CN105612234A - 粘合到箔片的方法 - Google Patents
粘合到箔片的方法 Download PDFInfo
- Publication number
- CN105612234A CN105612234A CN201380080186.XA CN201380080186A CN105612234A CN 105612234 A CN105612234 A CN 105612234A CN 201380080186 A CN201380080186 A CN 201380080186A CN 105612234 A CN105612234 A CN 105612234A
- Authority
- CN
- China
- Prior art keywords
- water
- composition
- adhesion agent
- agent composition
- bearing media
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011888 foil Substances 0.000 title description 11
- 238000000034 method Methods 0.000 title description 10
- 239000000203 mixture Substances 0.000 claims abstract description 82
- 239000012948 isocyanate Substances 0.000 claims abstract description 19
- -1 isocyanate compounds Chemical class 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 55
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 11
- 238000004040 coloring Methods 0.000 claims description 11
- 150000002513 isocyanates Chemical class 0.000 claims description 11
- 208000036758 Postinfectious cerebellitis Diseases 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 238000005829 trimerization reaction Methods 0.000 claims description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
- 101710130081 Aspergillopepsin-1 Proteins 0.000 claims description 3
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 claims description 3
- 230000000051 modifying effect Effects 0.000 claims description 3
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims 1
- 150000004756 silanes Chemical class 0.000 abstract description 9
- 239000012736 aqueous medium Substances 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000000758 substrate Substances 0.000 description 23
- 229920006254 polymer film Polymers 0.000 description 17
- 239000000178 monomer Substances 0.000 description 16
- 239000004698 Polyethylene Substances 0.000 description 12
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 9
- 229910000077 silane Inorganic materials 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- 239000010408 film Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 239000004593 Epoxy Substances 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 description 5
