CN107794514A - 复合材料耐火涂层及其应用 - Google Patents
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Abstract
本发明题为“复合材料耐火涂层及其应用”。在一个方面,本发明描述了包括耐磨涂层的制品,所述耐磨涂层采用一个或多个复合材料耐火层。例如,本文所述的带涂层的制品包括基底和通过CVD沉积的涂层,所述涂层粘附到所述基底,所述涂层包括多相耐火层,所述多相耐火层包括氧化铝相和氧化锆相,其中所述氧化锆相具有(200)生长方向的大于4的织构系数TC(200)。
Description
技术领域
本发明涉及耐火涂层,并且具体地讲,涉及通过化学气相沉积法(CVD)沉积以用于切削工具和/或磨损应用的复合材料耐火涂层。
背景技术
包括烧结碳化物切削工具在内的切削工具已用于带涂层的和不带涂层的条件两者中以便加工各种金属和合金。为了提高切削工具耐磨性、性能和寿命,已将一个或多个耐火材料层施加于切削工具表面。已通过CVD并通过物理气相沉积法(PVD)将例如TiC、TiCN、TiN和/或Al2O3施加于烧结碳化物基底。虽然在多种应用中能有效抑制磨损并延长工具寿命,但基于上述耐火材料的单层或多层构造的耐火涂层已日益达到其性能极限,从而要求开发用于切削工具的新涂层结构。
发明内容
在一个方面,本发明描述了包括耐磨涂层的制品,所述耐磨涂层采用一个或多个复合材料耐火层。简而言之,本文所述的带涂层的制品包括基底和通过CVD沉积的涂层,所述涂层粘附到所述基底,所述涂层包括多相耐火层,所述多相耐火层包括氧化铝相和氧化锆相,其中氧化锆相具有(200)生长方向的大于4的织构系数TC(200),所述织构系数(TC)被定义为:
其中
I(hkl)=(hkl)反射的测得强度
Io(hkl)=根据国际衍射数据中心(ICDD)卡号00-037-1484的(hkl)反射的标准强度
n=TC计算中使用的反射数目
TC计算中使用的(hkl)反射为(-111)、(111)、(200)、(-112)、(220)和(-221)。
在一些实施方案中,氧化铝相掺杂有锆。此外,在一些实施方案中,多相耐火层中铝与锆的比率为1.5至3。
这些和其他实施方案在下文的具体实施方式中进一步描述。
附图说明
图1示出了根据本文所述的一些实施方案的带涂层的切削刀片的基底。
图2为根据一个实施方案的示出了氧化锆相的多相耐火层的XRD,该XRD。
图3比较了本文所述的一个实施方案的复合材料涂层的锆掺杂氧化铝的XRD和标准氧化铝的XRD。
图4为根据本文所述的一个实施方案的多相耐火层的横截面扫描电子显微镜(SEM)图像。
图5为根据本文所述的一个实施方案的多相耐火层的横截面SEM图像。
图6为多相耐火层的横截面SEM图像。
具体实施方式
参考以下具体实施方式和示例以及前述和下述内容可更容易地理解本文所述的实施方案。然而,本文所述的元素、设备和方法并不限于具体实施方式和示例中所述的具体实施方案。应当认识到,这些实施方案仅示例性地说明本发明的原理。在不脱离本发明实质和范围的情况下,多种修改和变更对于本领域技术人员而言将是显而易见的。
在一个方面,本发明描述了制品,所述制品包括耐火涂层,所述耐火涂层采用复合材料结构。在一些实施方案中,具有此类耐火涂层的制品适用于高磨损和/或磨耗应用中,诸如金属切削操作。现在转到具体的组成部分,带涂层的制品包括基底。带涂层的制品可包括不违背本发明目的的任何基底。例如,基底可为切削工具或用于磨损应用中的工具。切削工具包括但不限于可转位切削刀片、端铣刀或钻孔器。可转位切削刀片可具有用于铣削或车削应用的任何所需ANSI标准几何形状。本文所述的带涂层的制品的基底可由烧结碳化物、碳化物、陶瓷、金属陶瓷、钢或其他合金形成。在一些实施方案中,烧结碳化物基底包含碳化钨(WC)。WC可以至少约80重量%的量或以至少约85重量%的量存在于切削工具基底中。另外,烧结碳化物的金属粘结剂可包含钴或钴合金。钴例如可以1重量%至15重量%范围内的量存在于烧结碳化物基底中。在一些实施方案中,钴以5重量%-12重量%或6重量%-10重量%范围内的量存在于烧结碳化物基底中。此外,烧结碳化物基底可表现出始于基底表面并从基底表面向内延伸的粘结剂富集区。
