CN110352209A - 含有生物成因碳的β-丙内酯基共聚物，其生产方法及其用途 - Google Patents

含有生物成因碳的β-丙内酯基共聚物，其生产方法及其用途 Download PDF

Info

Publication number
CN110352209A
CN110352209A CN201880004848.8A CN201880004848A CN110352209A CN 110352209 A CN110352209 A CN 110352209A CN 201880004848 A CN201880004848 A CN 201880004848A CN 110352209 A CN110352209 A CN 110352209A
Authority
CN
China
Prior art keywords
copolymer
beta
bpl
propiolactone
optionally substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201880004848.8A
Other languages
English (en)
Chinese (zh)
Inventor
萨德什·H·苏克拉杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novomel Corp
Original Assignee
Novomel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novomel Corp filed Critical Novomel Corp
Publication of CN110352209A publication Critical patent/CN110352209A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
    • C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D305/10—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having one or more double bonds between ring members or between ring members and non-ring members
    • C07D305/12—Beta-lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/664—Polyesters containing oxygen in the form of ether groups derived from hydroxy carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6882—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from hydroxy carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Biological Depolymerization Polymers (AREA)
CN201880004848.8A 2016-12-05 2018-02-05 含有生物成因碳的β-丙内酯基共聚物，其生产方法及其用途 Pending CN110352209A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/369,764 US10144802B2 (en) 2016-12-05 2016-12-05 Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof
PCT/US2018/016853 WO2018144998A1 (en) 2016-12-05 2018-02-05 Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof

Publications (1)

Publication Number Publication Date
CN110352209A true CN110352209A (zh) 2019-10-18

Family

ID=62196672

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880004848.8A Pending CN110352209A (zh) 2016-12-05 2018-02-05 含有生物成因碳的β-丙内酯基共聚物，其生产方法及其用途

Country Status (13)

Country Link
US (3) US10144802B2 (enExample)
EP (1) EP3548538B1 (enExample)
JP (1) JP2021506987A (enExample)
KR (1) KR20200107765A (enExample)
CN (1) CN110352209A (enExample)
AU (1) AU2018215539A1 (enExample)
BR (1) BR112019011536A2 (enExample)
CA (1) CA3046104A1 (enExample)
CO (1) CO2019005773A2 (enExample)
MA (1) MA46978A (enExample)
MX (1) MX2019006524A (enExample)
SA (1) SA519401899B1 (enExample)
WO (1) WO2018144998A1 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3148959B1 (en) 2014-05-30 2023-11-22 Novomer Inc. Integrated methods for chemical synthesis
AU2015292361B2 (en) 2014-07-25 2019-07-18 Novomer, Inc. Synthesis of metal complexes and uses thereof
EP3696161A1 (en) 2015-02-13 2020-08-19 Novomer, Inc. Continuous carbonylation processes
MA41508A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production d'acide polyacrylique
MA41507A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production de polymères
MA41514A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédés intégrés de synthèse chimique
WO2016130988A1 (en) 2015-02-13 2016-08-18 Novomer, Inc. Flexible chemical production platform
MA41510A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de production d'acide acrylique
CN115449058A (zh) 2015-07-31 2022-12-09 诺沃梅尔公司 用于丙烯酸及其前体的生产系统/生产方法
TW201802061A (zh) 2016-03-21 2018-01-16 諾沃梅爾公司 丙烯酸及其製造方法
AU2017353611A1 (en) 2016-11-02 2019-04-11 Novomer, Inc. Absorbent polymers, and methods and systems of producing thereof and uses thereof
US10144802B2 (en) 2016-12-05 2018-12-04 Novomer, Inc. Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof
US10500104B2 (en) 2016-12-06 2019-12-10 Novomer, Inc. Biodegradable sanitary articles with higher biobased content
US10065914B1 (en) 2017-04-24 2018-09-04 Novomer, Inc. Thermolysis of polypropiolactone to produce acrylic acid
US10676426B2 (en) 2017-06-30 2020-06-09 Novomer, Inc. Acrylonitrile derivatives from epoxide and carbon monoxide reagents
US10590099B1 (en) 2017-08-10 2020-03-17 Novomer, Inc. Processes for producing beta-lactone with heterogenous catalysts
ES2991139T3 (es) 2018-07-13 2024-12-02 Novomer Inc Espumas de polilactona y métodos de fabricación de las mismas
JP7368010B2 (ja) 2019-03-08 2023-10-24 ノボマー， インコーポレイテッド アミド化合物及びニトリル化合物を生成するための統合された方法及びシステム
JP2023542612A (ja) 2020-08-17 2023-10-11 ノボマー， インコーポレイテッド ベータプロピオラクトン及び官能化ベータプロピオラクトンベースのポリマー系
CN117157342A (zh) 2021-04-16 2023-12-01 诺沃梅尔公司 聚丙内酯和制备方法
CA3223981A1 (en) * 2021-06-29 2023-01-05 Steven Gray Poly (3-hydroxyacid) polymers from long-chain epoxides and their uses related to hot melt adhesives
WO2023003890A1 (en) * 2021-07-21 2023-01-26 Novomer, Inc. Methods for beta-lactone copolymerization
WO2024141770A1 (en) * 2022-12-28 2024-07-04 Bostik Sa Poly(3-hydroxyacid) polymers from long-chain epoxides and their uses related to hot melt adhesives
CN116444715A (zh) * 2023-03-08 2023-07-18 浙江卫星新材料科技有限公司 一种可完全生物降解高吸收性树脂的制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1026924A (en) * 1962-10-25 1966-04-20 Shell Int Research Process for the preparation of copolymers from beta-lactones and epoxides
US5032671A (en) * 1990-09-04 1991-07-16 Arco Chemical Technology, Inc. Preparation of lactone polymers using double metal cyanide catalysts
PL160092B1 (pl) * 1989-05-15 1993-02-26 Sposób wytwarzania makromonomerów poliestrowych PL
CN102612530A (zh) * 2009-10-14 2012-07-25 赢创德固赛有限公司 由内酯制备聚酯和共聚酯的方法
US20150376330A1 (en) * 2013-03-18 2015-12-31 Saudi Basic Industries Corporation Process for preparing a copolymer
WO2016131004A1 (en) * 2015-02-13 2016-08-18 Novomer, Inc. Integrated methods for chemical synthesis

