CN1067087C - 环状烯烃共聚物的生产方法及用该方法制造的共聚物 - Google Patents

环状烯烃共聚物的生产方法及用该方法制造的共聚物 Download PDF

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Publication number
CN1067087C
CN1067087C CN95103477A CN95103477A CN1067087C CN 1067087 C CN1067087 C CN 1067087C CN 95103477 A CN95103477 A CN 95103477A CN 95103477 A CN95103477 A CN 95103477A CN 1067087 C CN1067087 C CN 1067087C
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CN
China
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carbon atoms
group
cyclopentadienyl
indenyl
formula
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Expired - Fee Related
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CN95103477A
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English (en)
Chinese (zh)
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CN1112570A (zh
Inventor
阿部吉晴
相根敏裕
丰田昭德
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Ticona GmbH
Mitsui Chemical Industry Co Ltd
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Hoechst AG
Mitsui Chemical Industry Co Ltd
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Publication of CN1112570A publication Critical patent/CN1112570A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Printing Methods (AREA)
CN95103477A 1994-04-22 1995-04-22 环状烯烃共聚物的生产方法及用该方法制造的共聚物 Expired - Fee Related CN1067087C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP084725/94 1994-04-22
JP084725/1994 1994-04-22
JP8472594 1994-04-22

Publications (2)

Publication Number Publication Date
CN1112570A CN1112570A (zh) 1995-11-29
CN1067087C true CN1067087C (zh) 2001-06-13

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CN95103477A Expired - Fee Related CN1067087C (zh) 1994-04-22 1995-04-22 环状烯烃共聚物的生产方法及用该方法制造的共聚物

Country Status (7)

Country Link
US (1) US5559199A (https=)
EP (1) EP0678530B1 (https=)
KR (1) KR100231173B1 (https=)
CN (1) CN1067087C (https=)
CA (1) CA2147589C (https=)
DE (1) DE69521826T2 (https=)
TW (1) TW312696B (https=)

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JP3672315B2 (ja) * 1994-09-30 2005-07-20 日本ゼオン株式会社 開環重合体水素添加物
JP3517471B2 (ja) * 1994-12-28 2004-04-12 三井化学株式会社 環状オレフィン共重合体の製造方法
JPH08239426A (ja) * 1995-03-01 1996-09-17 Mitsui Petrochem Ind Ltd 環状オレフィン共重合体の製造方法
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
FI105196B (fi) * 1995-05-08 2000-06-30 Optatech Oy Amorfiset olefiini-ko/terpolymeerit
ATE194629T1 (de) * 1996-03-27 2000-07-15 Dow Chemical Co Hochlösliches aktivierungsmittel für olefinpolymerisationskatalysator
DE19623707A1 (de) * 1996-06-14 1997-12-18 Hoechst Ag Übergangsmetallverbindung
JP3817015B2 (ja) * 1997-04-14 2006-08-30 三井化学株式会社 環状オレフィン系共重合体およびその用途
US6451946B1 (en) 1998-12-11 2002-09-17 Sumitomo Chemical Company, Limited Copolymer, process for the production thereof, and molded article thereof
WO2000046254A1 (en) * 1999-02-04 2000-08-10 Idemitsu Petrochemical Co., Ltd. Catalyst for olefin polymerization, process for producing the same, and process for producing olefin polymer
US6150478A (en) * 1999-06-04 2000-11-21 Union Carbide Chemicals & Plastics Technology Corporation Ultrasonic catalyst feed for fluid bed olefin polymerization
US6875719B2 (en) 2000-04-27 2005-04-05 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
EP1179554A1 (en) * 2000-08-08 2002-02-13 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
CA2364756A1 (en) * 2001-12-10 2003-06-10 Nova Chemicals Corporation Catalyst activator
EP1586591A4 (en) * 2003-01-23 2006-06-14 Mitsui Chemicals Inc PROCESS FOR PRODUCING NON-CONJUGATED ETHYLENE / α-OLEFIN / POLYENE COPOLYMER AND NON-CONJUGATED ETHYLENE / α-OLEFIN / POLYENE COPOLYMER THUS OBTAINED
TWI255370B (en) * 2003-02-27 2006-05-21 Hon Hai Prec Ind Co Ltd Light guide plate used for liquid crystal display
US7022787B2 (en) * 2003-09-25 2006-04-04 E. I. Du Pont De Nemours And Company Olefin polymerization catalyst
US8168292B2 (en) * 2006-06-15 2012-05-01 Innegra Technologies, Llc Composite materials including amorphous thermoplastic fibers
US7550546B2 (en) * 2006-07-28 2009-06-23 Fujifilm Corporation Norbornene-based polymers, films, polarizing plates and liquid crystal display devices
JP4074879B1 (ja) 2006-10-18 2008-04-16 株式会社コナミデジタルエンタテインメント ゲーム装置、メッセージ表示方法、および、プログラム
DE102007015707A1 (de) 2007-04-02 2008-10-09 Topas Advanced Polymers Gmbh Cycloolefin-Copolymere, Verfahren zu ihrer Herstellung, deren Verwendung und Katalysatoren
JP2020516695A (ja) 2017-04-12 2020-06-11 ウリゲン ファーマシューティカルズ、インコーポレイテッド 改善された安定性を備えた注射器中に局所麻酔薬、緩衝液、およびグルコサミノグリカンを含む製品
CN111777702B (zh) * 2020-05-13 2022-07-01 拓烯科技(衢州)有限公司 一种改性环烯烃型无规共聚物及其制备方法
EP4182365A1 (en) * 2020-07-17 2023-05-24 Dow Global Technologies LLC Hydrocarbyl-modified methylaluminoxane cocatalysts for constrained geometry procatalysts
US12606647B2 (en) 2020-07-17 2026-04-21 Dow Global Technologies Llc Hydrocarbyl-modified methylaluminoxane cocatalysts for bis-phenylphenoxy metal-ligand complexes
CN115894757B (zh) * 2021-09-30 2024-06-04 中国石油化工股份有限公司 乙烯-烯醇共聚物及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2062201A1 (en) * 1991-03-09 1992-09-10 Michael-Joachim Brekner Process for the preparation of chemically homogeneous cycloolefin copolymers
US5225503A (en) * 1991-11-11 1993-07-06 Mitsui Petrochemical Industries, Ltd. Process for preparing cycloolefin random copolymer

