CS232720B2 - Method of flow catalytic production of ethylene polymers - Google Patents

Method of flow catalytic production of ethylene polymers Download PDF

Info

Publication number
CS232720B2
CS232720B2 CS819719A CS971981A CS232720B2 CS 232720 B2 CS232720 B2 CS 232720B2 CS 819719 A CS819719 A CS 819719A CS 971981 A CS971981 A CS 971981A CS 232720 B2 CS232720 B2 CS 232720B2
Authority
CS
Czechoslovakia
Prior art keywords
precursor
compound
aliphatic
ethylene
bed
Prior art date
Application number
CS819719A
Other languages
Czech (cs)
English (en)
Inventor
Burkhard E Wagner
George L Goelke
Frederick J Karol
Kathleen F George
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22821129&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CS232720(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Priority to CS833087A priority Critical patent/CS232750B2/cs
Publication of CS232720B2 publication Critical patent/CS232720B2/cs

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Luminescent Compositions (AREA)
  • Pyrane Compounds (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CS819719A 1980-12-24 1981-12-23 Method of flow catalytic production of ethylene polymers CS232720B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CS833087A CS232750B2 (cs) 1980-12-24 1983-05-02 Způsob přípravy «praveného prekursoru vhodného jako složka katalytického systému pro výrobu homopolymerů a kopolymerů ethylenu s vysokou hustotou

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/219,877 US4379758A (en) 1980-12-24 1980-12-24 Catalyst composition for polymerizing ethylene

Publications (1)

Publication Number Publication Date
CS232720B2 true CS232720B2 (en) 1985-02-14

Family

ID=22821129

Family Applications (1)

Application Number Title Priority Date Filing Date
CS819719A CS232720B2 (en) 1980-12-24 1981-12-23 Method of flow catalytic production of ethylene polymers

Country Status (27)

