CN115799601A - 锂离子电池 - Google Patents
锂离子电池 Download PDFInfo
- Publication number
- CN115799601A CN115799601A CN202210725516.7A CN202210725516A CN115799601A CN 115799601 A CN115799601 A CN 115799601A CN 202210725516 A CN202210725516 A CN 202210725516A CN 115799601 A CN115799601 A CN 115799601A
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- Prior art keywords
- negative electrode
- capacity
- positive electrode
- lithium
- discharge
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0438—Processes of manufacture in general by electrochemical processing
- H01M4/0459—Electrochemical doping, intercalation, occlusion or alloying
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
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- H—ELECTRICITY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
- H01M4/382—Lithium
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C01B35/12—Borates
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/32—Oxygen atoms
- C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B3/00—Preparation of cellulose esters of organic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/26—Cellulose ethers
- C08L1/28—Alkyl ethers
- C08L1/286—Alkyl ethers substituted with acid radicals, e.g. carboxymethyl cellulose [CMC]
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
- C08L5/04—Alginic acid; Derivatives thereof
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- H—ELECTRICITY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M2010/4292—Aspects relating to capacity ratio of electrodes/electrolyte or anode/cathode
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
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- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
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- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014-233341 | 2014-11-18 | ||
| JP2014233341A JP6355163B2 (ja) | 2014-11-18 | 2014-11-18 | リチウムイオン電池 |
| PCT/JP2015/079426 WO2016080128A1 (ja) | 2014-11-18 | 2015-10-19 | リチウムイオン電池 |
| CN201580062095.2A CN107112581A (zh) | 2014-11-18 | 2015-10-19 | 锂离子电池 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580062095.2A Division CN107112581A (zh) | 2014-11-18 | 2015-10-19 | 锂离子电池 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115799601A true CN115799601A (zh) | 2023-03-14 |
Family
ID=56013685
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210725516.7A Pending CN115799601A (zh) | 2014-11-18 | 2015-10-19 | 锂离子电池 |
| CN201580062095.2A Pending CN107112581A (zh) | 2014-11-18 | 2015-10-19 | 锂离子电池 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580062095.2A Pending CN107112581A (zh) | 2014-11-18 | 2015-10-19 | 锂离子电池 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US11088391B2 (enExample) |
| JP (1) | JP6355163B2 (enExample) |
| CN (2) | CN115799601A (enExample) |
| WO (1) | WO2016080128A1 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6854135B2 (ja) | 2017-01-17 | 2021-04-07 | 株式会社ダイセル | 電極用スラリー、電極及びその製造方法並びに二次電池 |
| US11621422B2 (en) | 2017-01-17 | 2023-04-04 | Daicel Corporation | Electrode slurry, electrode and process for producing the same, and secondary battery |
| JP2019114390A (ja) * | 2017-12-22 | 2019-07-11 | 日本ゼオン株式会社 | 電気化学デバイス用電解質組成物および電気化学デバイス用電極の製造方法 |
| JP7187156B2 (ja) | 2018-03-07 | 2022-12-12 | マクセル株式会社 | 電気化学素子用負極およびリチウムイオン二次電池 |
| EP3544099A1 (en) | 2018-03-21 | 2019-09-25 | Borregaard AS | Dispersant and binder for lithium ion batteries based on modified lignin and carboxymethyl cellulose |
| US12046710B2 (en) * | 2018-05-02 | 2024-07-23 | Jtekt Corporation | Lithium ion secondary battery |
| WO2019244955A1 (ja) | 2018-06-21 | 2019-12-26 | 株式会社Gsユアサ | 非水電解質二次電池用正極活物質、非水電解質二次電池用正極活物質の製造方法、非水電解質二次電池用正極、非水電解質二次電池、非水電解質二次電池の製造方法、及び非水電解質二次電池の使用方法 |
