CN111139319A - 一种降低果葡糖浆中5-羟甲基糠醛含量的系统及方法 - Google Patents
一种降低果葡糖浆中5-羟甲基糠醛含量的系统及方法 Download PDFInfo
- Publication number
- CN111139319A CN111139319A CN202010087317.9A CN202010087317A CN111139319A CN 111139319 A CN111139319 A CN 111139319A CN 202010087317 A CN202010087317 A CN 202010087317A CN 111139319 A CN111139319 A CN 111139319A
- Authority
- CN
- China
- Prior art keywords
- corn syrup
- high fructose
- fructose corn
- content
- syrup
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000019534 high fructose corn syrup Nutrition 0.000 title claims abstract description 143
- NOEGNKMFWQHSLB-UHFFFAOYSA-N 5-hydroxymethylfurfural Chemical compound OCC1=CC=C(C=O)O1 NOEGNKMFWQHSLB-UHFFFAOYSA-N 0.000 title claims abstract description 66
- RJGBSYZFOCAGQY-UHFFFAOYSA-N hydroxymethylfurfural Natural products COC1=CC=C(C=O)O1 RJGBSYZFOCAGQY-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000005342 ion exchange Methods 0.000 claims abstract description 41
- 150000001768 cations Chemical class 0.000 claims abstract description 22
- 150000001450 anions Chemical class 0.000 claims abstract description 18
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 238000001704 evaporation Methods 0.000 claims abstract description 16
- 238000013375 chromatographic separation Methods 0.000 claims abstract description 12
- 238000006317 isomerization reaction Methods 0.000 claims abstract description 10
- 230000008020 evaporation Effects 0.000 claims abstract description 9
- 238000004042 decolorization Methods 0.000 claims abstract description 8
- 238000000746 purification Methods 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims abstract description 3
- 235000021433 fructose syrup Nutrition 0.000 claims description 32
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 27
- 239000008103 glucose Substances 0.000 claims description 27
- 239000006188 syrup Substances 0.000 claims description 19
- 235000020357 syrup Nutrition 0.000 claims description 19
- 229930091371 Fructose Natural products 0.000 claims description 17
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 17
- 239000005715 Fructose Substances 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 15
- 239000000498 cooling water Substances 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 238000005349 anion exchange Methods 0.000 claims description 3
- 238000005341 cation exchange Methods 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims description 3
- PJVXUVWGSCCGHT-ZPYZYFCMSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;(3s,4r,5r)-1,3,4,5,6-pentahydroxyhexan-2-one Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O.OC[C@@H](O)[C@@H](O)[C@H](O)C(=O)CO PJVXUVWGSCCGHT-ZPYZYFCMSA-N 0.000 claims 1
- 240000008042 Zea mays Species 0.000 claims 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims 1
- 235000005822 corn Nutrition 0.000 claims 1
- 239000000047 product Substances 0.000 description 26