Country Link
US (1) US4379758A (ko)
EP (1) EP0055605B1 (ko)
JP (1) JPS57131207A (ko)
KR (1) KR870000215B1 (ko)
AT (1) ATE12506T1 (ko)
AU (1) AU545015B2 (ko)
BR (1) BR8108356A (ko)
CA (1) CA1173424A (ko)
CS (1) CS232720B2 (ko)
DD (1) DD202442A5 (ko)
DE (1) DE3169765D1 (ko)
DK (1) DK161650C (ko)
EG (1) EG15689A (ko)
ES (2) ES8305382A1 (ko)
FI (1) FI70418C (ko)
GR (1) GR77631B (ko)
HU (1) HU185489B (ko)
IE (1) IE52619B1 (ko)
IL (1) IL64514A (ko)
IN (1) IN155642B (ko)
MA (1) MA19356A1 (ko)
NO (1) NO160084C (ko)
NZ (1) NZ199249A (ko)
PH (1) PH17075A (ko)
PL (2) PL134401B1 (ko)
TR (1) TR21811A (ko)
ZA (1) ZA818699B (ko)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL71357A (en) * 1983-03-29 1987-03-31 Union Carbide Corp Process for producing low density ethylene copolymers
US4834947A (en) * 1983-09-01 1989-05-30 Mobil Oil Corporation Reactor system for rapid kill gas injection to gas phase polymerization reactors
JPH07116253B2 (ja) * 1986-01-21 1995-12-13 東ソー株式会社 ポリオレフインの製造方法
US4719193A (en) * 1986-09-30 1988-01-12 Union Carbide Corporation Processes for preparing polyethylene catalysts by heating catalyst precursors
US5064798A (en) * 1988-08-19 1991-11-12 Exxon Chemical Patents Inc. Catalyst for olefin polymerization
FI91968C (fi) * 1989-11-28 1994-09-12 Borealis Polymers Oy -olefiinien polymerointiin tarkoitettu prokatalyyttikompositio, sen valmistus ja käyttö
DK0446989T3 (da) * 1990-03-16 1996-09-16 Polimeri Europa Srl Katalysator på bærer til ethylenpolymerisation og copolymerisationen af ethylen med alfa-olefiner, dens fremstilling og brug
FI86989C (fi) * 1990-12-19 1992-11-10 Neste Oy Foerfarande foer framstaellning av en polymerisationskatalysatorkomponent foer olefiner, en polymerisationskatalysatorkomponent som har framstaellts enligt foerfarandet, och dess anvaendning
US5597770A (en) * 1991-05-30 1997-01-28 Hanwha Chemical Corporation Titanium-based catalyst composition for polymerizing ethylene
FI92405C (fi) 1992-12-22 1994-11-10 Borealis Holding As Uusi olefiinipolymerointikatalyytti, menetelmä sen valmistamiseksi ja sen käyttö olefiinien polymerointiin
US6384156B1 (en) 1994-08-02 2002-05-07 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization process
US5453471B1 (en) * 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
CN1098867C (zh) * 1998-01-14 2003-01-15 中国石油化工集团公司 淤浆法全密度聚乙烯高效催化剂
US6200509B1 (en) 1998-06-26 2001-03-13 Union Carbide Chemicals & Plastics Technology Corporation Form of synthetic rubber
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
US6780808B2 (en) * 2002-07-15 2004-08-24 Univation Technologies, Llc Enhanced solubility of magnesium halides and catalysts and polymerization process using same
US6855655B2 (en) * 2002-07-15 2005-02-15 Univation Technologies, Llc Supported polymerization catalyst
KR101113341B1 (ko) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US7629422B2 (en) 2004-12-21 2009-12-08 Univation Technologies, Llc Process for transitioning between Ziegler-Natta-based and chromium-based catalysts
US7714082B2 (en) * 2005-10-04 2010-05-11 Univation Technologies, Llc Gas-phase polymerization process to achieve a high particle density
EP1845112A1 (en) * 2006-04-12 2007-10-17 Total Petrochemicals Research Feluy Controlled distribution of active sites in Ziegler-Natta catalysts systems
US7754834B2 (en) * 2007-04-12 2010-07-13 Univation Technologies, Llc Bulk density promoting agents in a gas-phase polymerization process to achieve a bulk particle density
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
RU2527945C2 (ru) 2009-01-08 2014-09-10 Юнивейшн Текнолоджиз, Ллк Добавка для процессов полимеризации полиолефинов
US8076429B2 (en) * 2009-03-11 2011-12-13 Lummus Novolen Technology Gmbh Supertransparent high impact strength random block copolymer
CN102482372B (zh) 2009-07-23 2013-09-04 尤尼威蒂恩技术有限公司 聚合反应系统
SA111320792B1 (ar) 2010-09-29 2014-11-13 Univ Zhejiang مفاعل بلمرة للطبقة المميعة وطريقة لتحضير البوليمر
CN103347905B (zh) 2010-12-22 2015-12-16 尤尼威蒂恩技术有限责任公司 用于聚烯烃聚合方法的添加剂
RU2608744C2 (ru) * 2011-09-05 2017-01-23 Птт Глобал Кемикал Паблик Компани Лимитед Высокоактивный катализатор полимеризации олефинов с борсодержащей подложкой на основе оксида кремния и его изготовление
WO2013081748A1 (en) 2011-11-30 2013-06-06 Univation Technologies, Llc Methods and systems for catalyst delivery
EP2679609A1 (en) 2012-06-28 2014-01-01 Lummus Novolen Technology Gmbh Sterically demanding dialkoxydialkylsilanes as external donors for ziegler catalysts for the polymerization of propylene
IN2015DN03103A (ko) 2012-11-12 2015-10-02 Univation Tech Llc
EP3080200B1 (en) 2013-12-09 2018-11-14 Univation Technologies, LLC Feeding polymerization additives to polymerization processes
EP3247547B1 (en) 2015-01-21 2023-03-22 Univation Technologies, LLC Methods for gel reduction in polyolefins
SG11201705607QA (en) 2015-01-21 2017-08-30 Univation Tech Llc Methods for controlling polymer chain scission
CA3052770C (en) 2017-02-07 2021-09-07 Exxonmobil Chemical Patents Inc. Processes for reducing the loss of catalyst activity of a ziegler-natta catalyst
US11168157B2 (en) 2018-12-04 2021-11-09 Chevron Phillips Chemical Company Lp Melt flow index response in polyethylene reactors
CN116234837A (zh) 2020-07-22 2023-06-06 埃克森美孚化学专利公司 聚烯烃组合物及其制品
WO2022126068A1 (en) 2020-12-08 2022-06-16 Exxonmobil Chemical Patents Inc. High density polyethylene compositions with long-chain branching
WO2023081577A1 (en) 2021-11-02 2023-05-11 Exxonmobil Chemical Patents Inc. Polyethylene compositions, articles thereof, and methods thereof
EP4424723A1 (en) 2023-02-28 2024-09-04 Lummus Novolen Technology Gmbh Polypropylene production using a propylene stream comprising propane

