KR102555075B1 - Mww형 골격을 갖는 티타늄-함유 제올라이트 재료를 포함하는 조성물의 소성도를 감소시키기 위한 산 처리의 용도 - Google Patents

Mww형 골격을 갖는 티타늄-함유 제올라이트 재료를 포함하는 조성물의 소성도를 감소시키기 위한 산 처리의 용도 Download PDF

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KR102555075B1
KR102555075B1 KR1020197017197A KR20197017197A KR102555075B1 KR 102555075 B1 KR102555075 B1 KR 102555075B1 KR 1020197017197 A KR1020197017197 A KR 1020197017197A KR 20197017197 A KR20197017197 A KR 20197017197A KR 102555075 B1 KR102555075 B1 KR 102555075B1
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titanium
acid
type framework
composition
mww type
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KR20190089913A (ko
Inventor
안드레이-니콜라에 파불레스쿠
울리히 뮐러
한스-위르겐 뤼첼
게오르그 울
호아킴 엔리케 텔레스
도미닉 리델
다니엘 우르반크지크
울리케 베게를레
마르쿠스 베버
니콜라이 토니오 우어즈
크리스티안 뮐러
뤼디거 슈미트
페르난데츠 시아나 로마니
하랄트 뷔르츠
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바스프 에스이
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7088—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B01J20/28021—Hollow particles, e.g. hollow spheres, microspheres or cenospheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3071—Washing or leaching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
KR1020197017197A 2016-12-20 2017-12-20 Mww형 골격을 갖는 티타늄-함유 제올라이트 재료를 포함하는 조성물의 소성도를 감소시키기 위한 산 처리의 용도 Active KR102555075B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16205266.6 2016-12-20
EP16205266 2016-12-20
PCT/EP2017/083810 WO2018115118A1 (en) 2016-12-20 2017-12-20 Use of an acid treatment to decrease the plasticity of a composition comprising a titanium-containing zeolitic material having framework type mww

Publications (2)

Publication Number Publication Date
KR20190089913A KR20190089913A (ko) 2019-07-31
KR102555075B1 true KR102555075B1 (ko) 2023-07-12

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KR1020197017197A Active KR102555075B1 (ko) 2016-12-20 2017-12-20 Mww형 골격을 갖는 티타늄-함유 제올라이트 재료를 포함하는 조성물의 소성도를 감소시키기 위한 산 처리의 용도

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Country Link
US (1) US11351525B2 (cg-RX-API-DMAC7.html)
EP (1) EP3558517A1 (cg-RX-API-DMAC7.html)
JP (1) JP7296880B2 (cg-RX-API-DMAC7.html)
KR (1) KR102555075B1 (cg-RX-API-DMAC7.html)
CN (2) CN110087768B (cg-RX-API-DMAC7.html)
BR (1) BR112019011059B1 (cg-RX-API-DMAC7.html)
MY (1) MY199977A (cg-RX-API-DMAC7.html)
RU (1) RU2761301C2 (cg-RX-API-DMAC7.html)
WO (1) WO2018115118A1 (cg-RX-API-DMAC7.html)
ZA (1) ZA201903192B (cg-RX-API-DMAC7.html)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2018016297A (es) 2016-06-29 2019-09-16 Basf Se Proceso para la preparacion de aldehidos alfa, beta insaturados mediante oxidacion de alcoholes en presencia de una fase liquida.
CN110582481A (zh) 2017-05-03 2019-12-17 巴斯夫欧洲公司 用沸石将氧化乙烯转化为单乙醇胺和乙二胺的方法
CN115477310B (zh) * 2021-06-16 2023-11-28 中国石油化工股份有限公司 P-Ti-MWW分子筛及其制备方法与应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0689170B2 (ja) * 1985-09-24 1994-11-09 日本化学工業株式会社 樹脂組成物
JP3706457B2 (ja) * 1997-02-28 2005-10-12 帝人化成株式会社 熱可塑性樹脂組成物
DE10320635A1 (de) 2003-05-08 2004-11-18 Basf Ag Verfahren zur Herstellung von Propylenoxid
US8124555B2 (en) * 2010-02-01 2012-02-28 Lyondell Chemical Technology L.P. Process for making titanium-MWW zeolite
EP3216520B1 (en) * 2012-02-07 2024-07-17 Basf Se Molding containing a zeolitic mww type material containing ti and zn and use thereof as a catalyst
MY169039A (en) * 2012-10-18 2019-02-07 Basf Se Post-treatment of deboronated mww zeolite
CN103934039A (zh) * 2013-01-23 2014-07-23 中国石油化工股份有限公司 提高分子筛催化剂强度的方法
CN110002463B (zh) * 2013-02-05 2022-10-11 巴斯夫欧洲公司 制备具有mww骨架结构的含钛沸石材料的方法
CN105848781B (zh) * 2013-10-23 2020-07-17 巴斯夫欧洲公司 疏水性沸石材料的模制品及其制备方法
CN104437616B (zh) * 2014-11-21 2017-10-10 武汉工程大学 层状含介孔钛硅分子筛催化剂及其制备方法和应用

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US11351525B2 (en) 2022-06-07
JP7296880B2 (ja) 2023-06-23
JP2020502304A (ja) 2020-01-23
BR112019011059B1 (pt) 2022-08-09
CN110087768B (zh) 2023-09-01
KR20190089913A (ko) 2019-07-31
CN117046513A (zh) 2023-11-14
RU2019122860A (ru) 2021-01-25
CN110087768A (zh) 2019-08-02
RU2761301C2 (ru) 2021-12-07
ZA201903192B (en) 2024-09-25
WO2018115118A1 (en) 2018-06-28
RU2019122860A3 (cg-RX-API-DMAC7.html) 2021-04-21
EP3558517A1 (en) 2019-10-30
US20190321811A1 (en) 2019-10-24
BR112019011059A2 (pt) 2019-10-08
MY199977A (en) 2023-12-01

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