CS207728B2 - Herbicide means and method of making the active substance thereof - Google Patents
Herbicide means and method of making the active substance thereof Download PDFInfo
- Publication number
- CS207728B2 CS207728B2 CS7957A CS5779A CS207728B2 CS 207728 B2 CS207728 B2 CS 207728B2 CS 7957 A CS7957 A CS 7957A CS 5779 A CS5779 A CS 5779A CS 207728 B2 CS207728 B2 CS 207728B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- sodium
- salt
- glyphosate
- water
- plants
- Prior art date
Links
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 9
- 239000004009 herbicide Substances 0.000 title abstract description 4
- 239000013543 active substance Substances 0.000 title description 3
- 238000004519 manufacturing process Methods 0.000 title 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims abstract description 47
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 44
- 239000000203 mixture Substances 0.000 claims description 29
- 239000011734 sodium Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 239000004480 active ingredient Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 7
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 5
- 239000002671 adjuvant Substances 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 235000010265 sodium sulphite Nutrition 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000004280 Sodium formate Substances 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 239000001632 sodium acetate Substances 0.000 claims description 2
- 235000017281 sodium acetate Nutrition 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 2
- 235000019254 sodium formate Nutrition 0.000 claims description 2
- 235000019794 sodium silicate Nutrition 0.000 claims description 2
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims 1
- 150000003839 salts Chemical class 0.000 abstract description 32
- 240000000111 Saccharum officinarum Species 0.000 abstract description 11
- 235000007201 Saccharum officinarum Nutrition 0.000 abstract description 11
- 150000001875 compounds Chemical class 0.000 abstract description 9
- 229930006000 Sucrose Natural products 0.000 abstract description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 abstract description 4
- 239000005720 sucrose Substances 0.000 abstract description 4
- 241000196324 Embryophyta Species 0.000 description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 43
- 239000005562 Glyphosate Substances 0.000 description 38
- 229940097068 glyphosate Drugs 0.000 description 38
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 27
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 21
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 20
- -1 glyphosate anion Chemical class 0.000 description 20
- 239000000243 solution Substances 0.000 description 17
- 239000013078 crystal Substances 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 11
- 239000002585 base Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- 238000009472 formulation Methods 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000006386 neutralization reaction Methods 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 238000004448 titration Methods 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 4
- 239000012266 salt solution Substances 0.000 description 4
- 150000003871 sulfonates Chemical class 0.000 description 4
- 150000004685 tetrahydrates Chemical class 0.000 description 4
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- YWICANUUQPYHOW-UHFFFAOYSA-M sodium;2-(phosphonomethylamino)acetate Chemical compound [Na+].OP(O)(=O)CNCC([O-])=O YWICANUUQPYHOW-UHFFFAOYSA-M 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 240000006394 Sorghum bicolor Species 0.000 description 2
