ES8305382A1 - Procedimiento catalitico continuo para producir homopolimeros o copolimeros de etileno de alta densidad. - Google Patents

Procedimiento catalitico continuo para producir homopolimeros o copolimeros de etileno de alta densidad.

Info

Publication number
ES8305382A1
ES8305382A1 ES508324A ES508324A ES8305382A1 ES 8305382 A1 ES8305382 A1 ES 8305382A1 ES 508324 A ES508324 A ES 508324A ES 508324 A ES508324 A ES 508324A ES 8305382 A1 ES8305382 A1 ES 8305382A1
Authority
ES
Spain
Prior art keywords
precursor composition
compound
catalyst composition
polymerization process
polymerizing ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES508324A
Other languages
English (en)
Other versions
ES508324A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22821129&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES8305382(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES508324A0 publication Critical patent/ES508324A0/es
Publication of ES8305382A1 publication Critical patent/ES8305382A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyrane Compounds (AREA)
  • Luminescent Compositions (AREA)

Abstract

PROCEDIMIENTO CATALITICO PARA PRODUCIR HOMOPOLIMEROS O COPOLIMEROS DE ETILENO DE ALTA DENSIDAD. CONSISTE EN PONER EN CONTACTO ETILENO O UNA MEZCLA DE ETILENO Y UNA ALFAOLEFINA CON 3 A 8 ATOMOS DE CARBONO, A UNA TEMPERATURA COMPRENDIDA ENTRE 90 Y 115 GRADOS Y A UNA PRESION NO SUPERIOR A 70 KG/CM , EN UNA ZONA DE REACCION EN FASE GASEOSA, CON PARTICULAS DE UN SISTEMA CATALIZADOR QUE COMPRENDE UNA COMPOSICION PRECURSORA DE FORMULA (I), EN LA QUE R ES UN RADICAL DE HIDROCARBURO ALIFATICO O AROMATICO; X ES CL, BR, I O MEZCLAS DE LOS MISMOS; ED ES UN COMPUESTO ORGANICO DONADOR DE ELECTRONES; M ESTA COMPRENDIDO ENTRE 0,5 Y 56; N ES 0, 1 O 2; P ESTA COMPRENDIDO ENTRE 1 Y 116; Y Q ESTA COMPRENDIDO ENTRE 2 Y 85, Y UN COMPUESTO ACTIVADOR DE FORMULA (II), EN DONDE X ES CL; E ESTA COMPRENDIDA ENTRE 0 Y 1,5; F ES 0 O 1; Y D+E+F=3.
ES508324A 1980-12-24 1981-12-23 Procedimiento catalitico continuo para producir homopolimeros o copolimeros de etileno de alta densidad. Expired ES8305382A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/219,877 US4379758A (en) 1980-12-24 1980-12-24 Catalyst composition for polymerizing ethylene

Publications (2)

Publication Number Publication Date
ES508324A0 ES508324A0 (es) 1983-04-16
ES8305382A1 true ES8305382A1 (es) 1983-04-16

Family

ID=22821129

Family Applications (2)

Application Number Title Priority Date Filing Date
ES508324A Expired ES8305382A1 (es) 1980-12-24 1981-12-23 Procedimiento catalitico continuo para producir homopolimeros o copolimeros de etileno de alta densidad.
ES518715A Expired ES8401992A1 (es) 1980-12-24 1982-12-30 Procedimiento de obtencion de una composicion precursora catalitica para la produccion de homopolimeros o copolimeros de etileno de alta densidad.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES518715A Expired ES8401992A1 (es) 1980-12-24 1982-12-30 Procedimiento de obtencion de una composicion precursora catalitica para la produccion de homopolimeros o copolimeros de etileno de alta densidad.

Country Status (27)

