CN108383935A - 通过供给用选择的液体试剂饱和的负载催化剂得到的提高的聚合物熔体流动比率 - Google Patents
通过供给用选择的液体试剂饱和的负载催化剂得到的提高的聚合物熔体流动比率 Download PDFInfo
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- CN108383935A CN108383935A CN201810198034.4A CN201810198034A CN108383935A CN 108383935 A CN108383935 A CN 108383935A CN 201810198034 A CN201810198034 A CN 201810198034A CN 108383935 A CN108383935 A CN 108383935A
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- bis
- propyl
- catalyst
- alpha
- hafnium
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- 150000003440 styrenes Chemical class 0.000 description 1
- 125000005415 substituted alkoxy group Chemical group 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- RAJLLOJIESZCNI-UHFFFAOYSA-N tert-butyl(cyclohexyl)silane Chemical compound C(C)(C)(C)[SiH2]C1CCCCC1 RAJLLOJIESZCNI-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261671525P | 2012-07-13 | 2012-07-13 | |
| US61/671,525 | 2012-07-13 | ||
| CN201380034923.2A CN104540859A (zh) | 2012-07-13 | 2013-06-14 | 通过供给用选择的液体试剂饱和的负载催化剂得到的提高的聚合物熔体流动比率 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380034923.2A Division CN104540859A (zh) | 2012-07-13 | 2013-06-14 | 通过供给用选择的液体试剂饱和的负载催化剂得到的提高的聚合物熔体流动比率 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108383935A true CN108383935A (zh) | 2018-08-10 |
Family
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810198034.4A Pending CN108383935A (zh) | 2012-07-13 | 2013-06-14 | 通过供给用选择的液体试剂饱和的负载催化剂得到的提高的聚合物熔体流动比率 |
| CN201380034923.2A Pending CN104540859A (zh) | 2012-07-13 | 2013-06-14 | 通过供给用选择的液体试剂饱和的负载催化剂得到的提高的聚合物熔体流动比率 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380034923.2A Pending CN104540859A (zh) | 2012-07-13 | 2013-06-14 | 通过供给用选择的液体试剂饱和的负载催化剂得到的提高的聚合物熔体流动比率 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9512254B2 (https=) |
| EP (1) | EP2872539B1 (https=) |
| CN (2) | CN108383935A (https=) |
| BR (1) | BR112014032661B1 (https=) |
| ES (1) | ES2842573T3 (https=) |
| IN (1) | IN2014DN10082A (https=) |
| RU (1) | RU2645216C2 (https=) |
| WO (1) | WO2014011357A1 (https=) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110964143A (zh) * | 2018-09-30 | 2020-04-07 | 中国石油天然气股份有限公司 | 饮料瓶盖用聚乙烯基础树脂及其制备方法 |
| CN113056489A (zh) * | 2018-11-01 | 2021-06-29 | 埃克森美孚化学专利公司 | 淤浆修整催化剂进料器修改 |
| CN114901391A (zh) * | 2019-11-26 | 2022-08-12 | 埃克森美孚化学专利公司 | 生产负载型催化剂的系统和方法 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3126404B1 (en) | 2014-04-02 | 2019-08-21 | Univation Technologies, LLC | Continuity compositions and olefin polymerisation method using the same |
| KR20170029625A (ko) | 2014-07-18 | 2017-03-15 | 알이지 라이프 사이언시스, 엘엘씨 | 지방 디올의 미생물 생산 |
| EP3283536B1 (en) * | 2015-04-17 | 2024-07-17 | Univation Technologies, LLC | Catalysts for control of long chain branching |
| KR102065715B1 (ko) * | 2016-12-05 | 2020-01-13 | 주식회사 엘지화학 | 혼성 담지 촉매 |
| CN110461882B (zh) * | 2017-02-03 | 2021-12-14 | 埃克森美孚化学专利公司 | 制备聚乙烯聚合物的方法 |
| CA3063704A1 (en) | 2017-05-17 | 2018-11-22 | Univation Technologies, Llc | A hafnium complex; a supported hafnium complex; methods of forming a polymer using such complexes |
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| CN1370621A (zh) * | 2001-02-13 | 2002-09-25 | 弗纳技术股份有限公司 | 茂金属催化剂的制备方法 |
| CN1529719A (zh) * | 2000-11-30 | 2004-09-15 | 尤尼威蒂恩技术有限责任公司 | 聚合方法 |
| CN1918191A (zh) * | 2003-12-18 | 2007-02-21 | 英尼奥斯欧洲有限公司 | 聚合方法 |
