CN1751405A - 用于锂二次电池的负极活性物质、锂二次电池的负极和锂二次电池 - Google Patents
用于锂二次电池的负极活性物质、锂二次电池的负极和锂二次电池 Download PDFInfo
- Publication number
- CN1751405A CN1751405A CNA2004800047695A CN200480004769A CN1751405A CN 1751405 A CN1751405 A CN 1751405A CN A2004800047695 A CNA2004800047695 A CN A2004800047695A CN 200480004769 A CN200480004769 A CN 200480004769A CN 1751405 A CN1751405 A CN 1751405A
- Authority
- CN
- China
- Prior art keywords
- secondary battery
- lithium secondary
- active material
- particle
- littler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 113
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 98
- 239000007773 negative electrode material Substances 0.000 title description 2
- 239000000843 powder Substances 0.000 claims abstract description 100
- 238000000034 method Methods 0.000 claims abstract description 66
- 239000006185 dispersion Substances 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011368 organic material Substances 0.000 claims abstract description 13
- 230000008719 thickening Effects 0.000 claims abstract description 13
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 9
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 9
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 9
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims description 227
- 239000011149 active material Substances 0.000 claims description 125
- 239000011258 core-shell material Substances 0.000 claims description 57
- 239000003792 electrolyte Substances 0.000 claims description 12
- 230000009467 reduction Effects 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 239000013543 active substance Substances 0.000 abstract 6
- 230000000977 initiatory effect Effects 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 127
- 239000010439 graphite Substances 0.000 description 80
- 229910002804 graphite Inorganic materials 0.000 description 80
- 239000000463 material Substances 0.000 description 73
- 239000000203 mixture Substances 0.000 description 46
- 239000002002 slurry Substances 0.000 description 41
- -1 for example Substances 0.000 description 33
- 238000012360 testing method Methods 0.000 description 29
- 239000004020 conductor Substances 0.000 description 24
- 229910052799 carbon Inorganic materials 0.000 description 23
- 235000013339 cereals Nutrition 0.000 description 23
- 238000000576 coating method Methods 0.000 description 20
- 238000009826 distribution Methods 0.000 description 20
- 239000011248 coating agent Substances 0.000 description 19
- 239000006183 anode active material Substances 0.000 description 18
- 239000002131 composite material Substances 0.000 description 18
- 229920001577 copolymer Polymers 0.000 description 18
- 239000002904 solvent Substances 0.000 description 17
- 239000007770 graphite material Substances 0.000 description 16
- 230000004888 barrier function Effects 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 15
- 230000008569 process Effects 0.000 description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 13
- 229910003481 amorphous carbon Inorganic materials 0.000 description 13
- 238000005259 measurement Methods 0.000 description 13
- 238000001465 metallisation Methods 0.000 description 13
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000012298 atmosphere Substances 0.000 description 12
- 239000007833 carbon precursor Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- 229920000554 ionomer Polymers 0.000 description 12