烧结碳化物基底还可包含一种或多种添加剂,诸如例如下列元素和/或其化合物中的一种或多种:钛、铌、钒、钽、铬、锆和/或铪。在一些实施方案中,钛、铌、钒、钽、铬、锆和/或铪与基底的WC形成固溶体碳化物。在此类实施方案中,基底可以0.1重量%-5重量%范围内的量包含一种或多种固溶体碳化物。另外,烧结碳化物基底可包含氮。
切削工具基底可包括在基底的前刀面与一个或多个后刀面的接合点处形成的一个或多个切削刃。图1示出了根据本文所述的一个实施方案的切削刀片基底。如图1所示,基底(10)具有在基底前刀面(14)与后刀面(16)的接合点处形成的切削刃(12)。基底(10)还包括用于将基底(10)固定到刀架上的孔(18)。
如本文所述,粘附到基底的CVD涂层包括多相耐火层,所述多相耐火层包括氧化铝相和氧化锆相,其中氧化锆相具有大于4的TC(200),织构系数被定义为
其中
I(hkl)=(hkl)反射的测量强度
Io(hkl)=根据国际衍射数据中心(ICDD)卡号00-037-1484的(hkl)反射的标准强度
n=TC计算中使用的反射数目
TC计算中使用的(hkl)反射为(-111)、(111)、(200)、(-112)、(220)和(-221)。
在一些实施方案中,TC(200)具有选自表I的值。
表I–ZrO2相的TC(200)
≥4.5 |
≥5 |
≥5.5 |
4.1-6 |
在一些实施方案中,TC(-111)、TC(111)、TC(-112)、TC(220)和TC(-221)都同时小于1。图2为根据一个实施方案的示出了氧化锆相的多相耐火层的XRD。
用于计算TC(200)的XRD峰数据在布拉格聚焦衍射仪上测量。
入射光学器件包括:
在45KV和40MA下操作的长细焦点X射线管。
在自动模式下操作以确保在整个分析过程中辐照样品体积恒定的可变发散光学器件。
固定的防散射狭缝
接收光学器件包括:
在自动模式下操作以与自动发散狭缝匹配的可变防散射狭缝
在扫描模式下操作的多带固态检测器。
选择扫描参数(速度和计数时间)以确保在峰的半高宽(FWHM)和最强峰的约10,000个总计数下最少具有十个数据步。采集的数据首先从可变模式转换为可用于分析的固定模式。此转换使用以下公式完成:
其中a=发散角,L=样品上的辐照长度
使用峰查找软件分析校正强度,以确定所采集数据中所有峰的峰位。然后使用轮廓函数对峰进行精修,以精确地确定峰位和峰高。该峰数据用于多相耐火层的氧化锆织构系数分析和定量分析。由于CVD涂层结构的复杂性,不应用对峰强度的厚度校正。
氧化锆相可以不违背本发明目的的任何量存在于多相耐火层中。在一些实施方案中,氧化锆相以多相耐火层的5重量%-60重量%的量存在。在一些实施方案中,氧化锆相以选自表II的量存在。
表II–多相耐火层的ZrO2含量(重量%)
10-50 |
20-40 |
30-40 |
5-30 |
5-25 |
35-50 |
氧化锆相可主要表现出单斜晶体结构。在一些实施方案中,氧化锆相包括单斜晶相和正方晶相的混合物。例如,氧化锆相可为60%-99.9%的单斜晶,其余为正方晶。在其他实施方案中,氧化锆相中存在的正方晶相的量为1%-35%或5%-30%。
在一些实施方案中,氧化锆相分散在氧化铝相中。例如,氧化锆相可分散在整个氧化铝相中。在其他实施方案中,氧化锆相在氧化铝相中不均一分布,从而产生一个或多个氧化锆梯度。此外,氧化锆相的晶粒通常可表现出柱状形态。例如,在一些实施方案中,氧化锆晶粒具有大于1.3的纵横比,长轴垂直于或大体上垂直于基底。