Country Link
US (1) US4379758A (es)
EP (1) EP0055605B1 (es)
JP (1) JPS57131207A (es)
KR (1) KR870000215B1 (es)
AT (1) ATE12506T1 (es)
AU (1) AU545015B2 (es)
BR (1) BR8108356A (es)
CA (1) CA1173424A (es)
CS (1) CS232720B2 (es)
DD (1) DD202442A5 (es)
DE (1) DE3169765D1 (es)
DK (1) DK161650C (es)
EG (1) EG15689A (es)
ES (2) ES8305382A1 (es)
FI (1) FI70418C (es)
GR (1) GR77631B (es)
HU (1) HU185489B (es)
IE (1) IE52619B1 (es)
IL (1) IL64514A (es)
IN (1) IN155642B (es)
MA (1) MA19356A1 (es)
NO (1) NO160084C (es)
NZ (1) NZ199249A (es)
PH (1) PH17075A (es)
PL (2) PL135930B1 (es)
TR (1) TR21811A (es)
ZA (1) ZA818699B (es)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL71357A (en) * 1983-03-29 1987-03-31 Union Carbide Corp Process for producing low density ethylene copolymers
US4834947A (en) * 1983-09-01 1989-05-30 Mobil Oil Corporation Reactor system for rapid kill gas injection to gas phase polymerization reactors
JPH07116253B2 (ja) * 1986-01-21 1995-12-13 東ソー株式会社 ポリオレフインの製造方法
US4719193A (en) * 1986-09-30 1988-01-12 Union Carbide Corporation Processes for preparing polyethylene catalysts by heating catalyst precursors
US5064798A (en) * 1988-08-19 1991-11-12 Exxon Chemical Patents Inc. Catalyst for olefin polymerization
FI91968C (fi) * 1989-11-28 1994-09-12 Borealis Polymers Oy -olefiinien polymerointiin tarkoitettu prokatalyyttikompositio, sen valmistus ja käyttö
EP0446989B1 (en) * 1990-03-16 1996-05-22 ENICHEM S.p.A. Supported catalyst for ethylene polymerization and the copolymerization of ethylene with alpha-olefins, its preparation and use
FI86989C (fi) * 1990-12-19 1992-11-10 Neste Oy Foerfarande foer framstaellning av en polymerisationskatalysatorkomponent foer olefiner, en polymerisationskatalysatorkomponent som har framstaellts enligt foerfarandet, och dess anvaendning
US5597770A (en) * 1991-05-30 1997-01-28 Hanwha Chemical Corporation Titanium-based catalyst composition for polymerizing ethylene
FI92405C (fi) 1992-12-22 1994-11-10 Borealis Holding As Uusi olefiinipolymerointikatalyytti, menetelmä sen valmistamiseksi ja sen käyttö olefiinien polymerointiin
US6384156B1 (en) 1994-08-02 2002-05-07 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization process
US5453471B1 (en) * 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
CN1098867C (zh) * 1998-01-14 2003-01-15 中国石油化工集团公司 淤浆法全密度聚乙烯高效催化剂
US6200509B1 (en) 1998-06-26 2001-03-13 Union Carbide Chemicals & Plastics Technology Corporation Form of synthetic rubber
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
US6855655B2 (en) * 2002-07-15 2005-02-15 Univation Technologies, Llc Supported polymerization catalyst
US6780808B2 (en) * 2002-07-15 2004-08-24 Univation Technologies, Llc Enhanced solubility of magnesium halides and catalysts and polymerization process using same
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US7629422B2 (en) 2004-12-21 2009-12-08 Univation Technologies, Llc Process for transitioning between Ziegler-Natta-based and chromium-based catalysts
US7714082B2 (en) * 2005-10-04 2010-05-11 Univation Technologies, Llc Gas-phase polymerization process to achieve a high particle density
EP1845112A1 (en) * 2006-04-12 2007-10-17 Total Petrochemicals Research Feluy Controlled distribution of active sites in Ziegler-Natta catalysts systems
US7754834B2 (en) * 2007-04-12 2010-07-13 Univation Technologies, Llc Bulk density promoting agents in a gas-phase polymerization process to achieve a bulk particle density
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
US20110256632A1 (en) 2009-01-08 2011-10-20 Univation Technologies, Llc Additive for Polyolefin Polymerization Processes
US8076429B2 (en) 2009-03-11 2011-12-13 Lummus Novolen Technology Gmbh Supertransparent high impact strength random block copolymer
US8586685B2 (en) 2009-07-23 2013-11-19 Univation Technologies, Llc Polymerization reaction system
SA111320792B1 (ar) 2010-09-29 2014-11-13 Univ Zhejiang مفاعل بلمرة للطبقة المميعة وطريقة لتحضير البوليمر
WO2012087560A1 (en) 2010-12-22 2012-06-28 Univation Technologies, Llc Additive for polyolefin polymerization processes
RU2608744C2 (ru) * 2011-09-05 2017-01-23 Птт Глобал Кемикал Паблик Компани Лимитед Высокоактивный катализатор полимеризации олефинов с борсодержащей подложкой на основе оксида кремния и его изготовление
JP6154396B2 (ja) 2011-11-30 2017-06-28 ユニベーション・テクノロジーズ・エルエルシー 触媒送出方法及びシステム
EP2679609A1 (en) 2012-06-28 2014-01-01 Lummus Novolen Technology Gmbh Sterically demanding dialkoxydialkylsilanes as external donors for ziegler catalysts for the polymerization of propylene
CN104781628B (zh) 2012-11-12 2017-07-07 尤尼威蒂恩技术有限责任公司 用于气相聚合方法的再循环气体冷却器系统
JP2016539234A (ja) 2013-12-09 2016-12-15 ユニベーション・テクノロジーズ・エルエルシー 重合プロセスへの重合添加剤の供給
US10471641B2 (en) 2015-01-21 2019-11-12 Univation Technologies, Llc Methods for controlling polymer chain scission
EP3247547B1 (en) 2015-01-21 2023-03-22 Univation Technologies, LLC Methods for gel reduction in polyolefins
WO2018147931A1 (en) 2017-02-07 2018-08-16 Exxonmobil Chemical Patents Inc. Processes for reducing the loss of catalyst activity of a ziegler-natta catalyst
US11168157B2 (en) 2018-12-04 2021-11-09 Chevron Phillips Chemical Company Lp Melt flow index response in polyethylene reactors
CN116234837A (zh) 2020-07-22 2023-06-06 埃克森美孚化学专利公司 聚烯烃组合物及其制品
EP4259669A1 (en) 2020-12-08 2023-10-18 ExxonMobil Chemical Patents Inc. High density polyethylene compositions with long-chain branching
WO2023081577A1 (en) 2021-11-02 2023-05-11 Exxonmobil Chemical Patents Inc. Polyethylene compositions, articles thereof, and methods thereof

