CN1233648C - Salen催化剂、催化剂的制备和通过使用催化剂制备手性化合物的方法 - Google Patents

Salen催化剂、催化剂的制备和通过使用催化剂制备手性化合物的方法 Download PDF

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CN1233648C
CN1233648C CN02802133.9A CN02802133A CN1233648C CN 1233648 C CN1233648 C CN 1233648C CN 02802133 A CN02802133 A CN 02802133A CN 1233648 C CN1233648 C CN 1233648C
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China
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catalyzer
chirality
chemical formula
boron trifluoride
group
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Expired - Fee Related
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Chinese (zh)
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CN1463272A (zh
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金建中
李浩诚
金镐喆
尹鉁远
金成镇
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RSTECH CORP
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RSTECH CORP
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48—Ring-opening reactions
    • B01J2231/482—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates
    • B01J2231/485—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates kinetic resolution of epoxide racemates
    • B01J2231/487—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates kinetic resolution of epoxide racemates by hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN02802133.9A 2001-06-27 2002-06-26 Salen催化剂、催化剂的制备和通过使用催化剂制备手性化合物的方法 Expired - Fee Related CN1233648C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR200137081 2001-06-27
KR20010037081 2001-06-27
KR200235467 2002-06-24
KR1020020035467A KR100368002B1 (en) 2001-06-27 2002-06-24 Chiral salen catalyst and process for preparing chiral compounds from racemic epoxy compounds using the same

Publications (2)

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CN1463272A CN1463272A (zh) 2003-12-24
CN1233648C true CN1233648C (zh) 2005-12-28

