CN116157194A - 膜反应器 - Google Patents

膜反应器 Download PDF

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Publication number
CN116157194A
CN116157194A CN202280006336.1A CN202280006336A CN116157194A CN 116157194 A CN116157194 A CN 116157194A CN 202280006336 A CN202280006336 A CN 202280006336A CN 116157194 A CN116157194 A CN 116157194A
Authority
CN
China
Prior art keywords
catalyst
separation membrane
layer
membrane
buffer layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202280006336.1A
Other languages
English (en)
Chinese (zh)
Inventor
菅博史
鸟井淳史
饭田和希
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NGK Insulators Ltd
Original Assignee
NGK Insulators Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NGK Insulators Ltd filed Critical NGK Insulators Ltd
Publication of CN116157194A publication Critical patent/CN116157194A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/152—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/341—Apparatus, reactors with stationary catalyst bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/2485—Monolithic reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/06—Surface irregularities
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06—Tubular membrane modules
    • B01D63/066—Tubular membrane modules with a porous block having membrane coated passages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/145—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing embedded catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B01J2208/00238—Adjusting the heat-exchange profile by adapting catalyst tubes or the distribution thereof, e.g. by using inserts in some of the tubes or adding external fins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00884—Means for supporting the bed of particles, e.g. grids, bars, perforated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/021—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles comprising a plurality of beds with flow of reactants in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN202280006336.1A 2021-06-08 2022-06-08 膜反应器 Pending CN116157194A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2021-095823 2021-06-08
JP2021095823 2021-06-08
PCT/JP2022/023071 WO2022260063A1 (ja) 2021-06-08 2022-06-08 メンブレンリアクタ

Publications (1)

Publication Number Publication Date
CN116157194A true CN116157194A (zh) 2023-05-23

Family

ID=84426068

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202280006336.1A Pending CN116157194A (zh) 2021-06-08 2022-06-08 膜反应器

Country Status (6)

Country Link
US (1) US20230220283A1 (https=)
EP (1) EP4194078A4 (https=)
JP (2) JP7500781B2 (https=)
CN (1) CN116157194A (https=)
AU (2) AU2022288464B2 (https=)
WO (1) WO2022260063A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4477729A4 (en) * 2022-02-08 2025-08-06 Ngk Insulators Ltd REACTOR
WO2023157861A1 (ja) * 2022-02-21 2023-08-24 日本碍子株式会社 リアクタ
US20250065279A1 (en) * 2023-08-25 2025-02-27 Gti Energy Catalytic membrane reactor for in-situ water removal in the synthesis of valuable chemicals
WO2025249936A1 (ko) * 2024-05-29 2025-12-04 한국과학기술원 반응기

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006314876A (ja) * 2005-05-11 2006-11-24 Ngk Spark Plug Co Ltd 水素分離装置
JP2007269595A (ja) * 2006-03-31 2007-10-18 Ngk Spark Plug Co Ltd 水素製造装置
JP2017149616A (ja) * 2016-02-25 2017-08-31 日本碍子株式会社 水素回収メンブレンリアクター、水素回収システム及び水素回収方法
JP2018008940A (ja) * 2016-07-04 2018-01-18 公益財団法人地球環境産業技術研究機構 メタノール製造方法およびメタノール製造装置

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2631244B2 (ja) * 1990-10-19 1997-07-16 川崎重工業株式会社 燃料電池用水素製造方法及び装置
CH687004A5 (de) * 1994-04-08 1996-08-30 Methanol Casale Sa Membranreaktor fuer die Umsetzung von gasfoermigen Ausgangsstoffen.
JP3599370B2 (ja) * 1994-05-23 2004-12-08 日本碍子株式会社 水素製造装置
US6440895B1 (en) * 1998-07-27 2002-08-27 Battelle Memorial Institute Catalyst, method of making, and reactions using the catalyst
JP4204273B2 (ja) 2002-08-09 2009-01-07 日本碍子株式会社 Ｄｄｒ型ゼオライト膜複合体及びその製造方法
JP4347129B2 (ja) * 2004-04-28 2009-10-21 東京瓦斯株式会社 水素製造用反応筒及び反応板
JP2007055970A (ja) * 2005-08-26 2007-03-08 Mitsui Eng & Shipbuild Co Ltd メタノール製造用反応器及びメタノール製造方法
US7717272B2 (en) 2006-10-18 2010-05-18 Ngk Insulators, Ltd. Ceramic porous membrane and ceramic filter
JP4938522B2 (ja) * 2007-03-26 2012-05-23 日本碍子株式会社 選択透過膜型反応器
JP2011116603A (ja) * 2009-12-04 2011-06-16 Tokyo Gas Co Ltd 円筒形水素分離型改質器における水素分離膜用保護膜及びその形成方法
US10150721B2 (en) 2016-07-15 2018-12-11 Gas Technology Institute Catalytic membrane reactor for dimethyl ether synthesis from carbon dioxide and hydrogen
JP7076229B2 (ja) 2018-03-08 2022-05-27 Ｊｆｅスチール株式会社 二酸化炭素の再利用方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006314876A (ja) * 2005-05-11 2006-11-24 Ngk Spark Plug Co Ltd 水素分離装置
JP2007269595A (ja) * 2006-03-31 2007-10-18 Ngk Spark Plug Co Ltd 水素製造装置
JP2017149616A (ja) * 2016-02-25 2017-08-31 日本碍子株式会社 水素回収メンブレンリアクター、水素回収システム及び水素回収方法
JP2018008940A (ja) * 2016-07-04 2018-01-18 公益財団法人地球環境産業技術研究機構 メタノール製造方法およびメタノール製造装置

Also Published As

Publication number Publication date
EP4194078A4 (en) 2024-09-18
JP7500781B2 (ja) 2024-06-17
AU2024219588A1 (en) 2024-10-03
AU2024219588B2 (en) 2026-04-02
WO2022260063A1 (ja) 2022-12-15
JPWO2022260063A1 (https=) 2022-12-15
JP2024103728A (ja) 2024-08-01
US20230220283A1 (en) 2023-07-13
AU2022288464A1 (en) 2023-04-13
EP4194078A1 (en) 2023-06-14
AU2022288464B2 (en) 2024-06-13

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