CN1090532C - 催化剂、其制备方法和在合成甲硫醇中的应用 - Google Patents
催化剂、其制备方法和在合成甲硫醇中的应用 Download PDFInfo
- Publication number
- CN1090532C CN1090532C CN97119568A CN97119568A CN1090532C CN 1090532 C CN1090532 C CN 1090532C CN 97119568 A CN97119568 A CN 97119568A CN 97119568 A CN97119568 A CN 97119568A CN 1090532 C CN1090532 C CN 1090532C
- Authority
- CN
- China
- Prior art keywords
- wolframic acid
- catalyst
- aluminum oxide
- catalyzer
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000003054 catalyst Substances 0.000 title claims abstract description 25
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 9
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 51
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 31
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 18
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 14
- 229910052792 caesium Inorganic materials 0.000 claims abstract 3
- 239000002253 acid Substances 0.000 claims description 42
- 238000000034 method Methods 0.000 claims description 14
- 238000007598 dipping method Methods 0.000 claims description 11
- 238000000465 moulding Methods 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- -1 alkali metal salt Chemical class 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- AAQNGTNRWPXMPB-UHFFFAOYSA-N dipotassium;dioxido(dioxo)tungsten Chemical compound [K+].[K+].[O-][W]([O-])(=O)=O AAQNGTNRWPXMPB-UHFFFAOYSA-N 0.000 abstract description 4
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 abstract description 3
- 239000012190 activator Substances 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 15
- 239000001103 potassium chloride Substances 0.000 description 15
- 235000011164 potassium chloride Nutrition 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000002245 particle Substances 0.000 description 10
- 239000011148 porous material Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000008187 granular material Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- 238000005554 pickling Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 2
- 238000006424 Flood reaction Methods 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical compound CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
- C07C319/08—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by replacement of hydroxy groups or etherified or esterified hydroxy groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19639584A DE19639584A1 (de) | 1996-09-26 | 1996-09-26 | Katalysator, Verfahren zu seiner Herstellung und Verwendung zur Synthese von Methylmercaptan |
| DE19639584.4 | 1996-09-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1178137A CN1178137A (zh) | 1998-04-08 |
| CN1090532C true CN1090532C (zh) | 2002-09-11 |
Family
ID=7806976
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97119568A Expired - Lifetime CN1090532C (zh) | 1996-09-26 | 1997-09-25 | 催化剂、其制备方法和在合成甲硫醇中的应用 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5852219A (OSRAM) |
| EP (1) | EP0832687B1 (OSRAM) |
| JP (1) | JP3976852B2 (OSRAM) |
| CN (1) | CN1090532C (OSRAM) |
| BR (1) | BR9704898A (OSRAM) |
| DE (2) | DE19639584A1 (OSRAM) |
| ES (1) | ES2166029T3 (OSRAM) |
| RU (1) | RU2191069C2 (OSRAM) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1072522C (zh) * | 1998-09-10 | 2001-10-10 | 厦门大学 | 一种由含硫化氢的合成气合成甲硫醇的催化剂 |
| CN1072523C (zh) * | 1998-09-10 | 2001-10-10 | 厦门大学 | 一种含高硫化氢浓度的合成气制甲硫醇的催化剂 |
| GB2368672A (en) * | 2000-04-19 | 2002-05-08 | Ford Global Tech Inc | Online invention disclosure system |
| DE60127192T2 (de) * | 2000-06-27 | 2007-11-22 | Saudi Basic Industries Corp. | Katalysatoren für die Herstellung von Olefinen durch oxidative Dehydrierung |
| JP3757267B2 (ja) * | 2001-07-23 | 2006-03-22 | 独立行政法人産業技術総合研究所 | 多元系固体触媒の迅速探索方法 |
| JP3572548B2 (ja) | 2002-05-24 | 2004-10-06 | 日本酸素株式会社 | ガス精製方法及び装置 |
| DE10319739A1 (de) * | 2003-04-30 | 2004-11-18 | Basf Ag | Katalysator zur Herstellung von Methylmercaptan aus Methanol und Schwefelwasserstoff |
| DE10338887A1 (de) * | 2003-08-23 | 2005-03-17 | Degussa Ag | Katalysator zur Synthese von Alkylmercaptan und Verfahren zu seiner Herstellung |
| CN100345629C (zh) * | 2003-10-10 | 2007-10-31 | 德古萨股份公司 | 一种由含高浓度硫化氢的合成气合成甲硫醇的催化剂 |
| DE102004037739A1 (de) * | 2004-08-04 | 2006-03-16 | Degussa Ag | Wolframat enthaltende Katalysatoren zur Synthese von Alkylmercaptan und Verfahren zu ihrer Herstellung |
| DE102004061016A1 (de) * | 2004-12-18 | 2006-06-22 | Degussa Ag | Halogenidhaltige Alkaliwolframate enthaltende Katalysatoren zur Synthese von Alkylmercaptan und Verfahren zu ihrer Herstellung |
| DE102005016369A1 (de) | 2005-04-09 | 2006-10-12 | Degussa Ag | Verfahren zur kontinuierlichen Herstellung von Methylmercaptan |
