RU2645216C2 - Увеличенное отношение индексов расплава для полимера путем загрузки катализатора на подложке, насыщенного выбранным жидким агентом - Google Patents
Увеличенное отношение индексов расплава для полимера путем загрузки катализатора на подложке, насыщенного выбранным жидким агентом Download PDFInfo
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- RU2645216C2 RU2645216C2 RU2015104738A RU2015104738A RU2645216C2 RU 2645216 C2 RU2645216 C2 RU 2645216C2 RU 2015104738 A RU2015104738 A RU 2015104738A RU 2015104738 A RU2015104738 A RU 2015104738A RU 2645216 C2 RU2645216 C2 RU 2645216C2
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- Prior art keywords
- reactor
- ethylene
- alpha
- substrate
- hafnocene
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| US201261671525P | 2012-07-13 | 2012-07-13 | |
| US61/671,525 | 2012-07-13 | ||
| PCT/US2013/045938 WO2014011357A1 (en) | 2012-07-13 | 2013-06-14 | Increased polymer melt flow ratio via feed of a supported catalyst saturated with a selected liquid agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015104738A RU2015104738A (ru) | 2016-08-27 |
| RU2645216C2 true RU2645216C2 (ru) | 2018-02-19 |
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| RU2015104738A RU2645216C2 (ru) | 2012-07-13 | 2013-06-14 | Увеличенное отношение индексов расплава для полимера путем загрузки катализатора на подложке, насыщенного выбранным жидким агентом |
Country Status (8)
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| US (1) | US9512254B2 (https=) |
| EP (1) | EP2872539B1 (https=) |
| CN (2) | CN108383935A (https=) |
| BR (1) | BR112014032661B1 (https=) |
| ES (1) | ES2842573T3 (https=) |
| IN (1) | IN2014DN10082A (https=) |
| RU (1) | RU2645216C2 (https=) |
| WO (1) | WO2014011357A1 (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3126404B1 (en) | 2014-04-02 | 2019-08-21 | Univation Technologies, LLC | Continuity compositions and olefin polymerisation method using the same |
| KR20170029625A (ko) | 2014-07-18 | 2017-03-15 | 알이지 라이프 사이언시스, 엘엘씨 | 지방 디올의 미생물 생산 |
| EP3283536B1 (en) * | 2015-04-17 | 2024-07-17 | Univation Technologies, LLC | Catalysts for control of long chain branching |
| KR102065715B1 (ko) * | 2016-12-05 | 2020-01-13 | 주식회사 엘지화학 | 혼성 담지 촉매 |
| CN110461882B (zh) * | 2017-02-03 | 2021-12-14 | 埃克森美孚化学专利公司 | 制备聚乙烯聚合物的方法 |
| CA3063704A1 (en) | 2017-05-17 | 2018-11-22 | Univation Technologies, Llc | A hafnium complex; a supported hafnium complex; methods of forming a polymer using such complexes |
| CN110964143A (zh) * | 2018-09-30 | 2020-04-07 | 中国石油天然气股份有限公司 | 饮料瓶盖用聚乙烯基础树脂及其制备方法 |
| US20220056168A1 (en) * | 2018-11-01 | 2022-02-24 | Exxonmobil Chemical Patents Inc. | Slurry Trim Feeder Modifications |
| WO2021108049A1 (en) * | 2019-11-26 | 2021-06-03 | Exxonmobil Chemical Patents Inc. | Systems and methods for producing a supported catalyst |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5852143A (en) * | 1995-05-16 | 1998-12-22 | Union Carbide Chemicals & Plastics Technology Corporation | Production of polyethylene using stereoisomeric metallocenes |
| RU2179558C2 (ru) * | 1996-05-17 | 2002-02-20 | Дзе Дау Кемикал Компани | Способ получения сополимеров и содержащих их смесевых композиций |
| EP1234837A1 (en) * | 2001-02-13 | 2002-08-28 | Fina Technology, Inc. | Method for the preparation of metallocene catalysts |