Family Cites Families (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3169945A (en) 1956-04-13 1965-02-16 Union Carbide Corp Lactone polyesters
US3607841A (en) * 1967-03-22 1971-09-21 Kanegafuchi Spinning Co Ltd Production of poly-2,2-disubstituted-beta-propiolactones
GB1182376A (en) * 1968-07-01 1970-02-25 Shell Int Research Process for the Polymerization or Copolymerization of Beta-Propiolactones
US3678069A (en) 1968-12-04 1972-07-18 Phillips Petroleum Co Lactone polymerization with a dicarboxylic acid-water initiator
JPS5986621A (ja) * 1982-11-10 1984-05-18 Daicel Chem Ind Ltd 新規なグラフト重合体の製造方法
US5310948A (en) 1992-06-29 1994-05-10 Shell Oil Company Carbonylation of epoxides
US5349046A (en) * 1992-12-01 1994-09-20 Shell Oil Company Polymerization of β-lactones under rim conditions
BR9506651A (pt) 1994-01-28 1997-09-02 Procter & Gamble Polimeraração de beta-propiolactonas beta-substituidas iniciada por alcóxidos de alquilzinco
US6133402A (en) 1998-08-04 2000-10-17 Cornell Research Foundation, Inc. Polycarbonates made using high activity catalysts
US6608170B1 (en) 1999-03-31 2003-08-19 Cornell Research Foundation, Inc. Syndiotactic poly(lactic acid)
US6258869B1 (en) 1999-07-13 2001-07-10 Polymermann (Asia) Pvt. Ltd. Process for production of polyols, and polyols for polyurethane
US6316590B1 (en) 1999-11-10 2001-11-13 Cornell Research Foundation, Inc. Synthesis of stereospecific and atactic poly(lactic acid)s
WO2002034804A1 (en) 2000-10-24 2002-05-02 Cornell Research Foundation, Inc. Preparing isotactic stereoblock poly(lactic acid)
EP1354908A4 (en) * 2000-11-30 2005-11-30 Daicel Chem ALIPHATIC POLYESTER COPOLYMER AND PROCESS FOR THE PRODUCTION THEREOF, BIODEGRADABLE RESIN MOLDING BASED ON THE ALIPHATIC POLYESTER, AND LACTONE CONTAINING RESIN
US6767951B2 (en) * 2001-11-13 2004-07-27 Eastman Kodak Company Polyester nanocomposites
EP1461315B1 (en) 2001-12-06 2009-07-29 Cornell Research Foundation, Inc. Catalytic carbonylation of three and four membered heterocycles
DE10235317A1 (de) 2002-08-01 2004-02-12 Basf Ag Katalysator und Verfahren zur Carbonylierung von Oxiranen
KR20050121247A (ko) 2003-04-09 2005-12-26 쉘 인터내셔날 리써취 마트샤피지 비.브이. 에폭시드의 카보닐화
DE102004002875A1 (de) 2004-01-20 2005-10-06 Basf Ag Katalysator zur Carbonylierung von Oxiranen
EP1932868A4 (en) * 2005-10-05 2011-01-12 Asahi Glass Co Ltd SILYL GROUP-BASED POLYMER AND METHOD OF MANUFACTURING THEREOF
BRPI0721929B1 (pt) 2007-08-13 2018-11-27 Sumitomo Chemical Co grânulo revestido com resina de uretano
CN102421821B (zh) 2009-04-08 2014-12-10 诺沃梅尔公司 β-内酯的制造方法
US9156803B2 (en) 2010-08-28 2015-10-13 Novomer, Inc. Succinic anhydride from ethylene oxide
WO2012051219A2 (en) 2010-10-11 2012-04-19 Novomer, Inc. Polymer blends
EP2707353B1 (en) 2011-05-13 2021-03-31 Novomer, Inc. Carbonylation catalysts and method
CN103987682B (zh) 2011-10-26 2017-06-16 诺沃梅尔公司 用于由环氧化物制备丙烯酸酯的工艺
CN104245659B (zh) 2012-02-13 2016-08-24 诺沃梅尔公司 由环氧化物生产酸酐的方法
CN106588627A (zh) 2012-02-22 2017-04-26 诺沃梅尔公司 丙烯酸生产方法
KR20150036034A (ko) 2012-06-27 2015-04-07 노보머, 인코포레이티드 폴리에스터 제조를 위한 촉매 및 방법
CN104411661A (zh) 2012-07-02 2015-03-11 诺沃梅尔公司 丙烯酸酯生产工艺
EP2842583A1 (en) 2013-08-29 2015-03-04 Ella-CS, s.r.o. Biodegradable and bioerodible polyurethanes, method of preparation thereof and use thereof
WO2015085295A2 (en) 2013-12-07 2015-06-11 Novomer, Inc. Nanofiltration membranes and methods of use
CA2941714A1 (en) 2014-03-14 2015-09-17 Novomer, Inc. Catalysts for epoxide carbonylation
US10858329B2 (en) 2014-05-05 2020-12-08 Novomer, Inc. Catalyst recycle methods
EP3148959B1 (en) 2014-05-30 2023-11-22 Novomer Inc. Integrated methods for chemical synthesis
AU2015292361B2 (en) 2014-07-25 2019-07-18 Novomer, Inc. Synthesis of metal complexes and uses thereof
