CN1934232A - 润滑性水系聚氨酯树脂组合物、使用该组合物的镀锌系钢板的表面润滑处理方法及该表面处理钢板 - Google Patents
润滑性水系聚氨酯树脂组合物、使用该组合物的镀锌系钢板的表面润滑处理方法及该表面处理钢板 Download PDFInfo
- Publication number
- CN1934232A CN1934232A CNA2005800089300A CN200580008930A CN1934232A CN 1934232 A CN1934232 A CN 1934232A CN A2005800089300 A CNA2005800089300 A CN A2005800089300A CN 200580008930 A CN200580008930 A CN 200580008930A CN 1934232 A CN1934232 A CN 1934232A
- Authority
- CN
- China
- Prior art keywords
- steel sheet
- polyurethane resin
- zinc
- aqueous polyurethane
- plated steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 53
- 239000010959 steel Substances 0.000 title claims abstract description 53
- 229920005749 polyurethane resin Polymers 0.000 title claims abstract description 52
- 239000011342 resin composition Substances 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims description 34
- 230000001050 lubricating effect Effects 0.000 title claims description 17
- 239000007787 solid Substances 0.000 claims abstract description 42
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 27
- 229920000728 polyester Polymers 0.000 claims abstract description 27
- 229920000570 polyether Polymers 0.000 claims abstract description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002245 particle Substances 0.000 claims abstract description 21
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims description 52
- 239000011701 zinc Substances 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 21
- 229910052725 zinc Inorganic materials 0.000 claims description 21
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 17
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 239000000084 colloidal system Substances 0.000 claims description 10
- 230000007704 transition Effects 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 238000005461 lubrication Methods 0.000 claims description 6
- 239000000314 lubricant Substances 0.000 claims description 3
- 239000008247 solid mixture Substances 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 abstract description 20
- 230000007797 corrosion Effects 0.000 abstract description 20
- 238000000576 coating method Methods 0.000 abstract description 17
- 239000011248 coating agent Substances 0.000 abstract description 15
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- 239000008119 colloidal silica Substances 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
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- 210000000981 epithelium Anatomy 0.000 description 43
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- 229910052804 chromium Inorganic materials 0.000 description 17
- 239000011651 chromium Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- 150000003016 phosphoric acids Chemical class 0.000 description 13
- 239000000243 solution Substances 0.000 description 12
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 239000002253 acid Substances 0.000 description 9
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- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 9
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 239000007858 starting material Substances 0.000 description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 238000007747 plating Methods 0.000 description 6
- 229920005906 polyester polyol Polymers 0.000 description 6
