CN1537137A - 阻燃模塑组合物 - Google Patents
阻燃模塑组合物 Download PDFInfo
- Publication number
- CN1537137A CN1537137A CNA028137027A CN02813702A CN1537137A CN 1537137 A CN1537137 A CN 1537137A CN A028137027 A CNA028137027 A CN A028137027A CN 02813702 A CN02813702 A CN 02813702A CN 1537137 A CN1537137 A CN 1537137A
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- Prior art keywords
- moulding compound
- transition metal
- metal oxide
- epoxy
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- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 61
- 238000000465 moulding Methods 0.000 title claims abstract description 28
- 239000003063 flame retardant Substances 0.000 title claims abstract description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 229910000314 transition metal oxide Inorganic materials 0.000 claims abstract description 81
- 239000003870 refractory metal Substances 0.000 claims abstract description 15
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 11
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 11
- 150000002367 halogens Chemical class 0.000 claims abstract description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 11
- 239000011574 phosphorus Substances 0.000 claims abstract description 11
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims abstract description 11
- BIOOACNPATUQFW-UHFFFAOYSA-N calcium;dioxido(dioxo)molybdenum Chemical compound [Ca+2].[O-][Mo]([O-])(=O)=O BIOOACNPATUQFW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 7
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- 239000000206 moulding compound Substances 0.000 claims description 113
- 239000004593 Epoxy Substances 0.000 claims description 48
- 239000011347 resin Substances 0.000 claims description 41
- 229920005989 resin Polymers 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 36
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 26
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 22
- 229930003836 cresol Natural products 0.000 claims description 12
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- 239000004305 biphenyl Substances 0.000 claims description 11
- 238000013329 compounding Methods 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 239000010937 tungsten Substances 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 4
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052762 osmium Inorganic materials 0.000 claims description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 239000010948 rhodium Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 239000004065 semiconductor Substances 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
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- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 abstract description 2
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- 238000002485 combustion reaction Methods 0.000 description 10
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 8
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 8
- 239000002516 radical scavenger Substances 0.000 description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 7
- 239000006229 carbon black Substances 0.000 description 7
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- 229910021485 fumed silica Inorganic materials 0.000 description 7
- 229910000077 silane Inorganic materials 0.000 description 7
- 239000001993 wax Substances 0.000 description 7
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 4
- 229940087305 limonene Drugs 0.000 description 4
- 235000001510 limonene Nutrition 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 3
- -1 glycidyl compound Chemical class 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
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- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- 231100000357 carcinogen Toxicity 0.000 description 2
- 239000003183 carcinogenic agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 239000012747 synergistic agent Substances 0.000 description 2
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 2
- WFOVEDJTASPCIR-UHFFFAOYSA-N 3-[(4-methyl-5-pyridin-4-yl-1,2,4-triazol-3-yl)methylamino]-n-[[2-(trifluoromethyl)phenyl]methyl]benzamide Chemical compound N=1N=C(C=2C=CN=CC=2)N(C)C=1CNC(C=1)=CC=CC=1C(=O)NCC1=CC=CC=C1C(F)(F)F WFOVEDJTASPCIR-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229910001051 Magnalium Inorganic materials 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000013506 data mapping Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
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- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
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- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Substances C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/28—Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
- H01L23/29—Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the material, e.g. carbon
- H01L23/293—Organic, e.g. plastic
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3256—Molybdenum oxides, molybdates or oxide forming salts thereof, e.g. cadmium molybdate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3258—Tungsten oxides, tungstates, or oxide-forming salts thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
- C04B2235/424—Carbon black
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
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- C—CHEMISTRY; METALLURGY
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
- C04B2235/483—Si-containing organic compounds, e.g. silicone resins, (poly)silanes, (poly)siloxanes or (poly)silazanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- H01—ELECTRIC ELEMENTS
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- H05K3/22—Secondary treatment of printed circuits
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
Description
样品 | 18A | 19A | 20A | 21A | 22A | 23A |
氧化硅填料(wt%) | 83.09 | 82.89 | 82.49 | 81.69 | 80.19 | 83.19 |
联苯树脂(wt%) | 5.34 | 5.34 | 5.34 | 5.34 | 5.34 | 5.34 |
环氧甲酚线型酚醛清漆树脂(wt%) | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 |
煅制氧化硅(wt%) | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 |
炭黑着色剂(wt%) | 0.30 | 0.30 | 0.30 | 0.30 | 0.30 | 0.30 |
苧烯型硬化剂(来自Yuka Shell)(wt%) | 1.45 | 1.45 | 1.45 | 1.45 | 1.45 | 1.45 |
线型酚醛清漆树脂硬化剂(wt%) | 2.47 | 2.47 | 2.47 | 2.47 | 2.47 | 2.47 |
催化剂(wt%) | 0.23 | 0.23 | 0.23 | 0.23 | 0.23 | 0.23 |
蜡(wt%) | 0.74 | 0.74 | 0.74 | 0.74 | 0.74 | 0.74 |
硅烷(wt%) | 1.05 | 1.05 | 1.05 | 1.05 | 1.05 | 1.05 |
弹性体(wt%) | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 |
WO3(wt%) | 0.75 | 0.75 | 0.75 | 0.75 | 0.75 | 0.75 |
ZnMoO4(wt%) | 0.10 | 0.30 | 0.70 | 1.50 | 3.00 | 0 |
离子清除剂(wt%) | 1.58 | 1.58 | 1.58 | 1.58 | 1.58 | 1.58 |
样品 | 18A | 19A | 20A | 21A | 22A | 23A |
可燃性试验(UL94) | ||||||
总的燃烧时间(5bar)(s) | 60 | >139 | 25 | 29 | 9 | >97 |
状态 | 故障 | 故障 | V-1 | V-1 | V-0 | 故障 |
吸湿率(%) | ||||||
16小时 | 0.094 | 0.094 | 0.090 | 0.092 | 0.085 | 0.090 |
24小时 | 0.114 | 0.117 | 0.113 | 0.115 | 0.107 | 0.116 |
48小时 | 0.168 | 0.171 | 0.166 | 0.169 | 0.163 | 0.171 |
96小时 | 0.213 | 0.217 | 0.210 | 0.215 | 0.216 | 0.223 |
168小时 | 0.250 | 0.255 | 0.250 | 0.258 | 0.268 | 0.269 |
高压釜试验(%故障率) | ||||||
在2250小时试验之后 | 2.3 | 0.0 | 0.0 | 2.3 | 14.0 | 0.0 |
HTSL试验(%故障率) | ||||||
在1500小时试验之后 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 |
样品 | 34A | 35A | 36A | 37A | 38A | 39A |
氧化硅填料(wt%) | 81.20 | 81.10 | 80.90 | 80.50 | 79.70 | 78.20 |
联苯树脂(wt%) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 |
环氧甲酚线型酚醛清漆树脂(wt%) | 8.03 | 8.03 | 8.03 | 8.03 | 8.03 | 8.03 |
煅制氧化硅(wt%) | 0.60 | 0.60 | 0.60 | 0.60 | 0.60 | 0.60 |
炭黑着色剂(wt%) | 0.30 | 0.30 | 0.30 | 0.30 | 0.30 | 0.30 |
苧烯型硬化剂(来自Yuka Sbell)(wt%) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 |
线型酚醛清漆树脂硬化剂(wt%) | 4.58 | 4.58 | 4.58 | 4.58 | 4.58 | 4.58 |
催化剂(wt%) | 0.17 | 0.17 | 0.17 | 0.17 | 0.17 | 0.17 |
蜡(wt%) | 0.74 | 0.74 | 0.74 | 0.74 | 0.74 | 0.74 |
硅烷(wt%) | 1.05 | 1.05 | 1.05 | 1.05 | 1.05 | 1.05 |
弹性体(wt%) | 1.00 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 |
WO3(wt%) | 0.75 | 0.75 | 0.75 | 0.75 | 0.75 | 0.75 |
ZnMoO4(wt%) | 0.00 | 0.10 | 0.30 | 0.70 | 1.50 | 3.0 |
离子清除剂(wt%) | 1.58 | 1.58 | 1.58 | 1.58 | 1.58 | 1.58 |
样品 | 34A | 35A | 36A | 37A | 38A | 39A |
可燃性试验(UL94) | ||||||
总的燃烧时间(5bar)(s) | >138 | >72 | 41 | 42 | 58 | 9 |
状态 | 故障 | 故障 | V-1 | V-1 | V-1 | V-0 |
吸湿率(%) | ||||||
16小时 | 0.088 | 0.086 | 0.087 | 0.092 | 0.086 | 0.090 |
24小时 | 0.122 | 0.119 | 0.119 | 0.124 | 0.115 | 0.118 |
48小时 | 0.168 | 0.165 | 0.163 | 0.167 | 0.157 | 0.162 |
96小时 | 0.226 | 0.228 | 0.233 | 0.234 | 0.225 | 0.227 |
168小时 | 0.237 | 0.237 | 0.245 | 0.235 | 0.237 | 0.238 |
高压釜试验(%故障率) | ||||||
在2000小时试验之后 | 0.0 | 0.0 | 0.0 | 0.0 | 2.6 | 0.0 |
HTSL试验(%故障率) | ||||||
在1700小时试验之后 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 |
样品 | 40A | 33A | 41A | 42A | 43A | 44A | 45A |
氧化硅填料(wt%) | 83.94 | 83.19 | 82.44 | 80.94 | 83.19 | 82.44 | 80.94 |
联苯树脂(wt%) | 5.34 | 5.34 | 5.34 | 5.34 | 5.34 | 5.34 | 5.34 |
环氧甲酚线型酚醛清漆树脂(wt%) | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 |
煅制氧化硅(wt%) | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 | 0.40 |
炭黑着色剂(wt%) | 0.30 | 0.30 | 0.30 | 0.30 | 0.30 | 0.30 | 0.30 |
苧烯型硬化剂(来自Yuka Shell)(wt%) | 1.45 | 1.45 | 1.45 | 1.45 | 1.45 | 1.45 | 1.45 |
线型酚醛清漆树脂硬化剂(wt%) | 2.47 | 2.47 | 2.47 | 2.47 | 2.47 | 2.47 | 2.47 |
催化剂(wt%) | 0.23 | 0.23 | 0.23 | 0.23 | 0.23 | 0.23 | 0.23 |
