DE60200346D1 - Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators - Google Patents

Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators

Info

Publication number
DE60200346D1
DE60200346D1 DE60200346T DE60200346T DE60200346D1 DE 60200346 D1 DE60200346 D1 DE 60200346D1 DE 60200346 T DE60200346 T DE 60200346T DE 60200346 T DE60200346 T DE 60200346T DE 60200346 D1 DE60200346 D1 DE 60200346D1
Authority
DE
Germany
Prior art keywords
new
chiral
catalyst
salen
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60200346T
Other languages
English (en)
Other versions
DE60200346T2 (de
Inventor
Geon-Joong Kim
Ho-Seong Lee
Ho-Cheol Kim
Jin-Won Yun
Seong-Jin Kim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RS TECH CORP DAEJON
RS TECH CORP
Original Assignee
RS TECH CORP DAEJON
RS TECH CORP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020020035467A external-priority patent/KR100368002B1/ko
Application filed by RS TECH CORP DAEJON, RS TECH CORP filed Critical RS TECH CORP DAEJON
Publication of DE60200346D1 publication Critical patent/DE60200346D1/de
Application granted granted Critical
Publication of DE60200346T2 publication Critical patent/DE60200346T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48—Ring-opening reactions
    • B01J2231/482—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates
    • B01J2231/485—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates kinetic resolution of epoxide racemates
    • B01J2231/487—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates kinetic resolution of epoxide racemates by hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
DE60200346T 2001-06-27 2002-06-26 Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators Expired - Lifetime DE60200346T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
KR2001037081 2001-06-27
KR20010037081 2001-06-27
KR2002035467 2002-06-24
KR1020020035467A KR100368002B1 (en) 2001-06-27 2002-06-24 Chiral salen catalyst and process for preparing chiral compounds from racemic epoxy compounds using the same
PCT/KR2002/001219 WO2003002582A1 (en) 2001-06-27 2002-06-26 New chiral salen catalyst and methods for the preparation of chiral compounds from racemic epoxides by using new catalyst

Publications (2)

Publication Number Publication Date
DE60200346D1 true DE60200346D1 (de) 2004-05-13
DE60200346T2 DE60200346T2 (de) 2005-03-24

Family

ID=26639176

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60200346T Expired - Lifetime DE60200346T2 (de) 2001-06-27 2002-06-26 Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators

Country Status (9)