此外,氧化锆相在沉积状态下可表现出低水平的残余拉伸应力。在一些实施方案中,氧化锆相在沉积状态下表现出100MPa-400MPa的残余拉伸应力。在其他实施方案中,沉积氧化锆相的拉伸应力在150MPa-300MPa的范围内。残余应力和剪切应力通过x射线衍射使用转动(Chi tilt)Sin2ψ方法,参考单斜氧化锆晶相的(002)反射来测定。在布拉格衍射仪上采集数据并如上文所述进行处理。
然后使用以下公式,校正吸收和透明度的峰数据:
吸收校正
透明度校正
其中
并且
其中:
t=层厚度
μ=线性吸收系数(cm-1)
θ=2θ/2(度)
(ω-θ)=ω偏斜角(度)
ψ=倾斜角(Psi应力)(度)
τ=信息深度(微米)
R=测角仪半径(mm)
使用以下公式校正洛伦兹偏振的峰数据:
偏振校正
2θmon=石墨单色器的衍射角
使用Ladell模型移除Kα2峰。使用Pearson轮廓形状函数精修峰位。
残余应力由通用方程计算:
其中
=在角度和倾斜度ψ处的晶格常数
do=无应变晶格常数
=旋转角度
ψ=样品倾斜度
σ1&σ2=样品表面的主要应力张量
=在旋转角度处的应力
S1&1/2S2=X射线弹性常数
对于目前的氧化锆分析,根据文献,将泊松比(υ)设为0.23,并将弹性模量(E以GPa为单位)确定为220。
氧化铝相可以不违背本发明目的的任何量存在于多相耐火层中。在一些实施方案中,氧化铝相是多相耐火层的主相。例如,氧化铝相可以多相耐火层的55-95重量%的量存在。或者,氧化铝相以少于氧化锆相的量存在。根据CVD条件,氧化铝相可为α-氧化铝、κ-氧化铝或其混合物(α/κ)。此外,氧化铝相可掺杂有锆(Zr)。在一些实施方案中,锆以氧化铝相的0.1-5重量%的量存在于氧化铝相中。锆还可以选自表III的量存在于氧化铝相中。
表III–Zr掺杂物(占氧化铝相的重量%)
0.5-30 |
1-15 |
2-10 |
5-20 |
氧化铝相中锆的存在不可避免地改变了氧化铝晶格。掺入锆对氧化铝晶格的改变通过XRD得到证实。图3比较了本文所述的一个实施方案的复合材料涂层的锆掺杂氧化铝的XRD和标准氧化铝的XRD。如图3所示,氧化铝(024)和(116)反射示出了由于锆引起的晶格畸变导致的显著增宽。
与氧化锆相类似,氧化铝相晶粒还可表现出柱状形态,长轴垂直于或大体上垂直于基底。此外,氧化铝相在沉积状态下可表现出低残余拉伸应力。在一些实施方案中,氧化铝相在沉积状态下具有200Mpa-600Mpa或250Mpa-500MPa的残余拉伸应力。氧化铝相的残余应力可使用转动Sin2ψ方法,参考(116)反射来测定。对于氧化铝相分析,根据对单相α-氧化铝涂层的纳米压痕硬度的分析,将泊松比(υ)设为0.19,并将弹性模量(E以GPa为单位)确定为415。
使用Rietveld法,对耐火层的氧化锆相和氧化铝相实施定量分析。使用布拉格衍射仪采集数据并如上文所述进行处理。确定采集模式中的所有相,并为每种相选择结构数据以进行Rietveld分析。为了保持Rietveld分析的一致性,使用相同的结构数据进行所有涂层分析。使用的结构数据取自ICDD PDF4 2015数据库。使用的结构数据来自以下卡号:
04-001-7278 氧化锆(正方)
04-004-4339 氧化锆(单斜)
04-006-0204 氧碳氮化钛
03-065-9875 碳氮化钛
04-006-9359 氧化铝(α)
04-012-6907 氧化铝(κ)
04-016-3697 碳化钨
在Rietveld精修中,校正以下项的采集数据的参数:
样品位移
零点漂移
使用Chebyshev分布进行轮廓描绘的背景
每种相的Rietveld精修参数为:
标度因子
晶格参数
Caglioti V
Caglioti W
使用球面调和函数校正模式中的任何取向。