CN111944130B (zh) 2015-02-13 2022-10-25 诺沃梅尔公司 聚丙内酯生产方法和系统
EP3696161A1 (en) 2015-02-13 2020-08-19 Novomer, Inc. Continuous carbonylation processes
MA41508A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production d'acide polyacrylique
WO2016130988A1 (en) 2015-02-13 2016-08-18 Novomer, Inc. Flexible chemical production platform
MA41510A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de production d'acide acrylique
MA41513A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de distillation pour la production d'acide acrylique
MA41507A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production de polymères
CA2991207A1 (en) 2015-07-01 2017-01-05 Novomer, Inc. Methods for production of terephthalic acid from ethylene oxide
CN115449058A (zh) 2015-07-31 2022-12-09 诺沃梅尔公司 用于丙烯酸及其前体的生产系统/生产方法
TW201802061A (zh) 2016-03-21 2018-01-16 諾沃梅爾公司 丙烯酸及其製造方法
US20180305286A1 (en) 2016-03-21 2018-10-25 Novomer, Inc. Systems and Processes for Producing Organic Acids Direct from Beta-Lactones
TW201802062A (zh) 2016-03-21 2018-01-16 諾沃梅爾公司 製造超吸收性聚合物之系統及方法
US20180282251A1 (en) 2017-03-21 2018-10-04 Novomer, Inc. Systems and processes for producing organic acids direct from beta-lactones
EP3535305A4 (en) 2016-11-02 2020-06-24 Novomer, Inc. ABSORBENT POLYMERS, METHODS OF PRODUCTION AND USES THEREOF
AU2017353611A1 (en) 2016-11-02 2019-04-11 Novomer, Inc. Absorbent polymers, and methods and systems of producing thereof and uses thereof
US10144802B2 (en) * 2016-12-05 2018-12-04 Novomer, Inc. Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof
US20180155490A1 (en) 2016-12-05 2018-06-07 Novomer, Inc. Biodegradable polyols having higher biobased content
US10500104B2 (en) 2016-12-06 2019-12-10 Novomer, Inc. Biodegradable sanitary articles with higher biobased content
AR110833A1 (es) 2017-01-19 2019-05-08 Novomer Inc Métodos y sistemas para el tratamiento de óxido de etileno
KR20190126412A (ko) 2017-03-17 2019-11-11 노보머, 인코포레이티드 폴리아미드 및 이의 제조방법
US10065914B1 (en) 2017-04-24 2018-09-04 Novomer, Inc. Thermolysis of polypropiolactone to produce acrylic acid
US10676426B2 (en) 2017-06-30 2020-06-09 Novomer, Inc. Acrylonitrile derivatives from epoxide and carbon monoxide reagents
US20190002385A1 (en) 2017-06-30 2019-01-03 Novomer, Inc. Compositions for improved production of acrylic acid
US10899622B2 (en) 2017-06-30 2021-01-26 Novomer, Inc. Biobased carbon fibers and carbon black and methods of making the same
US10781156B2 (en) 2017-06-30 2020-09-22 Novomer, Inc. Compositions for improved production of acrylic acid
US10961209B2 (en) 2017-08-10 2021-03-30 Novomer, Inc. Processes for producing beta-lactone and beta-lactone derivatives with heterogenous catalysts
EP3679011A4 (en) 2017-09-09 2021-04-14 Novomer, Inc. AMIDE AND NITRILE COMPOUNDS AND PROCESSES FOR THE PRODUCTION AND USE OF THE SAME
US20190076835A1 (en) 2017-09-11 2019-03-14 Novomer, Inc. Processses using multifunctional catalysts
US20190076834A1 (en) 2017-09-11 2019-03-14 Novomer, Inc. Processes Using Multifunctional Catalysts
JP7114109B2 (ja) 2017-10-05 2022-08-08 ノボマー， インコーポレイテッド イソシアネート、誘導体及びその製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1026924A (en) * 1962-10-25 1966-04-20 Shell Int Research Process for the preparation of copolymers from beta-lactones and epoxides
PL160092B1 (pl) * 1989-05-15 1993-02-26 Sposób wytwarzania makromonomerów poliestrowych PL
US5032671A (en) * 1990-09-04 1991-07-16 Arco Chemical Technology, Inc. Preparation of lactone polymers using double metal cyanide catalysts
CN102612530A (zh) * 2009-10-14 2012-07-25 赢创德固赛有限公司 由内酯制备聚酯和共聚酯的方法
US20150376330A1 (en) * 2013-03-18 2015-12-31 Saudi Basic Industries Corporation Process for preparing a copolymer
WO2016131004A1 (en) * 2015-02-13 2016-08-18 Novomer, Inc. Integrated methods for chemical synthesis