- 229920001451 polypropylene glycol Polymers 0.000 description 5
- 150000005846 sugar alcohols Polymers 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 229920000620 organic polymer Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000003855 Adhesive Lamination Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000005030 aluminium foil Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 2
- 230000010148 water-pollination Effects 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 101000969688 Homo sapiens Macrophage-expressed gene 1 protein Proteins 0.000 description 1
- 101000629400 Homo sapiens Mesoderm-specific transcript homolog protein Proteins 0.000 description 1
- 229920006309 Invista Polymers 0.000 description 1
- 102100021285 Macrophage-expressed gene 1 protein Human genes 0.000 description 1
- 102100026821 Mesoderm-specific transcript homolog protein Human genes 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 101100166455 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) ccg-4 gene Proteins 0.000 description 1
- 101150114608 PPG1 gene Proteins 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 102000046669 Surf-1 Human genes 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical class CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- ONJMNXFNTYIEEA-UHFFFAOYSA-N benzene ethene Chemical compound C1=CC=CC=C1.C=C.C=C.C=C ONJMNXFNTYIEEA-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920001427 mPEG Polymers 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011104 metalized film Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 101150081019 surf1 gene Proteins 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
- C08G18/289—Compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4808—Mixtures of two or more polyetherdiols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
- C09J201/02—Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09J201/10—Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/80—Compositions for aqueous adhesives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
提供一种水性粘着剂组合物,其包含(i)含水介质;(ii)一种或多种分散于所述含水介质中的异氰酸酯化合物,和(iii)一种或多种分散于所述含水介质中的官能性硅烷化合物。
Description