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 2
- 235000021536 Sugar beet Nutrition 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000002479 acid--base titration Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 210000002858 crystal cell Anatomy 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229940001482 sodium sulfite Drugs 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical class [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- ZDSCFBCGDDCJFZ-UHFFFAOYSA-N 2-(methylamino)ethanesulfonic acid;sodium Chemical class [Na].CNCCS(O)(=O)=O ZDSCFBCGDDCJFZ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- OCILYPMSWAPTSR-UHFFFAOYSA-N CCCCN.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 Chemical compound CCCCN.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 OCILYPMSWAPTSR-UHFFFAOYSA-N 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000006122 Chenopodium album Species 0.000 description 1
- 235000011498 Chenopodium album var missouriense Nutrition 0.000 description 1
- 235000013328 Chenopodium album var. album Nutrition 0.000 description 1
- 235000014052 Chenopodium album var. microphyllum Nutrition 0.000 description 1
- 235000014050 Chenopodium album var. stevensii Nutrition 0.000 description 1
- 235000013012 Chenopodium album var. striatum Nutrition 0.000 description 1
- 240000001579 Cirsium arvense Species 0.000 description 1
- 235000005918 Cirsium arvense Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000001692 EU approved anti-caking agent Substances 0.000 description 1
- 241000508725 Elymus repens Species 0.000 description 1
- 240000008620 Fagopyrum esculentum Species 0.000 description 1
- 235000009419 Fagopyrum esculentum Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 244000203593 Piper nigrum Species 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000006286 aqueous extract Substances 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000012926 crystallographic analysis Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical class [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 150000004690 nonahydrates Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 229940079101 sodium sulfide Drugs 0.000 description 1
- ZGHLCBJZQLNUAZ-UHFFFAOYSA-N sodium sulfide nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Na+].[Na+].[S-2] ZGHLCBJZQLNUAZ-UHFFFAOYSA-N 0.000 description 1
- 229940048181 sodium sulfide nonahydrate Drugs 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- WMDLZMCDBSJMTM-UHFFFAOYSA-M sodium;sulfanide;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Na+].[SH-] WMDLZMCDBSJMTM-UHFFFAOYSA-M 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- ICESBGJHRQHALQ-UHFFFAOYSA-K trisodium;(carboxymethylamino)methyl-hydroxyphosphinate;2-[[hydroxy(oxido)phosphoryl]methylamino]acetate Chemical compound [Na+].[Na+].[Na+].OC(=O)CNCP(O)([O-])=O.OC(=O)CNCP([O-])([O-])=O ICESBGJHRQHALQ-UHFFFAOYSA-K 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/866,677 US4140513A (en) | 1978-01-03 | 1978-01-03 | Sodium sesquiglyphosate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS207728B2 true CS207728B2 (en) | 1981-08-31 |
Family
ID=25348146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS7957A CS207728B2 (en) | 1978-01-03 | 1979-01-02 | Herbicide means and method of making the active substance thereof |
Country Status (41)
| Country | Link |
|---|---|
| US (1) | US4140513A (no) |
| JP (1) | JPS54109921A (no) |
| AR (1) | AR221857A1 (no) |
| AT (1) | AT363274B (no) |
| AU (1) | AU522518B2 (no) |