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB827390A (en) * 1955-11-01 1960-02-03 Exxon Research Engineering Co Polymerisation of olefins
NL218674A (es) * 1956-09-17
US3444153A (en) * 1965-08-16 1969-05-13 Phillips Petroleum Co Polymerization process and catalyst for olefins
US4209601A (en) * 1975-01-10 1980-06-24 Nippon Oil Company, Limited Process for the production of polyolefins
DE2752577A1 (de) * 1977-11-25 1979-06-07 Hoechst Ag Verfahren zur herstellung eines mischkatalysators
CA1118148A (en) * 1978-12-14 1982-02-09 Union Carbide Corporation Preparation of high density ethylene polymers in fluid bed reactor
US4303771A (en) * 1978-12-14 1981-12-01 Union Carbide Corporation Process for the preparation of high density ethylene polymers in fluid bed reactor

Also Published As

Publication number Publication date
BR8108356A (pt) 1982-10-13
PL234595A1 (es) 1982-09-13
EP0055605B1 (en) 1985-04-03
US4379758A (en) 1983-04-12
IN155642B (es) 1985-02-16
EP0055605A3 (en) 1982-08-04
NO160084C (no) 1989-03-08
ES508324A0 (es) 1983-04-16
PL134401B1 (en) 1985-08-31
DK576781A (da) 1982-06-25
DK161650C (da) 1992-01-20
AU7879081A (en) 1982-07-01
AU545015B2 (en) 1985-06-27
JPS57131207A (en) 1982-08-14
KR830007724A (ko) 1983-11-04
IE813073L (en) 1982-06-24
EP0055605A2 (en) 1982-07-07
IL64514A0 (en) 1982-03-31
NZ199249A (en) 1984-05-31
ES518715A0 (es) 1984-02-01
DD202442A5 (de) 1983-09-14
DE3169765D1 (en) 1985-05-09
MA19356A1 (fr) 1982-07-01
PL135930B1 (en) 1986-01-31
EG15689A (en) 1987-03-30
IL64514A (en) 1984-10-31
NO814405L (no) 1982-06-25
FI70418B (fi) 1986-03-27
CA1173424A (en) 1984-08-28
NO160084B (no) 1988-11-28
HU185489B (en) 1985-02-28
IE52619B1 (en) 1988-01-06
CS232720B2 (en) 1985-02-14
TR21811A (tr) 1985-07-22
ATE12506T1 (de) 1985-04-15
GR77631B (es) 1984-09-25
PH17075A (en) 1984-05-24
FI814100L (fi) 1982-06-25
KR870000215B1 (ko) 1987-02-17
JPS6256885B2 (es) 1987-11-27
ZA818699B (en) 1982-11-24
DK161650B (da) 1991-07-29
ES8401992A1 (es) 1984-02-01
FI70418C (fi) 1986-09-19

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19970401