- DBXBTMSZEOQQDU-UHFFFAOYSA-N 3-hydroxyisobutyric acid Chemical compound OCC(C)C(O)=O DBXBTMSZEOQQDU-UHFFFAOYSA-N 0.000 description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
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- 239000007864 aqueous solution Substances 0.000 description 5
- UYFMQPGSLRHGFE-UHFFFAOYSA-N cyclohexylmethylcyclohexane;isocyanic acid Chemical class N=C=O.N=C=O.C1CCCCC1CC1CCCCC1 UYFMQPGSLRHGFE-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
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- 239000000463 material Substances 0.000 description 5
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- 230000001869 rapid Effects 0.000 description 5
- 239000003643 water by type Substances 0.000 description 5
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 4
- 229930185605 Bisphenol Natural products 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical group 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 3
- 229910000165 zinc phosphate Inorganic materials 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
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- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
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- 239000003814 drug Substances 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- MQXNNWDXHFBFEB-UHFFFAOYSA-N 2,2-bis(2-hydroxyphenyl)propane Chemical compound C=1C=CC=C(O)C=1C(C)(C)C1=CC=CC=C1O MQXNNWDXHFBFEB-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- YHFGMFYKZBWPRW-UHFFFAOYSA-N 3-methylpentane-1,1-diol Chemical compound CCC(C)CC(O)O YHFGMFYKZBWPRW-UHFFFAOYSA-N 0.000 description 1
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- 241001163841 Albugo ipomoeae-panduratae Species 0.000 description 1
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- 229920000877 Melamine resin Polymers 0.000 description 1
- 229910006776 Si—Zn Inorganic materials 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 229910007567 Zn-Ni Inorganic materials 0.000 description 1
- 229910007614 Zn—Ni Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- LJXTYJXBORAIHX-UHFFFAOYSA-N diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1 LJXTYJXBORAIHX-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
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- 239000003292 glue Substances 0.000 description 1
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- 230000002401 inhibitory effect Effects 0.000 description 1
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- 229910000765 intermetallic Inorganic materials 0.000 description 1
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- HXHCOXPZCUFAJI-UHFFFAOYSA-N prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1 HXHCOXPZCUFAJI-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- -1 silane compound Chemical class 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
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- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/041—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving a condensation reaction
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/045—Polyureas; Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/055—Particles related characteristics
- C10N2020/06—Particles of special shape or size