- 238000004519 manufacturing process Methods 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011265 semifinished product Substances 0.000 description 2
- 229920002261 Corn starch Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 210000003699 striated muscle Anatomy 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 210000001835 viscera Anatomy 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/06—Glucose; Glucose-containing syrups obtained by saccharification of starch or raw materials containing starch
- C13K1/08—Purifying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/02—Column or bed processes
- B01J47/026—Column or bed processes using columns or beds of different ion exchange materials in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/02—Column or bed processes
- B01J47/026—Column or bed processes using columns or beds of different ion exchange materials in series
- B01J47/028—Column or bed processes using columns or beds of different ion exchange materials in series with alternately arranged cationic and anionic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/02—Column or bed processes
- B01J47/04—Mixed-bed processes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Saccharide Compounds (AREA)
- Jellies, Jams, And Syrups (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
Description
Claims (10)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010087317.9A CN111139319A (zh) | 2020-02-11 | 2020-02-11 | 一种降低果葡糖浆中5-羟甲基糠醛含量的系统及方法 |
JP2022524000A JP7367210B2 (ja) | 2020-02-11 | 2021-02-07 | 果糖ブドウ糖液糖における5-ヒドロキシメチルフルフラールの含有量を低減させるシステムであって及び方法 |
PCT/CN2021/075695 WO2021160053A1 (zh) | 2020-02-11 | 2021-02-07 | 一种降低果葡糖浆中 5- 羟甲基糠醛含量的系统及方法 |
EP21753256.3A EP4023773B1 (en) | 2020-02-11 | 2021-02-07 | System for reducing content of 5-hydroxymethylfurfural in high-fructose corn syrup |
US17/775,002 US20220389526A1 (en) | 2020-02-11 | 2021-02-07 | System and method for reducing content of 5-hydroxymethylfurfural in high fructose corn syrup |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010087317.9A CN111139319A (zh) | 2020-02-11 | 2020-02-11 | 一种降低果葡糖浆中5-羟甲基糠醛含量的系统及方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN111139319A true CN111139319A (zh) | 2020-05-12 |
Family
ID=70527237
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010087317.9A Pending CN111139319A (zh) | 2020-02-11 | 2020-02-11 | 一种降低果葡糖浆中5-羟甲基糠醛含量的系统及方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20220389526A1 (zh) |
EP (1) | EP4023773B1 (zh) |
JP (1) | JP7367210B2 (zh) |
CN (1) | CN111139319A (zh) |
WO (1) | WO2021160053A1 (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112546674A (zh) * | 2020-12-23 | 2021-03-26 | 浙江华康药业股份有限公司 | 抑制葡萄糖在阴离子交换柱中异构为果糖的系统及方法 |
WO2021160053A1 (zh) * | 2020-02-11 | 2021-08-19 | 浙江华康药业股份有限公司 | 一种降低果葡糖浆中 5- 羟甲基糠醛含量的系统及方法 |
CN113774099A (zh) * | 2021-09-23 | 2021-12-10 | 黑龙江昊天玉米开发有限公司 | 一种低5-羟基-2-糠醛含量的果葡糖浆的制备方法 |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1239776A (en) * | 1968-10-02 | 1971-07-21 | Corn Products Co | Improved process for preparing sweet syrup |
