Sinterstabiler Katalysator für die Hydrierung und Dehydrierungen und Verfahren zu dessen Herstellung Withdrawn DE102007047434A1 (de)

Priority Applications (9)

Application Number Priority Date Filing Date Title
DE102007047434A DE102007047434A1 (de) 2007-10-04 2007-10-04 Sinterstabiler Katalysator für die Hydrierung und Dehydrierungen und Verfahren zu dessen Herstellung
US12/677,157 US20100204518A1 (en) 2007-10-04 2008-09-09 Sintering resistant catalyst for use in hydrogenation and dehydrogenation reactions and methods for producing the same
BRPI0817590-0A BRPI0817590A2 (pt) 2007-10-04 2008-09-20 Catalisador estável à sinterização para hidrogenação e desidrogenação e processo para a sua produção
RU2010116815/04A RU2480278C2 (ru) 2007-10-04 2008-09-20 Не подверженный спеканию катализатор гидрирования и дегидрирования и способ его получения
EP08802454A EP2200739A2 (de) 2007-10-04 2008-09-20 Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung
CN200880110149A CN101815575A (zh) 2007-10-04 2008-09-20 用于氢化和脱氢反应的烧结稳定的催化剂及其制备方法
PCT/EP2008/007954 WO2009043496A2 (de) 2007-10-04 2008-09-20 Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung
JP2010527353A JP5415425B2 (ja) 2007-10-04 2008-09-20 水素化および脱水素化反応において使用する焼結耐性触媒ならびにその製造方法
US13/625,972 US20130035511A1 (en) 2007-10-04 2012-09-25 Process for hydrogenating organic compounds with hydrogen in the gas phase in the presence of a catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102007047434A DE102007047434A1 (de) 2007-10-04 2007-10-04 Sinterstabiler Katalysator für die Hydrierung und Dehydrierungen und Verfahren zu dessen Herstellung

Publications (1)

Publication Number Publication Date
DE102007047434A1 true DE102007047434A1 (de) 2009-04-09

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DE102007047434A Withdrawn DE102007047434A1 (de) 2007-10-04 2007-10-04 Sinterstabiler Katalysator für die Hydrierung und Dehydrierungen und Verfahren zu dessen Herstellung

Country Status (8)

Country Link
US (2) US20100204518A1 (https=)
EP (1) EP2200739A2 (https=)
JP (1) JP5415425B2 (https=)
CN (1) CN101815575A (https=)
BR (1) BRPI0817590A2 (https=)
DE (1) DE102007047434A1 (https=)
RU (1) RU2480278C2 (https=)
WO (1) WO2009043496A2 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008060259A1 (de) 2008-12-03 2010-06-10 Bayer Technology Services Gmbh Katalysator für Oxidationsreaktionen in Gegenwart von Chlorwasserstoff und/oder Chlor und Verfahren zu dessen Herstellung, sowie dessen Verwendung
DE102009056700A1 (de) 2009-12-02 2011-06-16 Bayer Technology Services Gmbh Katalysator bestehend aus Silikathüllen und darin befindlichen, räumlich orientierten Nanopartikeln einer Rutheniumverbindung
CN116351441A (zh) * 2023-03-21 2023-06-30 北京化工大学 具有协同位点负载型选择性加氢催化剂及其制备方法和应用

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CN101972651B (zh) * 2010-10-20 2012-06-13 中南民族大学 一种金属钯纳米材料催化剂及其制备和应用
US9415442B2 (en) * 2011-04-11 2016-08-16 Council Of Scientific & Industrial Research Stable oxide encapsulated metal clusters and nanoparticles
CN103480369B (zh) * 2012-06-13 2015-05-20 中国石油天然气股份有限公司 一种铂纳米复合催化剂及其制备和应用
CN103990453A (zh) * 2014-05-30 2014-08-20 南京工业大学 一种催化加氢用催化剂制备方法
US9433932B2 (en) 2014-08-29 2016-09-06 National Cheng Kung University Hydrogenation catalyst and method of manufacturing the same
US9855547B2 (en) 2015-10-05 2018-01-02 GM Global Technology Operations LLC Low-temperature oxidation catalysts
US10046310B2 (en) 2015-10-05 2018-08-14 GM Global Technology Operations LLC Catalytic converters with age-suppressing catalysts
US9827562B2 (en) 2015-10-05 2017-11-28 GM Global Technology Operations LLC Catalytic converters with age-suppressing catalysts
US10422036B2 (en) 2015-10-23 2019-09-24 GM Global Technology Operations LLC Suppressing aging of platinum group metal particles in a catalytic converter
US9901907B1 (en) 2016-08-31 2018-02-27 GM Global Technology Operations LLC Catalytic converters with age-suppressing catalysts
US10159960B2 (en) 2016-10-25 2018-12-25 GM Global Technology Operations LLC Catalysts with atomically dispersed platinum group metal complexes
US10035133B2 (en) 2016-10-25 2018-07-31 GM Global Technology Operations LLC Catalysts with atomically dispersed platinum group metal complexes and a barrier disposed between the complexes
CN109833879B (zh) * 2017-11-24 2021-08-06 中国石油化工股份有限公司 一种渣油加氢催化剂及其制备方法
CN110252272B (zh) * 2019-06-17 2022-04-22 万华化学集团股份有限公司 一种连续大规模制备烯烃环氧化催化剂的方法及装置
CN112958080B (zh) * 2021-02-05 2022-10-11 浙江工业大学上虞研究院有限公司 一种介孔型钯催化剂的制备方法
CN112934220B (zh) * 2021-02-05 2022-10-04 浙江工业大学上虞研究院有限公司 一种中空型钯催化剂微球的制备方法
CN112958081B (zh) * 2021-02-05 2022-10-14 浙江工业大学上虞研究院有限公司 一种中空型复合钯催化剂的制备方法
CN116060137B (zh) * 2022-11-23 2023-10-27 中国农业大学 用于液体有机储氢材料加氢与脱氢的纳米金属催化剂及其制备方法和应用

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008060259A1 (de) 2008-12-03 2010-06-10 Bayer Technology Services Gmbh Katalysator für Oxidationsreaktionen in Gegenwart von Chlorwasserstoff und/oder Chlor und Verfahren zu dessen Herstellung, sowie dessen Verwendung
WO2010063388A3 (de) * 2008-12-03 2010-07-29 Bayer Technology Services Gmbh Katalysator für oxidationsreaktionen in gegenwart von chlorwasserstoff und/oder chlor und verfahren zu dessen herstellung, sowie dessen verwendung
DE102009056700A1 (de) 2009-12-02 2011-06-16 Bayer Technology Services Gmbh Katalysator bestehend aus Silikathüllen und darin befindlichen, räumlich orientierten Nanopartikeln einer Rutheniumverbindung
CN116351441A (zh) * 2023-03-21 2023-06-30 北京化工大学 具有协同位点负载型选择性加氢催化剂及其制备方法和应用

Also Published As

Publication number Publication date
JP5415425B2 (ja) 2014-02-12
JP2010540232A (ja) 2010-12-24
WO2009043496A3 (de) 2009-06-18
CN101815575A (zh) 2010-08-25
US20100204518A1 (en) 2010-08-12
BRPI0817590A2 (pt) 2015-03-31
WO2009043496A2 (de) 2009-04-09
RU2480278C2 (ru) 2013-04-27
RU2010116815A (ru) 2011-11-10
US20130035511A1 (en) 2013-02-07
EP2200739A2 (de) 2010-06-30

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