- 239000003960 organic solvent Substances 0.000 description 12
- 230000003746 surface roughness Effects 0.000 description 12
- 230000004087 circulation Effects 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000005977 Ethylene Substances 0.000 description 10
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 239000013078 crystal Substances 0.000 description 9
- 239000000835 fiber Substances 0.000 description 9
- 238000004898 kneading Methods 0.000 description 9
- 238000001507 sample dispersion Methods 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 239000000945 filler Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000007774 positive electrode material Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000000543 intermediate Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000007784 solid electrolyte Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 239000006230 acetylene black Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 229910003002 lithium salt Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000001237 Raman spectrum Methods 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 4
- 239000003125 aqueous solvent Substances 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 4
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- QHSJIZLJUFMIFP-UHFFFAOYSA-N ethene;1,1,2,2-tetrafluoroethene Chemical compound C=C.FC(F)=C(F)F QHSJIZLJUFMIFP-UHFFFAOYSA-N 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- 159000000002 lithium salts Chemical class 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 4
- 229920002857 polybutadiene Polymers 0.000 description 4
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 238000012216 screening Methods 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 3
- 229910013870 LiPF 6 Inorganic materials 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 239000011305 binder pitch Substances 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 150000003950 cyclic amides Chemical class 0.000 description 3
- 150000005676 cyclic carbonates Chemical class 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000005486 organic electrolyte Substances 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 229920006389 polyphenyl polymer Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000007790 scraping Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 229920001897 terpolymer Polymers 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 2
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- 229920000914 Metallic fiber Polymers 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 229910004283 SiO 4 Inorganic materials 0.000 description 2
- 229920006355 Tefzel Polymers 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- 239000005030 aluminium foil Substances 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000006231 channel black Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 150000004292 cyclic ethers Chemical class 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical group COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 2
- 150000004862 dioxolanes Chemical class 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 239000011532 electronic conductor Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 239000006232 furnace black Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000005087 graphitization Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 229910003480 inorganic solid Inorganic materials 0.000 description 2