为了确保Rietveld精修的正确性,需要对样品中的所有相进行精修。精修持续到至少达到0.9(90%)的拟合优度。一旦精修完成,除了复合材料层中的相以外的所有相都从精修中移除,并将复合材料层相标准化为100%。
多相耐火层可具有不违背本发明目的的任何厚度。在一些实施方案中,包含氧化铝相和氧化锆相的多相耐火层具有0.1μm-15μm的厚度。多相耐火层的厚度可选自表IV。
表IV–多相耐火层厚度(μm)
0.5-10 |
1-5 |
5-10 |
0.1-5 |
包含氧化铝相和氧化锆相的多相耐火层可直接沉积在基底表面上。另选地,本文所述的涂层还可包括多相耐火层与基底之间的一个或多个内层。在一些实施方案中,内层包含选自由铝和周期表的IVB族、VB族和VIB族的金属元素构成的组的一种或多种金属元素以及选自周期表的IIIA族、IVA族、VA族和VIA族的一种或多种非金属元素。在一些实施方案中,基底和多相耐火层之间的一个或多个内层包含选自铝及元素周期表的IVB族、VB族和VIB族的金属元素的一种或多种金属元素的碳化物、氮化物、碳氮化物、氧碳氮化物、氧化物或硼化物。
例如,一个或多个内层选自由氮化钛、碳氮化钛、氧碳氮化钛、碳化钛、氮化锆、碳氮化锆、氮化铪和碳氮化铪构成的组。另外,氧碳氮化钛的层可用作用于涂层的耐火层和内层的粘结层。涂层的内层可具有不违背本发明目的的任何厚度。在一些实施方案中,单个内层的厚度可为至少1.5μm。另选地,多个内层可共同实现至少1.5μm的厚度。
包含氧化铝相和氧化锆相的多相耐火层可为涂层的最外层。另选地,本文所述的涂层可包括在多相耐火层上的一个或多个外层。外层可包含选自由铝和周期表的IVB族、VB族和VIB族的金属元素构成的组的一种或多种金属元素以及选自周期表的IIIA族、IVA族、VA族和VIA族的一种或多种非金属元素。耐火层上的外层可包含选自由铝和周期表的IVB族、VB族和VIB族的金属元素构成的组的一种或多种金属元素的碳化物、氮化物、碳氮化物、氧碳氮化物、氧化物或硼化物。例如,一个或多个外层选自由氮化钛、碳氮化钛、氧碳氮化钛、碳化钛、氮化锆、碳氮化锆、氮化铪、碳氮化铪和氧化铝,以及它们的混合物构成的组。
本文所述涂层的外层可具有不违背本发明目的的任何厚度。在一些实施方案中,涂层外层的厚度可在0.2μm至5μm的范围内。
本文所述的涂层可经受涂布后处理。例如可将涂层用各种湿和/或干颗粒组合物喷射。涂布后喷射可以任何所需的方式实施。在一些实施方案中,涂布后喷射包括喷丸处理或压力喷射。压力喷射可以多种形式实施,包括压缩空气喷射、湿压缩空气喷射、加压液体喷射、湿喷射和蒸汽喷射。湿喷射例如使用无机和/或陶瓷颗粒(诸如氧化铝)和水的浆液实现。可将颗粒浆液以气动方式投射在带涂层的切削工具主体的表面以冲击涂层的表面。无机和/或陶瓷颗粒的尺寸通常可在约20μm与约100μm之间的范围内。
喷射参数包括压力、冲击角度、与部件表面的距离和持续时间。在一些实施方案中,冲击角度可在约10度至约90度的范围内,即,颗粒以约10度至约90度范围内的角度冲击涂层表面。在与带涂层的表面相距1-6英寸时,合适的压力可在30-55磅每平方英寸(psi)的范围内。此外,喷射的持续时间通常可在1秒至10秒或更长的范围内。喷射通常可在涂层的表面区域上实施,或可施加到精选的位置,诸如在切削工具的工件接触区中。工件接触区可以是切削工具的磨光区。
在其他实施方案中,涂层经受抛光涂布后处理。可用适当金刚石或陶瓷磨粒尺寸的糊剂实施抛光。在一些实施方案中,糊剂的磨粒尺寸在1μm至10μm的范围内。在一个实施方案中,使用5μm-10μm金刚石磨粒糊剂对涂层抛光。此外,可通过不违背本发明目的的任何设备诸如刷子,将磨粒糊剂施加到CVD涂层。在一个实施方案中,例如,使用扁平刷将磨粒糊剂施加到切削工具的工件接触区中的CVD涂层。