蜡(wt%) | 0.74 | 0.74 | 0.74 | 0.74 | 0.74 | 0.74 | 0.74 |
硅烷(wt%) | 1.05 | 1.05 | 1.05 | 1.05 | 1.05 | 1.05 | 1.05 |
弹性体(wt%) | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 | 1.50 |
WO3(wt%) | 0 | 0.75 | 1.50 | 3.00 | 0 | 0 | 0 |
ZnMoO4(wt%) | 0 | 0 | 0 | 0 | 0.75 | 1.50 | 3.00 |
离子清除剂(wt%) | 1.58 | 1.58 | 1.58 | 1.58 | 1.58 | 1.58 | 1.58 |
样品 | 40A | 33A | 41A | 42A | 43A | 44A | 45A |
可燃性试验(UL94) | |||||||
总的燃烧时间(5bar)(s) | 51 | >100 | >138 | >135 | >152 | >166 | >113 |
状态 | 故障 | 故障 | 故障 | 故障 | 故障 | 故障 | 故障 |
样品 | 17A | 18B |
氧化硅填料(wt%) | 79.81 | 80.17 |
联苯树脂(wt%) | 0.0 | 5.34 |
环氧甲酚线型酚醛清漆树脂(wt%) | 6.10 | 0.0 |
煅制氧化硅(wt%) | 0.80 | 0.60 |
炭黑着色剂(wt%) | 0.30 | 0.30 |
线型酚醛清漆树脂硬化剂(wt%) | 4.86 | 4.68 |
催化剂(wt%) | 0.24 | 0.22 |
蜡(wt%) | 0.74 | 0.74 |
硅烷(wt%) | 1.05 | 1.05 |
弹性体(wt%) | 0.50 | 0.50 |
WO3(wt%) | 0.75 | 0.75 |
ZnMoO4(wt%) | 3.00 | 3.00 |
MoO3(wt%) | 0.75 | 0.75 |
离子清除剂(wt%) | 1.50 | 1.50 |
样品 | 17A | 18B |
可燃性试验(UL94) | ||
总的燃烧时间(5bar)(s) | 1 | 4 |
状态 | V-0 | V-0 |
形成良好的精选固化物的最小时间(min) | 1.0 | 1.0 |
样品 | 80A | 10B | 79A | 81A |
氧化硅填料(wt%) | 80.78 | 80.78 | 80.78 | 83.45 |
联苯树脂(wt%) | 0.0 | 0.0 | 0.0 | 5.64 |
环氧甲酚线型酚醛清漆树脂(wt%) | 8.85 | 0.0 | 7.25 | 0.0 |
NC-3000P(wt%) | 0.0 | 9.75 | 0.0 | 0.0 |
煅制氧化硅(wt%) | 0.40 | 0.40 | 0.40 | 0.60 |
炭黑着色剂(wt%) | 0.30 | 0.30 | 0.30 | 0.30 |
线型酚醛清漆树脂硬化剂(wt%) | 4.89 | 3.99 | 1.44 | 1.64 |
MEH 7851(wt%) | 0.0 | 0.0 | 5.05 | 2.97 |
催化剂(wt%) | 0.16 | 0.16 | 0.16 | 0.16 |
蜡(wt%) | 0.74 | 0.74 | 0.74 | 0.86 |
硅烷(wt%) | 1.05 | 1.05 | 1.05 | 1.05 |
弹性体(wt%) | 0.50 | 0.50 | 0.50 | 1.00 |
WO3(wt%) | 0.75 | 0.75 | 0.75 | 0.75 |
离子清除剂(wt%) | 1.58 | 1.58 | 1.58 | 1.58 |
样品 | 80A | 10B | 79A | 81A |
可燃性试验(UL94) | ||||
总的燃烧时间(5bar)(s) | >114 | 2 | 8 | 14 |
状态 | 故障 | V-0 | V-0 | V-0 |
样品 | 101 | 102 |
氧化硅填料(wt%) | 79.55 | 79.55 |
环氧甲酚线型酚醛清漆树脂(wt%) | 6.11 | 6.11 |
炭黑着色剂(wt%) | 0.30 | 0.30 |
线型酚醛清漆树脂硬化剂(wt%) | 5.30 | 5.30 |
催化剂(wt%) | 0.12 | 0.12 |
蜡(wt%) | 0.74 | 0.74 |
硅烷(wt%) | 1.05 | 1.05 |
弹性体(wt%) | 1.50 | 1.50 |
WO3(wt%) | 0.75 | 0.75 |
ZnMoO4(wt%) | 3.00 | 0 |
CaMoO4(wt%) | 0 | 3.00 |
离子清除剂(wt%) | 1.58 | 1.58 |
样品 | 101 | 102 |
可燃性试验(UL94) | ||
总的燃烧时间(5bar)(s) | 0 | 23 |
状态 | V-0 | V-0 |
吸湿率(%) | ||
24小时 | 0.116 | 0.119 |
48小时 | 0.180 | 0.179 |
96小时 | 0.245 | 0.230 |
168小时 | 0.297 | 0.262 |
高压釜试验(%故障率) | ||
94小时 | 2.4 | 0 |
385小时 | 2.4 | 0 |
1010小时 | 2.4 | 0 |
1460小时 | 2.4 | 0 |
1655小时 | 2.4 | 8.6 |
1960小时 | 2.4 | 8.6 |
2073小时 | 2.4 | 11.4 |
2691小时 | 21.4 | 40.0 |
3064小时 | 42.9 | 65.7 |
在@200℃下的HTSL试验1(%故障率) | ||
132小时 | 0 | 0 |
572小时 | 0 | 0 |
1100小时 | 0 | 0 |
1584小时 | 2.1 | 0 |
2288小时 | 2.1 | 0 |
3234小时 | 8.3 | 18.8 |
在@200℃下的HTSL试验1(%故障率) | ||
132小时 | 0 | 0 |
572小时 | 0 | 0 |
1100小时 | 0 | 0 |
1584小时 | 2.8 | 0 |
2288小时 | 2.8 | 0 |
3234小时 | 25.0 | 10.0 |
Claims (35)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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US31178401P | 2001-08-10 | 2001-08-10 | |
US60/311,784 | 2001-08-10 | ||
US10/097,153 US6610406B2 (en) | 2000-03-23 | 2002-03-13 | Flame retardant molding compositions |
US10/097,153 | 2002-03-13 |
Publications (2)
Publication Number | Publication Date |