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
S. GLOWINKOWSKI: "Nuclear magnetic resonance studies of molecular dynamics of fl-propiolactone homopolymer and its block copolymer with fl-butyrolactone", POLYMER, vol. 30, 31 March 1989 (1989-03-31), pages 519 - 523, XP024116045, DOI: 10.1016/0032-3861(89)90024-4 *

Also Published As

Publication number Publication date
CO2019005773A2 (es) 2019-06-19
WO2018144998A1 (en) 2018-08-09
US20190071538A1 (en) 2019-03-07
JP2021506987A (ja) 2021-02-22
BR112019011536A2 (pt) 2019-10-08
US11655333B2 (en) 2023-05-23
US10669373B2 (en) 2020-06-02
US20200262973A1 (en) 2020-08-20
US20180155491A1 (en) 2018-06-07
EP3548538A1 (en) 2019-10-09
SA519401899B1 (ar) 2022-10-10
CA3046104A1 (en) 2018-08-09
KR20200107765A (ko) 2020-09-16
AU2018215539A1 (en) 2019-06-20
MX2019006524A (es) 2019-10-22
MA46978A (fr) 2019-10-09
US10144802B2 (en) 2018-12-04
EP3548538B1 (en) 2022-07-27

Similar Documents

Publication Publication Date Title
US11655333B2 (en) Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof
US11155511B2 (en) Distillation process for production of acrylic acid
JP2019070058A (ja) アクリル酸の生成のためのプロセス
CN107406362B (zh) 灵活的化学生产平台
JP6847843B2 (ja) ポリプロピオラクトンの生成のためのプロセスおよびシステム
JP2021506988A (ja) より高いバイオベース含量を有する生分解可能なポリマー
JP2018506628A (ja) ポリアクリル酸生成のためのシステムおよびプロセス
JP2018505286A (ja) ポリマー生成のためのシステムおよびプロセス
JP2010536993A (ja) エポキシドおよび環状無水物の共重合
WO2013138243A1 (en) Bifunctional compounds

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination