CN1309586A - 脱铝的催化剂载体、制备这种催化剂载体的方法以及在含有酸浸渍的这种催化剂载体的催化剂存在下使c2或c3烯烃与水水合的方法 - Google Patents
脱铝的催化剂载体、制备这种催化剂载体的方法以及在含有酸浸渍的这种催化剂载体的催化剂存在下使c2或c3烯烃与水水合的方法 Download PDFInfo
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- CN1309586A CN1309586A CN99808573A CN99808573A CN1309586A CN 1309586 A CN1309586 A CN 1309586A CN 99808573 A CN99808573 A CN 99808573A CN 99808573 A CN99808573 A CN 99808573A CN 1309586 A CN1309586 A CN 1309586A
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- catalyst
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C11/00—Fermentation processes for beer
- C12C11/02—Pitching yeast
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
- C07C29/05—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis
- C07C29/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis the acid being phosphoric acid
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mycology (AREA)
- Biochemistry (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Microbiology (AREA)
- Environmental & Geological Engineering (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Description
标准实验条件 | |
工艺参数 | 数值 |
总反应压力 | 70巴 |
反应器温度(等温) | 240℃ |
GHSV | 21.3升/分/升催化剂 |
水∶乙烯 | 1.0∶0.3摩尔比 |
载体材料 | KA-1(südehemie) |
性质(浸渍过的载体) | 新载体 | 未处理过的老载体 | 处理过的老载体 |
耐压性 | 20牛/毫米 | 40牛/毫米 | 30牛/毫米 |
比表面(BET) | 20米2/克 | 4米2/克 | 3米2克 |
累积孔体积 | 0.7毫升/克 | 0.4毫升/克 | 0.4毫升/克 |
铝含量 | 1.3重量% | 0.31重量% | <0.03重量% |
硅含量 | 25重量% | 25重量% | 24重量% |
H2PO4含量 | 35重量% | 36重量% | 35重量% |
实验开始时的乙烯转化率 | 5% | 5% | 6% |
在实验开始时的体积时间产率 | 77.4克/升催化剂/小时 | 76.4/升催化剂/小时 | 79.8克/升催化剂/小时 |
Claims (35)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19829747.5 | 1998-07-03 | ||
DE19829747A DE19829747A1 (de) | 1998-07-03 | 1998-07-03 | Entaluminierter Katalysatorträger, Verfahren zur Herstellung des Katalysatorträgers und Verfahren zur Hydratisierung von C2- oder C3-Olefinen mit Wasser in Gegenwart eines Katalysators, der aus diesem mit Säure getränkten Katalysatorträger besteht |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1309586A true CN1309586A (zh) | 2001-08-22 |
CN1117614C CN1117614C (zh) | 2003-08-13 |
Family
ID=7872866
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN99808573A Expired - Lifetime CN1117614C (zh) | 1998-07-03 | 1999-07-01 | 脱铝的催化剂载体、其制备方法及其应用 |
Country Status (15)
Country | Link |
---|---|
US (3) | US6881699B1 (zh) |
EP (2) | EP1096997B1 (zh) |
JP (2) | JP2002519190A (zh) |
KR (1) | KR100706055B1 (zh) |
CN (1) | CN1117614C (zh) |
AT (1) | ATE226109T1 (zh) |
AU (1) | AU746348B2 (zh) |
CA (1) | CA2336316C (zh) |
DE (3) | DE19829747A1 (zh) |
EA (1) | EA004067B1 (zh) |
PL (1) | PL201697B1 (zh) |
SK (1) | SK284617B6 (zh) |
TW (1) | TW490318B (zh) |
WO (2) | WO2000001481A1 (zh) |
ZA (1) | ZA200007651B (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1553885A (zh) * | 2001-07-06 | 2004-12-08 | 3M | 用于排气系统的无机纤维基材及其制造方法 |
KR100515586B1 (ko) * | 2002-10-14 | 2005-09-16 | 주식회사 엘지화학 | 활성이 우수한 인산촉매를 이용한 이소프로필알코올의제조방법 |