CN102326728A (zh) * | 2011-06-30 | 2012-01-25 | 山东香驰健源生物科技有限公司 | 一种除去果葡糖浆中的5-羟甲基糠醛的方法 |
CN102876758A (zh) * | 2012-09-28 | 2013-01-16 | 浙江华康药业股份有限公司 | 一种果葡糖浆的制备方法 |
CN103549237A (zh) * | 2013-11-11 | 2014-02-05 | 山东西王糖业有限公司 | 除去果葡糖浆中糠醛的方法 |
CN104651541A (zh) * | 2015-01-20 | 2015-05-27 | 西王药业有限公司 | 结晶果糖生产过程中降低5-羟甲基糠醛的工艺方法 |
CN105255968A (zh) * | 2015-11-18 | 2016-01-20 | 昆山品青生物科技有限公司 | 一种f55果葡糖浆的制备方法 |
CN105316374A (zh) * | 2014-07-11 | 2016-02-10 | 武汉中粮食品科技有限公司 | 一种制糖的方法 |
CN205512099U (zh) * | 2016-01-25 | 2016-08-31 | 鲁洲生物科技(四川)有限公司 | 一种制备f55果糖的系统 |
CN107012262A (zh) * | 2017-03-21 | 2017-08-04 | 广州双桥股份有限公司 | 一种液体糖的生产方法 |
CN107058428A (zh) * | 2016-12-22 | 2017-08-18 | 河南飞天农业开发股份有限公司 | 一种果糖、麦芽糖同线生产工艺 |
CN107495084A (zh) * | 2017-09-08 | 2017-12-22 | 宁波大学 | 一种去除f55果葡糖浆中异戊醛的方法 |
CN211848008U (zh) * | 2020-02-11 | 2020-11-03 | 浙江华康药业股份有限公司 | 一种降低果葡糖浆中5-羟甲基糠醛含量的系统 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5241340B2 (zh) * | 1973-05-16 | 1977-10-18 | ||
JPS56148300A (en) * | 1980-04-21 | 1981-11-17 | Organo Kk | Purification of saccharide containing fructose in high concentration |
JPS5747499A (en) * | 1980-09-05 | 1982-03-18 | Mitsui Toatsu Chemicals | Purification of particulate saccharified solution |
JPH0693840B2 (ja) * | 1985-10-04 | 1994-11-24 | 昭和産業株式会社 | 糖液の精製方法 |
JP4210396B2 (ja) | 1999-08-27 | 2009-01-14 | オルガノ株式会社 | デンプン糖液脱塩処理方法及び脱塩処理システム |
FR2912036B1 (fr) | 2007-02-01 | 2009-10-02 | Nutritis | Sirops de sucres de fruits a haute teneur en fructose,et procede de preparation. |
JP5989459B2 (ja) | 2012-08-28 | 2016-09-07 | オルガノ株式会社 | 糖液精製システム及び糖液精製方法 |
CN104498639B (zh) * | 2014-12-10 | 2017-12-05 | 广州双桥股份有限公司 | 一种高果糖浆的生产工艺 |
CN204710317U (zh) * | 2015-05-27 | 2015-10-21 | 宋昭语 | 一种高效反应釜 |
CN206478858U (zh) * | 2017-01-20 | 2017-09-08 | 北京易科联盟清洁技术发展有限公司 | 利用热泵回收巴氏杀菌装置余热用于加热生产用热水系统 |
CN109402191A (zh) * | 2018-01-15 | 2019-03-01 | 吉林中粮生化有限公司 | 大米f55果葡糖浆的制备方法 |
CN109136302B (zh) * | 2018-08-23 | 2021-11-16 | 湖南汇升生物科技有限公司 | 一种在淀粉糖生产中控制糠醛超标的生产方法 |
CN110551776A (zh) * | 2019-10-10 | 2019-12-10 | 中粮融氏生物科技有限公司 | 一种抗结晶果葡糖浆及其制备方法 |
CN111139319A (zh) * | 2020-02-11 | 2020-05-12 | 浙江华康药业股份有限公司 | 一种降低果葡糖浆中5-羟甲基糠醛含量的系统及方法 |
-
2020
- 2020-02-11 CN CN202010087317.9A patent/CN111139319A/zh active Pending
-
2021
- 2021-02-07 US US17/775,002 patent/US20220389526A1/en active Pending
- 2021-02-07 WO PCT/CN2021/075695 patent/WO2021160053A1/zh active Application Filing
- 2021-02-07 JP JP2022524000A patent/JP7367210B2/ja active Active
- 2021-02-07 EP EP21753256.3A patent/EP4023773B1/en active Active
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1239776A (en) * | 1968-10-02 | 1971-07-21 | Corn Products Co | Improved process for preparing sweet syrup |
CN102326728A (zh) * | 2011-06-30 | 2012-01-25 | 山东香驰健源生物科技有限公司 | 一种除去果葡糖浆中的5-羟甲基糠醛的方法 |
CN102876758A (zh) * | 2012-09-28 | 2013-01-16 | 浙江华康药业股份有限公司 | 一种果葡糖浆的制备方法 |
