CN1639212A - 作为脱蜡添加剂的共聚物 - Google Patents
作为脱蜡添加剂的共聚物 Download PDFInfo
- Publication number
- CN1639212A CN1639212A CNA03804952XA CN03804952A CN1639212A CN 1639212 A CN1639212 A CN 1639212A CN A03804952X A CNA03804952X A CN A03804952XA CN 03804952 A CN03804952 A CN 03804952A CN 1639212 A CN1639212 A CN 1639212A
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- CN
- China
- Prior art keywords
- ester
- multipolymer
- methyl
- dewaxing
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000012188 paraffin wax Substances 0.000 claims abstract description 13
- 239000002480 mineral oil Substances 0.000 claims abstract description 9
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 9
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
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- 125000004494 ethyl ester group Chemical group 0.000 description 5
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- 238000005227 gel permeation chromatography Methods 0.000 description 5
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- 239000000243 solution Substances 0.000 description 5
- 238000005809 transesterification reaction Methods 0.000 description 5
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 4
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
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- 241000612703 Augusta Species 0.000 description 1
- VCKHUTJVGJBGFO-UHFFFAOYSA-N C(=C)C=1NC=CN1.CC1=C(C(=O)O)C=CC=C1C(=O)O Chemical compound C(=C)C=1NC=CN1.CC1=C(C(=O)O)C=CC=C1C(=O)O VCKHUTJVGJBGFO-UHFFFAOYSA-N 0.000 description 1
- RORCIEJDYKQKJL-UHFFFAOYSA-N C(=C)[O].C(C(=C)C)(=O)O Chemical compound C(=C)[O].C(C(=C)C)(=O)O RORCIEJDYKQKJL-UHFFFAOYSA-N 0.000 description 1
- LRZYLLVRVRDUOP-UHFFFAOYSA-N C(C)C(C(=O)P(O)(O)=O)=C(C)CC Chemical compound C(C)C(C(=O)P(O)(O)=O)=C(C)CC LRZYLLVRVRDUOP-UHFFFAOYSA-N 0.000 description 1
- GEXBPPNORUPMKU-UHFFFAOYSA-N C(C=C)(=O)OC.CC(CO)CCC(CO)C Chemical compound C(C=C)(=O)OC.CC(CO)CCC(CO)C GEXBPPNORUPMKU-UHFFFAOYSA-N 0.000 description 1
- VGIIKDXZZPQRQL-UHFFFAOYSA-N C(C=CC)(=O)OCCCCCCCCCCCCCCC Chemical compound C(C=CC)(=O)OCCCCCCCCCCCCCCC VGIIKDXZZPQRQL-UHFFFAOYSA-N 0.000 description 1
- BDJVEBUABHVBJH-UHFFFAOYSA-N C(CCCCCCCCCC)OC(=O)C=CC Chemical compound C(CCCCCCCCCC)OC(=O)C=CC BDJVEBUABHVBJH-UHFFFAOYSA-N 0.000 description 1
- HHCXCCCCGSADTD-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCCC)OC(=O)C=CC Chemical compound C(CCCCCCCCCCCCCCCCCC)OC(=O)C=CC HHCXCCCCGSADTD-UHFFFAOYSA-N 0.000 description 1
- SLUBNSHWAOBMCN-UHFFFAOYSA-N C1(CCCCC1)[O].CC(C(=O)O)=C Chemical compound C1(CCCCC1)[O].CC(C(=O)O)=C SLUBNSHWAOBMCN-UHFFFAOYSA-N 0.000 description 1
- NJOLLDDWCSUSCA-UHFFFAOYSA-N C=C.BrC=1C(=C(C=CC1)Br)Br Chemical compound C=C.BrC=1C(=C(C=CC1)Br)Br NJOLLDDWCSUSCA-UHFFFAOYSA-N 0.000 description 1
- DUUSWXBAUSDNRJ-UHFFFAOYSA-N CC(=C)C([O])=O Chemical compound CC(=C)C([O])=O DUUSWXBAUSDNRJ-UHFFFAOYSA-N 0.000 description 1