- 239000010416 ion conductor Substances 0.000 description 2
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- 150000002642 lithium compounds Chemical class 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000010301 surface-oxidation reaction Methods 0.000 description 2
- 239000006234 thermal black Substances 0.000 description 2
- 238000004227 thermal cracking Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 229910000314 transition metal oxide Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- PYOKUURKVVELLB-UHFFFAOYSA-N trimethyl orthoformate Chemical compound COC(OC)OC PYOKUURKVVELLB-UHFFFAOYSA-N 0.000 description 2
- 229920005609 vinylidenefluoride/hexafluoropropylene copolymer Polymers 0.000 description 2
- 238000004736 wide-angle X-ray diffraction Methods 0.000 description 2
- TWNIBLMWSKIRAT-RWOPYEJCSA-N (1r,2s,3s,4s,5r)-6,8-dioxabicyclo[3.2.1]octane-2,3,4-triol Chemical compound O1[C@@]2([H])OC[C@]1([H])[C@@H](O)[C@H](O)[C@@H]2O TWNIBLMWSKIRAT-RWOPYEJCSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- CFQPVBJOKYSPKG-UHFFFAOYSA-N 1,3-dimethylimidazol-2-one Chemical compound CN1C=CN(C)C1=O CFQPVBJOKYSPKG-UHFFFAOYSA-N 0.000 description 1
- OHZAHWOAMVVGEL-UHFFFAOYSA-N 2,2'-bithiophene Chemical compound C1=CSC(C=2SC=CC=2)=C1 OHZAHWOAMVVGEL-UHFFFAOYSA-N 0.000 description 1
- IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical compound O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- PPDFQRAASCRJAH-UHFFFAOYSA-N 2-methylthiolane 1,1-dioxide Chemical compound CC1CCCS1(=O)=O PPDFQRAASCRJAH-UHFFFAOYSA-N 0.000 description 1
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical group O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 1
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-OUBTZVSYSA-N Ammonia-15N Chemical compound [15NH3] QGZKDVFQNNGYKY-OUBTZVSYSA-N 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 229910018871 CoO 2 Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- 229910000760 Hardened steel Inorganic materials 0.000 description 1
- 229910013043 Li3PO4-Li2S-SiS2 Inorganic materials 0.000 description 1
- 229910013035 Li3PO4-Li2S—SiS2 Inorganic materials 0.000 description 1
- 229910012810 Li3PO4—Li2S-SiS2 Inorganic materials 0.000 description 1
- 229910012797 Li3PO4—Li2S—SiS2 Inorganic materials 0.000 description 1
- 229910012047 Li4SiO4-LiI-LiOH Inorganic materials 0.000 description 1
- 229910012075 Li4SiO4-LiI—LiOH Inorganic materials 0.000 description 1
- 229910012057 Li4SiO4—LiI—LiOH Inorganic materials 0.000 description 1
- 229910010238 LiAlCl 4 Inorganic materials 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- 229910013292 LiNiO Inorganic materials 0.000 description 1
- 229910013872 LiPF Inorganic materials 0.000 description 1
- 229910012513 LiSbF 6 Inorganic materials 0.000 description 1
- 101150058243 Lipf gene Proteins 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- BEKPOUATRPPTLV-UHFFFAOYSA-N [Li].BCl Chemical compound [Li].BCl BEKPOUATRPPTLV-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 125000004054 acenaphthylenyl group Chemical group C1(=CC2=CC=CC3=CC=CC1=C23)* 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- HXGDTGSAIMULJN-UHFFFAOYSA-N acetnaphthylene Natural products C1=CC(C=C2)=C3C2=CC=CC3=C1 HXGDTGSAIMULJN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 150000003983 crown ethers Chemical class 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- CUIWZLHUNCCYBL-UHFFFAOYSA-N decacyclene Chemical compound C12=C([C]34)C=CC=C4C=CC=C3C2=C2C(=C34)C=C[CH]C4=CC=CC3=C2C2=C1C1=CC=CC3=CC=CC2=C31 CUIWZLHUNCCYBL-UHFFFAOYSA-N 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000009795 derivation Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229940035423 ethyl ether Drugs 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 1