| CN1968980A (zh) * | 2004-06-21 | 2007-05-23 | 尤尼威蒂恩技术有限公司 | 可控制组成分布的制备聚合物的方法 |
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| US6468936B1 (en) * | 1993-04-28 | 2002-10-22 | Fina Technology, Inc. | Solid MAO/metallocene catalyst complex for propylene polymerization |
| ATE223929T1 (de) * | 1995-05-16 | 2002-09-15 | Univation Tech Llc | Herstellung von polyethylen unter verwendung eines stereoisomeren metallocens |
| JPH09309926A (ja) * | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
| US6245868B1 (en) * | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
| US20020137861A1 (en) * | 2000-12-04 | 2002-09-26 | Woo Min Song | Polymerization process |
| DE602004021787D1 (de) * | 2003-03-28 | 2009-08-13 | Union Carbide Chem Plastic | Katalysatoren basiert auf chrom in einem mineralöl und verfahren zur polymerisation von ethylen |
| ATE401123T1 (de) * | 2004-12-17 | 2008-08-15 | Borealis Tech Oy | Verfahren zur polymerisation von olefinen in gegenwart eines olefin polymerisationskatalysators |
| RU2587080C2 (ru) * | 2010-11-30 | 2016-06-10 | Юнивейшн Текнолоджиз, Ллк | Способы полимеризации олефинов с использованием экстрагированных карбоксилатов металлов |
| WO2013028283A1 (en) * | 2011-08-19 | 2013-02-28 | Univation Technologies, Llc | Catalyst systems and methods for using same to produce polyolefin products |
| CA2749835C (en) * | 2011-08-23 | 2018-08-21 | Nova Chemicals Corporation | Feeding highly active phosphinimine catalysts to a gas phase reactor |
-
2013
- 2013-06-14 BR BR112014032661-4A patent/BR112014032661B1/pt active IP Right Grant
- 2013-06-14 CN CN201810198034.4A patent/CN108383935A/zh active Pending
- 2013-06-14 WO PCT/US2013/045938 patent/WO2014011357A1/en not_active Ceased
- 2013-06-14 RU RU2015104738A patent/RU2645216C2/ru active
- 2013-06-14 EP EP13734881.9A patent/EP2872539B1/en active Active
- 2013-06-14 IN IN10082DEN2014 patent/IN2014DN10082A/en unknown
- 2013-06-14 US US14/406,369 patent/US9512254B2/en active Active
- 2013-06-14 CN CN201380034923.2A patent/CN104540859A/zh active Pending
- 2013-06-14 ES ES13734881T patent/ES2842573T3/es active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1529719A (zh) * | 2000-11-30 | 2004-09-15 | 尤尼威蒂恩技术有限责任公司 | 聚合方法 |
| CN1370621A (zh) * | 2001-02-13 | 2002-09-25 | 弗纳技术股份有限公司 | 茂金属催化剂的制备方法 |
| CN1918191A (zh) * | 2003-12-18 | 2007-02-21 | 英尼奥斯欧洲有限公司 | 聚合方法 |
| CN1968980A (zh) * | 2004-06-21 | 2007-05-23 | 尤尼威蒂恩技术有限公司 | 可控制组成分布的制备聚合物的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110964143A (zh) * | 2018-09-30 | 2020-04-07 | 中国石油天然气股份有限公司 | 饮料瓶盖用聚乙烯基础树脂及其制备方法 |
| CN113056489A (zh) * | 2018-11-01 | 2021-06-29 | 埃克森美孚化学专利公司 | 淤浆修整催化剂进料器修改 |
| CN113056489B (zh) * | 2018-11-01 | 2023-04-14 | 埃克森美孚化学专利公司 | 淤浆修整催化剂进料器修改 |
| CN114901391A (zh) * | 2019-11-26 | 2022-08-12 | 埃克森美孚化学专利公司 | 生产负载型催化剂的系统和方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112014032661B1 (pt) | 2021-11-23 |
| CN104540859A (zh) | 2015-04-22 |
| ES2842573T3 (es) | 2021-07-14 |
| US9512254B2 (en) | 2016-12-06 |
| EP2872539A1 (en) | 2015-05-20 |
| US20150133614A1 (en) | 2015-05-14 |
| RU2645216C2 (ru) | 2018-02-19 |
| EP2872539B1 (en) | 2020-12-09 |
| IN2014DN10082A (https=) | 2015-08-21 |
| WO2014011357A1 (en) | 2014-01-16 |
| BR112014032661A2 (pt) | 2017-06-27 |
| RU2015104738A (ru) | 2016-08-27 |
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