CN110087768B - 酸处理以使包含具有mww骨架类型的含钛沸石材料的组合物的可塑性降低的用途 - Google Patents

酸处理以使包含具有mww骨架类型的含钛沸石材料的组合物的可塑性降低的用途 Download PDF

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Publication number
CN110087768B
CN110087768B CN201780078886.3A CN201780078886A CN110087768B CN 110087768 B CN110087768 B CN 110087768B CN 201780078886 A CN201780078886 A CN 201780078886A CN 110087768 B CN110087768 B CN 110087768B
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China
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titanium
framework type
mww framework
acid
zeolite material
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Chinese (zh)
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CN110087768A (zh
Inventor
A-N·帕乌莱斯库
U·穆勒
H-J·卢茨伊勒
G·尤尔
J·H·泰勒斯
D·里德尔
D·乌尔班奇克
U·韦格利
M·韦伯
N·T·沃兹
C·穆勒
R·施密特
X·罗马尼费尔南德斯
H·维尔茨
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B01J20/28021—Hollow particles, e.g. hollow spheres, microspheres or cenospheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3071—Washing or leaching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7088—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
CN201780078886.3A 2016-12-20 2017-12-20 酸处理以使包含具有mww骨架类型的含钛沸石材料的组合物的可塑性降低的用途 Active CN110087768B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311004026.9A CN117046513A (zh) 2016-12-20 2017-12-20 酸处理以使包含具有mww骨架类型的含钛沸石材料的组合物的可塑性降低的用途

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16205266.6 2016-12-20
EP16205266 2016-12-20
PCT/EP2017/083810 WO2018115118A1 (en) 2016-12-20 2017-12-20 Use of an acid treatment to decrease the plasticity of a composition comprising a titanium-containing zeolitic material having framework type mww

Related Child Applications (1)

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CN202311004026.9A Division CN117046513A (zh) 2016-12-20 2017-12-20 酸处理以使包含具有mww骨架类型的含钛沸石材料的组合物的可塑性降低的用途

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CN110087768B true CN110087768B (zh) 2023-09-01

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CN202311004026.9A Pending CN117046513A (zh) 2016-12-20 2017-12-20 酸处理以使包含具有mww骨架类型的含钛沸石材料的组合物的可塑性降低的用途

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Country Status (10)

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US (1) US11351525B2 (cg-RX-API-DMAC7.html)
EP (1) EP3558517A1 (cg-RX-API-DMAC7.html)
JP (1) JP7296880B2 (cg-RX-API-DMAC7.html)
KR (1) KR102555075B1 (cg-RX-API-DMAC7.html)
CN (2) CN110087768B (cg-RX-API-DMAC7.html)
BR (1) BR112019011059B1 (cg-RX-API-DMAC7.html)
MY (1) MY199977A (cg-RX-API-DMAC7.html)
RU (1) RU2761301C2 (cg-RX-API-DMAC7.html)
WO (1) WO2018115118A1 (cg-RX-API-DMAC7.html)
ZA (1) ZA201903192B (cg-RX-API-DMAC7.html)

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Publication number Priority date Publication date Assignee Title
MX2018016297A (es) 2016-06-29 2019-09-16 Basf Se Proceso para la preparacion de aldehidos alfa, beta insaturados mediante oxidacion de alcoholes en presencia de una fase liquida.
CN110582481A (zh) 2017-05-03 2019-12-17 巴斯夫欧洲公司 用沸石将氧化乙烯转化为单乙醇胺和乙二胺的方法
CN115477310B (zh) * 2021-06-16 2023-11-28 中国石油化工股份有限公司 P-Ti-MWW分子筛及其制备方法与应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013117536A2 (en) * 2012-02-07 2013-08-15 Basf Se Micropowder and molding containing a zeolitic material containing ti and zn
CN103934039A (zh) * 2013-01-23 2014-07-23 中国石油化工股份有限公司 提高分子筛催化剂强度的方法
CN104437616A (zh) * 2014-11-21 2015-03-25 武汉工程大学 层状含介孔钛硅分子筛催化剂及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0689170B2 (ja) * 1985-09-24 1994-11-09 日本化学工業株式会社 樹脂組成物
JP3706457B2 (ja) * 1997-02-28 2005-10-12 帝人化成株式会社 熱可塑性樹脂組成物
DE10320635A1 (de) 2003-05-08 2004-11-18 Basf Ag Verfahren zur Herstellung von Propylenoxid
US8124555B2 (en) * 2010-02-01 2012-02-28 Lyondell Chemical Technology L.P. Process for making titanium-MWW zeolite
MY169039A (en) * 2012-10-18 2019-02-07 Basf Se Post-treatment of deboronated mww zeolite
CN110002463B (zh) * 2013-02-05 2022-10-11 巴斯夫欧洲公司 制备具有mww骨架结构的含钛沸石材料的方法
CN105848781B (zh) * 2013-10-23 2020-07-17 巴斯夫欧洲公司 疏水性沸石材料的模制品及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013117536A2 (en) * 2012-02-07 2013-08-15 Basf Se Micropowder and molding containing a zeolitic material containing ti and zn
CN103934039A (zh) * 2013-01-23 2014-07-23 中国石油化工股份有限公司 提高分子筛催化剂强度的方法
CN104437616A (zh) * 2014-11-21 2015-03-25 武汉工程大学 层状含介孔钛硅分子筛催化剂及其制备方法和应用

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄宗理等.可塑性.《地球科学大辞典 应用学科卷》.地质出版社,2005,第664页. *

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US11351525B2 (en) 2022-06-07
JP7296880B2 (ja) 2023-06-23
JP2020502304A (ja) 2020-01-23
BR112019011059B1 (pt) 2022-08-09
KR20190089913A (ko) 2019-07-31
CN117046513A (zh) 2023-11-14
RU2019122860A (ru) 2021-01-25
KR102555075B1 (ko) 2023-07-12
CN110087768A (zh) 2019-08-02
RU2761301C2 (ru) 2021-12-07
ZA201903192B (en) 2024-09-25
WO2018115118A1 (en) 2018-06-28
RU2019122860A3 (cg-RX-API-DMAC7.html) 2021-04-21
EP3558517A1 (en) 2019-10-30
US20190321811A1 (en) 2019-10-24
BR112019011059A2 (pt) 2019-10-08
MY199977A (en) 2023-12-01

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