CN103549237A (zh) * | 2013-11-11 | 2014-02-05 | 山东西王糖业有限公司 | 除去果葡糖浆中糠醛的方法 |
CN105316374A (zh) * | 2014-07-11 | 2016-02-10 | 武汉中粮食品科技有限公司 | 一种制糖的方法 |
CN104651541A (zh) * | 2015-01-20 | 2015-05-27 | 西王药业有限公司 | 结晶果糖生产过程中降低5-羟甲基糠醛的工艺方法 |
CN105255968A (zh) * | 2015-11-18 | 2016-01-20 | 昆山品青生物科技有限公司 | 一种f55果葡糖浆的制备方法 |
CN205512099U (zh) * | 2016-01-25 | 2016-08-31 | 鲁洲生物科技(四川)有限公司 | 一种制备f55果糖的系统 |
CN107058428A (zh) * | 2016-12-22 | 2017-08-18 | 河南飞天农业开发股份有限公司 | 一种果糖、麦芽糖同线生产工艺 |
CN107012262A (zh) * | 2017-03-21 | 2017-08-04 | 广州双桥股份有限公司 | 一种液体糖的生产方法 |
CN107495084A (zh) * | 2017-09-08 | 2017-12-22 | 宁波大学 | 一种去除f55果葡糖浆中异戊醛的方法 |
CN211848008U (zh) * | 2020-02-11 | 2020-11-03 | 浙江华康药业股份有限公司 | 一种降低果葡糖浆中5-羟甲基糠醛含量的系统 |
Non-Patent Citations (1)
Title |
---|
陈春霞;邹德君;赵红云;: "果葡糖浆生产过程中5-糠醛的控制方法探究", 现代食品, no. 05, pages 99 - 103 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021160053A1 (zh) * | 2020-02-11 | 2021-08-19 | 浙江华康药业股份有限公司 | 一种降低果葡糖浆中 5- 羟甲基糠醛含量的系统及方法 |
CN112546674A (zh) * | 2020-12-23 | 2021-03-26 | 浙江华康药业股份有限公司 | 抑制葡萄糖在阴离子交换柱中异构为果糖的系统及方法 |
CN113774099A (zh) * | 2021-09-23 | 2021-12-10 | 黑龙江昊天玉米开发有限公司 | 一种低5-羟基-2-糠醛含量的果葡糖浆的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
EP4023773C0 (en) | 2024-02-14 |
US20220389526A1 (en) | 2022-12-08 |
EP4023773A1 (en) | 2022-07-06 |
WO2021160053A1 (zh) | 2021-08-19 |
JP2022553391A (ja) | 2022-12-22 |
EP4023773A4 (en) | 2022-12-28 |
EP4023773B1 (en) | 2024-02-14 |
JP7367210B2 (ja) | 2023-10-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP7367210B2 (ja) | 果糖ブドウ糖液糖における5-ヒドロキシメチルフルフラールの含有量を低減させるシステムであって及び方法 | |
CN111269107B (zh) | 一种l-乳酸提纯精制方法 | |
CN101565762B (zh) | 一种淀粉糖生产方法 | |
CN109503676B (zh) | 一种从木糖母液中制备木糖醇和混合糖浆的方法 | |
CN102634228B (zh) | 甘蔗糖蜜生产高色率双倍焦糖色的方法 | |
CN102912043B (zh) | 一种纯化果糖生产方法 | |
CN102876758A (zh) | 一种果葡糖浆的制备方法 | |
CN104630312A (zh) | 一种用葡萄糖母液生产果葡糖浆的方法 | |
CN104673942A (zh) | 一种蔗糖生产结晶果糖的方法 | |
CN105256079A (zh) | 果糖生产过程中的果葡糖浆的纯化方法 | |
CN211848008U (zh) | 一种降低果葡糖浆中5-羟甲基糠醛含量的系统 | |
LU505290B1 (en) | Method for purifying L-lactic acid | |
CN105331751A (zh) | 以甘蔗为原料生产医药无水结晶果糖的方法 | |
CN101863737A (zh) | 一种精制木糖醇发酵液的方法 | |
CN102964393A (zh) | 利用木糖母液生产木糖的方法 | |
CN101864469A (zh) | 一种果葡糖浆的生产工艺 | |
JP2024507212A (ja) | キシロース母液を用いたキシリトール・カラメル色素併産システム、及び方法 | |
CN100507008C (zh) | 采用离子交换树脂对葡萄糖糖化液进行脱色的方法 | |
CN100534996C (zh) | 一种晶体卫茅醇的制备方法 | |
JP2024507514A (ja) | キシリトール発酵液の精製システム及びその方法 | |
CN110904170B (zh) | 一种f-55果葡糖浆的制备方法 | |
CN101381354A (zh) | 一种粗品维生素c钠盐转化成粗维生素c的生产工艺 | |
CN1687432A (zh) | 一种以蔗糖为原料制备甘露醇的方法 | |
CN112410387A (zh) | 低碘值超高麦芽糖浆的生产方法 | |
CN108034773B (zh) | 一种利用模拟移动床连续离交生产结晶糖的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Cheng Xinping Inventor after: Chen Shengrong Inventor after: ZhuGe Jun Inventor after: Cheng Yuqing Inventor after: Han Xinfeng Inventor after: Luo Jiaxing Inventor after: Li Mian Inventor before: Chen Shengrong Inventor before: ZhuGe Jun Inventor before: Cheng Yuqing Inventor before: Han Xinfeng Inventor before: Luo Jiaxing |