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB827390A (en) * 1955-11-01 1960-02-03 Exxon Research Engineering Co Polymerisation of olefins
NL106201C (ko) * 1956-09-17
US3444153A (en) * 1965-08-16 1969-05-13 Phillips Petroleum Co Polymerization process and catalyst for olefins
US4209601A (en) * 1975-01-10 1980-06-24 Nippon Oil Company, Limited Process for the production of polyolefins
DE2752577A1 (de) * 1977-11-25 1979-06-07 Hoechst Ag Verfahren zur herstellung eines mischkatalysators
US4303771A (en) * 1978-12-14 1981-12-01 Union Carbide Corporation Process for the preparation of high density ethylene polymers in fluid bed reactor
CA1118148A (en) * 1978-12-14 1982-02-09 Union Carbide Corporation Preparation of high density ethylene polymers in fluid bed reactor

Also Published As

Publication number Publication date
KR830007724A (ko) 1983-11-04
GR77631B (ko) 1984-09-25
PL234595A1 (ko) 1982-09-13
DD202442A5 (de) 1983-09-14
NZ199249A (en) 1984-05-31
FI814100L (fi) 1982-06-25
MA19356A1 (fr) 1982-07-01
EP0055605A3 (en) 1982-08-04
AU545015B2 (en) 1985-06-27
US4379758A (en) 1983-04-12
ZA818699B (en) 1982-11-24
ES518715A0 (es) 1984-02-01
IL64514A (en) 1984-10-31
CA1173424A (en) 1984-08-28
PL134401B1 (en) 1985-08-31
PH17075A (en) 1984-05-24
ES508324A0 (es) 1983-04-16
DK161650C (da) 1992-01-20
JPS6256885B2 (ko) 1987-11-27
IL64514A0 (en) 1982-03-31
EP0055605A2 (en) 1982-07-07
ES8401992A1 (es) 1984-02-01
FI70418B (fi) 1986-03-27
DK576781A (da) 1982-06-25
EP0055605B1 (en) 1985-04-03
NO160084C (no) 1989-03-08
NO160084B (no) 1988-11-28
PL135930B1 (en) 1986-01-31
DE3169765D1 (en) 1985-05-09
IE52619B1 (en) 1988-01-06
AU7879081A (en) 1982-07-01
IE813073L (en) 1982-06-24
NO814405L (no) 1982-06-25
BR8108356A (pt) 1982-10-13
ATE12506T1 (de) 1985-04-15
EG15689A (en) 1987-03-30
DK161650B (da) 1991-07-29
HU185489B (en) 1985-02-28
IN155642B (ko) 1985-02-16
JPS57131207A (en) 1982-08-14
ES8305382A1 (es) 1983-04-16
FI70418C (fi) 1986-09-19
TR21811A (tr) 1985-07-22
KR870000215B1 (ko) 1987-02-17

Similar Documents

Publication Publication Date Title
CS232720B2 (en) Method of flow catalytic production of ethylene polymers
EP0004647B1 (en) Process for copolymerizing ethylene
EP0043220B1 (en) Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization
US4427573A (en) Polymerization catalyst, process for preparing, and use for ethylene polymerization
US4363904A (en) High tear strength polymers
US4354009A (en) Catalyst composition for copolymerizing ethylene
US4481301A (en) Highly active catalyst composition for polymerizing alpha-olefins
US4379759A (en) Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
US4359561A (en) High tear strength polymers
FI66402C (fi) Sfaeriska polymerisationskatalysatorer som innehaoller fyllmedel och anvaendningen av dessa katalysatorer foer polymerisering av etylen
US20060281879A1 (en) Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions
US5019633A (en) Catalyst composition for polymerizing ethylene
US4892853A (en) Ethylene polymerization catalyst
CS264328B2 (en) Process for preparing carrier catalyst for the polymerization of alpha-olefines
EP0021605B1 (en) High tear strength ethylene-based hydrocarbon polymers, film formed from such polymers, and process for making such polymers
US5025072A (en) Highly active catalyst composition for polymerizing alpha-olefins
EP0083456B1 (en) Improved process for copolymerizing ethylene
EP0499093A2 (en) Process for reducing hexane extractables from ethylene copolymers
US4605638A (en) Highly active catalyst composition for polymerizing alpha-olefins
EP0012148B1 (en) Process for the preparation of high density ethylene polymers in fluid bed reactor
CS232750B2 (cs) Způsob přípravy «praveného prekursoru vhodného jako složka katalytického systému pro výrobu homopolymerů a kopolymerů ethylenu s vysokou hustotou
CS214686B2 (cs) Způsob přípravy katalytického systému pro polymeraci nebo kopolymeraci ethylenu
CS213374B2 (cs) Způsob katalytické výroby homopolymerů a kopolymerů ethylenu
CS215015B2 (cs) Způsob katalytické výroby ethylenového kopolymeru
CS213382B2 (cs) Způsob katalytické5výroby homopolymerů o kopolymerů ethylenu