ATE293139T1 - Formbare zusammensetzungen mit flammhemmenden eigenschaften - Google Patents
Formbare zusammensetzungen mit flammhemmenden eigenschaftenInfo
- Publication number
- ATE293139T1 ATE293139T1 AT02752715T AT02752715T ATE293139T1 AT E293139 T1 ATE293139 T1 AT E293139T1 AT 02752715 T AT02752715 T AT 02752715T AT 02752715 T AT02752715 T AT 02752715T AT E293139 T1 ATE293139 T1 AT E293139T1
- Authority
- AT
- Austria
- Prior art keywords
- flame retardant
- molding compositions
- retardant properties
- retardant molding
- moldable compositions
- Prior art date
Links
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003063 flame retardant Substances 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000000465 moulding Methods 0.000 abstract 3
- 229910000314 transition metal oxide Inorganic materials 0.000 abstract 2
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- BIOOACNPATUQFW-UHFFFAOYSA-N calcium;dioxido(dioxo)molybdenum Chemical compound [Ca+2].[O-][Mo]([O-])(=O)=O BIOOACNPATUQFW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 239000003870 refractory metal Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/28—Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
- H01L23/29—Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the material, e.g. carbon
- H01L23/293—Organic, e.g. plastic
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3256—Molybdenum oxides, molybdates or oxide forming salts thereof, e.g. cadmium molybdate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3258—Tungsten oxides, tungstates, or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
- C04B2235/424—Carbon black
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
- C04B2235/483—Si-containing organic compounds, e.g. silicone resins, (poly)silanes, (poly)siloxanes or (poly)silazanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/28—Applying non-metallic protective coatings
- H05K3/285—Permanent coating compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Structures Or Materials For Encapsulating Or Coating Semiconductor Devices Or Solid State Devices (AREA)
- Epoxy Resins (AREA)
- Organic Insulating Materials (AREA)
- Reinforced Plastic Materials (AREA)
- Fireproofing Substances (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US31178401P | 2001-08-10 | 2001-08-10 | |
US10/097,153 US6610406B2 (en) | 2000-03-23 | 2002-03-13 | Flame retardant molding compositions |
PCT/US2002/024979 WO2003014210A1 (en) | 2000-03-23 | 2002-08-07 | Flame retardant molding compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE293139T1 true ATE293139T1 (de) | 2005-04-15 |
Family
ID=31497878
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT02752715T ATE293139T1 (de) | 2001-08-10 | 2002-08-07 | Formbare zusammensetzungen mit flammhemmenden eigenschaften |
Country Status (11)
Country | Link |
---|---|
US (1) | US6610406B2 (de) |
EP (1) | EP1414895B1 (de) |
JP (1) | JP2004537629A (de) |
KR (1) | KR100886121B1 (de) |
CN (1) | CN1274744C (de) |
AT (1) | ATE293139T1 (de) |
CA (1) | CA2449052A1 (de) |
DE (1) | DE60203719T2 (de) |
MX (1) | MXPA03011143A (de) |
TW (1) | TWI227257B (de) |
WO (1) | WO2003014210A1 (de) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI398461B (zh) * | 2004-03-16 | 2013-06-11 | Sumitomo Bakelite Co | 環氧樹脂組成物及半導體裝置 |
JP5470680B2 (ja) * | 2007-02-06 | 2014-04-16 | 日亜化学工業株式会社 | 発光装置及びその製造方法並びに成形体 |
JP5682110B2 (ja) * | 2009-12-25 | 2015-03-11 | 日立化成株式会社 | 熱硬化性樹脂組成物並びにこれを用いたプリプレグ及び積層板 |
US20120276392A1 (en) * | 2009-12-25 | 2012-11-01 | Hitachi Chemical Company, Ltd. | Thermosetting resin composition, method for producing resin composition varnish, prepreg and laminate |
ITRM20110593A1 (it) * | 2011-11-09 | 2013-05-10 | Antonio Naddeo | Procedimento di fabbricazione di prodotti ignifughi |
CN103554844B (zh) * | 2013-10-29 | 2016-02-17 | 广东生益科技股份有限公司 | 一种热固性树脂组合物及其用途 |
US10531555B1 (en) * | 2016-03-22 | 2020-01-07 | The United States Of America As Represented By The Secretary Of The Army | Tungsten oxide thermal shield |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2250483A (en) | 1937-08-10 | 1941-07-29 | Hopkinson Harry | Fireproofing composition and method |
US2610920A (en) | 1948-11-01 | 1952-09-16 | Hopkinson Harry | Flameproofing composition |
GB1102921A (en) | 1965-02-11 | 1968-02-14 | Ici Ltd | Stabilised polyamide compositions |
US3897346A (en) | 1972-06-16 | 1975-07-29 | Gaf Corp | Flame retardant agent for synthetic plastics |
US4097287A (en) | 1975-09-04 | 1978-06-27 | Kansai Paint Co., Ltd. | Inorganic film forming composition for coating |
US4028333A (en) | 1975-12-18 | 1977-06-07 | Velsicol Chemical Corporation | Flame retardant polymeric compositions containing melamine hydrohalides |
US4098748A (en) | 1976-08-16 | 1978-07-04 | Amax Inc. | Plasticized polyvinyl chloride resin composition containing molybdenum flame retardant and antimony compound smoke suppressant agent |
JPS543152A (en) | 1977-06-09 | 1979-01-11 | Matsushita Electric Ind Co Ltd | Flame-retardant resin composition |
US4446061A (en) | 1979-10-25 | 1984-05-01 | Monsanto Company | Composition containing reaction products of metal oxides and salts with phosphorus compounds |
US4439572A (en) | 1981-10-26 | 1984-03-27 | The Sherwin-Williams Company | Zinc oxide-zinc salt smoke suppressant/flame retardants |
JPS59182546A (ja) | 1983-03-31 | 1984-10-17 | Nitto Electric Ind Co Ltd | 半導体装置 |
BR8402638A (pt) | 1983-06-10 | 1985-04-30 | Goodrich Co B F | Composicao de cloreto de polivinila pos-clorada |
US4753916A (en) | 1986-09-17 | 1988-06-28 | E. I. Du Pont De Nemours And Company | Metal oxides of molybdenum or molybdenum and tungsten |
US4806577A (en) | 1986-11-18 | 1989-02-21 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Adhesive composition |
US4892683A (en) | 1988-05-20 | 1990-01-09 | Gary Chemical Corporation | Flame retardant low smoke poly(vinyl chloride) thermoplastic compositions |
US5059640A (en) | 1988-06-16 | 1991-10-22 | The United States Of America As Represented By The Secretary Of The Navy | Epoxy corrosion-resistant coating |
US5476716A (en) | 1988-10-17 | 1995-12-19 | The Dexter Corporation | Flame retardant epoxy molding compound, method and encapsulated device |
DE3939953A1 (de) | 1989-12-02 | 1991-06-06 | Bayer Ag | Verfahren zur herstellung feinteiliger keramischer oxid-pulver aus vorlaeuferverbindungen |
US5342553A (en) | 1991-11-22 | 1994-08-30 | U. S. Borax Inc. | Process of making zinc borate and fire-retarding compositions thereof |
US5422092A (en) | 1992-09-08 | 1995-06-06 | Kabushiki Kaisha Kaisui Kagaku Kenkyujo | Flame retardant and flame-retardant resin composition |
US5906679A (en) | 1994-06-06 | 1999-05-25 | Nissan Chemical Industries, Ltd. | Coating compositions employing zinc antimonate anhydride particles |
US5766568A (en) | 1995-08-03 | 1998-06-16 | Tateho Chemical Industries Co., Ltd. | Method of producing composite metal hydroxide, composite metal hydroxide obtained thereby and a flame retardant composition obtained thereby and therewith |
JPH0959461A (ja) | 1995-08-29 | 1997-03-04 | Daicel Chem Ind Ltd | 難燃性樹脂組成物 |
WO1999001507A1 (en) | 1997-07-02 | 1999-01-14 | Sumitomo Bakelite Company, Ltd. | Epoxy resin compositions for encapsulating semiconductors, and semiconductor devices |
JPH11140277A (ja) | 1997-11-10 | 1999-05-25 | Sumitomo Bakelite Co Ltd | エポキシ樹脂組成物及びこれを用いた半導体装置 |
JP3994511B2 (ja) | 1998-03-23 | 2007-10-24 | 日立化成工業株式会社 | 半導体封止用エポキシ樹脂組成物及びそれを用いた半導体装置 |
JP3479827B2 (ja) | 1998-04-27 | 2003-12-15 | 信越化学工業株式会社 | 半導体封止用エポキシ樹脂組成物及び半導体装置 |
US6297306B1 (en) | 1998-05-15 | 2001-10-02 | Shin-Etsu Chemical Co., Ltd. | Semiconductor encapsulating epoxy resin composition and semiconductor device |
JP3707043B2 (ja) | 1999-03-18 | 2005-10-19 | 三菱瓦斯化学株式会社 | プリント配線板用プリプレグ及び積層板 |
TW538482B (en) | 1999-04-26 | 2003-06-21 | Shinetsu Chemical Co | Semiconductor encapsulating epoxy resin composition and semiconductor device |
JP3540215B2 (ja) | 1999-09-29 | 2004-07-07 | 株式会社東芝 | エポキシ樹脂組成物及び樹脂封止型半導体装置 |
US6432540B1 (en) * | 2000-03-23 | 2002-08-13 | Loctite Corporation | Flame retardant molding compositions |
-
2002
- 2002-03-13 US US10/097,153 patent/US6610406B2/en not_active Expired - Lifetime
- 2002-06-13 TW TW91112898A patent/TWI227257B/zh not_active IP Right Cessation
- 2002-08-07 MX MXPA03011143A patent/MXPA03011143A/es active IP Right Grant
- 2002-08-07 CN CNB028137027A patent/CN1274744C/zh not_active Expired - Fee Related
- 2002-08-07 DE DE2002603719 patent/DE60203719T2/de not_active Expired - Lifetime
- 2002-08-07 CA CA 2449052 patent/CA2449052A1/en not_active Abandoned
- 2002-08-07 EP EP20020752715 patent/EP1414895B1/de not_active Expired - Lifetime
- 2002-08-07 WO PCT/US2002/024979 patent/WO2003014210A1/en active IP Right Grant
- 2002-08-07 JP JP2003519151A patent/JP2004537629A/ja active Pending
- 2002-08-07 AT AT02752715T patent/ATE293139T1/de not_active IP Right Cessation
- 2002-08-07 KR KR1020037015804A patent/KR100886121B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP1414895A1 (de) | 2004-05-06 |
JP2004537629A (ja) | 2004-12-16 |
TWI227257B (en) | 2005-02-01 |
US6610406B2 (en) | 2003-08-26 |
MXPA03011143A (es) | 2004-02-26 |
KR20040024559A (ko) | 2004-03-20 |
KR100886121B1 (ko) | 2009-02-27 |
DE60203719D1 (de) | 2005-05-19 |
EP1414895B1 (de) | 2005-04-13 |
CN1274744C (zh) | 2006-09-13 |
US20020143091A1 (en) | 2002-10-03 |
DE60203719T2 (de) | 2006-03-09 |
CA2449052A1 (en) | 2003-02-20 |
WO2003014210A1 (en) | 2003-02-20 |
CN1537137A (zh) | 2004-10-13 |
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