DE102008060888A1 (de) | 2008-12-09 | 2010-06-10 | Evonik Stockhausen Gmbh | Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase |
US8197779B2 (en) * | 2009-01-08 | 2012-06-12 | Lg Hausys, Ltd. | Catalyst for removing nitrogen oxides from exhaust gas, method for preparing the same and method for removing nitrogen oxides using the same from exhaust gas |
DE102011005608A1 (de) | 2011-03-16 | 2012-09-20 | Evonik Oxeno Gmbh | Mischoxidzusammensetzungen und Verfahren zur Herstellung von Isoolefinen |
EP2939995A1 (en) | 2014-04-30 | 2015-11-04 | Sasol Solvents Germany GmbH | Improved water management for the production of isopropyl alcohol by gas phase propylene hydration |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2579601A (en) | 1950-08-16 | 1951-12-25 | Shell Dev | Olefin hydration process |
DE1193928B (de) † | 1960-05-25 | 1965-06-03 | Ministerul Ind Petrolului | Verfahren zur Abtrennung und Reinigung von Benzol aus Benzinen und anderen Kohlenwasserstoffgemischen durch extraktive Kristallisation |
GB981237A (en) | 1961-02-21 | 1965-01-20 | Hibernia Chemie G M B H | Process for the production of a catalyst for the catalytic hydration of olefins intoalcohols |
DE1156772B (de) * | 1961-02-21 | 1963-11-07 | Bergwerksgesellschaft Hibernia | Verfahren zur Herstellung eines Katalysators fuer die Herstellung von Alkoholen durch katalytische Hydratation von Olefinen |
US3311568A (en) | 1965-02-01 | 1967-03-28 | Nii Sint Spirtov I Orch Produk | Method for production of catalyst for hydration of olefins to alcohols |
GB1306141A (zh) * | 1969-04-01 | 1973-02-07 | ||
DE2908491A1 (de) | 1979-03-05 | 1980-09-18 | Huels Chemische Werke Ag | Verfahren zur herstellung eines katalysators fuer die hydratation von olefinen zu alkoholen |
US4581215A (en) * | 1981-06-26 | 1986-04-08 | Mobil Oil Corporation | Para-selective zeolite catalysts treated with halogen compounds |
US5248841A (en) * | 1982-04-30 | 1993-09-28 | Mobil Oil Corporation | Hydrocarbon conversion with ZSM-22 zeolite |
US4548914A (en) | 1983-08-26 | 1985-10-22 | Mobil Oil Corporation | Zeolite catalysts of improved activity and para-selectivity |
US4696732A (en) * | 1984-10-29 | 1987-09-29 | Mobil Oil Corporation | Simultaneous hydrotreating and dewaxing of petroleum feedstocks |
DE3687592T2 (de) * | 1985-05-14 | 1993-05-19 | Mobil Oil Corp | Verfahren zur synthese von zeolithen. |
US4714537A (en) * | 1985-06-08 | 1987-12-22 | Mobil Oil Corporation | Process for cyclic dewaxing/regeneration of hydrocarbon feedstocks |
DE3709401A1 (de) * | 1987-03-21 | 1988-09-29 | Huels Chemische Werke Ag | Verfahren zur herstellung eines katalysators fuer die hydratation von olefinen zu alkoholen |
JPH01156772A (ja) * | 1987-12-15 | 1989-06-20 | Canon Inc | 複写装置 |
JP2593538B2 (ja) | 1987-12-30 | 1997-03-26 | モービル・オイル・コーポレイション | イソプロピルアルコールの製法 |
US4967020A (en) | 1987-12-30 | 1990-10-30 | Mobil Oil Corporation | Process for the hydration olefins |
US4919790A (en) * | 1988-01-19 | 1990-04-24 | Mobil Oil Corporation | Method for hydrocarbon dewaxing utilizing a reactivated spent MTG zeolite catalyst |
