CN1098281C - 烯烃聚合催化剂体系、其生产方法和用途 - Google Patents
烯烃聚合催化剂体系、其生产方法和用途 Download PDFInfo
- Publication number
- CN1098281C CN1098281C CN97192604A CN97192604A CN1098281C CN 1098281 C CN1098281 C CN 1098281C CN 97192604 A CN97192604 A CN 97192604A CN 97192604 A CN97192604 A CN 97192604A CN 1098281 C CN1098281 C CN 1098281C
- Authority
- CN
- China
- Prior art keywords
- compound
- catalyst system
- transition metal
- organic solvent
- metal compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI960363 | 1996-01-26 | ||
| FI960363A FI104825B (fi) | 1996-01-26 | 1996-01-26 | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1211995A CN1211995A (zh) | 1999-03-24 |
| CN1098281C true CN1098281C (zh) | 2003-01-08 |
Family
ID=8545089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97192604A Expired - Fee Related CN1098281C (zh) | 1996-01-26 | 1997-01-24 | 烯烃聚合催化剂体系、其生产方法和用途 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6225423B1 (cg-RX-API-DMAC7.html) |
| EP (1) | EP0876405B2 (cg-RX-API-DMAC7.html) |
| JP (1) | JP2000504045A (cg-RX-API-DMAC7.html) |
| CN (1) | CN1098281C (cg-RX-API-DMAC7.html) |
| AT (1) | ATE190631T1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU1547497A (cg-RX-API-DMAC7.html) |
| DE (1) | DE69701447T3 (cg-RX-API-DMAC7.html) |
| FI (1) | FI104825B (cg-RX-API-DMAC7.html) |
| WO (1) | WO1997027224A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6136742A (en) | 1996-09-24 | 2000-10-24 | Exxon Chemical Patents, Inc. | Metallocene catalyst systems |
| US6977283B1 (en) | 1998-04-07 | 2005-12-20 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| US6245868B1 (en) | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
| EP2275455A1 (en) * | 1998-10-27 | 2011-01-19 | Westlake Longview Corporation | Process for the polymerization of olefins; polyethylenes, and films and articles produced therefrom |
| WO2001025296A1 (en) | 1999-10-02 | 2001-04-12 | Borealis Technology Oy | Modified supported catalysts for the polymerization of olefins |
| US7041617B2 (en) * | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
| US6593267B2 (en) | 2000-12-18 | 2003-07-15 | Univation Technologies, Llc | Method for preparing a supported catalyst system and its use in a polymerization process |
| US6933258B2 (en) | 2000-12-19 | 2005-08-23 | Univation Technologies, L.L.C. | Catalyst composition and methods for its preparation and use in a polymerization process |
| JP2002338617A (ja) * | 2001-05-22 | 2002-11-27 | Sumitomo Chem Co Ltd | ビニル化合物重合用触媒成分、ビニル化合物重合用触媒、ビニル化合物重合体の製造方法および遷移金属化合物の使用方法 |
| GB0118010D0 (en) | 2001-07-24 | 2001-09-19 | Borealis Tech Oy | Catalysts |
| RU2307838C2 (ru) * | 2001-09-14 | 2007-10-10 | Бп Корпорейшн Норт Америка Инк. | Латентные металлоценовые каталитические системы для полимеризации олефинов |
| US6689852B2 (en) | 2002-01-15 | 2004-02-10 | Exxonmobil Research And Engineering Company | Modifiers for improved olefin polymerization with activated neutral aluminum compounds |
| TWI300782B (en) * | 2002-08-29 | 2008-09-11 | Ineos Europe Ltd | Supported polymerisation catalysts |
| US7365039B2 (en) | 2003-03-21 | 2008-04-29 | Dow Global Technologies Inc. | Morphology controlled olefin polymerization process |
| GB0319773D0 (en) * | 2003-08-22 | 2003-09-24 | Bp Chem Int Ltd | Supported polymerisation catalysts |