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/079—Liquid crystals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/14—Electric or magnetic purposes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Lubricants (AREA)
- Polyurethanes Or Polyureas (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
No | 商标 | 固体成分浓度 | 熔点 | 粒径 | 备注 |
b1 | ケミパ一ルWF640 | 40% | 113℃ | 1.0μm | 用于实施例 |
b2 | ケミパ一ルWP250 | 40% | 148℃ | 0.8μm | 用于实施例 |
b3 | ケミパ一ルW400 | 40% | 113℃ | 4.0μm | 用于实施例 |
b4 | ケミパ一ルW200 | 40% | 113℃ | 6.0μm | 用于比较例 |
No | 商标 | 固体成分浓度 | 粒径 | 备注 |
c1 | スノ一テツクス-C | 20% | 20nm | 用于实 |
施例 | ||||
c2 | スノ一テツクス-XS | 15% | 5nm | 用于实施例 |
c3 | MP-2040 | 40% | 200nm | 用于比较例 |
No | (a)聚氨酯树脂 | (b)聚烯烃树脂 | (c)胶体二氧化硅 |
d1 | a1(70) | b1(10) | c1(20) |
d2 | a2(75) | b1(10) | c1(15) |
d3 | a3(65) | b1(10) | c1(25) |
d4 | a3(60) | b1(2) | c1(38) |
d5 | a1(60) | b1(20) | c1(20) |
d6 | a1(80) | b1(15) | c1(5) |
d7 | a1(70) | b2(10) | c1(20) |
d8 | a1(70) | b3(10) | c1(20) |
d9 | a1(70) | b1(10) | c2(20) |
No | (a)聚氨酯树脂 | (b)聚烯烃树脂 | (c)胶体二氧化硅 | 备注 |
d10 | a4(70) | b1(10) | c1(20) | 成分(a)在本申请发明范围外 |
d11 | a5(75) | b1(10) | c1(15) | 成分(a)在本申请发明范围外 |
d12 | a1(65) | b4(10) | c1(25) | 成分(b)在本申请发明范围外 |
d13 | a1(70) | b1(10) | c3(20) | 成分(c)在本申请发明范围外 |
d14 | a1(80) | 无 | c1(20) | 无成分(b) |
d15 | a1(85) | b1(15) | 无 | 无成分(c) |
实施例No | 原材料 | 基底处理 | 润滑性树脂组合物处理 | 皮膜性能 | ||||||
种类 | 附着量*1 | 种类 | 附着量(g/m2)*1 | 温度(℃)*2 | 耐蚀性 | 耐碱性 | 粘附性 | 润滑性 | ||
1 | EG | 铬酸盐 | 0.02 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
2 | EG | 铬酸盐 | 0.02 | d2 | 1.0 | 120 | 4 | 4 | 4 | 4 |
3 | EG | 铬酸盐 | 0.02 | d3 | 1.0 | 120 | 4 | 4 | 4 | 4 |
4 | EG | 铬酸盐 | 0.02 | d4 | 1.0 | 120 | 4 | 4 | 4 | 4 |
5 | EG | 铬酸盐 | 0.02 | d5 | 1.0 | 120 | 4 | 4 | 4 | 4 |
6 | EG | 铬酸盐 | 0.02 | d6 | 1.0 | 120 | 4 | 4 | 4 | 4 |
7 | EG | 铬酸盐 | 0.02 | d7 | 1.0 | 120 | 4 | 4 | 4 | 4 |
8 | EG | 铬酸盐 | 0.02 | d8 | 1.0 | 120 | 4 | 4 | 4 | 4 |
9 | EG | 铬酸盐 | 0.02 | d9 | 1.0 | 120 | 4 | 4 | 4 | 4 |
10 | GI | 铬酸盐 | 0.02 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
11 | GI | 铬酸盐 | 0.02 | d2 | 1.0 | 120 | 4 | 4 | 4 | 4 |
12 | GI | 铬酸盐 | 0.02 | d3 | 1.0 | 120 | 4 | 4 | 4 | 4 |
13 | GI | 铬酸盐 | 0.02 | d7 | 1.0 | 120 | 4 | 4 | 4 | 4 |
14 | GI | 铬酸盐 | 0.02 | d8 | 1.0 | 120 | 4 | 4 | 4 | 4 |
15 | GL | 铬酸盐 | 0.02 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
16 | GL | 铬酸盐 | 0.02 | d2 | 1.0 | 120 | 4 | 4 | 4 | 4 |
17 | GL | 铬酸盐 | 0.02 | d3 | 1.0 | 120 | 4 | 4 | 4 | 4 |
18 | GL | 铬酸盐 | 0.02 | d7 | 1.0 | 120 | 4 | 4 | 4 | 4 |
19 | GL | 铬酸盐 | 0.02 | d8 | 1.0 | 120 | 4 | 4 | 4 | 4 |
20 | ZL | 铬酸盐 | 0.02 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
21 | ZL | 铬酸盐 | 0.02 | d2 | 1.0 | 120 | 4 | 4 | 4 | 4 |
22 | ZL | 铬酸盐 | 0.02 | d3 | 1.0 | 120 | 4 | 4 | 4 | 4 |
24 | ZL | 铬酸盐 | 0.02 | d7 | 1.0 | 120 | 4 | 4 | 4 | 4 |
25 | ZL | 铬酸盐 | 0.02 | d8 | 1.0 | 120 | 4 | 4 | 4 | 4 |
实施例No | 原材料 | 基底处理 | 润滑性树脂组合物处理 | 皮膜性能 | ||||||
种类 | 附着量*1 | 种类 | 附着量(g/m2)*1 | 温度(℃)*2 | 耐蚀性 | 耐碱性 | 粘附性 | 润滑性 | ||
26 | SD | 铬酸盐 | 0.02 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
27 | SD | 铬酸盐 | 0.02 | d2 | 1.0 | 120 | 4 | 4 | 4 | 4 |
28 | SD | 铬酸盐 | 0.02 | d3 | 1.0 | 120 | 4 | 4 | 4 | 4 |
29 | SD | 铬酸盐 | 0.02 | d7 | 1.0 | 120 | 4 | 4 | 4 | 4 |
30 | SD | 铬酸盐 | 0.02 | d8 | 1.0 | 120 | 4 | 4 | 4 | 4 |
31 | EG | 铬酸盐 | 0.02 | d1 | 0.5 | 120 | 4 | 4 | 4 | 4 |