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US (1) US6884750B2 (enExample)
EP (1) EP1292602B1 (enExample)
JP (1) JP3968076B2 (enExample)
CN (1) CN1233648C (enExample)
AT (1) ATE263626T1 (enExample)
AU (1) AU2002345388A1 (enExample)
DE (1) DE60200346T2 (enExample)
ES (1) ES2217245T3 (enExample)
WO (1) WO2003002582A1 (enExample)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1380342B1 (en) 2001-04-18 2009-07-01 Sumitomo Chemical Company, Limited Complex catalyst, process for producing the complex catalyst, and process for producing alcohol derivative with the complex catalyst
DE10130229A1 (de) * 2001-06-22 2003-01-02 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
US6639087B2 (en) * 2001-08-22 2003-10-28 Rhodia Pharma Solutions Inc. Kinetic resolution method
UA79300C2 (en) * 2002-08-12 2007-06-11 Janssen Pharmaceutica Nv N-aryl piperidine substituted biphenylcarboxamides as inhibitors of apolipoprotein b secretion
EP1469005B1 (de) * 2003-02-12 2006-08-30 Saltigo GmbH Verfahren zur asymmetrischen Hydrierung von Ketocarbonsäureestern
EP1469006A3 (de) * 2003-02-12 2005-03-16 Bayer Chemicals AG Verfahren zur Reduktion von Ketocarbonsäureestern
TWI258478B (en) 2003-10-31 2006-07-21 Arena Pharm Inc Tetrazole derivatives and methods of treatment of metabolic-related disorders thereof
US7304172B2 (en) * 2004-10-08 2007-12-04 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
PE20060949A1 (es) 2004-12-23 2006-10-11 Arena Pharm Inc Derivados fusionados de pirazol como agonistas del receptor de niacina
WO2006099162A2 (en) * 2005-03-14 2006-09-21 Georgia Tech Research Corporation Polymeric salen compounds and methods thereof
WO2007089025A1 (ja) 2006-02-01 2007-08-09 Sumitomo Chemical Company, Limited 光学活性なアルコール化合物の製造法
CN101374791B (zh) * 2006-02-01 2012-07-18 住友化学株式会社 制备光学活性的醇化合物的方法
US20090286968A1 (en) * 2008-04-25 2009-11-19 Auburn University 2-Quinoxalinol Salen Compounds and Uses Thereof
BRPI0911886B1 (pt) 2008-05-09 2019-09-24 Cornell University Métodos de sintetização de um polímero de poli(carbonato de etileno) e complexos metálicos
CN101328264B (zh) * 2008-07-10 2010-12-15 浙江大学 用离子液体支载催化剂制备聚碳酸酯的方法
PL2321364T3 (pl) 2008-08-22 2016-01-29 Novomer Inc Sposoby syntezy polimerów
KR102089887B1 (ko) 2008-09-08 2020-03-16 사우디 아람코 테크놀로지스 컴퍼니 폴리카보네이트 폴리올 조성물
WO2010033705A1 (en) 2008-09-17 2010-03-25 Novomer, Inc. Aliphatic polycarbonate quench method
WO2010062703A1 (en) 2008-11-01 2010-06-03 Novomer, Inc. Polycarbonate block copolymers
KR101885503B1 (ko) 2009-12-24 2018-08-07 사우디 아람코 테크놀로지스 컴퍼니 폴리사이클릭 구아니딘 화합물의 합성방법
KR101805648B1 (ko) 2010-09-14 2017-12-14 사우디 아람코 테크놀로지스 컴퍼니 중합체 합성용의 촉매 및 방법
CN101967165B (zh) * 2010-09-21 2012-09-05 中国科学院上海有机化学研究所 桥链双希夫碱-钴络合物及其合成方法和用途
JP6031442B2 (ja) 2010-09-22 2016-11-24 ノボマー， インコーポレイテッド 置換サリチルアルデヒド誘導体の合成
CN106939078B (zh) 2011-05-09 2020-12-11 沙特阿美技术公司 聚合物组合物及方法
CN102295579B (zh) * 2011-06-22 2014-05-21 安庆金泉药业有限公司 一种(r)-4-氰基-3-羟基丁酸乙酯的合成工艺
ES2749324T3 (es) 2011-07-25 2020-03-19 Saudi Aramco Tech Co Composiciones poliméricas y métodos
KR102070803B1 (ko) 2011-12-11 2020-03-02 사우디 아람코 테크놀로지스 컴퍼니 2가음이온성 반대이온을 갖는 살렌 착물
CN102580777B (zh) * 2011-12-19 2013-11-20 浙江大学 负载型salen锰配合物催化剂及其制备方法和应用
EP2794719B1 (en) 2011-12-20 2023-08-23 Saudi Aramco Technologies Company Methods for polymer synthesis
CN103301882B (zh) * 2012-03-16 2015-04-22 中国科学院大连化学物理研究所 一种用于拆分外消旋环氧烷烃的催化剂及其应用
KR102110746B1 (ko) 2012-04-16 2020-05-14 사우디 아람코 테크놀로지스 컴퍼니 접착제 조성물 및 방법
ES2974014T3 (es) 2012-05-24 2024-06-25 Saudi Aramco Tech Co Sistema de polimerización para la copolimerización de CO2 y epóxidos y método relacionado
KR102096761B1 (ko) 2012-08-24 2020-04-03 사우디 아람코 테크놀로지스 컴퍼니 금속 착물
EP3584267A1 (en) 2012-11-07 2019-12-25 Saudi Aramco Technologies Company High strength polyurethane foam compositions and methods
EP3126424B1 (en) 2014-04-03 2020-09-30 Saudi Aramco Technologies Company Aliphatic polycarbonate polyol compositions
CN104610263B (zh) * 2014-09-17 2016-06-29 成都理工大学 手性咪唑啉酮-酚
CN104356098A (zh) * 2014-11-10 2015-02-18 舒兰市金马化工有限公司 一种手性环氧氯丙烷的制备方法
CN104607250B (zh) * 2015-02-02 2016-11-30 舒兰市金马化工有限公司 一种多面体低聚倍半硅氧烷树枝状大分子催化剂及其应用
CN104804044A (zh) * 2015-03-10 2015-07-29 沈阳化工大学 Ru(II)-Salen金属配合物及其制备方法
CN107226797B (zh) * 2016-08-29 2019-05-17 沈阳金久奇科技有限公司 一种手性化合物2，2-二甲基-3-(环氧乙烷-2-基)丙酸甲酯的制备方法
US11230625B2 (en) 2018-04-18 2022-01-25 Saudi Aramco Technologies Company End-group isomerization of poly(alkylene carbonate) polymers
CN111097529B (zh) * 2018-10-25 2023-05-02 中国石油化工股份有限公司 高性能纳米笼限域催化剂、制备方法及应用
WO2020028606A1 (en) 2018-08-02 2020-02-06 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
WO2020068796A1 (en) 2018-09-24 2020-04-02 Saudi Aramco Technologies Company Polycarbonate block copolymers and methods thereof
JP2024525422A (ja) 2021-06-23 2024-07-12 サウジ アラムコ テクノロジーズ カンパニー ポリオール組成物及び方法
CN117658953B (zh) * 2023-12-04 2026-01-30 上海中化科技有限公司 手性环氧化合物、手性β-内酯及聚羟基脂肪酸酯的制备方法
CN119684154B (zh) * 2024-11-08 2026-06-12 湖北远大生命科学与技术有限责任公司 一种多核Salen催化剂和其制备方法及应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US566393A (en) * 1896-08-25 Andrew fyrberg
US5637739A (en) * 1990-03-21 1997-06-10 Research Corporation Technologies, Inc. Chiral catalysts and catalytic epoxidation catalyzed thereby
DE4435158A1 (de) * 1994-09-30 1996-04-04 Degussa Verfahren zur Herstellung von Salcomin
US6262278B1 (en) * 1995-03-14 2001-07-17 President And Fellows Of Harvard College Stereoselective ring opening reactions
US5665890A (en) 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US6521561B1 (en) * 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
EP1289655B1 (en) * 2000-05-24 2005-12-28 Rstech Co., Ltd. A method for preparing chiral compounds from racemic epoxides using chiral salen catalysts
CA2489593C (en) * 2002-06-13 2009-09-29 Teva Pharmaceutical Industries Ltd Epimerization of analogs of vitamin d

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DE60200346T2 (de) 2005-03-24
EP1292602B1 (en) 2004-04-07
ES2217245T3 (es) 2004-11-01
JP3968076B2 (ja) 2007-08-29
WO2003002582A1 (en) 2003-01-09
EP1292602A1 (en) 2003-03-19
US6884750B2 (en) 2005-04-26
JP2004521740A (ja) 2004-07-22
DE60200346D1 (de) 2004-05-13
US20030216250A1 (en) 2003-11-20
EP1292602A4 (en) 2003-07-09
ATE263626T1 (de) 2004-04-15
AU2002345388A1 (en) 2003-03-03
CN1463272A (zh) 2003-12-24

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