| WO2012074709A1 (en) * | 2010-11-30 | 2012-06-07 | Univation Technologies, Llc | Processes for the polymerization of olefins with extracted metal carboxylate salts |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6468936B1 (en) * | 1993-04-28 | 2002-10-22 | Fina Technology, Inc. | Solid MAO/metallocene catalyst complex for propylene polymerization |
| US6245868B1 (en) * | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
| US6720396B2 (en) * | 2000-11-30 | 2004-04-13 | Univation Technologies, Llc | Polymerization process |
| US20020137861A1 (en) * | 2000-12-04 | 2002-09-26 | Woo Min Song | Polymerization process |
| DE602004021787D1 (de) * | 2003-03-28 | 2009-08-13 | Union Carbide Chem Plastic | Katalysatoren basiert auf chrom in einem mineralöl und verfahren zur polymerisation von ethylen |
| GB0329348D0 (en) * | 2003-12-18 | 2004-01-21 | Bp Chem Int Ltd | Polymerisation process |
| US7157531B2 (en) * | 2004-06-21 | 2007-01-02 | Univation Technologies, Llc | Methods for producing polymers with control over composition distribution |
| ATE401123T1 (de) * | 2004-12-17 | 2008-08-15 | Borealis Tech Oy | Verfahren zur polymerisation von olefinen in gegenwart eines olefin polymerisationskatalysators |
| WO2013028283A1 (en) * | 2011-08-19 | 2013-02-28 | Univation Technologies, Llc | Catalyst systems and methods for using same to produce polyolefin products |
| CA2749835C (en) * | 2011-08-23 | 2018-08-21 | Nova Chemicals Corporation | Feeding highly active phosphinimine catalysts to a gas phase reactor |
-
2013
- 2013-06-14 BR BR112014032661-4A patent/BR112014032661B1/pt active IP Right Grant
- 2013-06-14 CN CN201810198034.4A patent/CN108383935A/zh active Pending
- 2013-06-14 WO PCT/US2013/045938 patent/WO2014011357A1/en not_active Ceased
- 2013-06-14 RU RU2015104738A patent/RU2645216C2/ru active
- 2013-06-14 EP EP13734881.9A patent/EP2872539B1/en active Active
- 2013-06-14 IN IN10082DEN2014 patent/IN2014DN10082A/en unknown
- 2013-06-14 US US14/406,369 patent/US9512254B2/en active Active
- 2013-06-14 CN CN201380034923.2A patent/CN104540859A/zh active Pending
- 2013-06-14 ES ES13734881T patent/ES2842573T3/es active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5852143A (en) * | 1995-05-16 | 1998-12-22 | Union Carbide Chemicals & Plastics Technology Corporation | Production of polyethylene using stereoisomeric metallocenes |
| RU2179558C2 (ru) * | 1996-05-17 | 2002-02-20 | Дзе Дау Кемикал Компани | Способ получения сополимеров и содержащих их смесевых композиций |
| EP1234837A1 (en) * | 2001-02-13 | 2002-08-28 | Fina Technology, Inc. | Method for the preparation of metallocene catalysts |
| WO2012074709A1 (en) * | 2010-11-30 | 2012-06-07 | Univation Technologies, Llc | Processes for the polymerization of olefins with extracted metal carboxylate salts |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112014032661B1 (pt) | 2021-11-23 |
| CN104540859A (zh) | 2015-04-22 |
| ES2842573T3 (es) | 2021-07-14 |
| US9512254B2 (en) | 2016-12-06 |
| EP2872539A1 (en) | 2015-05-20 |
| US20150133614A1 (en) | 2015-05-14 |
| CN108383935A (zh) | 2018-08-10 |
| EP2872539B1 (en) | 2020-12-09 |
| IN2014DN10082A (https=) | 2015-08-21 |
| WO2014011357A1 (en) | 2014-01-16 |
| BR112014032661A2 (pt) | 2017-06-27 |
| RU2015104738A (ru) | 2016-08-27 |
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