Country Link
US (1) US6884750B2 (de)
EP (1) EP1292602B1 (de)
JP (1) JP3968076B2 (de)
CN (1) CN1233648C (de)
AT (1) ATE263626T1 (de)
AU (1) AU2002345388A1 (de)
DE (1) DE60200346T2 (de)
ES (1) ES2217245T3 (de)
WO (1) WO2003002582A1 (de)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002085516A1 (fr) 2001-04-18 2002-10-31 Sumitomo Chemical Company, Limited Catalyseur complexe, son procede de production, et procede de production d'un derive d'alcool faisant appel a ce catalyseur complexe
DE10130229A1 (de) * 2001-06-22 2003-01-02 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
US6639087B2 (en) * 2001-08-22 2003-10-28 Rhodia Pharma Solutions Inc. Kinetic resolution method
UA79300C2 (en) * 2002-08-12 2007-06-11 Janssen Pharmaceutica Nv N-aryl piperidine substituted biphenylcarboxamides as inhibitors of apolipoprotein b secretion
EP1469006A3 (de) * 2003-02-12 2005-03-16 Bayer Chemicals AG Verfahren zur Reduktion von Ketocarbonsäureestern
ATE338050T1 (de) * 2003-02-12 2006-09-15 Saltigo Gmbh Verfahren zur asymmetrischen hydrierung von ketocarbonsäureestern
TWI258478B (en) 2003-10-31 2006-07-21 Arena Pharm Inc Tetrazole derivatives and methods of treatment of metabolic-related disorders thereof
US7304172B2 (en) * 2004-10-08 2007-12-04 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
PE20060949A1 (es) 2004-12-23 2006-10-11 Arena Pharm Inc Derivados fusionados de pirazol como agonistas del receptor de niacina
WO2006099162A2 (en) * 2005-03-14 2006-09-21 Georgia Tech Research Corporation Polymeric salen compounds and methods thereof
WO2007089025A1 (ja) 2006-02-01 2007-08-09 Sumitomo Chemical Company, Limited 光学活性なアルコール化合物の製造法
CN101374791B (zh) * 2006-02-01 2012-07-18 住友化学株式会社 制备光学活性的醇化合物的方法
US20090286968A1 (en) * 2008-04-25 2009-11-19 Auburn University 2-Quinoxalinol Salen Compounds and Uses Thereof
WO2009137540A1 (en) 2008-05-09 2009-11-12 Cornell University Polymers of ethylene oxide and carbon dioxide
CN101328264B (zh) * 2008-07-10 2010-12-15 浙江大学 用离子液体支载催化剂制备聚碳酸酯的方法
SG10201701421PA (en) 2008-08-22 2017-04-27 Novomer Inc Catalysts and methods for polymer synthesis
KR20200028511A (ko) 2008-09-08 2020-03-16 사우디 아람코 테크놀로지스 컴퍼니 폴리카보네이트 폴리올 조성물
CN102197062B (zh) 2008-09-17 2015-07-08 诺沃梅尔公司 脂族聚碳酸酯淬灭方法
WO2010062703A1 (en) 2008-11-01 2010-06-03 Novomer, Inc. Polycarbonate block copolymers
NO2515648T3 (de) 2009-12-24 2018-01-13
CN103201034A (zh) 2010-09-14 2013-07-10 诺沃梅尔公司 用于聚合物合成的催化剂和方法
CN101967165B (zh) * 2010-09-21 2012-09-05 中国科学院上海有机化学研究所 桥链双希夫碱-钴络合物及其合成方法和用途
CN103228137B (zh) 2010-09-22 2018-11-27 沙特阿美技术公司 取代的水杨醛衍生物的合成
CN106939078B (zh) 2011-05-09 2020-12-11 沙特阿美技术公司 聚合物组合物及方法
CN102295579B (zh) * 2011-06-22 2014-05-21 安庆金泉药业有限公司 一种(r)-4-氰基-3-羟基丁酸乙酯的合成工艺
KR20190006203A (ko) 2011-07-25 2019-01-17 사우디 아람코 테크놀로지스 컴퍼니 폴리우레탄에 이용하기 위한 지방족 폴리카보네이트
KR20200014932A (ko) 2011-12-11 2020-02-11 사우디 아람코 테크놀로지스 컴퍼니 2가음이온성 반대이온을 갖는 살렌 착물
CN102580777B (zh) * 2011-12-19 2013-11-20 浙江大学 负载型salen锰配合物催化剂及其制备方法和应用
CN104114605B (zh) 2011-12-20 2018-06-22 沙特阿美技术公司 聚合物合成的方法
CN103301882B (zh) * 2012-03-16 2015-04-22 中国科学院大连化学物理研究所 一种用于拆分外消旋环氧烷烃的催化剂及其应用
US20130274401A1 (en) 2012-04-16 2013-10-17 Novomer, Inc. Adhesive compositions and methods
EP2855558B1 (de) 2012-05-24 2018-12-26 Saudi Aramco Technologies Company Polymerisationssystem für die copolymerisation von co2 und epoxiden sowie zugehöriges verfahren
KR102096761B1 (ko) 2012-08-24 2020-04-03 사우디 아람코 테크놀로지스 컴퍼니 금속 착물
EP3584267A1 (de) 2012-11-07 2019-12-25 Saudi Aramco Technologies Company Hochfeste polyurethanschaumzusammensetzungen und verfahren
WO2015154001A1 (en) 2014-04-03 2015-10-08 Novomer, Inc. Aliphatic polycarbonate polyol compositions
CN104610263B (zh) * 2014-09-17 2016-06-29 成都理工大学 手性咪唑啉酮-酚
CN104356098A (zh) * 2014-11-10 2015-02-18 舒兰市金马化工有限公司 一种手性环氧氯丙烷的制备方法
CN104607250B (zh) * 2015-02-02 2016-11-30 舒兰市金马化工有限公司 一种多面体低聚倍半硅氧烷树枝状大分子催化剂及其应用
CN104804044A (zh) * 2015-03-10 2015-07-29 沈阳化工大学 Ru(II)-Salen金属配合物及其制备方法
CN107226797B (zh) * 2016-08-29 2019-05-17 沈阳金久奇科技有限公司 一种手性化合物2，2-二甲基-3-(环氧乙烷-2-基)丙酸甲酯的制备方法
US11230625B2 (en) 2018-04-18 2022-01-25 Saudi Aramco Technologies Company End-group isomerization of poly(alkylene carbonate) polymers
CN111097529B (zh) * 2018-10-25 2023-05-02 中国石油化工股份有限公司 高性能纳米笼限域催化剂、制备方法及应用
US11180609B2 (en) 2018-08-02 2021-11-23 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
JP2022502536A (ja) 2018-09-24 2022-01-11 サウジ アラムコ テクノロジーズ カンパニー ポリカーボネートブロックコポリマーおよびその方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US566393A (en) * 1896-08-25 Andrew fyrberg
US5637739A (en) 1990-03-21 1997-06-10 Research Corporation Technologies, Inc. Chiral catalysts and catalytic epoxidation catalyzed thereby
DE4435158A1 (de) * 1994-09-30 1996-04-04 Degussa Verfahren zur Herstellung von Salcomin
US6262278B1 (en) * 1995-03-14 2001-07-17 President And Fellows Of Harvard College Stereoselective ring opening reactions
US5665890A (en) * 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US6521561B1 (en) * 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
DE60116295D1 (de) * 2000-05-24 2006-02-02 Rstech Co Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatoren
CA2489593C (en) * 2002-06-13 2009-09-29 Teva Pharmaceutical Industries Ltd Epimerization of analogs of vitamin d