- 125000000457 gamma-lactone group Chemical group 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002641 lithium Chemical class 0.000 description 1
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011302 mesophase pitch Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229910000484 niobium oxide Inorganic materials 0.000 description 1
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 150000005181 nitrobenzenes Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920003208 poly(ethylene sulfide) Polymers 0.000 description 1
- 229920002627 poly(phosphazenes) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000379 polypropylene carbonate Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000009700 powder processing Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 239000003115 supporting electrolyte Substances 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- RIUWBIIVUYSTCN-UHFFFAOYSA-N trilithium borate Chemical compound [Li+].[Li+].[Li+].[O-]B([O-])[O-] RIUWBIIVUYSTCN-UHFFFAOYSA-N 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
细度计的类型 | 刻度间隔(μm) | 检验范围(μm) |
细度计(100μm) | 10 | 40-90 |
细度计(50μm) | 5 | 15-40 |
细度计(25μm) | 2.5 | 5-15 |
应用标准,JIS B06590(用于比较的标准表面粗糙度片) | ||
按部分进行分级 | 粗糙度符号 | 三角形符号 |
细度计的槽/刮刀的尖端 | SN4 | |
细度计/刮刀的其他部分 | SN5 | |
实施例 | 负极活性材料粉末 | 负极板的表面粗糙度(Ra)(μm) | 电池性能 | |||||||||||||
种类 | 性质 | 初始输出(%) | 高温循环中的容量保持率(%) | 脉冲循环后的恢复率(%) | ||||||||||||
d002(nm) | Lc(nm) | R值(-) | Δv(cm-1) | 激光衍射 | BET比表面积(m2/g) | 用细度计检测 | ||||||||||
平均粒径(D50)(μm) | 最大粒径(Dmax)(μm) | 最大分散粒径(μm) | 35-50μm粒子数 | 平均分散粒径(μm) | ||||||||||||
实施例 | 1 | 无定形涂覆石墨粉末 | 0.336 | ≥100 | 0.33 | 29.0 | 11 | 32 | 5.5 | 25 | 0 | 20 | 2 | 161 | 84 | 85 |
2 | 无定形涂覆石墨粉末 | 0.336 | ≥100 | 0.41 | 35.6 | 11 | 34 | 3.7 | 25 | 0 | 20 | 2 | 150 | 88 | 88 | |
3 | 无定形涂覆石墨粉末 | 0.336 | ≥100 | 0.61 | 59.0 | 12 | 34 | 2.0 | 25 | 0 | 20 | 2 | 156 | 89 | 88 | |
4 | 天然石墨粉末 | 0.335 | ≥100 | 0.16 | 25.8 | 11 | 39 | 10.6 | 35 | 1 | 25 | 1 | 156 | 83 | 78 | |
5 | 无定形涂覆石墨粉末 | 0.336 | ≥100 | 0.38 | 36.0 | 15 | 68 | 2.3 | 50 | 8 | 30 | 3 | 150 | 86 | 86 | |
6 | 细的石墨复合粉末 | 0.335 | ≥100 | 0.16 | 24.3 | 13 | 45 | 4.8 | 40 | 9 | 30 | 3 | 156 | 82 | 73 | |
7 | 无定形碳粉末 | 0.345 | 3.8 | 0.99 | 54.3 | 11 | 38 | 7.0 | 40 | 15 | 30 | 3 | 122 | 89 | 90 |
实施例 | 负极活性材料粉末 | 负极板的表面粗糙度(Ra)(μm) | 电池性能 | |||||||||||||
种类 | 性质 | 初始输出(%) | 高温循环中的容量保持率(%) | 脉冲循环后的恢复率(%) | ||||||||||||
d002(nm) | Lc(nm) | R值(-) | △v(cm-1) | 激光衍射 | BET比表面积(m2/g) | 用细度计检测 | ||||||||||
平均粒径(D50)(μm) | 最大粒径(Dmax)(μm) | 最大分散粒径(μm) | 35-50μm粒子数 | 平均分散粒径(μm) | ||||||||||||
比较例 | 1 | 无定形涂覆石墨粉末 | 0.336 | ≥100 | 0.38 | 36.0 | 22 | 101 | 2.3 | 70 | ≥20 | 60 | 8 | 100 | 80 | 停止* |
2 | 细的石墨复合粉末 | 0.335 | ≥100 | 0.16 | 24.3 | 17 | 90 | 4.7 | 60 | ≥20 | 50 | 8 | 106 | 80 | 停止* | |
3 | 无定形涂覆石墨粉末 | 0.336 | ≥100 | 0.38 | 36.0 | 21 | 90 | 2.3 | 60 | ≥20 | 50 | 8 | 100 | 82 | 停止* |
Claims (4)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP42985/2003 | 2003-02-20 | ||
JP2003042985 | 2003-02-20 | ||
