ATE263626T1 - Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators - Google Patents

Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators

Info

Publication number
ATE263626T1
ATE263626T1 AT02743918T AT02743918T ATE263626T1 AT E263626 T1 ATE263626 T1 AT E263626T1 AT 02743918 T AT02743918 T AT 02743918T AT 02743918 T AT02743918 T AT 02743918T AT E263626 T1 ATE263626 T1 AT E263626T1
Authority
AT
Austria
Prior art keywords
new
chiral
catalyst
salen
racemic
Prior art date
Application number
AT02743918T
Other languages
English (en)
Inventor
Geon-Joong Kim
Ho-Seong Lee
Ho-Cheol Kim
Jin-Won Yun
Seong-Jin Kim
Original Assignee
Rs Tech Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020020035467A external-priority patent/KR100368002B1/ko
Application filed by Rs Tech Corp filed Critical Rs Tech Corp
Application granted granted Critical
Publication of ATE263626T1 publication Critical patent/ATE263626T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48—Ring-opening reactions
    • B01J2231/482—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates
    • B01J2231/485—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates kinetic resolution of epoxide racemates
    • B01J2231/487—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates kinetic resolution of epoxide racemates by hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT02743918T 2001-06-27 2002-06-26 Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators ATE263626T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR20010037081 2001-06-27
KR1020020035467A KR100368002B1 (en) 2001-06-27 2002-06-24 Chiral salen catalyst and process for preparing chiral compounds from racemic epoxy compounds using the same
PCT/KR2002/001219 WO2003002582A1 (en) 2001-06-27 2002-06-26 New chiral salen catalyst and methods for the preparation of chiral compounds from racemic epoxides by using new catalyst

Publications (1)

Publication Number Publication Date
ATE263626T1 true ATE263626T1 (de) 2004-04-15

Family

ID=26639176

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02743918T ATE263626T1 (de) 2001-06-27 2002-06-26 Neuer chiraler salen-katalysator und verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung des neuen katalysators

Country Status (9)

Country Link
US (1) US6884750B2 (de)
EP (1) EP1292602B1 (de)
JP (1) JP3968076B2 (de)
CN (1) CN1233648C (de)
AT (1) ATE263626T1 (de)
AU (1) AU2002345388A1 (de)
DE (1) DE60200346T2 (de)
ES (1) ES2217245T3 (de)
WO (1) WO2003002582A1 (de)

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ATE338050T1 (de) * 2003-02-12 2006-09-15 Saltigo Gmbh Verfahren zur asymmetrischen hydrierung von ketocarbonsäureestern
EP1469006A3 (de) * 2003-02-12 2005-03-16 Bayer Chemicals AG Verfahren zur Reduktion von Ketocarbonsäureestern
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US7304172B2 (en) * 2004-10-08 2007-12-04 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
PE20060949A1 (es) 2004-12-23 2006-10-11 Arena Pharm Inc Derivados fusionados de pirazol como agonistas del receptor de niacina
WO2006099162A2 (en) * 2005-03-14 2006-09-21 Georgia Tech Research Corporation Polymeric salen compounds and methods thereof
CN101374792B (zh) 2006-02-01 2012-03-28 住友化学株式会社 制备光学活性的醇化合物的方法
EP1982972A4 (de) * 2006-02-01 2009-09-09 Sumitomo Chemical Co Verfahren zur herstellung einer optisch aktiven alkoholverbindung
US20090286968A1 (en) * 2008-04-25 2009-11-19 Auburn University 2-Quinoxalinol Salen Compounds and Uses Thereof
CN104193980B (zh) 2008-05-09 2018-11-13 康奈尔大学 环氧乙烷与二氧化碳的聚合物
CN101328264B (zh) * 2008-07-10 2010-12-15 浙江大学 用离子液体支载催化剂制备聚碳酸酯的方法
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CN101967165B (zh) * 2010-09-21 2012-09-05 中国科学院上海有机化学研究所 桥链双希夫碱-钴络合物及其合成方法和用途
CN109970755B (zh) 2010-09-22 2022-04-05 沙特阿美技术公司 取代的水杨醛衍生物的合成
CN106939078B (zh) 2011-05-09 2020-12-11 沙特阿美技术公司 聚合物组合物及方法
CN102295579B (zh) * 2011-06-22 2014-05-21 安庆金泉药业有限公司 一种(r)-4-氰基-3-羟基丁酸乙酯的合成工艺
US9453100B2 (en) 2011-07-25 2016-09-27 Novomer, Inc. Polymer compositions and methods
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CN102580777B (zh) * 2011-12-19 2013-11-20 浙江大学 负载型salen锰配合物催化剂及其制备方法和应用
EP2794719B1 (de) 2011-12-20 2023-08-23 Saudi Aramco Technologies Company Verfahren zur polymersynthese
CN103301882B (zh) * 2012-03-16 2015-04-22 中国科学院大连化学物理研究所 一种用于拆分外消旋环氧烷烃的催化剂及其应用
CN110791246B (zh) 2012-04-16 2022-04-22 沙特阿美技术公司 粘合剂组合物和方法
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Also Published As

Publication number Publication date
DE60200346D1 (de) 2004-05-13
DE60200346T2 (de) 2005-03-24
CN1233648C (zh) 2005-12-28
US6884750B2 (en) 2005-04-26
EP1292602B1 (de) 2004-04-07
JP2004521740A (ja) 2004-07-22
AU2002345388A1 (en) 2003-03-03
WO2003002582A1 (en) 2003-01-09
EP1292602A1 (de) 2003-03-19
CN1463272A (zh) 2003-12-24
US20030216250A1 (en) 2003-11-20
ES2217245T3 (es) 2004-11-01
JP3968076B2 (ja) 2007-08-29
EP1292602A4 (de) 2003-07-09

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