- BHVQBTYQHWWPLL-UHFFFAOYSA-N CC(C(=O)O)=C.C(C1=CC=CC=C1)[O] Chemical compound CC(C(=O)O)=C.C(C1=CC=CC=C1)[O] BHVQBTYQHWWPLL-UHFFFAOYSA-N 0.000 description 1
- RTOLYLCWGYQESB-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCCCCCCOC(=O)C=CC Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)C=CC RTOLYLCWGYQESB-UHFFFAOYSA-N 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- GDFCSMCGLZFNFY-UHFFFAOYSA-N Dimethylaminopropyl Methacrylamide Chemical compound CN(C)CCCNC(=O)C(C)=C GDFCSMCGLZFNFY-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- SQHOHKQMTHROSF-UHFFFAOYSA-N but-1-en-2-ylbenzene Chemical compound CCC(=C)C1=CC=CC=C1 SQHOHKQMTHROSF-UHFFFAOYSA-N 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- GQVCNZBQZKXBMX-UHFFFAOYSA-N butan-2-one;toluene Chemical compound CCC(C)=O.CC1=CC=CC=C1 GQVCNZBQZKXBMX-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- AWGWKAZLSXEUBI-UHFFFAOYSA-N carboxy 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(O)=O AWGWKAZLSXEUBI-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- JNNKWUPPLJTSSJ-UHFFFAOYSA-N chloromethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCl JNNKWUPPLJTSSJ-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- WDNCEPPQUKCFBL-UHFFFAOYSA-N cyclopentyl but-2-enoate Chemical compound CC=CC(=O)OC1CCCC1 WDNCEPPQUKCFBL-UHFFFAOYSA-N 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- IYNRVIKPUTZSOR-UHFFFAOYSA-N ethenyl but-2-enoate Chemical compound CC=CC(=O)OC=C IYNRVIKPUTZSOR-UHFFFAOYSA-N 0.000 description 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 150000002237 fumaric acid derivatives Chemical class 0.000 description 1
- 102000054766 genetic haplotypes Human genes 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 150000003944 halohydrins Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- DXSOPPVDQKAVFB-UHFFFAOYSA-N heptadecyl but-2-enoate Chemical compound C(CCCCCCCCCCCCCCCC)OC(=O)C=CC DXSOPPVDQKAVFB-UHFFFAOYSA-N 0.000 description 1
- DOBPEHKISOHXTE-UHFFFAOYSA-N heptyl but-2-enoate Chemical compound CCCCCCCOC(=O)C=CC DOBPEHKISOHXTE-UHFFFAOYSA-N 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000007074 heterocyclization reaction Methods 0.000 description 1
- LAAFBFYXEJYWMQ-UHFFFAOYSA-N hexadecyl but-2-enoate Chemical compound C(CCCCCCCCCCCCCCC)OC(=O)C=CC LAAFBFYXEJYWMQ-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- BAZQYVYVKYOAGO-UHFFFAOYSA-M loxoprofen sodium hydrate Chemical group O.O.[Na+].C1=CC(C(C([O-])=O)C)=CC=C1CC1C(=O)CCC1 BAZQYVYVKYOAGO-UHFFFAOYSA-M 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- UNBDCVXGGDKSCP-UHFFFAOYSA-N methyl 2-methylidenetetradecanoate Chemical compound CCCCCCCCCCCCC(=C)C(=O)OC UNBDCVXGGDKSCP-UHFFFAOYSA-N 0.000 description 1
- 239000012120 mounting media Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- GFNHASIYLNRZIC-UHFFFAOYSA-N phosphono 2-methyl-3-propylhex-2-enoate Chemical compound CCCC(CCC)=C(C)C(=O)OP(O)(O)=O GFNHASIYLNRZIC-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- BVMNCGXSFZQPNI-UHFFFAOYSA-N prop-2-ynyl but-2-enoate Chemical compound CC=CC(=O)OCC#C BVMNCGXSFZQPNI-UHFFFAOYSA-N 0.000 description 1
- RYYCFQTWLMFJIG-UHFFFAOYSA-N propylcyanamide Chemical compound CCCNC#N RYYCFQTWLMFJIG-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- NCYNWQDLQJUTIY-UHFFFAOYSA-N tetradecyl but-2-enoate Chemical compound CCCCCCCCCCCCCCOC(=O)C=CC NCYNWQDLQJUTIY-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
- C10G73/02—Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils
- C10G73/06—Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils with the use of solvents
- C10G73/08—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Lubricants (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
Description
过滤 P6 P6 P7 P7 P8 P8时间 没有 (800ppm) (800ppm) (1370ppm)(1370ppm)(1230ppm)(1230ppm)[s] 添加剂 + + + + + +P1 C1 P1 C1 P1 C1(300ppm) (300ppm) (200ppm) (200ppm) (200ppm) (200ppm)0 0 0 0 0 0 0 010 1 7 3 9 6 5 220 2 9 14 8 9 330 2 10 8 17 11 10 440 3 11 9 19 13 12 550 3.5 12 9 21 14 13.5 660 4 13 9.5 23 15 14.5 770 5 14 10 24.5 17 15.5 880 5.5 15 10.5 26 18 16.5 990 6.5 16 11 27.5 19 17.5 9.5100 7 16.5 11 28 20 18 10120 8 18 12 30.5 22 20 10140 8.5 19.5 12.5 33 23.5 21 11160 9.5 21 13 36 25 22.5 11180 10 22 14 37.5 27 23.5 12200 10 23.5 15 39.5 28 25 12.5240 11 25 16 42.5 30 27 13300 12 28.5 18 47.5 34 30 15600 16 39 24.5 69.5 47 41 20 |
过滤 没有添加剂 P6(800ppm) P7(1370ppm) P6(800ppm)时间 + + +[s] P1(300ppm) P1(200ppm) C1(300ppm)0 0 0 0 0100 8.5 18 19 16200 11 24.5 27 22300 12.5 30 32 26.5420 14 35 38 31480 15 38 40 33600 16.5 42 45 37720 17.5 46 49 40840 18.5 50 53 42.5900 19.5 52.5 55 44 |
过滤 没有 P6(800ppm) P6(800ppm)时间 添加剂 + + |
[s] P1(150ppm) C1(400ppm)0 0 0 050 17 38 31100 24 55 45150 29 68 56 |
过滤 没有 C1 P1 P2 P4 P5时间[s] 添加剂 (300ppm) (300ppm) (300ppm) (300ppm) (300ppm)0 0 0 0 0 0 010 1 1 3 1 3.5 220 2 1 4.5 2 4.5 3.530 2 1.5 5.5 2.5 5.5 540 3 2 6.5 3.5 6.5 650 3.5 2.5 8 4.5 7.5 760 4 3 9 6 8.5 870 5 3.5 9 7 9.5 8.580 5.5 4 10 8 10 990 6.5 4.5 10.5 8.5 10 9.5100 7 5 11 8.5 10 9.5120 8 5.5 12 9.5 11 10140 8.5 6 13 10 11.5 10 |
160 9.5 6.5 14 10 12 11180 10 7 14.5 10.5 13 11.5200 10 7.5 15 11 14 12240 11 8 17 12 15 13300 12 9 18.5 13 16.5 14600 16 12 26 18 23 19.5 |
Claims (15)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10208799.7 | 2002-03-01 | ||
DE10208799 | 2002-03-01 |
Publications (2)
Publication Number | Publication Date |
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CN1639212A true CN1639212A (zh) | 2005-07-13 |
CN100335515C CN100335515C (zh) | 2007-09-05 |
Family
ID=27770908
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNB03804952XA Expired - Lifetime CN100335515C (zh) | 2002-03-01 | 2003-02-14 | 作为脱蜡添加剂的共聚物 |
Country Status (12)
Country | Link |
---|---|
US (1) | US7728093B2 (zh) |