JP2598679B2 (ja) * | 1988-05-31 | 1997-04-09 | 株式会社妙徳 | 固定装置 |
JPH0283649A (ja) * | 1988-09-20 | 1990-03-23 | Fujitsu Ltd | バス監視方式 |
US5080778A (en) * | 1988-12-27 | 1992-01-14 | Uop | Hydrocarbon conversion process using novel silica-substituted aluminas |
DE4107607A1 (de) * | 1991-03-09 | 1992-09-10 | Tetra Pak Gmbh | Ausgiesseinrichtung fuer eine fliessmittelpackung und verfahren zur herstellung derselben |
US5366948A (en) | 1991-03-12 | 1994-11-22 | Mobil Oil Corp. | Catalyst and catalytic conversion therewith |
DE4107973A1 (de) * | 1991-03-13 | 1992-09-17 | Huels Chemische Werke Ag | Verfahren zur herstellung eines katalysators fuer die hydratation von olefinen zu alkoholen |
JP2606487B2 (ja) * | 1991-06-25 | 1997-05-07 | 日本電気株式会社 | 半導体装置 |
US5288739A (en) | 1992-06-04 | 1994-02-22 | Demmel Edward J | Production of attrition-resistant catalyst binders through use of delaminated clay |
GB9214688D0 (en) | 1992-07-10 | 1992-08-19 | Bp Chem Int Ltd | Olfin hydration catalysts |
US5883035A (en) | 1997-11-05 | 1999-03-16 | Engelhard Corporation | Mesoporous silicoaluminate products and production thereof by controlled acid extraction of aluminum from calcium bentonite clay |
-
1998
- 1998-07-03 DE DE19829747A patent/DE19829747A1/de not_active Ceased
-
1999
- 1999-06-29 CA CA002336316A patent/CA2336316C/en not_active Expired - Lifetime
- 1999-06-29 EP EP99931210A patent/EP1096997B1/de not_active Revoked
- 1999-06-29 WO PCT/EP1999/004486 patent/WO2000001481A1/de not_active Application Discontinuation
- 1999-06-29 DE DE59911373T patent/DE59911373D1/de not_active Expired - Fee Related
- 1999-06-29 JP JP2000557916A patent/JP2002519190A/ja active Pending
- 1999-07-01 CN CN99808573A patent/CN1117614C/zh not_active Expired - Lifetime
- 1999-07-01 DE DE59903105T patent/DE59903105D1/de not_active Expired - Lifetime
- 1999-07-01 PL PL345333A patent/PL201697B1/pl unknown
- 1999-07-01 KR KR1020017000048A patent/KR100706055B1/ko not_active IP Right Cessation
- 1999-07-01 AU AU56165/99A patent/AU746348B2/en not_active Expired
- 1999-07-01 SK SK2009-2000A patent/SK284617B6/sk not_active IP Right Cessation
- 1999-07-01 EP EP99942719.8A patent/EP1098700B2/de not_active Expired - Lifetime
- 1999-07-01 US US09/701,054 patent/US6881699B1/en not_active Expired - Lifetime
- 1999-07-01 AT AT99942719T patent/ATE226109T1/de not_active IP Right Cessation
- 1999-07-01 JP JP2000557915A patent/JP4489295B2/ja not_active Expired - Fee Related
- 1999-07-01 EA EA200100086A patent/EA004067B1/ru not_active IP Right Cessation
- 1999-07-01 WO PCT/DE1999/001898 patent/WO2000001480A1/de active IP Right Grant
- 1999-07-02 TW TW088111294A patent/TW490318B/zh not_active IP Right Cessation
-
2000
- 2000-12-19 ZA ZA200007651A patent/ZA200007651B/xx unknown
-
2003
- 2003-08-06 US US10/634,879 patent/US6881700B2/en not_active Expired - Lifetime
-
2004
- 2004-10-26 US US10/973,759 patent/US20050131259A1/en not_active Abandoned
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