| EP3813163B1 (en) | 2018-06-21 | 2024-10-30 | GS Yuasa International Ltd. | Positive active material for nonaqueous electrolyte secondary battery, method for producing positive active material for nonaqueous electrolyte secondary battery, positive electrode for nonaqueous electrolyte secondary battery, nonaqueous electrolyte secondary battery, method for manufacturing nonaqueous electrolyte secondary battery, and method of using nonaqueous electrolyte secondary battery |
| CN110676514B (zh) * | 2018-07-03 | 2022-02-18 | 国家能源投资集团有限责任公司 | 锂离子电池单体及其化成方法 |
| JP7734326B2 (ja) * | 2020-10-30 | 2025-09-05 | パナソニックIpマネジメント株式会社 | 非水電解質二次電池 |
| CN112420982A (zh) * | 2020-11-02 | 2021-02-26 | 四川大学 | 一种钙钛矿钒酸盐共混活性材料的电极极片 |
| CN113093031B (zh) * | 2021-03-19 | 2024-01-19 | 北京工业大学 | 一种基于电压逆推检测锂离子电池正极材料过放电程度的方法 |
| CN113193166B (zh) * | 2021-04-28 | 2022-09-16 | 珠海冠宇电池股份有限公司 | 正极片、电芯及电池 |
| EP4447182A1 (en) * | 2021-12-09 | 2024-10-16 | Kyocera Corporation | Electrolyte solution, secondary battery and semi-solid battery |
| KR20230117994A (ko) * | 2022-02-03 | 2023-08-10 | 주식회사 엘지에너지솔루션 | 리튬 이차전지 |
| CN114242945B (zh) * | 2022-02-24 | 2022-07-12 | 中创新航科技股份有限公司 | 一种确定负极容量与正极容量之比的方法及相关的锂离子电池 |
| JP7702988B2 (ja) * | 2023-05-30 | 2025-07-04 | プライムプラネットエナジー&ソリューションズ株式会社 | リチウムイオン二次電池およびその製造方法 |
| WO2024262638A1 (ja) * | 2023-06-23 | 2024-12-26 | Orlib株式会社 | 二次電池 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3379541B2 (ja) * | 1992-07-06 | 2003-02-24 | 宇部興産株式会社 | 二次電池 |
| EP0580164B1 (en) * | 1992-07-24 | 1999-01-07 | Matsushita Electric Industrial Co., Ltd. | Magnetic recording medium and its manufacturing method |
| US7468223B2 (en) * | 2000-06-22 | 2008-12-23 | Uchicago Argonne, Llc | Lithium metal oxide electrodes for lithium cells and batteries |
| JP4175792B2 (ja) * | 2001-08-27 | 2008-11-05 | セントラル硝子株式会社 | 電気化学ディバイス用電解液またはゲル電解質並びに電池 |
| JP3982230B2 (ja) * | 2001-10-18 | 2007-09-26 | 日本電気株式会社 | 二次電池用負極およびそれを用いた二次電池 |
| JP2004063394A (ja) | 2002-07-31 | 2004-02-26 | Sanyo Electric Co Ltd | 非水電解質電池 |
| JP5433164B2 (ja) * | 2008-04-28 | 2014-03-05 | 日立ビークルエナジー株式会社 | リチウムイオン二次電池 |
| JP5402411B2 (ja) | 2009-08-31 | 2014-01-29 | 日産自動車株式会社 | リチウムイオン二次電池およびその製造方法 |
| JP5099168B2 (ja) | 2010-04-16 | 2012-12-12 | 株式会社豊田自動織機 | リチウムイオン二次電池 |
| JP2012216401A (ja) * | 2011-03-31 | 2012-11-08 | Fuji Heavy Ind Ltd | リチウムイオン蓄電デバイス |
| US9601228B2 (en) * | 2011-05-16 | 2017-03-21 | Envia Systems, Inc. | Silicon oxide based high capacity anode materials for lithium ion batteries |
| JP2013242997A (ja) * | 2012-05-18 | 2013-12-05 | Shin Etsu Chem Co Ltd | リチウムイオン二次電池 |
| JP2012169300A (ja) * | 2012-06-06 | 2012-09-06 | Hitachi Maxell Energy Ltd | 非水二次電池 |
| JP2014096300A (ja) * | 2012-11-09 | 2014-05-22 | National Institute Of Advanced Industrial & Technology | 蓄電デバイス |
| CN103915609B (zh) * | 2012-12-31 | 2017-10-13 | 宁波杉杉新材料科技有限公司 | 硅‑氧化硅‑碳复合材料、锂离子二次电池负极材料、其制备方法和应用 |
| JP6184273B2 (ja) * | 2013-09-25 | 2017-08-23 | 株式会社東芝 | 非水電解質二次電池及び電池パック |
| CN103887515A (zh) * | 2014-04-20 | 2014-06-25 | 天津市捷威动力工业有限公司 | 一种锂离子电池负极及使用该种负极的锂离子电池 |
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2014
- 2014-11-18 JP JP2014233341A patent/JP6355163B2/ja active Active
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2015
- 2015-10-19 CN CN202210725516.7A patent/CN115799601A/zh active Pending
- 2015-10-19 US US15/527,169 patent/US11088391B2/en active Active
- 2015-10-19 CN CN201580062095.2A patent/CN107112581A/zh active Pending
- 2015-10-19 WO PCT/JP2015/079426 patent/WO2016080128A1/ja not_active Ceased
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| Publication number | Publication date |
|---|---|
| CN107112581A (zh) | 2017-08-29 |
| US20170338511A1 (en) | 2017-11-23 |
| WO2016080128A1 (ja) | 2016-05-26 |
| JP6355163B2 (ja) | 2018-07-11 |
| JP2016100054A (ja) | 2016-05-30 |
| US11088391B2 (en) | 2021-08-10 |
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