| BE (1) | BE873199A (no) |
| BG (2) | BG40656A3 (no) |
| BR (1) | BR7900007A (no) |
| CA (1) | CA1120951A (no) |
| CH (1) | CH641187A5 (no) |
| CS (1) | CS207728B2 (no) |
| DD (1) | DD140968A5 (no) |
| DE (1) | DE2900025C2 (no) |
| DK (1) | DK158356C (no) |
| EG (1) | EG13903A (no) |
| ES (1) | ES476485A1 (no) |
| FI (1) | FI65437C (no) |
| FR (1) | FR2413398A1 (no) |
| GB (1) | GB2011906B (no) |
| HK (1) | HK684A (no) |
| HU (1) | HU184659B (no) |
| IE (1) | IE47773B1 (no) |
| IL (1) | IL56356A (no) |
| IN (1) | IN150741B (no) |
| IT (1) | IT1162701B (no) |
| KE (1) | KE3342A (no) |
| MW (1) | MW179A1 (no) |
| MX (1) | MX5697E (no) |
| MY (1) | MY8400322A (no) |
| NL (1) | NL7812635A (no) |
| NO (1) | NO150841C (no) |
| PH (1) | PH19009A (no) |
| PL (2) | PL114405B1 (no) |
| PT (1) | PT69016A (no) |
| RO (2) | RO79038B (no) |
| SE (1) | SE444685B (no) |
| SG (1) | SG54883G (no) |
| SU (1) | SU1050565A3 (no) |
| YU (1) | YU310178A (no) |
| ZA (1) | ZA787349B (no) |
| ZM (1) | ZM279A1 (no) |
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| US4481026A (en) * | 1982-11-16 | 1984-11-06 | Stauffer Chemical Company | Aluminum N-phosphonomethylglycine and its use as a herbicide |
| US4472189A (en) * | 1982-12-27 | 1984-09-18 | Stauffer Chemical Co. | Stannic N-phosphonomethyglycine and its use as a herbicide |
| US5580841A (en) * | 1985-05-29 | 1996-12-03 | Zeneca Limited | Solid, phytoactive compositions and method for their preparation |
| FI86501C (fi) * | 1985-05-29 | 1992-09-10 | Stauffer Chemical Co | Fast, i huvudsak icke-hygroskopisk fytoaktiv blandning och dess framstaellningsfoerfarande. |
| US5468718A (en) * | 1985-10-21 | 1995-11-21 | Ici Americas Inc. | Liquid, phytoactive compositions and method for their preparation |
| BR8600460A (pt) * | 1986-02-04 | 1987-09-01 | Monsanto Brasil | Processo para preparacao de um sal de metal alcalino particulado de n-fosfonometilglicina |
| US5047079A (en) * | 1986-08-18 | 1991-09-10 | Ici Americas Inc. | Method of preparation and use of solid, phytoactive compositions |
| NZ231897A (en) | 1988-12-30 | 1992-09-25 | Monsanto Co | Dry water-soluble granular composition comprising glyphosate and a liquid surfactant |
| DK165156C (da) * | 1989-12-20 | 1993-03-01 | Cheminova Agro As | Herbicid formulering indeholdende glyphosatsyre |
| DE4029304A1 (de) * | 1990-09-15 | 1992-03-19 | Hoechst Ag | Synergistische herbizide mittel |
| US6930075B1 (en) | 1990-11-02 | 2005-08-16 | Monsanto Technology, Llc | Fatty acid-based herbicidal composition |
| IL101539A (en) | 1991-04-16 | 1998-09-24 | Monsanto Europe Sa | Mono-ammonium salts of the history of N phosphonomethyl glycyl which are not hygroscopes, their preparations and pesticides containing |
| MY111437A (en) * | 1992-07-31 | 2000-05-31 | Monsanto Co | Improved glyphosate herbicide formulation. |
| DE19533523A1 (de) * | 1995-09-11 | 1997-03-13 | Bayer Ag | Verwendung von N-Phosphonomethyl-glycinestern in wäßriger Lösung als Herbizide |
| WO1999004635A1 (en) * | 1997-07-22 | 1999-02-04 | Monsanto Company | High-loaded ammonium glyphosate formulations |
| CA2297749A1 (en) * | 1997-07-30 | 1999-02-11 | Monsanto Company | Process and compositions promoting biological effectiveness of exogenous chemical substances in plants |
| ITTO980048A1 (it) * | 1998-01-20 | 1999-07-20 | Ipici Spa | Composizioni erbicide, procedimenti per la loro preparazione ed impieghi |
| MY119091A (en) * | 1998-02-13 | 2005-03-31 | Monsanto Technology Llc | Storage-stable composition containing exogenous chemical substance and siloxane surfactant |
| GB9819693D0 (en) | 1998-09-10 | 1998-11-04 | Zeneca Ltd | Glyphosate formulation |