可将本文所述的涂层喷射或抛光足以实现所需的表面粗糙度(Ra)和/或其他参数(诸如降低涂层中的残余拉伸应力)的时间段。在一些实施方案中,经受涂布后处理的涂层的表面粗糙度(Ra)选自表V。
表V–涂布后表面粗糙度(Ra)
涂层表面粗糙度(Ra)-nm |
≤500 |
≤250 |
<200 |
10-250 |
50-175 |
25-150 |
可使用可从纽约普莱恩维尤的维易科仪器公司(Veeco Instruments,Inc.,Plainview,New York)商购获得的NT系列光学轮廓仪,通过光学轮廓术来测定涂层表面粗糙度。
此外,在一些实施方案中,涂布后处理不移除涂层的一个或多个外层。在一些实施方案中,例如,涂布后处理不移除TiN、TiCN和/或TiOCN的外层。另选地,涂布后处理可移除或部分地移除一个或多个外层,诸如TiN、TiCN和TiOCN。
如本文所述,多相耐火层通过CVD沉积。多相耐火层可由H2、N2、CO2、HCl、AlCl3、ZrCl4和H2S的气体混合物沉积。AlCl3和ZrCl4可在多相耐火层的引发和生长期间同时引入沉积室。在多相耐火层成核期间ZrCl4的存在与之前技术不同,其中首先将氧化铝层成核,随后在氧化铝层生长期间引入ZrCl4。本发明的CVD方法还与之前的技术不同,其中氧化铝层和氧化锆层以分层形式彼此独立地生长。在一些实施方案中,AlCl3和ZrCl4在350-400℃下在单独的金属屑和HCl发生器中形成。用于沉积多相耐火层的一般CVD处理参数提供于表VI中。
表VI–多相耐火层CVD处理参数
多相耐火层可直接沉积在基底表面上。另选地,一个或多个涂层内层可位于基底和多相耐火层之间。用于各内层的一般CVD沉积参数提供于表VII中。
表VII–用于内层沉积的CVD参数
在一些实施方案中,用于内层沉积的前述一般CVD参数可被应用于在耐火层上沉积一个或多个外层。
在以下非限制性实施例中对这些和其他实施方案进行进一步说明。
实施例1–带涂层的切削工具
通过将烧结碳化钨(WC-Co)切削刀片基底[ANSI标准几何形状CNMG432RN]放入轴流热壁CVD反应器中,来制备本文所述的带涂层的切削工具。切削刀片包含6重量%的钴粘结剂,余量为1μm至5μm尺寸的WC晶粒。根据表VIII和IX将本文所述的包含多相耐火层的涂层沉积在切削刀片上。该多相耐火层包含Zr掺杂的氧化铝相和氧化锆相。将TiN的外层沉积在纳米复合材料耐火层上以完成该涂层。另选地,如果需要,可将TiOCN的外层沉积在纳米复合材料耐火层上以完成该涂层。
表VIII–涂层的CVD沉积
*另选形式的外层
表IX–CVD沉积步骤
*另选形式的外层
所得的涂层表现出表X中所提供的特性。
表X–CVD涂层的特性
涂层 | 厚度(μm) |
TiN | 0.7 |
MT-TiCN | 8.4 |
HT-TiCN/TiOCN | 1.1 |
ZrAl2O3/ZrO2复合材料 | 10.6 |
TiN* | 1.6 |
*通过涂布后处理移除
随后通过上文所述的颗粒浆液涂布后处理移除表X中列出的TiN外层。带涂层的切削刀片表现出5.2的平均TC(200)。图4为从本发明示例的一个切削刀片获得的多相耐火层的横截面SEM。如SEM所示,多相耐火层包含分散在氧化铝(暗相)中的氧化锆(明相)。氧化锆相可包括在整个氧化铝基质中的大晶粒以及小微晶。
实施例2–带涂层的切削工具
通过将烧结碳化钨(WC-Co)切削刀片基底[ANSI标准几何形状CNMG432RN]放入轴流热壁CVD反应器中,来制备本文所述的带涂层的切削工具。切削刀片包含6重量%的钴粘结剂,余量为1μm至5μm尺寸的WC晶粒。根据表XI将本文所述的包含多相耐火层的涂层沉积在切削刀片上。该多相耐火层包含Zr掺杂的氧化铝相和氧化锆相。将TiN的外层沉积在纳米复合材料耐火层上以完成该涂层。另选地,如果需要,可将TiOCN的外层沉积在纳米复合材料耐火层上以完成该涂层。