| KR20120039069A (ko) * | 2003-08-22 | 2012-04-24 | 이네오스 유럽 리미티드 | 지지 중합 촉매 |
| GB0402959D0 (en) * | 2004-02-11 | 2004-03-17 | Bp Chem Int Ltd | Supported polymerisation catalysts |
| US7294599B2 (en) * | 2004-06-25 | 2007-11-13 | Chevron Phillips Chemical Co. | Acidic activator-supports and catalysts for olefin polymerization |
| EP1731536A1 (en) * | 2005-06-09 | 2006-12-13 | Innovene Manufacturing France SAS | Supported polymerisation catalysts |
| JP5156197B2 (ja) * | 2006-04-20 | 2013-03-06 | 日本ポリプロ株式会社 | オレフィン重合体の製造方法 |
| US20070255022A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Fluorinated transition metal catalysts and formation thereof |
| CN101802019B (zh) | 2007-08-16 | 2014-01-08 | 尤尼威蒂恩技术有限责任公司 | 连续性添加剂及其在聚合工艺中的用途 |
| RU2527945C2 (ru) | 2009-01-08 | 2014-09-10 | Юнивейшн Текнолоджиз, Ллк | Добавка для процессов полимеризации полиолефинов |
| WO2010080871A1 (en) | 2009-01-08 | 2010-07-15 | Univation Technologies, Llc | Additive for gas phase polymerization processes |
| WO2011017092A1 (en) | 2009-07-28 | 2011-02-10 | Univation Technologies, Llc | Polymerization process using a supported constrained geometry catalyst |
| US8858525B2 (en) * | 2009-11-20 | 2014-10-14 | Cryovac, Inc. | Noise dampening film |
| WO2012087560A1 (en) | 2010-12-22 | 2012-06-28 | Univation Technologies, Llc | Additive for polyolefin polymerization processes |
| EP2610269A1 (en) | 2011-12-28 | 2013-07-03 | Saudi Basic Industries Corporation | Catalyst composition and method for preparing the same |
| JP2016539234A (ja) | 2013-12-09 | 2016-12-15 | ユニベーション・テクノロジーズ・エルエルシー | 重合プロセスへの重合添加剤の供給 |
| US12404353B2 (en) | 2020-03-25 | 2025-09-02 | Japan Polypropylene Corporation | Olefin polymerization catalyst, olefin polymerization catalyst production method, and olefin polymer production method using the olefin polymerization catalyst |
| KR102513518B1 (ko) | 2020-12-23 | 2023-03-22 | 디엘케미칼 주식회사 | 메탈로센 올레핀 중합 공정용 대전방지제를 이용한 올레핀 중합 방법 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0354893A2 (en) * | 1988-08-05 | 1990-02-14 | Fina Technology, Inc. | Process for producing large symmetrical polymer particles |
| US5416179A (en) * | 1994-03-16 | 1995-05-16 | Phillips Petroleum Company | Catalyst compositions and olefin polymerization |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2154242A (en) | 1984-02-03 | 1985-09-04 | Bp Chem Int Ltd | Continuous slurry process for producing olefin (co)polymers |
| US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| ES2157911T3 (es) | 1987-02-02 | 2001-09-01 | Fina Technology | Procedimiento para aumentar la eficacia de un catalizador prepolimerizado. |
| CA2090962A1 (en) | 1990-09-14 | 1992-03-15 | Howard W. Turner | Ionic catalyst for the production of poly-.alpha.-olefins of controlled tacticity |
| DE4120006A1 (de) | 1991-06-18 | 1992-12-24 | Basf Ag | Durch vorpolymerisation getraegerte katalysatorsysteme zur herstellung von polyalk-1-enen |
| DE4121368A1 (de) | 1991-06-28 | 1993-01-07 | Hoechst Ag | Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen |
| DE4139262A1 (de) | 1991-11-29 | 1993-06-03 | Basf Ag | Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen |
| EP0567952B1 (en) | 1992-04-29 | 1997-12-03 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| EP1110974B1 (en) | 1992-08-05 | 2007-11-28 | ExxonMobil Chemical Patents Inc. | Method for preparing a supported activator component |
| EP0586167B1 (en) | 1992-09-04 | 2000-07-12 | BP Chemicals Limited | Catalyst compositions and process for preparing Polyolefins |
| DE4242486A1 (de) | 1992-12-16 | 1994-06-23 | Basf Ag | Propylen-Homopolymere |
| US5347024A (en) | 1993-03-19 | 1994-09-13 | The Dow Chemical Company | Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation |
| ES2117279T3 (es) * | 1993-05-25 | 1998-08-01 | Exxon Chemical Patents Inc | Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso. |
| CA2166055C (en) | 1993-06-24 | 2006-10-17 | Jo Ann Marie Canich | Process for producing amorphous poly-.alpha.-olefins with a monocyclopentadienyl transition metal catalyst system |
| CN1131953A (zh) | 1993-08-06 | 1996-09-25 | 埃克森化学专利公司 | 聚合催化剂及其制备和用途 |
| US5466649A (en) | 1993-10-15 | 1995-11-14 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| DE4337232A1 (de) | 1993-10-30 | 1995-05-04 | Basf Ag | Racemische Metallocenkomplexe und Verfahren zu ihrer Herstellung |
| ES2140557T3 (es) | 1993-11-19 | 2000-03-01 | Exxon Chemical Patents Inc | Sistemas cataliticos de polimerizacion, su produccion y uso. |
| DE4344688A1 (de) | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| IT1273615B (it) † | 1995-05-05 | 1997-07-08 | Enichem Spa | Catalizzatore a migliorata attivita' per la (co)polimerizzazione dell'etilene |
-
1996
- 1996-01-26 FI FI960363A patent/FI104825B/fi not_active IP Right Cessation
-
1997
- 1997-01-24 JP JP9526578A patent/JP2000504045A/ja not_active Ceased
- 1997-01-24 AT AT97901637T patent/ATE190631T1/de not_active IP Right Cessation
- 1997-01-24 US US09/101,869 patent/US6225423B1/en not_active Expired - Lifetime
- 1997-01-24 WO PCT/FI1997/000034 patent/WO1997027224A1/en not_active Ceased
- 1997-01-24 AU AU15474/97A patent/AU1547497A/en not_active Abandoned
- 1997-01-24 DE DE69701447T patent/DE69701447T3/de not_active Expired - Lifetime
- 1997-01-24 CN CN97192604A patent/CN1098281C/zh not_active Expired - Fee Related
- 1997-01-24 EP EP97901637A patent/EP0876405B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0354893A2 (en) * | 1988-08-05 | 1990-02-14 | Fina Technology, Inc. | Process for producing large symmetrical polymer particles |
| US5416179A (en) * | 1994-03-16 | 1995-05-16 | Phillips Petroleum Company | Catalyst compositions and olefin polymerization |
Also Published As
| Publication number | Publication date |
|---|---|
| FI960363A0 (fi) | 1996-01-26 |
| CN1211995A (zh) | 1999-03-24 |
| ATE190631T1 (de) | 2000-04-15 |
| JP2000504045A (ja) | 2000-04-04 |
| FI960363L (fi) | 1997-07-27 |
| FI104825B (fi) | 2000-04-14 |
| AU1547497A (en) | 1997-08-20 |
| US6225423B1 (en) | 2001-05-01 |
| DE69701447D1 (de) | 2000-04-20 |
| EP0876405A1 (en) | 1998-11-11 |
| EP0876405B1 (en) | 2000-03-15 |
| DE69701447T2 (de) | 2000-09-14 |
| WO1997027224A1 (en) | 1997-07-31 |
| DE69701447T3 (de) | 2007-07-12 |
| EP0876405B2 (en) | 2007-01-03 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20030108 Termination date: 20160124 |
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| EXPY | Termination of patent right or utility model |