| CN1277474C (zh) | 1998-11-23 | 2006-10-04 | 孟山都公司 | 草甘膦除草剂的浓缩储藏和运输系统 |
| KR20010104684A (ko) | 1998-11-23 | 2001-11-26 | 죤 에이치. 뷰센 | 고농축 수성 글리포세이트 조성물 |
| ATE285680T1 (de) | 1998-11-30 | 2005-01-15 | Flamel Tech Sa | Förderung der biologischen effektivität exogener chemischer substanzen in pflanzen |
| US6369001B1 (en) | 1999-08-11 | 2002-04-09 | Monsanto Technology, Llc | Microemulsion coformulation of a graminicide and a water-soluble herbicide |
| US6746976B1 (en) | 1999-09-24 | 2004-06-08 | The Procter & Gamble Company | Thin until wet structures for acquiring aqueous fluids |
| JP5433120B2 (ja) | 1999-09-30 | 2014-03-05 | モンサント テクノロジー エルエルシー | 向上した安定性を有するパッケージミックス農薬組成物 |
| US6992045B2 (en) * | 2000-05-19 | 2006-01-31 | Monsanto Technology Llc | Pesticide compositions containing oxalic acid |
| MY158895A (en) | 2000-05-19 | 2016-11-30 | Monsanto Technology Llc | Potassium glyphosate formulations |
| US7135437B2 (en) | 2000-05-19 | 2006-11-14 | Monsanto Technology Llc | Stable liquid pesticide compositions |
| US6300323B1 (en) | 2000-08-08 | 2001-10-09 | Ishihara Sangyo Kaisha, Ltd. | (Poly)ethereal ammonium salts of herbicides bearing acidic moieties and their use as herbicides |
| DE10052489A1 (de) | 2000-10-23 | 2002-05-02 | Hermania Dr Schirm Gmbh | Feste Glyphosat-Formulierung und Verfahren zur Herstellung |
| EP1494534A4 (en) * | 2002-04-01 | 2005-08-17 | Valent Biosciences Corp | IMPROVED HERBICIDE COMPOSITION |
| US20050037924A1 (en) * | 2002-08-31 | 2005-02-17 | Monsanto Technology Llc | Sodium glyphosate compositions and process for their preparation |
| EP1538910A2 (en) * | 2002-08-31 | 2005-06-15 | Monsanto Technology LLC | Process for the preparation of a dry pesticidal composition containing a dicarboxylate component |
| US8470741B2 (en) * | 2003-05-07 | 2013-06-25 | Croda Americas Llc | Homogeneous liquid saccharide and oil systems |
| EP1791431B1 (en) * | 2004-09-17 | 2012-01-25 | Monsanto Technology, LLC | Glyphosate formulations with early burndown symptoms |
| US7223718B2 (en) * | 2005-03-07 | 2007-05-29 | Falcon Lab Llc | Enhanced glyphosate herbicidal concentrates |
| US20070049498A1 (en) * | 2005-09-01 | 2007-03-01 | Brigance Mickey R | Agricultural compositions which enhance performance of herbicides |
| CA2727924C (en) * | 2008-06-18 | 2016-05-24 | Stepan Company | Ultra-high loading glyphosate concentrate |
| US8536095B2 (en) | 2008-07-03 | 2013-09-17 | Monsanto Technology Llc | Combinations of derivatized saccharide surfactants and etheramine oxide surfactants as herbicide adjuvants |
| HUE035603T2 (en) * | 2008-09-29 | 2018-05-28 | Monsanto Technology Llc | Glyphosate preparations containing amidoalkylamine surfactants |
| BRPI1016258B1 (pt) | 2009-06-30 | 2018-11-21 | Flamel Tech S A | sais derivados de n-fosfonometilglicina guanidina e composição herbicida aquosa |
| US20110071027A1 (en) * | 2009-09-18 | 2011-03-24 | Volker Heide | High strength aqueous glyphosate salt concentrates and methods |
| US8835356B2 (en) | 2009-11-16 | 2014-09-16 | Imtrade Australia Pty Ltd | High load glyphosate formulations |
| AU2011323770B2 (en) | 2010-10-25 | 2015-07-16 | Stepan Company | Glyphosate formulations based on compositions derived from natural oil metathesis |
| US10694743B2 (en) | 2014-07-02 | 2020-06-30 | Stepan Company | Agricultural compositions with reduced aquatic toxicity |
| CN109310095A (zh) | 2016-05-11 | 2019-02-05 | 孟山都技术公司 | 含酰胺基烷基胺表面活性剂的草甘膦制剂 |
| UY37356A (es) | 2016-08-09 | 2018-03-23 | Monsanto Technology Llc | Composiciones de concentrados herbicidas sólidos |