粘着剂组合物的一个重要用途是粘合层压物的层。举例来说,经常需要提供可以将金属箔片粘合到聚合物膜的粘着剂组合物。因安全性和环境保护的原因,需要粘着剂组合物是水性的。使用水性粘着剂组合物以粘合层压物的层的所需方法是干燥粘合层压工艺,其为以下方法:将水性粘着剂组合物的层涂覆到第一衬底,随后将水性粘着剂组合物干燥或使其干燥,随后使第二衬底与经干燥粘着剂组合物接触,通常经由将两个衬底配合在一起并且形成层压物的热紧压夹。
US2010/0081742描述可以用于使沙粒和其它介质着色的水基有色聚氨基甲酸酯涂层。由US2010/0081742描述的涂层任选地含有交联剂,例如β-(3,4-环氧环己基)乙基三乙氧基硅烷。
需要提供一种使用水性粘着剂组合物来将金属箔片粘合到聚合物膜的方法。尤其需要提供一种使用水性粘着剂组合物的干燥粘合层压的方法,其中第一衬底是金属箔片并且第二衬底是聚合物膜。还需要的是能够使用是所述方法的水性粘着剂组合物。
以下是本发明的陈述。
本发明的第一方面是一种水性粘着剂组合物,其包含
(i)含水介质
(ii)一种或多种分散于所述含水介质中的异氰酸酯化合物,和
(iii)一种或多种分散于所述含水介质中的官能性硅烷化合物,
其中所述异氰酸酯化合物选自由以下组成的群组:
(a)一种或多种亲水改性的寡异氰酸酯,
(b)一种或多种异氰酸酯-官能性聚氨基甲酸酯,其中所述聚氨基甲酸酯包含一种或多种聚醚多元醇、一种或多种聚酯多元醇或其混合物与一种或多种聚异氰酸酯的反应产物,和
(c)(a)与(b)的混合物;
其中所述粘着剂组合物不含着色剂。
本发明的第二方面是将金属箔片粘合到聚合物膜的方法,其包含以下步骤:
(A)将水性粘着剂组合物的层涂覆到所述聚合物膜或金属箔片的表面,
(B)干燥所述粘着剂组合物的所述层以产生经干燥粘着剂的层,和
(C)所述干燥后,使金属箔片或聚合物膜的表面与所述经干燥粘着剂组合物的所述层接触,
其中所述水性粘着剂组合物描述于本发明的第一方面中。
以下是本发明的详细描述。
如本文中所使用,除非上下文另作明确指示,否则以下术语具有所指定的定义。
金属箔片是长度和宽度各自是至少1cm并且厚度是0.5mm或小于0.5mm的一块金属。聚合物膜是由有机聚合物制成的长度和宽度各自是至少1cm并且厚度是0.5mm或小于0.5mm的一块材料。
如果组合物在25℃下是液体并且按组合物的重量计含有30重量%或大于30重量%的水,那么组合物在本文中称为水性的。水性组合物含有离散液滴或粒子可以任选地悬浮于其中的连续流体介质。连续流体介质含有水,其量按连续流体介质的重量计是50重量%或大于50重量%。连续流体介质在本文中称为含水介质。
含于水性组合物中的不为水的化合物在本文中称为分散于含水介质中。所述化合物可以经溶解或悬浮或其组合。悬浮化合物呈现为离散液滴或粒子;所述粒子可能含有两种或更多种物质。悬浮液滴或粒子的重量平均直径是5nm或大于5nm。溶解于含水介质中的化合物分散为个别分子。
异氰酸酯是含有一个或多个侧异氰酸酯基-NCO的化合物。每分子含有一个以上异氰酸酯基的异氰酸酯是聚异氰酸酯。恰好含有两个异氰酸酯基的异氰酸酯是二异氰酸酯。单体二异氰酸酯具有结构OCN-R1-NCO,其中-R1是二价有机基团,不具有异氰酸酯基的,不具有氨基甲酸酯键,并且分子量小于500。
多元醇是每分子具有两个或更多个-OH基团的化合物。二醇恰好每分子具有两个-OH基团。
如本文中所使用,着色剂是任何染料或颜料。着色剂可以是有机或无机的或其组合。
本发明的粘着剂组合物包含含水介质。优选地,含水介质中水的量按水的重量计是70重量%或大于70重量%;或80重量%或大于80重量%;或90重量%或大于90重量%。
本发明的粘着剂组合物含有一种或多种异氰酸酯化合物。优选地,粘着剂组合物含有一种或多种聚异氰酸酯。优选聚异氰酸酯是一种或多种氨基甲酸酯预聚物、一种或多种异氰酸酯三聚体以及其混合物。
异氰酸酯三聚体是单体二异氰酸酯的三聚体。优选的是亲水改性的异氰酸酯三聚体,其具有结构
其中三个R基团彼此相同,并且其中G是含有至少一个亲水性基团的有机基团。优选的R基团是脂肪族基;更优选的是正己基和二甲基环己基;更优选的是正己基。优选的亲水性基团是阴离子基团和亲水性环氧烷基团;更优选的是亲水性环氧烷基团。优选的亲水性环氧烷基团是-(CH2CH2O)n-,其中n是3到50。在阴离子基团之中,优选的是硫酸根和羧酸根;更优选的是硫酸根。
氨基甲酸酯预聚物是一种或多种聚异氰酸酯与一种或多种多元醇或一种或多种多元胺或其混合物的反应产物。在制备氨基甲酸酯预聚物中,使用摩尔过量的聚异氰酸酯,并且氨基甲酸酯预聚物是聚异氰酸酯。对于制备氨基甲酸酯预聚物,优选的聚异氰酸酯是单体二异氰酸酯,其分子量是300或小于300;更优选地275或小于275。对于制备氨基甲酸酯预聚物,优选的聚异氰酸酯是芳香族单体二异氰酸酯;更优选的是一种或多种MDI异构体;更优选的是4,4′-MDI和4,4′-MDI与其它MDI异构体的混合物;更优选的是4,4′-MDI。对于制备氨基甲酸酯预聚物,一种或多种聚异氰酸酯优选地与一种或多种多元醇反应。优选的多元醇的重量平均分子量是500或大于500;更优选地800或大于800。优选的多元醇的重量平均分子量是5000或小于5000;更优选地2500或小于2500。优选地,重量平均分子量小于800的多元醇不用于制备氨基甲酸酯预聚物。优选的多元醇是二醇。优选的多元醇是聚醚多元醇、聚酯多元醇以及其混合物;更优选的是聚醚多元醇。优选的聚醚多元醇是聚四亚甲基醚二醇、聚丙二醇以及其混合物。
