CN1332966C - 桥接双(茚基)金属茂化合物 - Google Patents

桥接双(茚基)金属茂化合物 Download PDF

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Publication number
CN1332966C
CN1332966C CNB018134017A CN01813401A CN1332966C CN 1332966 C CN1332966 C CN 1332966C CN B018134017 A CNB018134017 A CN B018134017A CN 01813401 A CN01813401 A CN 01813401A CN 1332966 C CN1332966 C CN 1332966C
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CN
China
Prior art keywords
indenyl
rac
zirconium
bis
tert
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB018134017A
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English (en)
Chinese (zh)
Other versions
CN1444594A (zh
Inventor
T·J·伯克哈特
U·M·斯特林
J·R·哈特
W·T·海古德
R·T·李
J·C·维奇尼
M·C·库奇塔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/620,198 external-priority patent/US6380330B1/en
Priority claimed from US09/619,759 external-priority patent/US6376408B1/en
Priority claimed from US09/620,304 external-priority patent/US6376412B1/en
Priority claimed from US09/619,752 external-priority patent/US6399723B1/en
Priority claimed from US09/620,303 external-priority patent/US6414095B1/en
Priority claimed from US09/620,522 external-priority patent/US6380124B1/en
Priority claimed from US09/620,302 external-priority patent/US6376411B1/en
Priority claimed from US09/619,749 external-priority patent/US6376407B1/en
Priority claimed from US09/619,764 external-priority patent/US6376409B1/en
Priority claimed from US09/619,750 external-priority patent/US6380120B1/en
Priority claimed from US09/620,175 external-priority patent/US6376410B1/en
Priority claimed from US09/619,748 external-priority patent/US6376627B1/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of CN1444594A publication Critical patent/CN1444594A/zh
Application granted granted Critical
Publication of CN1332966C publication Critical patent/CN1332966C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB018134017A 2000-06-30 2001-05-21 桥接双(茚基)金属茂化合物 Expired - Lifetime CN1332966C (zh)

Applications Claiming Priority (29)

Application Number Priority Date Filing Date Title
US21559700P 2000-06-30 2000-06-30
US21545900P 2000-06-30 2000-06-30
US60/215,459 2000-06-30
US60/215,597 2000-06-30
US09/620,303 US6414095B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,522 US6380124B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,302 US6376411B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,302 2000-07-19
US09/620,522 2000-07-19
US09/620,304 2000-07-19
US09/619,752 2000-07-19
US09/619,749 US6376407B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,198 US6380330B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,175 US6376410B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,759 US6376408B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,198 2000-07-19
US09/619,748 US6376627B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,750 US6380120B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,764 2000-07-19
US09/619,749 2000-07-19
US09/619,748 2000-07-19
US09/620,303 2000-07-19
US09/619,759 2000-07-19
US09/619,764 US6376409B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,752 US6399723B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,304 US6376412B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,175 2000-07-19
US09/619,750 2000-07-19
EP01941551A EP1313746B1 (en) 2000-06-30 2001-05-21 Metallocenes with a bridged 4-phenyl-indenyl-ligand for olefin polymerisation

Publications (2)

Publication Number Publication Date
CN1444594A CN1444594A (zh) 2003-09-24
CN1332966C true CN1332966C (zh) 2007-08-22

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Family Applications (2)

Application Number Title Priority Date Filing Date
CNB018134017A Expired - Lifetime CN1332966C (zh) 2000-06-30 2001-05-21 桥接双(茚基)金属茂化合物
CNB018133959A Expired - Fee Related CN1274701C (zh) 2000-06-30 2001-05-21 用于烯烃聚合的含有桥接4－苯基－茚基配体的金属茂

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNB018133959A Expired - Fee Related CN1274701C (zh) 2000-06-30 2001-05-21 用于烯烃聚合的含有桥接4－苯基－茚基配体的金属茂

Country Status (6)

Country Link
EP (2) EP1313746B1 (enExample)
JP (1) JP2004502699A (enExample)
CN (2) CN1332966C (enExample)
AT (1) ATE300550T1 (enExample)
DE (1) DE60112307T8 (enExample)
WO (1) WO2002002576A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105829326B (zh) * 2013-12-19 2019-11-08 埃克森美孚化学专利公司 桥连双(茚基)过渡金属络合物、其制备与应用

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* Cited by examiner, † Cited by third party
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