EP (1) | EP1453872B1 (zh) |
JP (1) | JP4605750B2 (zh) |
KR (2) | KR100905211B1 (zh) |
CN (1) | CN100335515C (zh) |
AU (1) | AU2003210270A1 (zh) |
BR (1) | BRPI0308077B1 (zh) |
CA (1) | CA2477081C (zh) |
HU (1) | HUE030226T2 (zh) |
MX (1) | MXPA04008420A (zh) |
PT (1) | PT1453872E (zh) |
WO (1) | WO2003074578A1 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103339234A (zh) * | 2011-02-09 | 2013-10-02 | 赢创油品添加剂有限公司 | 将矿物油组合物脱蜡的方法 |
CN108949221A (zh) * | 2018-07-17 | 2018-12-07 | 中国石油大学(华东) | 一种磁性脱蜡剂及磁性脱蜡方法 |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100905211B1 (ko) | 2002-03-01 | 2009-07-01 | 에보니크 로막스 아디티페스 게엠베하 | 탈왁스 첨가제로서의 공중합체 |
DE10249295A1 (de) | 2002-10-22 | 2004-05-13 | Rohmax Additives Gmbh | Polymerdispersionen mit hoher Stabilität und Verfahren zur Herstellung |
DE10249294A1 (de) * | 2002-10-22 | 2004-05-13 | Rohmax Additives Gmbh | Stabile Polymerdispersionen und Verfahren zur Herstellung |
DE10249292A1 (de) * | 2002-10-22 | 2004-05-13 | Rohmax Additives Gmbh | Polymerdispersionen mit geringer Viskosität und Verfahren zur Herstellung |
DE10314776A1 (de) * | 2003-03-31 | 2004-10-14 | Rohmax Additives Gmbh | Schmierölzusammensetzung mit guten Reibeigenschaften |
DE102004018093A1 (de) * | 2004-04-08 | 2005-10-27 | Rohmax Additives Gmbh | Polymere mit H-Brücken bildenden Funktionalitäten |
DE102004018094A1 (de) * | 2004-04-08 | 2005-11-03 | Rohmax Additives Gmbh | Polymere mit H-Brücken bildenden Funktionalitäten zur Verbesserung des Verschleißschutzes |
DE102004021778A1 (de) * | 2004-04-30 | 2005-12-08 | Rohmax Additives Gmbh | Verwendung von Polyalkyl(meth)acrylaten in Schmierölzusammensetzungen |
US7429555B2 (en) * | 2004-04-30 | 2008-09-30 | Rohmax Additives Gmbh | Lubricating grease with high water resistance |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103339234A (zh) * | 2011-02-09 | 2013-10-02 | 赢创油品添加剂有限公司 | 将矿物油组合物脱蜡的方法 |
CN103339234B (zh) * | 2011-02-09 | 2016-01-20 | 赢创油品添加剂有限公司 | 将矿物油组合物脱蜡的方法 |
CN108949221A (zh) * | 2018-07-17 | 2018-12-07 | 中国石油大学(华东) | 一种磁性脱蜡剂及磁性脱蜡方法 |
CN108949221B (zh) * | 2018-07-17 | 2020-12-01 | 中国石油大学(华东) | 一种磁性脱蜡剂及磁性脱蜡方法 |
Also Published As
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KR100950175B1 (ko) | 2010-03-30 |
JP4605750B2 (ja) | 2011-01-05 |
BR0308077A (pt) | 2004-12-21 |
KR20080112422A (ko) | 2008-12-24 |
CN100335515C (zh) | 2007-09-05 |
HUE030226T2 (en) | 2017-04-28 |
EP1453872A1 (de) | 2004-09-08 |
WO2003074578A1 (de) | 2003-09-12 |
JP2005526873A (ja) | 2005-09-08 |
CA2477081C (en) | 2009-12-01 |
AU2003210270A1 (en) | 2003-09-16 |
KR20040105743A (ko) | 2004-12-16 |
BRPI0308077B1 (pt) | 2017-06-06 |
US7728093B2 (en) | 2010-06-01 |
US20050148749A1 (en) | 2005-07-07 |
CA2477081A1 (en) | 2003-09-12 |
MXPA04008420A (es) | 2005-05-17 |
KR100905211B1 (ko) | 2009-07-01 |
PT1453872E (pt) | 2016-06-02 |
EP1453872B1 (de) | 2016-04-13 |
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