CN1168861C - 含脱乙酰壳多糖的丙烯腈系纤维及其制备方法 - Google Patents
含脱乙酰壳多糖的丙烯腈系纤维及其制备方法 Download PDFInfo
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- CN1168861C CN1168861C CNB971987823A CN97198782A CN1168861C CN 1168861 C CN1168861 C CN 1168861C CN B971987823 A CNB971987823 A CN B971987823A CN 97198782 A CN97198782 A CN 97198782A CN 1168861 C CN1168861 C CN 1168861C
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Classifications
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- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
- D01F9/21—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F9/22—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
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- D—TEXTILES; PAPER
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- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
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- D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
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- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/54—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated nitriles
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- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
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Abstract
Description
制备条件 | 脱乙酰壳多糖含量 | 脱乙酰壳多糖在纤维横截面中的分散态 | 细胞数变化上的差异 | 纤维间摩擦系数 | 染色透明性 | ||||||||
膨胀度% | 脱乙酰壳多糖总含量(A)% | 可提取脱乙酰壳多糖含量(B)% | A-B% | 测量数 | 平均直径nm | σnm | SF | σ | 洗涤前 | 洗涤十次后 | |||
对比例1 | 80 | 0.03 | 0.01 | 0.02 | 120 | 1.7 | 2.3 | 200 | 68 | 0.8 | 0.7 | 0.385 | 好 |
实施例1 | 80 | 0.06 | 0.03 | 0.03 | 100 | 2.9 | 2.1 | 230 | 80 | 1.8 | 1.7 | 0.33 | 好 |
实施例2 | 80 | 0.1 | 0.03 | 0.07 | 100 | 5.4 | 3.7 | 270 | 95 | 2 | 1.9 | 0.31 | 好 |
实施例3 | 80 | 0.2 | 0.06 | 0.14 | 100 | 7.4 | 4 | 280 | 100 | 5.4 | 5.2 | 0.29 | 好 |
实施例4 | 80 | 0.3 | 0.1 | 0.2 | 100 | 10.6 | 4.8 | 250 | 130 | 5.4 | 5.2 | 0.28 | 好 |
实施例5 | 80 | 0.9 | 0.5 | 0.4 | 100 | 26.8 | 10.4 | 270 | 120 | 5.5 | 5.3 | 0.27 | 好 |
实施例6 | 80 | 1.0 | 0.6 | 0.4 | 100 | 30.1 | 12.7 | 280 | 110 | 5.4 | 5.4 | 0.255 | 好 |
实施例7 | 80 | 1.5 | 0.9 | 0.6 | 100 | 45.9 | 25.9 | 260 | 50 | 5.4 | 5.4 | 0.26 | 好 |
对比例2 | 80 | 2.8 | 2 | 0.8 | 100 | 98.6 | 46.8 | 300 | 150 | 5.5 | 5.4 | 0.255 | 稍差 |
对比例3 | - | 0.06 | 0.05 | 0.01 | 100 | 其中没有检测到脱乙酰壳多糖细颗粒 | 1.7 | 0.7 | 0.34 | 好 | |||
实施例8 | 100 | 0.1 | 0.03 | 0.07 | 185 | 3.5 | 3.2 | 240 | 95 | 5.1 | 4.9 | 0.365 | 好 |
实施例9 | 60 | 0.1 | 0.05 | 0.05 | 165 | 2.2 | 2 | 190 | 80 | 5.3 | 5.1 | 0.312 | 好 |
实施例10 | 40 | 0.1 | 0.06 | 0.04 | 170 | 2 | 1.9 | 180 | 80 | 5.2 | 5 | 0.298 | 好 |
实施例11 | 130 | 0.1 | 0.03 | 0.07 | 180 | 7.5 | 9.8 | 280 | 110 | 4.8 | 4.1 | 0.384 | 好 |
对比例4 | 250 | 0.1 | 0.02 | 0.08 | 150 | 12.5 | 23.8 | 315 | 305 | 5.5 | 1.5 | 0.396 | 好 |
对比例5 | 20 | 0.1 | 0.07 | 0.03 | 195 | 0.6 | 0.5 | 155 | 85 | 5.5 | 1.2 | 0.255 | 好 |
脱乙酰壳多糖含量 | 季铵盐含量% | 纤维间摩擦系数 | 细胞数变化上的差异 | 染色透明性 | ||||
脱乙酰壳多糖总含量(A)% | 可提取脱乙酰壳多糖含量(B)% | A-B% | 洗涤前 | 洗涤十次后 | ||||
实施例12 | 0.09 | 0.05 | 0.04 | 0.33 | 0.285 | 5.1 | 4.8 | ◎ |
实施例13 | 0.25 | 0.17 | 0.08 | 0.42 | 0.275 | 5.4 | 5.2 | ◎ |
实施例14 | 1.0 | 0.65 | 0.35 | 1.05 | 0.260 | 5.5 | 5.2 | ◎ |
实施例15 | 1.6 | 1.00 | 0.6 | 1.67 | 0.265 | 5.5 | 5.3 | ○ |
实施例17 | 0.09 | 0.05 | 0.04 | 0.29 | 0.320 | 2.8 | 2.2 | ◎ |
实施例18 | 0.09 | 0.05 | 0.04 | 0.38 | 0.290 | 2.6 | 2.0 | ◎ |
实施例19 | 0.09 | 0.05 | 0.04 | 0.32 | 0.295 | 5.0 | 4.8 | ◎ |
实施例20 | 0.09 | 0.05 | 0.04 | 0.34 | 0.293 | 5.3 | 4.5 | ◎ |
实施例21 | 0.09 | 0.05 | 0.04 | 0.37 | 0.275 | 5.0 | 4.3 | ◎ |
实施例22 | 0.1 | 0.07 | 0.03 | 0.35 | 0.283 | 5.1 | 4.8 | ◎ |
实施例23 | 0.25 | 0.16 | 0.09 | 0.48 | 0.287 | 5.5 | 5.1 | ◎ |