表XI–涂层的CVD沉积
*另选形式的外层
沉积的时间、温度和压力提供于表IX中。所得涂层表现出表XII中所提供的特性。随后通过上文所述的颗粒浆液涂布后处理移除表XII中列出的TiN外层。带涂层的切削刀片表现出4.15的平均TC(200)。图5为从本发明示例的一个切削刀片获得的多相耐火层的横截面SEM。存在大的氧化锆晶粒以及较小的微晶。
表XII–CVD涂层的特性
涂层 | 厚度(μm) |
TiN | 0.5 |
MT-TiCN | 8.3 |
HT-TiCN/TiOCN | 1.0 |
ZrAl2O3/ZrO2复合材料 | 7.7 |
TiN* | 1.6 |
*通过涂布后处理移除
实施例3–带涂层的切削工具
通过将烧结碳化钨(WC-Co)切削刀片基底[ANSI标准几何形状CNMG432RN]放入轴流热壁CVD反应器中,来制备带涂层的切削工具。切削刀片包含6重量%的钴粘结剂,余量为1μm至5μm尺寸的WC晶粒。根据表XIII将本文所述的包含多相耐火层的涂层沉积在切削刀片上。该多相耐火层包含Zr掺杂的氧化铝相和氧化锆相。将TiN的外层沉积在纳米复合材料耐火层上以完成该涂层。另选地,如果需要,可将TiOCN的外层沉积在纳米复合材料耐火层上以完成该涂层。
表XIII–涂层的CVD沉积
*另选形式的外层
沉积的时间、温度和压力提供于表IX中。所得涂层表现出表XIV中所提供的特性。随后通过上文所述的颗粒浆液涂布后处理移除表XIV中列出的TiN外层。带涂层的切削刀片表现出3.5的平均TC(200)。图6为从本发明示例的一个切削刀片获得的多相耐火层的横截面SEM。
表XIV–CVD涂层的特性
涂层 | 厚度(μm) |
TiN | 0.7 |
MT-TiCN | 8.6 |
HT-TiCN/TiOCN | 1.0 |
ZrAl2O3/ZrO2复合材料 | 9.9 |
TiN* | 1.6 |
*通过涂布后处理移除
实施例4–金属切削测试
使实施例1-3和比较例1的带涂层的切削刀片根据以下参数经受连续车削测试。比较例1采用与实施例1-3相同的烧结碳化物基底,并表现出表XV的涂层结构。
表XV–比较例1的CVD涂层的特性
涂层 | 厚度(μm) |
TiN | 0.7 |
MT-TiCN | 8.5 |
HT-TiCN/TiOCN | 1.1 |
Al2O3 | 5.3 |
比较例1的CVD涂层包括TiN外层,随后通过上文所述的颗粒浆液涂布后处理将其移除。对于车削测试而言,通过侧面磨损(VB)>0.3mm来记录寿命终止(EOL)。比较例1的切削寿命被标准化,表示100%的寿命。
车削参数
工件:4340钢
速度:750sfm
进料速率:0.012ipr
切削深度:0.1mm
导程角:-5°
连续车削测试的结果提供于表XVI中。
表XVI–连续车削测试结果
带涂层的切削刀片 | 寿命(%) |
比较例1 | 100 |
实施例1 | 118 |
实施例2 | 113 |
实施例3 | 89 |
如表XVI中所提供,实施例1和实施例2的带涂层的切削刀片具有大于4的氧化锆TC(200),提供了显著延长的切削寿命。实施例3的切削刀片的TC(200)小于4,无法匹配比较例1的性能。
实施例5–金属切削测试
使实施例1-3和比较例1的带涂层的切削刀片根据以下参数经受连续车削测试。对于车削测试而言,通过凹陷磨损(CW)>0.1mm来记录寿命终止(EOL)。比较例1的切削寿命被标准化,表示100%的寿命。
车削参数
工件:1045钢
速度:1000sfm
进料速率:0.012ipr
切削深度:0.08mm
导程角:-5°
连续车削测试的结果提供于表XVII中。
表XVII–连续车削测试结果
带涂层的切削刀片 | 寿命(%) |
比较例1 | 100 |
实施例1 | 159 |
实施例2 | 100 |
实施例3 | 134 |
