DE69701447T2 - Olefinpolymerisationskatalysatoren, dessen herstellung und verwendung - Google Patents
Olefinpolymerisationskatalysatoren, dessen herstellung und verwendungInfo
- Publication number
- DE69701447T2 DE69701447T2 DE69701447T DE69701447T DE69701447T2 DE 69701447 T2 DE69701447 T2 DE 69701447T2 DE 69701447 T DE69701447 T DE 69701447T DE 69701447 T DE69701447 T DE 69701447T DE 69701447 T2 DE69701447 T2 DE 69701447T2
- Authority
- DE
- Germany
- Prior art keywords
- transition metal
- reaction product
- organic solvent
- metal compound
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI960363 | 1996-01-26 | ||
FI960363A FI104825B (fi) | 1996-01-26 | 1996-01-26 | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
PCT/FI1997/000034 WO1997027224A1 (en) | 1996-01-26 | 1997-01-24 | Olefin polymerization catalyst system, producing and using it |
Publications (3)
Publication Number | Publication Date |
---|---|
DE69701447D1 DE69701447D1 (de) | 2000-04-20 |
DE69701447T2 true DE69701447T2 (de) | 2000-09-14 |
DE69701447T3 DE69701447T3 (de) | 2007-07-12 |
Family
ID=8545089
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69701447T Expired - Lifetime DE69701447T3 (de) | 1996-01-26 | 1997-01-24 | Olefinpolymerisationskatalysatoren, dessen herstellung und verwendung |
Country Status (9)
Country | Link |
---|---|
US (1) | US6225423B1 (de) |
EP (1) | EP0876405B2 (de) |
JP (1) | JP2000504045A (de) |
CN (1) | CN1098281C (de) |
AT (1) | ATE190631T1 (de) |
AU (1) | AU1547497A (de) |
DE (1) | DE69701447T3 (de) |
FI (1) | FI104825B (de) |
WO (1) | WO1997027224A1 (de) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6136742A (en) | 1996-09-24 | 2000-10-24 | Exxon Chemical Patents, Inc. | Metallocene catalyst systems |
US6977283B1 (en) | 1998-04-07 | 2005-12-20 | Exxonmobil Chemical Patents Inc. | Polymerization process |
US6245868B1 (en) | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
KR100610968B1 (ko) * | 1998-10-27 | 2006-08-10 | 이스트만 케미칼 캄파니 | 올레핀의 중합 방법, 신규한 폴리에틸렌, 및 이로부터제조된 필름 및 제품 |
EP1218423B1 (de) | 1999-10-02 | 2005-03-16 | Borealis Technology Oy | Geträgerter und modifizierter katalysator für die polymerisation von olefine |
US7041617B2 (en) | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
US6593267B2 (en) | 2000-12-18 | 2003-07-15 | Univation Technologies, Llc | Method for preparing a supported catalyst system and its use in a polymerization process |
US6933258B2 (en) | 2000-12-19 | 2005-08-23 | Univation Technologies, L.L.C. | Catalyst composition and methods for its preparation and use in a polymerization process |
JP2002338617A (ja) * | 2001-05-22 | 2002-11-27 | Sumitomo Chem Co Ltd | ビニル化合物重合用触媒成分、ビニル化合物重合用触媒、ビニル化合物重合体の製造方法および遷移金属化合物の使用方法 |
GB0118010D0 (en) | 2001-07-24 | 2001-09-19 | Borealis Tech Oy | Catalysts |
US6689852B2 (en) | 2002-01-15 | 2004-02-10 | Exxonmobil Research And Engineering Company | Modifiers for improved olefin polymerization with activated neutral aluminum compounds |
TWI300782B (en) * | 2002-08-29 | 2008-09-11 | Ineos Europe Ltd | Supported polymerisation catalysts |
EP1611169B1 (de) | 2003-03-21 | 2010-06-02 | Dow Global Technologies Inc. | Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie |
ES2391973T3 (es) * | 2003-08-22 | 2012-12-03 | Ineos Commercial Services Uk Limited | Catalizadores de polimerización soportados |
GB0319773D0 (en) * | 2003-08-22 | 2003-09-24 | Bp Chem Int Ltd | Supported polymerisation catalysts |
GB0402959D0 (en) * | 2004-02-11 | 2004-03-17 | Bp Chem Int Ltd | Supported polymerisation catalysts |
US7294599B2 (en) | 2004-06-25 | 2007-11-13 | Chevron Phillips Chemical Co. | Acidic activator-supports and catalysts for olefin polymerization |
EP1731536A1 (de) * | 2005-06-09 | 2006-12-13 | Innovene Manufacturing France SAS | Unterstützte Polymerisationskatalysatoren |
JP5156197B2 (ja) * | 2006-04-20 | 2013-03-06 | 日本ポリプロ株式会社 | オレフィン重合体の製造方法 |
US20070255022A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Fluorinated transition metal catalysts and formation thereof |
WO2009023111A1 (en) | 2007-08-16 | 2009-02-19 | Univation Technologies, Llc | Continuity additives and their use in polymerization processes |
JP5661645B2 (ja) | 2009-01-08 | 2015-01-28 | ユニベーション・テクノロジーズ・エルエルシー | ポリオレフィン重合プロセス用の添加剤 |
WO2010080871A1 (en) | 2009-01-08 | 2010-07-15 | Univation Technologies, Llc | Additive for gas phase polymerization processes |
RU2549541C2 (ru) | 2009-07-28 | 2015-04-27 | Юнивейшн Текнолоджиз, Ллк | Способ полимеризации с использованием нанесенного катализатора с затрудненной геометрией |
US8858525B2 (en) * | 2009-11-20 | 2014-10-14 | Cryovac, Inc. | Noise dampening film |
CN103347905B (zh) | 2010-12-22 | 2015-12-16 | 尤尼威蒂恩技术有限责任公司 | 用于聚烯烃聚合方法的添加剂 |
EP2610269A1 (de) | 2011-12-28 | 2013-07-03 | Saudi Basic Industries Corporation | Katalysatorzusammensetzung und Herstellungsverfahren dafür |
JP2016539234A (ja) | 2013-12-09 | 2016-12-15 | ユニベーション・テクノロジーズ・エルエルシー | 重合プロセスへの重合添加剤の供給 |
EP4105246A4 (de) | 2020-03-25 | 2023-09-06 | Japan Polypropylene Corporation | Katalysator für olefinpolymerisation, verfahren zur herstellung eines katalysators für olefinpolymerisation und verfahren zur herstellung eines olefinpolymers unter verwendung dieses katalysators für olefinpolymerisation |
KR102513518B1 (ko) | 2020-12-23 | 2023-03-22 | 디엘케미칼 주식회사 | 메탈로센 올레핀 중합 공정용 대전방지제를 이용한 올레핀 중합 방법 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2154242A (en) | 1984-02-03 | 1985-09-04 | Bp Chem Int Ltd | Continuous slurry process for producing olefin (co)polymers |
US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
DE3789500T2 (de) | 1987-02-02 | 1994-08-04 | Fina Technology | Verfahren zur Verbesserung der Effektivität eines vorpolymerisierten Katalysators. |
DE68919156T3 (de) * | 1988-08-05 | 2002-08-14 | Fina Technology | Verfahren zur Herstellung grosser symmetrischer Polymerteilchen. |
ATE134658T1 (de) | 1990-09-14 | 1996-03-15 | Exxon Chemical Patents Inc | Ionischer katalysator zur herstellung von polyalphaolefinen mit kontrollierter takticität |
DE4120006A1 (de) | 1991-06-18 | 1992-12-24 | Basf Ag | Durch vorpolymerisation getraegerte katalysatorsysteme zur herstellung von polyalk-1-enen |
DE4121368A1 (de) | 1991-06-28 | 1993-01-07 | Hoechst Ag | Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen |
DE4139262A1 (de) | 1991-11-29 | 1993-06-03 | Basf Ag | Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen |
EP0567952B1 (de) | 1992-04-29 | 1997-12-03 | Hoechst Aktiengesellschaft | Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung |
US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
DE69331112T2 (de) | 1992-08-05 | 2002-06-20 | Exxonmobil Chem Patents Inc | Ionische übergangsmetallkatalysatoreren auf träger für olefinpolymerisation |
DE69328996T2 (de) | 1992-09-04 | 2000-11-16 | Bp Chem Int Ltd | Katalysatorzusammensetzung und Verfahren zur Herstellung von Polyolefinen |
DE4242486A1 (de) | 1992-12-16 | 1994-06-23 | Basf Ag | Propylen-Homopolymere |
US5347024A (en) | 1993-03-19 | 1994-09-13 | The Dow Chemical Company | Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation |
RU2126017C1 (ru) * | 1993-05-25 | 1999-02-10 | Эксон Кемикэл Пейтентс Инк. | Металлоценовые каталитические системы на подложке для полимеризации олефинов, способ их получения, гомо- или сополимеры пропилена и способ их получения |
CA2166055C (en) | 1993-06-24 | 2006-10-17 | Jo Ann Marie Canich | Process for producing amorphous poly-.alpha.-olefins with a monocyclopentadienyl transition metal catalyst system |
EP0719287B1 (de) | 1993-08-06 | 1999-12-29 | Exxon Chemical Patents Inc. | Polymerisationskataylsatoren, ihre herstellung und verwendung |
US5466649A (en) | 1993-10-15 | 1995-11-14 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
DE4337232A1 (de) | 1993-10-30 | 1995-05-04 | Basf Ag | Racemische Metallocenkomplexe und Verfahren zu ihrer Herstellung |
ES2140557T3 (es) | 1993-11-19 | 2000-03-01 | Exxon Chemical Patents Inc | Sistemas cataliticos de polimerizacion, su produccion y uso. |
DE4344688A1 (de) | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
US5416179A (en) * | 1994-03-16 | 1995-05-16 | Phillips Petroleum Company | Catalyst compositions and olefin polymerization |
IT1273615B (it) † | 1995-05-05 | 1997-07-08 | Enichem Spa | Catalizzatore a migliorata attivita' per la (co)polimerizzazione dell'etilene |
-
1996
- 1996-01-26 FI FI960363A patent/FI104825B/fi not_active IP Right Cessation
-
1997
- 1997-01-24 JP JP9526578A patent/JP2000504045A/ja not_active Ceased
- 1997-01-24 AT AT97901637T patent/ATE190631T1/de not_active IP Right Cessation
- 1997-01-24 CN CN97192604A patent/CN1098281C/zh not_active Expired - Fee Related
- 1997-01-24 US US09/101,869 patent/US6225423B1/en not_active Expired - Lifetime
- 1997-01-24 AU AU15474/97A patent/AU1547497A/en not_active Abandoned
- 1997-01-24 EP EP97901637A patent/EP0876405B2/de not_active Expired - Lifetime
- 1997-01-24 WO PCT/FI1997/000034 patent/WO1997027224A1/en active IP Right Grant
- 1997-01-24 DE DE69701447T patent/DE69701447T3/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69701447D1 (de) | 2000-04-20 |
US6225423B1 (en) | 2001-05-01 |
ATE190631T1 (de) | 2000-04-15 |
EP0876405B1 (de) | 2000-03-15 |
FI960363A (fi) | 1997-07-27 |
EP0876405B2 (de) | 2007-01-03 |
CN1211995A (zh) | 1999-03-24 |
DE69701447T3 (de) | 2007-07-12 |
JP2000504045A (ja) | 2000-04-04 |
FI960363A0 (fi) | 1996-01-26 |
AU1547497A (en) | 1997-08-20 |
CN1098281C (zh) | 2003-01-08 |
FI104825B (fi) | 2000-04-14 |
EP0876405A1 (de) | 1998-11-11 |
WO1997027224A1 (en) | 1997-07-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8366 | Restricted maintained after opposition proceedings |