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US4614778A (en) * 1984-02-03 1986-09-30 Hirokazu Kajiura Random copolymer
JPS6198780A (ja) * 1984-10-22 1986-05-17 Mitsui Petrochem Ind Ltd 新規合成ワツクス
JPS61115916A (ja) * 1984-11-12 1986-06-03 Mitsui Petrochem Ind Ltd 新重合体
JPS61120816A (ja) * 1984-11-19 1986-06-07 Mitsui Petrochem Ind Ltd 新規な付加共重合体
JPH0713084B2 (ja) * 1985-03-26 1995-02-15 三井石油化学工業株式会社 環状オレフイン系共重合体の製法
US5179171A (en) * 1985-05-24 1993-01-12 Mitsui Petrochemical Industries, Ltd. Random copolymer, and process for production thereof
US5003019A (en) * 1987-03-02 1991-03-26 Mitsui Petrochemical Industries, Ltd. Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
US5128446A (en) * 1988-09-07 1992-07-07 Mitsui Petrochemical Industries, Ltd. Process for producing cycloolefin random copolymer
US5008359A (en) * 1988-11-25 1991-04-16 Weyerhaeuser Company Isocyanate modified cellulose products and method for their manufacture
JP2730940B2 (ja) * 1988-12-27 1998-03-25 三井化学株式会社 環状オレフィン系共重合体の製造方法
DE3922546A1 (de) * 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
JP2868569B2 (ja) * 1990-02-13 1999-03-10 三井化学株式会社 環状オレフィン系ランダム共重合体の製造方法
ATE212042T1 (de) * 1990-03-06 2002-02-15 Mitsui Chemicals Inc Statistische cycloolefincopolymere und verfahren zu ihrer herstellung
DE69132693T3 (de) * 1990-10-05 2010-01-21 Idemitsu Kosan Co. Ltd. Copolymere von Cycloolefinen, daraus hergestellte Zusammensetzungen und Formteile
EP0501370B1 (de) * 1991-02-27 1998-11-25 Ticona GmbH Verfahren zur Herstellung von Cycloolefin(co)polymeren mit enger Molekulargewichtsverteilung
JPH05320258A (ja) * 1992-05-15 1993-12-03 Mitsui Petrochem Ind Ltd 環状オレフィン共重合用触媒および環状オレフィンの共重合方法
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Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2062201A1 (en) * 1991-03-09 1992-09-10 Michael-Joachim Brekner Process for the preparation of chemically homogeneous cycloolefin copolymers
US5225503A (en) * 1991-11-11 1993-07-06 Mitsui Petrochemical Industries, Ltd. Process for preparing cycloolefin random copolymer

Also Published As

Publication number Publication date
KR100231173B1 (ko) 1999-11-15
TW312696B (https=) 1997-08-11
US5559199A (en) 1996-09-24
DE69521826T2 (de) 2002-04-11
CA2147589C (en) 2006-04-18
CN1112570A (zh) 1995-11-29
EP0678530B1 (en) 2001-07-25
KR950032326A (ko) 1995-12-20
DE69521826D1 (de) 2001-08-30
CA2147589A1 (en) 1995-10-23
EP0678530A1 (en) 1995-10-25

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Owner name: MITSUI CHEMICALS, INC.; TERKAU CO., LTD.

Free format text: FORMER OWNER: MITSUI CHEMICALS, INC.; HOCHST CO.,LTD.

Effective date: 20010817

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20010817

Patentee after: Mitsui Chemical Industry Co., Ltd.

Patentee after: Ticona GmbH

Patentee before: Mitsui Chemical Industry Co., Ltd.

Patentee before: Hoechst AG

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20010613

Termination date: 20100422