PCT/JP2004/001793 WO2004075319A1 (ja) | 2003-02-20 | 2004-02-18 | リチウム二次電池用負極活物質、リチウム二次電池負極及びリチウム二次電池 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1751405A true CN1751405A (zh) | 2006-03-22 |
CN1751405B CN1751405B (zh) | 2010-12-08 |
Family
ID=32905385
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2004800047695A Expired - Lifetime CN1751405B (zh) | 2003-02-20 | 2004-02-18 | 锂二次电池的负极和锂二次电池 |
CNB2004800101524A Expired - Fee Related CN100377393C (zh) | 2003-02-20 | 2004-02-18 | 用于锂二次电池的负极和锂二次电池 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004800101524A Expired - Fee Related CN100377393C (zh) | 2003-02-20 | 2004-02-18 | 用于锂二次电池的负极和锂二次电池 |
Country Status (5)
Country | Link |
---|---|
US (1) | US7208248B2 (zh) |
EP (1) | EP1596451A4 (zh) |
KR (1) | KR100754258B1 (zh) |
CN (2) | CN1751405B (zh) |
WO (1) | WO2004075319A1 (zh) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102341947A (zh) * | 2009-03-18 | 2012-02-01 | 日立麦克赛尔能源株式会社 | 电化学元件 |
CN101636862B (zh) * | 2007-03-26 | 2012-03-21 | 丰田自动车株式会社 | 经处理的活性材料、其处理方法及含有该经处理的活性材料的糊料 |
CN102473915A (zh) * | 2010-06-30 | 2012-05-23 | 松下电器产业株式会社 | 非水电解质二次电池用负极及其制造方法 |
CN104114488A (zh) * | 2011-12-16 | 2014-10-22 | 杰富意化学株式会社 | 非晶碳粒子的制造方法、非晶碳粒子、锂离子二次电池用负极材料以及锂离子二次电池 |
CN105308787A (zh) * | 2013-03-14 | 2016-02-03 | Nec能源元器件株式会社 | 锂离子二次电池及其充电方法 |
CN108155351A (zh) * | 2016-12-06 | 2018-06-12 | 宁德时代新能源科技股份有限公司 | 锂离子电池及其负极材料 |
CN110048082A (zh) * | 2019-04-03 | 2019-07-23 | 合肥国轩高科动力能源有限公司 | 减小锂离子电池石墨负极极片取向值的方法及所得极片 |
CN111656577A (zh) * | 2018-01-17 | 2020-09-11 | 远景Aesc能源元器件有限公司 | 锂离子电池用电极以及锂离子电池 |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060036147A1 (en) * | 2004-07-20 | 2006-02-16 | Scimed Life Systems, Inc. | Systems and methods for detecting and presenting textural information from medical images |
CN100438197C (zh) * | 2004-09-24 | 2008-11-26 | 比亚迪股份有限公司 | 一种非水电解液及其锂离子二次电池 |
KR100759751B1 (ko) * | 2006-05-08 | 2007-10-04 | 주식회사 에코프로 | 하이드로 싸이클론을 이용한 리튬 이차전지 양극 활물질의제조방법 및 그 제조장치 |
JP2010034024A (ja) * | 2008-06-25 | 2010-02-12 | Hitachi Maxell Ltd | リチウムイオン二次電池 |
JP5367521B2 (ja) * | 2009-09-18 | 2013-12-11 | Jx日鉱日石エネルギー株式会社 | リチウム二次電池の負極用炭素材料及びその製造方法 |
JP2011142066A (ja) * | 2009-12-11 | 2011-07-21 | Sanyo Electric Co Ltd | リチウム二次電池 |
US10461366B1 (en) | 2010-01-18 | 2019-10-29 | Enevate Corporation | Electrolyte compositions for batteries |
US20170040598A1 (en) | 2015-08-07 | 2017-02-09 | Enevate Corporation | Surface modification of silicon particles for electrochemical storage |
US9553303B2 (en) | 2010-01-18 | 2017-01-24 | Enevate Corporation | Silicon particles for battery electrodes |
US11380890B2 (en) | 2010-01-18 | 2022-07-05 | Enevate Corporation | Surface modification of silicon particles for electrochemical storage |
US20130040206A1 (en) * | 2010-02-26 | 2013-02-14 | Zeon Corporation | All solid-state secondary battery and a production method of an all solid-state secondary battery |
US20110256449A1 (en) * | 2010-04-19 | 2011-10-20 | Conocophillips Company | Organic coated fine particle powders |
EP2600449A4 (en) * | 2010-07-30 | 2016-09-28 | Hitachi Chemical Co Ltd | MINUS POLYMER FOR A LITHIUMION SECONDARY BATTERY, MINUS POLICE FOR A LITHIUMION SECONDARY BATTERY, AND A LITHIUMION SECONDARY BATTERY |
CN102332604A (zh) * | 2011-03-09 | 2012-01-25 | 东莞新能源科技有限公司 | 一种高功率锂离子电池 |
US8481425B2 (en) | 2011-05-16 | 2013-07-09 | United Microelectronics Corp. | Method for fabricating through-silicon via structure |