优选的氨基甲酸酯预聚物制备为聚氨基甲酸酯分散体,其是氨基甲酸酯预聚物的粒子悬浮于含水介质中的组合物。
本发明的组合物含有一种或多种官能性硅烷。官能性硅烷是具有以下结构的化合物
其中A是氨基、环氧基、甲基丙烯酰基、乙烯基、巯基、脲或异氰酸酯基。基团-R1-是二价有机基团。优选地,-R1-是烃基;更优选地烷基;更优选地直链烷基,更优选地具有1到6个碳原子的直链烷基;更优选地具有2到4个碳原子的直链烷基。-R2、-R3和-R4中的每一个独立地是-O-R5或-R6,其中-R5和-R6中的每一个独立地是烷基;优选地具有1到6个碳原子的烷基;更优选地甲基、乙基或异丙基;更优选地甲基或乙基。优选地,-R2、-R3和-R4中的一个或多个是-O-R5;更优选地-R2、-R3和-R4中的两个或更多个是-O-R5。优选地,-R2、-R3和-R4中的两个或更多个彼此一致。
环氧基是含有环氧环的任何基团。环氧基包括例如环氧醚基和β-(3,4-环氧环己基)基团。环氧醚基具有结构
优选地,A-是环氧醚基、氨基或巯基。
优选地,官能性硅烷可溶于水中或可悬浮于水中。如果在25℃下一个或多个pH值在1与7之间,在所述pH值下可以溶解于水中的官能性硅烷的量按水的重量计是2重量%或大于2重量%,那么官能性硅烷在本文中视为可溶于水中。无论是否在官能性硅烷的溶解形式中,一个或多个-OR5基团转化成-OH基团,官能性硅烷在本文中视为可溶的。如果在25℃下2克或大于2克的官能性硅烷可以悬浮于100克水中,以形成在25℃下存放时不沉降或聚结24小时的悬浮液,那么官能性硅烷在本文中视为可悬浮。
优选地,水性粘着剂组合物不含有任何着色剂。也就是说,水性粘着剂组合物完全不含着色剂或含有以按组合物的总重量计0.1重量%或小于0.1重量%的量的着色剂。本文中认为,如果水性粘着剂组合物含有以按组合物的总重量计0.1重量%或小于0.1重量%的量的着色剂,那么组合物将含有此类少量的着色剂,着色剂的量视为可忽略,并且组合物被视为等效于不含有任何着色剂的组合物。
水性粘着剂组合物任选地含有一种或多种非氨基甲酸酯聚合物。优选的非氨基甲酸酯聚合物是乙烯基聚合物,其为含有烯系不饱和单体的聚合单元的聚合物。更优选的非氨基甲酸酯聚合物含有一种或多种丙烯酸单体、一种或多种乙烯基芳香族单体或其组合的聚合单元。丙烯酸单体是丙烯酸、甲基丙烯酸、其酯以及其酰胺。乙烯基芳香族单体包括苯乙烯和经取代苯乙烯。
当存在一种或多种非氨基甲酸酯聚合物时,所述聚合物的优选形式是如悬浮于含水介质中的粒子。
优选地,水性粘着剂组合物不含有任何乙烯基聚合物,所述任何乙烯基聚合物含有任何乙烯基硅烷单体的任何聚合单元。乙烯基硅烷单体是在其分子中具有可聚合的碳-碳双键和一个或多个硅原子的单体。
在本发明的实践中,水性粘着剂组合物的层优选地涂覆到金属箔片或聚合物膜的表面。更优选地,水性粘着剂组合物的层涂覆到金属箔片的表面。优选地,金属箔片是铝箔。优选地,金属箔片的厚度是1μm或大于1μm;更优选地3μm或大于3μm。优选地,金属箔片的厚度是25μm或小于25μm;更优选地15μm或小于15μm。
优选地,将水性粘着剂组合物的层干燥或使其干燥以形成经干燥粘着剂组合物的层。可以通过任何方法实现干燥,包括例如时间推移、施加热和曝露于流动空气中的一种或多种。当按水(作为水性粘着剂组合物的一部分而应用)的重量计,粘着剂组合物的层中剩余的水量是10重量%或小于10重量%时,粘着剂组合物的层被视为干燥的。
粘着剂组合物的干燥层优选地与聚合物膜或金属箔片的表面接触。更优选地,粘着剂组合物的干燥层与聚合物膜的表面接触。优选地,粘着剂组合物的干燥层使用将两个衬底配合在一起并且形成层压物的热紧压夹来使得与聚合物膜或金属箔片的表面接触。
用于聚合物膜的优选聚合物是有机聚合物和金属化有机聚合物;更优选的是聚烯烃、聚烯烃共聚物、聚酯、聚碳酸酯、聚酰胺以及其金属化膜。聚烯烃是烯烃单体的均聚物和共聚物,所述烯烃单体是含有一个或多个碳-碳双键的烃分子。聚烯烃共聚物是一种或多种烯烃单体的共聚物,所述烯烃单体具有一种或多种乙酸乙烯酯、丙烯酸酯单体和甲基丙烯酸酯单体。优选的聚合物是聚乙烯、聚对苯二甲酸乙二醇酯和尼龙;更优选的是聚乙烯。
聚合物膜与经干燥粘着剂组合物的层接触后,因此形成的复合物品优选地经历机械力以使聚合物膜和金属箔片压向彼此。所述机械力优选地通过在滚筒之间传送复合物品来施加。
在本发明的一些实施例中,由金属箔片、粘着剂组合物的层和聚合物膜制成的复合物品是含有其它层的较大复合物品的一部分。其它层可能含有一个或多个聚合物膜、粘着剂组合物的一个或多个层和一个或多个金属箔片;存在于其它层中的任何聚合物膜、粘着剂组合物或金属箔片可能彼此相同或不同,并且来自存在于上文所描述复合物品中的聚合物膜、粘着剂组合物和金属箔片。