如表XVII中所提供,实施例1和实施例3的带涂层的切削刀片提供了显著延长的切削寿命。实施例2的切削刀片具有与比较例1相当的性能。
针对实现本发明多个目的,现已描述了本发明的多个实施方案。应当认识到,这些实施方案仅示例性地说明本发明的原理。在不脱离本发明实质和范围的情况下,其多种修改和变更对于本领域技术人员而言将是显而易见的。
Claims (22)
1.一种带涂层的制品,包括:
基底;和
通过化学气相沉积(CVD)法沉积的涂层,所述涂层粘附到所述基底,所述涂层包括多相耐火层,所述多相耐火层包括氧化铝相和氧化锆相,其中所述氧化锆相具有(200)生长方向的大于4的织构系数TC(200),所述织构系数(TC)被定义为:
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I(hkl)=所述(hkl)反射的测得强度
Io(hkl)=根据国际衍射数据中心(ICDD)卡号00-037-1484的所述(hkl)反射的标准强度
n=TC计算中使用的反射数目
所述TC计算中使用的(hkl)反射为(-111)、(111)、(200)、(-112)、(220)和(-221)。
2.根据权利要求1所述的带涂层的制品,其中所述TC(200)大于4.5。
3.根据权利要求1所述的带涂层的制品,其中所述TC(200)大于5。
4.根据权利要求1所述的带涂层的制品,其中所述TC(200)大于5.5。
5.根据权利要求1所述的带涂层的制品,其中所述TC(200)为4.1至6。
6.根据权利要求1所述的带涂层的制品,其中所述氧化铝相掺杂有锆。
7.根据权利要求6所述的带涂层的制品,其中锆以所述氧化铝相的0.1重量%-3重量%的量存在于所述氧化铝相中。
8.根据权利要求6所述的带涂层的制品,其中所述氧化铝相为α-氧化铝、κ-氧化铝或其混合物。
9.根据权利要求1所述的带涂层的制品,其中所述氧化锆相分散在所述氧化铝相中。
10.根据权利要求1所述的带涂层的制品,其中所述多相耐火层中铝与锆的比率(Al/Zr)为1.5至3。
11.根据权利要求1所述的带涂层的制品,其中氧化锆以所述多相耐火层的20重量%-40重量%的量存在。
12.根据权利要求1所述的带涂层的制品,其中所述氧化锆相主要表现出单斜晶体结构。
13.根据权利要求1所述的带涂层的制品,其中所述氧化锆相包括单斜晶相和正方晶相的混合物。
14.根据权利要求13所述的带涂层的制品,其中所述氧化锆相为60%-99.9%的单斜晶。
15.根据权利要求13所述的带涂层的制品,其中所述氧化锆相为1%-10%的正方晶。
16.根据权利要求1所述的带涂层的制品,其中所述涂层还包括所述多相耐火层和所述基底之间的一个或多个内层。
17.根据权利要求16所述的带涂层的制品,其中所述一个或多个内层包含选自由铝及元素周期表的IVB族、VB族和VIB族的金属元素组成的组的一种或多种金属元素以及选自由元素周期表的IIIA族、IVA族、VA族和VIA族的非金属元素组成的组的一种或多种非金属元素。
18.根据权利要求1所述的带涂层的制品,其中所述涂层还包括所述多相耐火层上的一个或多个外层。
19.根据权利要求18所述的带涂层的制品,其中所述一个或多个外层包含选自由铝及元素周期表的IVB族、VB族和VIB族的金属元素组成的组的一种或多种金属元素以及选自由元素周期表的IIIA族、IVA族、VA族和VIA族的非金属元素组成的组的一种或多种非金属元素。
20.根据权利要求1所述的带涂层的制品,其中所述基底为切削工具。
21.根据权利要求1所述的带涂层的制品,其中所述切削工具为切削刀片或旋转切削工具。
22.根据权利要求1所述的带涂层的制品,其中所述基底为烧结碳化物、碳化物、金属陶瓷、陶瓷或钢。
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