32 | EG | 铬酸盐 | 0.02 | d1 | 3.0 | 120 | 4 | 3 | 4 | 4 |
33 | GI | 铬酸盐 | 0.02 | d1 | 3.0 | 120 | 4 | 4 | 4 | 4 |
34 | GL | 铬酸盐 | 0.02 | d1 | 3.0 | 120 | 4 | 4 | 4 | 4 |
35 | ZL | 铬酸盐 | 0.02 | d1 | 3.0 | 120 | 4 | 4 | 4 | 4 |
36 | SD | 铬酸盐 | 0.02 | d1 | 3.0 | 120 | 4 | 4 | 4 | 4 |
37 | EG | 铬酸盐 | 0.02 | d1 | 5.0 | 120 | 4 | 4 | 4 | 4 |
38 | EG | 铬酸盐 | 0.001 | d1 | 1.0 | 120 | 3 | 4 | 3 | 4 |
39 | EG | 铬酸盐 | 0.1 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
40 | EG | 铬酸盐 | 0.02 | d1 | 1.0 | 100 | 4 | 4 | 4 | 4 |
41 | EG | 铬酸盐 | 0.02 | d1 | 1.0 | 150 | 4 | 4 | 4 | 4 |
42 | EG | 铬酸盐 | 0.02 | d1 | 1.0 | 180 | 4 | 4 | 4 | 4 |
43 | GI | 铬酸盐 | 0.02 | d1 | 1.0 | 180 | 4 | 4 | 4 | 4 |
44 | GL | 铬酸盐 | 0.02 | d1 | 1.0 | 180 | 4 | 4 | 4 | 4 |
45 | ZL | 铬酸盐 | 0.02 | d1 | 1.0 | 180 | 4 | 4 | 4 | 4 |
46 | SD | 铬酸盐 | 0.02 | d1 | 1.0 | 180 | 4 | 4 | 4 | 4 |
47 | EG | 铬酸盐 | 0.02 | d1 | 1.0 | 200 | 4 | 4 | 4 | 4 |
48 | EG | 磷酸盐 | 2.0 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
49 | EG | 磷酸盐 | 2.0 | d2 | 1.0 | 120 | 4 | 4 | 4 | 4 |
50 | EG | 磷酸盐 | 2.0 | d3 | 1.0 | 120 | 4 | 4 | 4 | 4 |
51 | EG | 磷酸盐 | 2.0 | d4 | 1.0 | 120 | 4 | 4 | 4 | 4 |
52 | EG | 磷酸盐 | 2.0 | d5 | 1.0 | 120 | 4 | 4 | 4 | 4 |
53 | EG | 磷酸盐 | 2.0 | d6 | 1.0 | 120 | 4 | 4 | 4 | 4 |
实施例No | 原材料 | 基底处理 | 润滑性树脂组合物处理 | 皮膜性能 | ||||||
种类 | 附着量*1 | 种类 | 附着量(g/m2)*1 | 温度(℃)*2 | 耐蚀性 | 耐碱性 | 粘附性 | 润滑性 | ||
54 | EG | 磷酸盐 | 2.0 | d7 | 1.0 | 120 | 4 | 4 | 4 | 4 |
55 | EG | 磷酸盐 | 2.0 | d8 | 1.0 | 120 | 4 | 4 | 4 | 4 |
56 | EG | 磷酸盐 | 2.0 | d9 | 1.0 | 120 | 4 | 4 | 4 | 4 |
57 | GI | 磷酸盐 | 2.0 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
58 | GL | 磷酸盐 | 2.0 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
59 | ZL | 磷酸盐 | 2.0 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
60 | SD | 磷酸盐 | 2.0 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
61 | EG | 非铬 | 0.2 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
62 | EG | 非铬 | 0.2 | d2 | 1.0 | 120 | 4 | 4 | 4 | 4 |
63 | EG | 非铬 | 0.2 | d3 | 1.0 | 120 | 4 | 4 | 4 | 4 |
64 | EG | 非铬 | 0.2 | d4 | 1.0 | 120 | 4 | 4 | 4 | 4 |
65 | EG | 非铬 | 0.2 | d5 | 1.0 | 120 | 4 | 4 | 4 | 4 |
66 | EG | 非铬 | 0.2 | d6 | 1.0 | 120 | 4 | 4 | 4 | 4 |
67 | EG | 非铬 | 0.2 | d7 | 1.0 | 120 | 4 | 4 | 4 | 4 |
68 | EG | 非铬 | 0.2 | d8 | 1.0 | 120 | 4 | 4 | 4 | 4 |
69 | EG | 非铬 | 0.2 | d9 | 1.0 | 120 | 4 | 4 | 4 | 4 |
70 | GI | 非铬 | 0.2 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
71 | GL | 非铬 | 0.2 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
72 | ZL | 非铬 | 0.2 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
73 | SD | 非铬 | 0.2 | d1 | 1.0 | 120 | 4 | 4 | 4 | 4 |
74 | SD | 无 | - | d1 | 2.0 | 120 | 4 | 4 | 4 | 4 |
比较例No | 原材料 | 底层 | 面层 | 皮膜性能 | ||||||
种类 | 附着量*1 | 种类 | 附着量(g/m2)*1 | 温度(℃)*2 | 耐蚀性 | 耐碱性 | 粘附性 | 润滑性 | ||
1 | EG | 铬酸盐 | 0.02 | d10 | 1.0 | 120 | 3 | 2 | 1 | 2 |
2 | EG | 铬酸盐 | 0.02 | d11 | 1.0 | 120 | 3 | 2 | 3 | 1 |
3 | EG | 铬酸盐 | 0.02 | d12 | 1.0 | 120 | 3 | 3 | 3 | 1 |
4 | EG | 铬酸盐 | 0.02 | d13 | 1.0 | 120 | 2 | 1 | 3 | 3 |
5 | EG | 铬酸盐 | 0.02 | d14 | 1.0 | 120 | 3 | 2 | 3 | 1 |
6 | EG | 铬酸盐 | 0.02 | d15 | 1.0 | 120 | 1 | 1 | 1 | 2 |
7 | GI | 铬酸盐 | 0.02 | d10 | 1.0 | 120 | 3 | 2 | 1 | 2 |
8 | GL | 铬酸盐 | 0.02 | d10 | 1.0 | 120 | 3 | 2 | 1 | 2 |
9 | ZL | 铬酸盐 | 0.02 | d10 | 1.0 | 120 | 3 | 2 | 1 | 2 |