Also Published As

Publication number Publication date
CN1463272A (zh) 2003-12-24
ATE263626T1 (de) 2004-04-15
JP3968076B2 (ja) 2007-08-29
US20030216250A1 (en) 2003-11-20
DE60200346T2 (de) 2005-03-24
WO2003002582A1 (en) 2003-01-09
EP1292602A4 (de) 2003-07-09
JP2004521740A (ja) 2004-07-22
EP1292602B1 (de) 2004-04-07
ES2217245T3 (es) 2004-11-01
AU2002345388A1 (en) 2003-03-03
CN1233648C (zh) 2005-12-28
US6884750B2 (en) 2005-04-26
EP1292602A1 (de) 2003-03-19

Similar Documents

Publication Publication Date Title
DE60200346D1 (de) Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators
DE60235979D1 (de) Verfahren zur herstellung von gereinigter terephtalsäure
Pellissier Recent developments in dynamic kinetic resolution
EA200870340A1 (ru) Способ синтеза 5-алкоксиметилфурфураловых эфиров и их применение
DE60011055D1 (de) Verfahren zur herstellung von aromatischen carbonsäuren
ATE314144T1 (de) Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatoren
SG151330A1 (en) Process for production of optically active amine derivatives
ATE426586T1 (de) Verfahren zur herstellung von cyclohexanon und cyclohexanol
ATE448235T1 (de) Verfahren zur herstellung von isocyanatosilan und silylisocyanurat
ATE444942T1 (de) Verfahren zur herstellung von porösem keramikmaterial
DE502005010231D1 (de) Wolframat enthaltende katalysatoren zur synthese von alkylmercaptan und verfahren zu ihrer herstellung
ATE453622T1 (de) Verfahren zur herstellung von enantiomeren angereicherten cyclischen beta-aryl- oder heteroarylcarbonsäuren
ATE526305T1 (de) Verfahren zur herstellung von 4-aminodiphenylamin
ATE543793T1 (de) Verfahren zur herstellung von benzoesäureestern
ATE344228T1 (de) Verfahren zur herstellung von ethylenaminen
DE69909921D1 (de) Verfahren zur herstellung von n-methyl-pyrrolidon
WO2008099882A1 (ja) ２－メチル－３－（３，４－メチレンジオキシフェニル）プロパナール及びその製造方法
EA200801410A1 (ru) Способ производства диалкилкарбоната и диола в промышленном масштабе
ATE381561T1 (de) Verfahren zur herstellung von chiralen propionsäurederivaten
ATE330922T1 (de) Verfahren zur herstellung von propan-1,3-diol durch gasphasen-hydrierung von .beta.- propiolacton, oligomeren von .beta.-propiolacton, 3-hydroxypropionsäureestern oder gemischen davon
CN103111323B (zh) 手性n，n-二烷基-1，2-环己二胺催化剂及其制备方法和应用
CN105461516B (zh) 一种l‑薄荷醇的合成工艺
DE60220312D1 (de) Verfahren zur herstellung und fraktionierung von gelbildenden und nicht gelbildenden carrageenanen aus zweikomponentigem tang
EA200801182A1 (ru) Способ производства диалкилкарбоната и диола в промышленном масштабе
ATE471306T1 (de) Verfahren zur herstellung von 1,4- butandiol

Legal Events

Date Code Title Description
8332 No legal effect for de
8370 Indication related to discontinuation of the patent is to be deleted
8364 No opposition during term of opposition