| DE102006032635A1 (de) | 2006-07-13 | 2008-01-17 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Alkylmercaptanen in einem Mehrzonenfestbettreaktor |
| TWI446964B (zh) | 2007-05-09 | 2014-08-01 | Shell Int Research | 環氧化催化劑，製備該催化劑之方法及製備烯烴氧化物、１，２-二醇、１，２-二醇醚、１，２-碳酸酯或烷醇胺之方法 |
| DE102007024576A1 (de) | 2007-05-25 | 2009-05-20 | Evonik Degussa Gmbh | Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoff- und wasserstoffhaltigen Verbindungen |
| CN102264637B (zh) | 2008-12-23 | 2013-11-13 | 巴斯夫欧洲公司 | 压缩含硫化氢的气体的方法 |
| DE102009027837A1 (de) | 2009-07-20 | 2011-01-27 | Evonik Degussa Gmbh | Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoffhaltigen Verbindungen, Schwefel und Wasserstoff |
| KR101068112B1 (ko) * | 2010-02-22 | 2011-09-27 | 한국에너지기술연구원 | 텅스텐 옥사이드 알루미나 촉매의 제조 방법, 텅스텐 옥사이드 알루미나 촉매 및 이 촉매를 이용한 유리지방산이 포함되어 있는 폐식용유로부터 유리지방산을 제거하는 방법 |
| EP3187261A1 (de) * | 2015-12-30 | 2017-07-05 | Evonik Degussa GmbH | Verfahren zur herstellung eines ein alkalimetall und eines übergangsmetall in oxidierter form enthaltenden katalysators |
| EP3464239B1 (en) | 2016-05-31 | 2021-03-31 | Novus International Inc. | Process for producing methyl mercaptan from dimethyl sulfide |
| EP3689451A1 (en) | 2019-01-29 | 2020-08-05 | Evonik Operations GmbH | Catalyst for the synthesis of alkyl mercaptan and process for its preparation |
| CN114478334B (zh) * | 2022-02-25 | 2023-11-10 | 新疆广汇陆友硫化工有限公司 | 一种甲硫醇硫化法生产二甲基二硫的方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3935276A (en) * | 1973-11-30 | 1976-01-27 | Rhone-Poulenc Industries | Process for the manufacture of methyl mercaptan |
| JPS58159456A (ja) * | 1982-03-17 | 1983-09-21 | Seitetsu Kagaku Co Ltd | メチルメルカプタンの製造方法 |
| JPS6084239A (ja) * | 1983-10-14 | 1985-05-13 | Agency Of Ind Science & Technol | アセトアルデヒドの製造法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2820062A (en) * | 1954-08-11 | 1958-01-14 | Pure Oil Co | Preparation of organic thiols |
| US5057481A (en) * | 1987-02-20 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US4908343A (en) * | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US5283369A (en) * | 1992-03-24 | 1994-02-01 | Elf Atochem North America, Inc. | Selective synthesis of mercaptans and catalyst therefor |
| RU2056940C1 (ru) * | 1992-03-26 | 1996-03-27 | Специальное конструкторско-технологическое бюро катализаторов с опытным заводом | Способ получения катализатора для синтеза метилмеркаптана и диметилсульфида |
-
1996
- 1996-09-26 DE DE19639584A patent/DE19639584A1/de not_active Withdrawn
-
1997
- 1997-06-30 US US08/885,045 patent/US5852219A/en not_active Expired - Lifetime
- 1997-07-10 DE DE59705162T patent/DE59705162D1/de not_active Expired - Lifetime
- 1997-07-10 ES ES97111737T patent/ES2166029T3/es not_active Expired - Lifetime
- 1997-07-10 EP EP97111737A patent/EP0832687B1/de not_active Expired - Lifetime
- 1997-09-24 JP JP25840497A patent/JP3976852B2/ja not_active Expired - Lifetime
- 1997-09-25 CN CN97119568A patent/CN1090532C/zh not_active Expired - Lifetime
- 1997-09-26 RU RU97116038/04A patent/RU2191069C2/ru not_active IP Right Cessation
- 1997-09-26 BR BR9704898A patent/BR9704898A/pt not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3935276A (en) * | 1973-11-30 | 1976-01-27 | Rhone-Poulenc Industries | Process for the manufacture of methyl mercaptan |
| JPS58159456A (ja) * | 1982-03-17 | 1983-09-21 | Seitetsu Kagaku Co Ltd | メチルメルカプタンの製造方法 |
| JPS6084239A (ja) * | 1983-10-14 | 1985-05-13 | Agency Of Ind Science & Technol | アセトアルデヒドの製造法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE19639584A1 (de) | 1998-04-23 |
| US5852219A (en) | 1998-12-22 |
| MX9707253A (es) | 1998-03-31 |
| EP0832687B1 (de) | 2001-10-31 |
| EP0832687A2 (de) | 1998-04-01 |
| CN1178137A (zh) | 1998-04-08 |
| EP0832687A3 (de) | 1998-07-01 |
| RU2191069C2 (ru) | 2002-10-20 |
| ES2166029T3 (es) | 2002-04-01 |
| JPH10109031A (ja) | 1998-04-28 |
| DE59705162D1 (de) | 2001-12-06 |
| JP3976852B2 (ja) | 2007-09-19 |
| BR9704898A (pt) | 1998-10-27 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: EVONIK DEGUSSA CO., LTD. Free format text: FORMER NAME: DEGUSSA CO., LTD. Owner name: DEGUSSA CO., LTD. Free format text: FORMER NAME: DIGUSSA CO., LTD. |
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| CP03 | Change of name, title or address |
Address after: essen Patentee after: EVONIK DEGUSSA GmbH Address before: Dusseldorf, Federal Republic of Germany Patentee before: DEGUSSA GmbH Address after: Dusseldorf, Federal Republic of Germany Patentee after: DEGUSSA GmbH Address before: Frankfurt, Federal Republic of Germany Patentee before: Degussa AG |
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| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20020911 |