实施例24 | 1.03 | 0.67 | 0.36 | 1.02 | 0.274 | 5.3 | 5.1 | ◎ |
实施例25 | 1.51 | 0.97 | 0.54 | 1.67 | 0.265 | 5.5 | 5.2 | ○ |
实施例27 | 0.1 | 0.06 | 0.04 | 0.29 | 0.334 | 4.2 | 3.5 | ◎ |
实施例28 | 0.1 | 0.06 | 0.04 | 0.40 | 0.298 | 3.2 | 2.3 | ◎ |
实施例29 | 0.1 | 0.06 | 0.04 | 0.32 | 0.295 | 5.0 | 4.8 | ◎ |
实施例30 | 0.1 | 0.06 | 0.04 | 0.39 | 0.287 | 4.8 | 4.4 | ◎ |
实施例31 | 0.1 | 0.06 | 0.04 | 0.47 | 0.269 | 5.2 | 4.5 | ◎ |
对比例6 | 0.04 | 0.02 | 0.02 | 0.31 | 0.380 | 2.2 | 1.2 | ◎ |
对比例7 | 2.4 | 1.38 | 1.02 | 2.88 | 0.375 | ×a) | ×a) | ×a) |
对比例8 | 0.4 | 0.26 | 0.14 | 3.25 | 0.378 | × | × | × |
对比例9 | 0 | 0.25 | 0.455 | 2.8 | 0.9 | ◎ | ||
对比例10 | 0.06 | 0.04 | 0.02 | 0.29 | 0.388 | 4.1 | 3.5 | ◎ |
比较例11 | 2.48 | 1.44 | 1.04 | 2.96 | 0.367 | × | × | × |
Claims (15)
Applications Claiming Priority (12)
Application Number | Priority Date | Filing Date | Title |
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JP24513696A JP3286180B2 (ja) | 1996-02-08 | 1996-09-17 | 抗菌性アクリル繊維およびその製造方法 |
JP245137/96 | 1996-09-17 | ||
JP245136/1996 | 1996-09-17 | ||
JP24513796 | 1996-09-17 | ||
JP245136/96 | 1996-09-17 | ||
JP245137/1996 | 1996-09-17 | ||
JP29909996A JP3450137B2 (ja) | 1996-11-11 | 1996-11-11 | キトサン含有繊維及びその製造方法 |
JP299099/1996 | 1996-11-11 | ||
JP299099/96 | 1996-11-11 | ||
JP179863/97 | 1997-07-04 | ||
JP1997179863A JP3544825B6 (ja) | 1996-09-17 | 1997-07-04 | 抗菌性アクリル繊維及びその製造方法 |
JP179863/1997 | 1997-07-04 |
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CNB2004100325936A Division CN1276147C (zh) | 1996-09-17 | 1997-08-06 | 含脱乙酰壳多糖的丙烯腈系纤维的制备方法 |
Publications (2)
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CN1233296A CN1233296A (zh) | 1999-10-27 |
CN1168861C true CN1168861C (zh) | 2004-09-29 |
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CNB971987823A Expired - Lifetime CN1168861C (zh) | 1996-09-17 | 1997-08-06 | 含脱乙酰壳多糖的丙烯腈系纤维及其制备方法 |
CNB2004100325936A Expired - Lifetime CN1276147C (zh) | 1996-09-17 | 1997-08-06 | 含脱乙酰壳多糖的丙烯腈系纤维的制备方法 |
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CNB2004100325936A Expired - Lifetime CN1276147C (zh) | 1996-09-17 | 1997-08-06 | 含脱乙酰壳多糖的丙烯腈系纤维的制备方法 |
Country Status (6)
Country | Link |
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US (2) | US6551705B1 (zh) |
KR (1) | KR100441358B1 (zh) |
CN (2) | CN1168861C (zh) |
GB (1) | GB2339717B (zh) |
TW (1) | TW369571B (zh) |
WO (1) | WO1998012369A1 (zh) |
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1997
- 1997-08-06 CN CNB971987823A patent/CN1168861C/zh not_active Expired - Lifetime
- 1997-08-06 KR KR10-1999-7002195A patent/KR100441358B1/ko not_active IP Right Cessation
- 1997-08-06 CN CNB2004100325936A patent/CN1276147C/zh not_active Expired - Lifetime
- 1997-08-06 GB GB9905546A patent/GB2339717B/en not_active Expired - Fee Related
- 1997-08-06 WO PCT/JP1997/002725 patent/WO1998012369A1/ja active IP Right Grant
- 1997-08-08 TW TW086111551A patent/TW369571B/zh not_active IP Right Cessation
-
1999
- 1999-03-17 US US09/271,272 patent/US6551705B1/en not_active Expired - Lifetime
-
2000
- 2000-06-27 US US09/605,707 patent/US6524508B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
GB2339717A (en) | 2000-02-09 |
CN1233296A (zh) | 1999-10-27 |
US6551705B1 (en) | 2003-04-22 |
KR100441358B1 (ko) | 2004-07-23 |
KR20000036151A (ko) | 2000-06-26 |
CN1536163A (zh) | 2004-10-13 |
GB2339717B (en) | 2000-10-11 |
WO1998012369A1 (fr) | 1998-03-26 |
GB2339717A8 (en) | 2001-01-03 |
US6524508B1 (en) | 2003-02-25 |
CN1276147C (zh) | 2006-09-20 |
GB9905546D0 (en) | 1999-05-05 |
TW369571B (en) | 1999-09-11 |
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