US8822336B2 (en) | 2011-06-16 | 2014-09-02 | United Microelectronics Corp. | Through-silicon via forming method |
US8828745B2 (en) | 2011-07-06 | 2014-09-09 | United Microelectronics Corp. | Method for manufacturing through-silicon via |
US8518823B2 (en) | 2011-12-23 | 2013-08-27 | United Microelectronics Corp. | Through silicon via and method of forming the same |
US8609529B2 (en) | 2012-02-01 | 2013-12-17 | United Microelectronics Corp. | Fabrication method and structure of through silicon via |
US8691600B2 (en) | 2012-05-02 | 2014-04-08 | United Microelectronics Corp. | Method for testing through-silicon-via (TSV) structures |
US8691688B2 (en) | 2012-06-18 | 2014-04-08 | United Microelectronics Corp. | Method of manufacturing semiconductor structure |
US9275933B2 (en) | 2012-06-19 | 2016-03-01 | United Microelectronics Corp. | Semiconductor device |
US8900996B2 (en) | 2012-06-21 | 2014-12-02 | United Microelectronics Corp. | Through silicon via structure and method of fabricating the same |
US8525296B1 (en) | 2012-06-26 | 2013-09-03 | United Microelectronics Corp. | Capacitor structure and method of forming the same |
US8912844B2 (en) | 2012-10-09 | 2014-12-16 | United Microelectronics Corp. | Semiconductor structure and method for reducing noise therein |
US9035457B2 (en) | 2012-11-29 | 2015-05-19 | United Microelectronics Corp. | Substrate with integrated passive devices and method of manufacturing the same |
US8716104B1 (en) | 2012-12-20 | 2014-05-06 | United Microelectronics Corp. | Method of fabricating isolation structure |
US8884398B2 (en) | 2013-04-01 | 2014-11-11 | United Microelectronics Corp. | Anti-fuse structure and programming method thereof |
US9287173B2 (en) | 2013-05-23 | 2016-03-15 | United Microelectronics Corp. | Through silicon via and process thereof |
US10062898B2 (en) | 2013-07-10 | 2018-08-28 | GM Global Technology Operations LLC | Surface coating method and method for improving electrochemical performance of an electrode for a lithium based battery |
DE102014109441B4 (de) * | 2013-07-10 | 2023-10-12 | GM Global Technology Operations LLC (n. d. Ges. d. Staates Delaware) | Oberflächenbeschichtungsverfahren und verfahren zur herstellung einer elektrode für eine lithium-basierte batterie |
US9123730B2 (en) | 2013-07-11 | 2015-09-01 | United Microelectronics Corp. | Semiconductor device having through silicon trench shielding structure surrounding RF circuit |
US9024416B2 (en) | 2013-08-12 | 2015-05-05 | United Microelectronics Corp. | Semiconductor structure |
US8916471B1 (en) | 2013-08-26 | 2014-12-23 | United Microelectronics Corp. | Method for forming semiconductor structure having through silicon via for signal and shielding structure |
US9048223B2 (en) | 2013-09-03 | 2015-06-02 | United Microelectronics Corp. | Package structure having silicon through vias connected to ground potential |
US9117804B2 (en) | 2013-09-13 | 2015-08-25 | United Microelectronics Corporation | Interposer structure and manufacturing method thereof |
US9343359B2 (en) | 2013-12-25 | 2016-05-17 | United Microelectronics Corp. | Integrated structure and method for fabricating the same |
US10340203B2 (en) | 2014-02-07 | 2019-07-02 | United Microelectronics Corp. | Semiconductor structure with through silicon via and method for fabricating and testing the same |
WO2016065230A1 (en) | 2014-10-23 | 2016-04-28 | Energizer Brands, Llc | Zinc anode composition |
