CN1146471C - 催化加氢脱氯制取三氟氯乙烯和三氟乙烯所用催化剂 - Google Patents
催化加氢脱氯制取三氟氯乙烯和三氟乙烯所用催化剂 Download PDFInfo
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- CN1146471C CN1146471C CNB011334320A CN01133432A CN1146471C CN 1146471 C CN1146471 C CN 1146471C CN B011334320 A CNB011334320 A CN B011334320A CN 01133432 A CN01133432 A CN 01133432A CN 1146471 C CN1146471 C CN 1146471C
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Abstract
Description
反应运转时 间(hr) | 试样J(Ru-Cu-La-Li/C) | ||||
反应条件 | CF113(%mol) | SCTFE(%mol) | SCTFE+TrFE(%mol) | ||
温度(℃) | F113空速(hr-1) | ||||
初始 | 200250 | 1.92.9 | 89.499.9 | 89.785.7 | 95.195.6 |
50 | 185 | 1.2 | 71.6 | 90.5 | 97.9 |
100 | 194 | 1.2 | 77.3 | 89.6 | 98.2 |
200 | 204 | 1.2 | 76.6 | 88.3 | 98.2 |
300 | 212 | 1.2 | 74.3 | 87.3 | 98.0 |
400 | 222 | 1.2 | 72.7 | 86.3 | 97.8 |
500 | 241 | 1.2 | 75.6 | 84.7 | 97.0 |
550 | 260 | 1.2 | 75.5 | 85.1 | 96.5 |
600 | 285 | 1.2 | 72.2 | 81.8 | 96.7 |
反 应运转时间(hr) | 试 样 D (Ru-Cu/C) | ||||
反 应 条 件 | CF113(%mol) | SCTFE(%mol) | SCTFE+TrFE(%mol) | ||
温度(℃) | F113空速(hr-1) | ||||
50 | 1 74 | 1.2 | 76.68 | 91.07 | 98.24 |
100 | 181 | 1.2 | 74.67 | 89.41 | 98.21 |
200 | 195 | 1.2 | 71.42 | 86.77 | 97.90 |
300 | 217 | 1.2 | 73.32 | 83.45 | 97.53 |
400 | 241 | 1.2 | 74.26 | 79.75 | 97.00 |
500 | 295 | 1.2 | 71.28 | 77.83 | 95.82 |
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Priority Applications (1)
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CNB011334320A CN1146471C (zh) | 2001-11-07 | 2001-11-07 | 催化加氢脱氯制取三氟氯乙烯和三氟乙烯所用催化剂 |
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CNB011334320A CN1146471C (zh) | 2001-11-07 | 2001-11-07 | 催化加氢脱氯制取三氟氯乙烯和三氟乙烯所用催化剂 |
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Publication Number | Publication Date |
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CN1351903A CN1351903A (zh) | 2002-06-05 |
CN1146471C true CN1146471C (zh) | 2004-04-21 |
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CNB011334320A Expired - Fee Related CN1146471C (zh) | 2001-11-07 | 2001-11-07 | 催化加氢脱氯制取三氟氯乙烯和三氟乙烯所用催化剂 |
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CN (1) | CN1146471C (zh) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7135601B2 (en) | 2005-03-28 | 2006-11-14 | Honeywell International Inc. | Catalytic method for the production of fluoroalkylenes from chlorofluorohydrocarbons |
CN101020135B (zh) * | 2006-02-16 | 2010-11-10 | 中国科学院大连化学物理研究所 | 一种用于处理生物制药废水的催化剂及制法和应用 |
CN101450308B (zh) * | 2007-11-28 | 2012-05-09 | 中国石油化工股份有限公司 | 一种炭负载型贵金属催化剂及其制备方法 |
CN103007956A (zh) * | 2011-09-28 | 2013-04-03 | 中化蓝天集团有限公司 | 一种在三氟乙烯生产中联产1,1,2-三氟乙烷的方法 |
CN103920533B (zh) * | 2014-05-06 | 2016-04-20 | 济南大学 | 棕榈树皮负载纳米Pd-Cu催化剂的制备方法及应用 |
CN104028302B (zh) * | 2014-05-06 | 2016-04-20 | 济南大学 | 一种亚麻负载纳米Pd- Ni催化剂的制备方法及应用 |
CN104148111A (zh) * | 2014-07-16 | 2014-11-19 | 常熟三爱富氟化工有限责任公司 | 一种新型脱氯加氢催化剂的制备方法 |
CN105457651B (zh) * | 2014-09-05 | 2018-12-11 | 浙江蓝天环保高科技股份有限公司 | 一种加氢脱氯催化剂及其在三氟氯乙烯制备中的应用 |
CN111013604B (zh) * | 2019-11-21 | 2023-02-03 | 浙江工业大学 | 一种催化加氢脱氯用催化剂及其制备方法和应用 |
CN112547036B (zh) * | 2020-12-10 | 2022-09-30 | 中化蓝天集团有限公司 | 一种三氟三氯乙烷加氢脱氯催化剂及其制备方法 |
CN115364888B (zh) * | 2022-10-25 | 2022-12-30 | 山东华夏神舟新材料有限公司 | 一种负载型加氢脱氯催化剂及其制备方法、用途和采用该催化剂制备三氟氯乙烯的方法 |
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