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CN1537137A true CN1537137A (zh) | 2004-10-13 |
CN1274744C CN1274744C (zh) | 2006-09-13 |
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CNB028137027A Expired - Fee Related CN1274744C (zh) | 2001-08-10 | 2002-08-07 | 阻燃模塑组合物 |
Country Status (11)
Country | Link |
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US (1) | US6610406B2 (zh) |
EP (1) | EP1414895B1 (zh) |
JP (1) | JP2004537629A (zh) |
KR (1) | KR100886121B1 (zh) |
CN (1) | CN1274744C (zh) |
AT (1) | ATE293139T1 (zh) |
CA (1) | CA2449052A1 (zh) |
DE (1) | DE60203719T2 (zh) |
MX (1) | MXPA03011143A (zh) |
TW (1) | TWI227257B (zh) |
WO (1) | WO2003014210A1 (zh) |
Families Citing this family (7)
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TWI398461B (zh) * | 2004-03-16 | 2013-06-11 | Sumitomo Bakelite Co | 環氧樹脂組成物及半導體裝置 |
JP5470680B2 (ja) * | 2007-02-06 | 2014-04-16 | 日亜化学工業株式会社 | 発光装置及びその製造方法並びに成形体 |
JP5682110B2 (ja) * | 2009-12-25 | 2015-03-11 | 日立化成株式会社 | 熱硬化性樹脂組成物並びにこれを用いたプリプレグ及び積層板 |
US20120276392A1 (en) * | 2009-12-25 | 2012-11-01 | Hitachi Chemical Company, Ltd. | Thermosetting resin composition, method for producing resin composition varnish, prepreg and laminate |
ITRM20110593A1 (it) * | 2011-11-09 | 2013-05-10 | Antonio Naddeo | Procedimento di fabbricazione di prodotti ignifughi |
CN103554844B (zh) * | 2013-10-29 | 2016-02-17 | 广东生益科技股份有限公司 | 一种热固性树脂组合物及其用途 |
US10531555B1 (en) * | 2016-03-22 | 2020-01-07 | The United States Of America As Represented By The Secretary Of The Army | Tungsten oxide thermal shield |
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2002
- 2002-03-13 US US10/097,153 patent/US6610406B2/en not_active Expired - Lifetime
- 2002-06-13 TW TW91112898A patent/TWI227257B/zh not_active IP Right Cessation
- 2002-08-07 MX MXPA03011143A patent/MXPA03011143A/es active IP Right Grant
- 2002-08-07 CN CNB028137027A patent/CN1274744C/zh not_active Expired - Fee Related
- 2002-08-07 DE DE2002603719 patent/DE60203719T2/de not_active Expired - Lifetime
- 2002-08-07 CA CA 2449052 patent/CA2449052A1/en not_active Abandoned
- 2002-08-07 EP EP20020752715 patent/EP1414895B1/en not_active Expired - Lifetime
- 2002-08-07 WO PCT/US2002/024979 patent/WO2003014210A1/en active IP Right Grant
- 2002-08-07 JP JP2003519151A patent/JP2004537629A/ja active Pending
- 2002-08-07 AT AT02752715T patent/ATE293139T1/de not_active IP Right Cessation
- 2002-08-07 KR KR1020037015804A patent/KR100886121B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
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EP1414895A1 (en) | 2004-05-06 |
JP2004537629A (ja) | 2004-12-16 |
TWI227257B (en) | 2005-02-01 |
US6610406B2 (en) | 2003-08-26 |
MXPA03011143A (es) | 2004-02-26 |
KR20040024559A (ko) | 2004-03-20 |
KR100886121B1 (ko) | 2009-02-27 |
DE60203719D1 (de) | 2005-05-19 |
EP1414895B1 (en) | 2005-04-13 |
CN1274744C (zh) | 2006-09-13 |
US20020143091A1 (en) | 2002-10-03 |
ATE293139T1 (de) | 2005-04-15 |
DE60203719T2 (de) | 2006-03-09 |
CA2449052A1 (en) | 2003-02-20 |
WO2003014210A1 (en) | 2003-02-20 |
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