10 | SD | 铬酸盐 | 0.02 | d10 | 1.0 | 120 | 3 | 2 | 1 | 2 |
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JP2004017313A JP4671609B2 (ja) | 2004-01-26 | 2004-01-26 | 潤滑性水系ポリウレタン樹脂組成物、それを用いる亜鉛系メッキ鋼板の表面潤滑処理方法及びその表面処理鋼板 |
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KR (1) | KR100744094B1 (zh) |
CN (1) | CN100554389C (zh) |
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TW (1) | TWI300094B (zh) |
WO (1) | WO2005071052A1 (zh) |
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CN104497841A (zh) * | 2014-12-15 | 2015-04-08 | 中国钢研科技集团有限公司 | 一种镀锌钢板表面水性无铬润滑处理剂及其使用方法 |
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JP5135669B2 (ja) * | 2005-09-16 | 2013-02-06 | 新日鐵住金株式会社 | 塗装金属材の製造方法 |
AR082749A1 (es) | 2009-04-15 | 2013-01-09 | Bayer Materialscience Ag | Dispersiones de poliuretano para la pasivacion organica |
JP4980470B2 (ja) * | 2009-05-11 | 2012-07-18 | 新日本製鐵株式会社 | 表面処理金属材及びその製造方法 |
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JP2511497B2 (ja) * | 1988-05-31 | 1996-06-26 | 川崎製鉄株式会社 | 成形性に優れた潤滑樹脂処理鋼板 |
JP2719571B2 (ja) * | 1992-11-12 | 1998-02-25 | 日本パーカライジング株式会社 | 水系潤滑性塗料組成物 |
JP2743237B2 (ja) * | 1992-12-02 | 1998-04-22 | 新日本製鐵株式会社 | プレス油省略可能非脱膜型潤滑めっき鋼板 |
JPH0711089A (ja) * | 1993-06-21 | 1995-01-13 | Kansai Paint Co Ltd | 潤滑性皮膜を形成可能な組成物及びこれを使用した潤滑性の優れた金属板 |
JPH09221690A (ja) * | 1995-12-12 | 1997-08-26 | New Japan Chem Co Ltd | 冷凍機用潤滑油 |
JP2000239690A (ja) * | 1998-12-25 | 2000-09-05 | Nippon Parkerizing Co Ltd | 耐傷つき性に優れた潤滑皮膜形成用水系金属表面処理組成物 |
JP2002012885A (ja) * | 2000-06-28 | 2002-01-15 | Nippon Parkerizing Co Ltd | 水系潤滑剤及び金属材料の表面処理方法 |
JP2002144478A (ja) * | 2000-11-16 | 2002-05-21 | Nippon Steel Corp | 成形性に優れたアルカリ可溶型潤滑表面処理金属製品 |
JP2003003278A (ja) * | 2001-03-30 | 2003-01-08 | Nippon Steel Corp | 連続成形性に優れたアルカリ可溶型潤滑表面処理金属製品 |
JP3547414B2 (ja) * | 2001-08-17 | 2004-07-28 | 新日本製鐵株式会社 | 加工部の耐食性に優れ環境負荷の小さい非脱膜型潤滑めっき鋼板 |
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CN103102790A (zh) * | 2013-01-30 | 2013-05-15 | 马鞍山钢铁股份有限公司 | 一种镀锌钢板用润滑涂料、自润滑镀锌钢板及其生产方法 |
CN103102790B (zh) * | 2013-01-30 | 2016-02-10 | 马鞍山钢铁股份有限公司 | 一种镀锌钢板用润滑涂料、自润滑镀锌钢板及其生产方法 |
CN104497841A (zh) * | 2014-12-15 | 2015-04-08 | 中国钢研科技集团有限公司 | 一种镀锌钢板表面水性无铬润滑处理剂及其使用方法 |
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KR100744094B1 (ko) | 2007-08-01 |
TW200536932A (en) | 2005-11-16 |
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Owner name: NIPPON STEEL + SUMITOMO METAL CORPORATION Free format text: FORMER NAME: SHIN NIPPON STEEL LTD. |
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CP01 | Change in the name or title of a patent holder |
Address after: Tokyo, Japan, Japan Patentee after: Nippon Steel Corporation Patentee after: Nihon Parkerizing Co., Ltd. Address before: Tokyo, Japan, Japan Patentee before: Nippon Steel Corporation Patentee before: Nihon Parkerizing Co., Ltd. |
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CP01 | Change in the name or title of a patent holder |
Address after: Tokyo, Japan, Japan Co-patentee after: Nihon Parkerizing Co., Ltd. Patentee after: Nippon Iron & Steel Corporation Address before: Tokyo, Japan, Japan Co-patentee before: Nihon Parkerizing Co., Ltd. Patentee before: Nippon Steel Corporation |
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CP01 | Change in the name or title of a patent holder |