US10205206B2 (en) | 2014-10-08 | 2019-02-12 | Energizer Brands, Llc | Zinc-air electrochemical cell |
US10381643B2 (en) | 2014-10-08 | 2019-08-13 | Energizer Brands, Llc | Fluorosurfactant as a zinc corrosion inhibitor |
US10312501B2 (en) | 2014-12-10 | 2019-06-04 | GM Global Technology Operations LLC | Electrolyte and negative electrode structure |
US20160172710A1 (en) | 2014-12-10 | 2016-06-16 | The Regents Of The University Of California | Electrolyte and negative electrode structure |
KR102659163B1 (ko) * | 2016-04-20 | 2024-04-22 | 삼성전자주식회사 | 양극 및 이를 포함하는 리튬전지 |
CN107482203B (zh) * | 2017-08-21 | 2020-12-18 | 北方奥钛纳米技术有限公司 | 石墨负极材料的包覆改性方法及石墨负极材料和应用 |
WO2019066480A2 (ko) | 2017-09-28 | 2019-04-04 | 주식회사 엘지화학 | 전극 슬러리의 공정성 예측 및 전극 바인더 선정 방법 |
WO2019112643A1 (en) | 2017-12-07 | 2019-06-13 | Enevate Corporation | Composite comprising silicon carbide and carbon particles |
KR20220111852A (ko) * | 2021-02-03 | 2022-08-10 | 현대자동차주식회사 | 액상 교반을 통한 전고체 전지용 고체전해질의 제조방법 |
US11387443B1 (en) | 2021-11-22 | 2022-07-12 | Enevate Corporation | Silicon based lithium ion battery and improved cycle life of same |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3188033B2 (ja) * | 1993-04-02 | 2001-07-16 | 三洋電機株式会社 | 非水系二次電池 |
CA2238286C (en) * | 1995-11-14 | 2004-02-17 | Osaka Gas Company Limited | Material for negative electrode of lithium secondary battery, method for production thereof and lithium secondary battery using the same |
JP3575651B2 (ja) * | 1996-06-04 | 2004-10-13 | 株式会社デンソー | 二次電池用負極および非水電解質二次電池 |
JPH1078123A (ja) * | 1996-09-05 | 1998-03-24 | Toyota Motor Corp | 変速機の制御装置 |
JP3541913B2 (ja) * | 1996-11-27 | 2004-07-14 | 株式会社デンソー | 非水電解液二次電池 |
US5908715A (en) * | 1997-05-30 | 1999-06-01 | Hughes Electronics Corporation | Composite carbon materials for lithium ion batteries, and method of producing same |
KR100483126B1 (ko) * | 1997-05-30 | 2005-04-14 | 마츠시타 덴끼 산교 가부시키가이샤 | 비수전해질 2차전지 |
JP4187347B2 (ja) * | 1998-04-02 | 2008-11-26 | 三星エスディアイ株式会社 | リチウムイオン電池用負極活物質の製造方法 |
EP1122803A4 (en) | 1998-10-09 | 2005-04-13 | Showa Denko Kk | CARBON MATERIAL FOR CELL AND CELL CONTAINING SAME |
JP2000323174A (ja) | 1999-05-12 | 2000-11-24 | Japan Storage Battery Co Ltd | 非水電解質二次電池 |
JP4751497B2 (ja) | 1999-12-20 | 2011-08-17 | 日本ゼオン株式会社 | リチウムイオン二次電池電極の製法、電極及び電池 |
JP5303817B2 (ja) * | 2001-07-25 | 2013-10-02 | ソニー株式会社 | 非水電解質二次電池 |
JP4207443B2 (ja) | 2002-03-20 | 2009-01-14 | 日本ゼオン株式会社 | 二次電池電極用スラリー組成物、二次電池電極および二次電池 |
JP3709987B2 (ja) * | 2001-12-04 | 2005-10-26 | 日本カーボン株式会社 | リチウムイオン系二次電池用負極材およびその製造方法、および該負極材を用いたリチウムイオン系二次電池 |
KR20020042586A (ko) * | 2002-05-10 | 2002-06-05 | 이영균 | 인편상 흑연으로부터 구형화된 흑연 재료를 제조하는 방법및 이를 사용한 리튬 2차 전지용 음극 활물질의 제조방법 |
JP2004103435A (ja) * | 2002-09-11 | 2004-04-02 | Hitachi Maxell Ltd | リチウム二次電池 |
-
2004
- 2004-02-18 CN CN2004800047695A patent/CN1751405B/zh not_active Expired - Lifetime
- 2004-02-18 KR KR1020057015468A patent/KR100754258B1/ko active IP Right Grant
- 2004-02-18 EP EP04712180A patent/EP1596451A4/en not_active Withdrawn
- 2004-02-18 CN CNB2004800101524A patent/CN100377393C/zh not_active Expired - Fee Related
- 2004-02-18 WO PCT/JP2004/001793 patent/WO2004075319A1/ja active Application Filing
-
2005
- 2005-08-18 US US11/206,159 patent/US7208248B2/en not_active Expired - Lifetime
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101636862B (zh) * | 2007-03-26 | 2012-03-21 | 丰田自动车株式会社 | 经处理的活性材料、其处理方法及含有该经处理的活性材料的糊料 |