| EP3628738A1 (en) | 2018-09-25 | 2020-04-01 | KWS SAAT SE & Co. KGaA | Method for controlling weed beets and other weeds |
| EP3628160A1 (en) | 2018-09-25 | 2020-04-01 | KWS SAAT SE & Co. KGaA | Use of glyphosate herbicide for controlling unwanted vegetation in beta vulgaris growing areas |
| CN116574129A (zh) * | 2023-04-14 | 2023-08-11 | 湖北泰盛化工有限公司 | 一种消除细晶的草甘膦结晶方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL38138A (en) * | 1970-11-19 | 1974-07-31 | Ciba Geigy Ag | Process and compositions containing thiourea derivatives for the promotion of fruit abscission |
| US3853530A (en) * | 1971-03-10 | 1974-12-10 | Monsanto Co | Regulating plants with n-phosphonomethylglycine and derivatives thereof |
| US3799758A (en) * | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
| PH16509A (en) * | 1971-03-10 | 1983-11-08 | Monsanto Co | N-phosphonomethylglycine phytotoxicant composition |
-
1978
- 1978-01-03 US US05/866,677 patent/US4140513A/en not_active Expired - Lifetime
- 1978-12-27 RO RO96069A patent/RO79038B/ro unknown
- 1978-12-27 YU YU03101/78A patent/YU310178A/xx unknown
- 1978-12-27 RO RO78115568A patent/RO89365A/ro unknown
- 1978-12-28 JP JP16599778A patent/JPS54109921A/ja active Granted
- 1978-12-28 CH CH1325478A patent/CH641187A5/de not_active IP Right Cessation
- 1978-12-28 ZA ZA00787349A patent/ZA787349B/xx unknown
- 1978-12-29 ES ES476485A patent/ES476485A1/es not_active Expired
- 1978-12-29 NL NL7812635A patent/NL7812635A/xx unknown
- 1978-12-29 BE BE192664A patent/BE873199A/xx not_active IP Right Cessation
-
1979
- 1979-01-02 BG BG043569A patent/BG40656A3/xx unknown
- 1979-01-02 NO NO790009A patent/NO150841C/no unknown
- 1979-01-02 ZM ZM2/79A patent/ZM279A1/xx unknown
- 1979-01-02 IL IL56356A patent/IL56356A/xx unknown
- 1979-01-02 IT IT19009/79A patent/IT1162701B/it active
- 1979-01-02 PL PL1979212563A patent/PL114405B1/pl unknown
- 1979-01-02 DK DK000979A patent/DK158356C/da not_active IP Right Cessation
- 1979-01-02 DE DE2900025A patent/DE2900025C2/de not_active Expired
- 1979-01-02 PH PH22009A patent/PH19009A/en unknown
- 1979-01-02 BG BG041935A patent/BG29424A3/xx unknown
- 1979-01-02 EG EG6/79A patent/EG13903A/xx active
- 1979-01-02 PT PT69016A patent/PT69016A/pt unknown
- 1979-01-02 IE IE10/79A patent/IE47773B1/en unknown
- 1979-01-02 CA CA000318977A patent/CA1120951A/en not_active Expired
- 1979-01-02 AR AR275038A patent/AR221857A1/es active
- 1979-01-02 FR FR7900052A patent/FR2413398A1/fr active Granted
- 1979-01-02 AU AU43047/79A patent/AU522518B2/en not_active Ceased
- 1979-01-02 AT AT0001179A patent/AT363274B/de not_active IP Right Cessation
- 1979-01-02 CS CS7957A patent/CS207728B2/cs unknown
- 1979-01-02 DD DD79210300A patent/DD140968A5/de not_active IP Right Cessation
- 1979-01-02 MW MW1/79A patent/MW179A1/xx unknown
- 1979-01-02 FI FI790006A patent/FI65437C/fi not_active IP Right Cessation
- 1979-01-02 SE SE7900016A patent/SE444685B/sv not_active IP Right Cessation
- 1979-01-02 IN IN3/CAL/79A patent/IN150741B/en unknown
- 1979-01-02 PL PL1979223647A patent/PL119534B1/pl unknown
- 1979-01-02 BR BR7900007A patent/BR7900007A/pt unknown
- 1979-01-02 GB GB7933A patent/GB2011906B/en not_active Expired
- 1979-01-02 HU HU79MO1033A patent/HU184659B/hu not_active IP Right Cessation
- 1979-01-03 MX MX797623U patent/MX5697E/es unknown
-
1980
- 1980-02-08 SU SU802877858A patent/SU1050565A3/ru active
-
1983
- 1983-08-29 SG SG548/83A patent/SG54883G/en unknown
- 1983-10-27 KE KE3342A patent/KE3342A/xx unknown
-
1984
- 1984-01-05 HK HK6/84A patent/HK684A/xx unknown
- 1984-12-30 MY MY322/84A patent/MY8400322A/xx unknown
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