CN102341947A (zh) * | 2009-03-18 | 2012-02-01 | 日立麦克赛尔能源株式会社 | 电化学元件 |
CN102473915A (zh) * | 2010-06-30 | 2012-05-23 | 松下电器产业株式会社 | 非水电解质二次电池用负极及其制造方法 |
CN104114488B (zh) * | 2011-12-16 | 2016-10-19 | 杰富意化学株式会社 | 非晶碳粒子的制造方法、非晶碳粒子、锂离子二次电池用负极材料以及锂离子二次电池 |
CN104114488A (zh) * | 2011-12-16 | 2014-10-22 | 杰富意化学株式会社 | 非晶碳粒子的制造方法、非晶碳粒子、锂离子二次电池用负极材料以及锂离子二次电池 |
CN105308787B (zh) * | 2013-03-14 | 2017-12-29 | Nec 能源元器件株式会社 | 锂离子二次电池及其充电方法 |
CN105308787A (zh) * | 2013-03-14 | 2016-02-03 | Nec能源元器件株式会社 | 锂离子二次电池及其充电方法 |
US10069177B2 (en) | 2013-03-14 | 2018-09-04 | Nec Energy Devices, Ltd. | Lithium ion secondary battery and charging method therefor |
CN108155351A (zh) * | 2016-12-06 | 2018-06-12 | 宁德时代新能源科技股份有限公司 | 锂离子电池及其负极材料 |
WO2018103332A1 (zh) * | 2016-12-06 | 2018-06-14 | 宁德时代新能源科技股份有限公司 | 锂离子电池及其负极材料 |
CN108155351B (zh) * | 2016-12-06 | 2021-06-22 | 宁德时代新能源科技股份有限公司 | 锂离子电池及其负极材料 |
CN111656577A (zh) * | 2018-01-17 | 2020-09-11 | 远景Aesc能源元器件有限公司 | 锂离子电池用电极以及锂离子电池 |
CN111656577B (zh) * | 2018-01-17 | 2023-01-10 | 远景Aesc日本有限公司 | 锂离子电池用电极以及锂离子电池 |
CN110048082A (zh) * | 2019-04-03 | 2019-07-23 | 合肥国轩高科动力能源有限公司 | 减小锂离子电池石墨负极极片取向值的方法及所得极片 |
Also Published As
Publication number | Publication date |
---|---|
US20060035146A1 (en) | 2006-02-16 |
CN1751405B (zh) | 2010-12-08 |
EP1596451A4 (en) | 2008-07-09 |
EP1596451A1 (en) | 2005-11-16 |
US7208248B2 (en) | 2007-04-24 |
CN1774826A (zh) | 2006-05-17 |
WO2004075319A1 (ja) | 2004-09-02 |
KR100754258B1 (ko) | 2007-09-03 |
CN100377393C (zh) | 2008-03-26 |
KR20050106023A (ko) | 2005-11-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1751405A (zh) | 用于锂二次电池的负极活性物质、锂二次电池的负极和锂二次电池 | |
CN1076711C (zh) | 石墨颗粒、其生产方法、含该颗粒的负极和锂二次电池 | |
CN1157813C (zh) | 锂离子蓄电池负极材料用的石墨粉 | |
EP1605536A1 (en) | Negative electrode of lithium secondary battery and lithium secondary battery | |
CN1228872C (zh) | 锂二次电池 | |
CN1091954C (zh) | 用于锂二次电池的碳素材料及其制造工艺 | |
CN1088266C (zh) | 非水电解液二次电池 | |
CN1802761A (zh) | 用于电池电极的碳材料及其制备方法和用途 | |
CN1897330A (zh) | 非水电解质二次电池 | |
CN1265480C (zh) | 电池 | |
CN1495938A (zh) | 用于非水电解质二次电池的阴极材料、其生产方法以及非水电解质二次电池 | |
CN1585159A (zh) | 电极用复合颗粒及其制造方法、电极及其制造方法以及电化学元件及其制造方法 | |
CN1340869A (zh) | 阴极活性材料及其制备方法,非水电解质电池及其制备方法 | |
KR20170111637A (ko) | 전극 슬러리의 제조방법 | |
CN101053098A (zh) | 用于非水二次电池的负极材料、用于非水二次电池的负极、和非水二次电池 | |
CN1685556A (zh) | 非水电解质溶液和使用它的非水电解质溶液二次电池 | |
CN1925192A (zh) | 非水电解质二次电池 | |
CN1461283A (zh) | 球形碳及其制备方法 | |
CN1816927A (zh) | 电极用碳素材料及其制造方法、电池用电极及其制造方法、电极及其制造方法 | |
CN1198255A (zh) | 非水电解液蓄电池用负极材料及使用这种负极材料的非水电解液蓄电池 | |
JP4765253B2 (ja) | リチウム二次電池用負極活物質、リチウム二次電池負極及びリチウム二次電池 | |
CN1830103A (zh) | 高密度电极及使用该电极的电池 | |
KR20150107674A (ko) | 리튬이온 이차전지용 부극 활물질 및 그것을 사용한 리튬이온 이차전지 부극 및 리튬이온 이차전지 | |
CN1272863C (zh) | 二次电池用正极活性物质和采用该物质的非水电解液二次电池及其正极活性物质的分析方法 | |
CN1881664A (zh) | 石墨颗粒 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP01 | Change in the name or title of a patent holder |
Address after: Tokyo, Japan Patentee after: MITSUBISHI CHEMICAL Corp. Address before: Tokyo, Japan Patentee before: MITSUBISHI RAYON Co.,Ltd. |
|
CP01 | Change in the name or title of a patent holder | ||
TR01 | Transfer of patent right |
Effective date of registration: 20170912 Address after: Tokyo, Japan Patentee after: MITSUBISHI RAYON Co.,Ltd. Address before: Tokyo, Japan Patentee before: MITSUBISHI CHEMICAL Corp. |
|
TR01 | Transfer of patent right | ||
CX01 | Expiry of patent term |
Granted publication date: 20101208 |
|
CX01 | Expiry of patent term |