举例来说,在一些实施例中,较大复合物品制备如下。将粘着剂组合物的第一层涂覆到聚对苯二甲酸乙二醇酯膜,并且使第一粘着剂组合物与金属箔片的一个表面接触。随后,在金属箔片的相反表面上,涂覆粘着剂组合物的第二层,并且使第二粘着剂组合物与聚乙烯的聚合物膜的表面接触。优选地,在所述实施例之中,粘着剂组合物的第一层和粘着剂组合物的第二层是本发明的水性粘着剂组合物的层,并且优选地每一层在与下一衬底接触前干燥。
以下是本发明的实例。
在实例中使用以下成分:
SPU1+CatF=AdcoteTM545-75EA(“SPU1”)加催化剂F(“CatF”)是来自陶氏化学公司(DowChemicalCompany)的双组分溶剂型粘着剂产品
乳胶“L”是ROBONDTML-168A,来自陶氏化学公司的水性乳胶共聚物;含有一种或多种丙烯酸单体的聚合单元。
异氰酸酯1=ROBONDTMCOREACTANTCR3A,来自陶氏化学公司的水可分散性脂肪族异氰酸酯三聚体
PTMEG1=TetrathaneTM2000聚四亚甲基醚二醇,MW=2000,来自英威达(Invista)。
PPG1=VaranolTMV9287A聚丙二醇,MW=2000,来自陶氏化学公司
PEG1=CarbowaxTMPEG1000聚乙二醇,分子量1000,来自陶氏化学公司
MPEG1=CarbowaxTMMPEG1000甲氧基聚乙二醇,分子量1000,来自陶氏化学公司
MDI=IsonateTM125M,来自陶氏化学公司
Surf1=RhodacalTMDS4表面活性剂,十二烷基苯磺酸钠,来自罗地亚(Rhodia)
箔膜是由中国(China)当地供应商供应的7μm铝箔
Ny是尼龙膜,15μm厚
PET是聚对苯二甲酸乙二醇酯膜,12μm厚
PE是聚乙烯膜,50μm厚
硅烷1=SilquestTMA1100γ氨基丙基三乙氧基硅烷,由迈图(Momentive)供应
硅烷2=SilquestTMA189巯基-丙基三甲氧基硅烷,由迈图供应
硅烷3=SilquestTMA187γ-(2,3-环氧丙氧基)丙基三甲氧基硅烷,由迈图供应
DI水是去离子水
成分如下用于实例。“Comp.”意指比较并且“Ex.”意指实例,“Ingr”意指成分并且“No.”意指编号。
为制备实例1和实例2以及比较实例10,在氮气净化下将成分No.1到No.4添加到1升玻璃瓶子中。随后添加成分No.5和7(如果使用),并且将瓶子缓慢地加热到约80℃。将瓶子保持在80℃下2到3小时;检验NCO含量,并且维持温度直到获得NCO含量的理论值。将所得预聚物放置在塑料瓶子中并且用考雷司(Cowles)桨叶在约3000rpm下搅拌。随后在高速搅拌下在冷温度(5℃)下将成分No.9、之后成分No.8添加到塑料罐中,以确保达到均质的水包油分散体,随后将成分No.6缓慢地添加到分散体中,并且继续搅拌以产生稳定的分散体。对于实例2和比较实例10,在逐滴添加成分No.10的同时用磁性旋转棒对分散体进行搅拌;随后继续搅拌30分钟。
Ingr.No. | 成分 | Ex.3 | Ex.4. | Ex.5. |
1a | 比较实例10 | 50g | 50g | 50g |
2a | 硅烷1 | 0.15g | 0 | 0 |
3a | 硅烷2 | 0 | 0.15 | 0 |
4a | 硅烷3 | 0 | 0 | 0.15 |
Ingr.No. | 成分 | Ex.6 | Ex.7 | Ex.8 | Comp.Ex.9 |
1b | 乳胶L | 50g | 50g | 50g | 50g |
2b | 硅烷1 | 0.15g | 0 | 0 | 0 |
3b | 硅烷2 | 0 | 0.15 | 0 | 0 |
4b | 硅烷3 | 0 | 0 | 0.15 | 0 |
5b | 异氰酸酯1 | 1g | 1g | 1g | 1g |
Ingr.No. | 成分 | Comp.Ex.11 |
1c | SPU1 | 90g |
2c | Cat F | 10g |
对于实例3、4、5、6、7、8、比较9和比较11,使用磁性旋转棒混合以上所展示的成分。
对于每个实例,使用K101控制涂布机(RKPrintCoatInstrumentsLtd.)将粘着剂混合物涂布于第一衬底上,以得到2.3g/m2的干燥涂层重量。将经涂布衬底放置在80℃下的烘箱中,持续30秒到2分钟以去除水。使第二衬底与干燥粘着剂接触,并且使用夹温是约68℃的热轧层压机HL-101(ChemInstruments,Inc.)形成层压物。在约23℃下将层压样品存放3-7,并且随后通过两个不同测试对粘着强度进行测试:粘合强度和沸点强度。
在粘合强度测试中,切割15mm宽的条带并且随后使用拉力测试仪以25cm/min剥离。记录最大剥离力并且以牛顿(Newton)单位报道。失效模式记录如下:
FF:无膜伸长情况下的膜失效(衬底在无伸长的情况下断裂)
FT:拉伸伸长下的膜撕裂(衬底伸长并且还断裂)
在袋中沸腾测试中,将固化层压物切成8cm×12cm大小,并且使用HSG-C热封机器(BruggerFeinmechanikGmbH)在140℃和300N/15mm压力的条件下制备成内部具有去离子水的袋子,持续1秒。避免将水喷溅于热封区域上。用不可消除的标记来标记热封区域或层压区域中任何明显的预先存在的缺陷。随后将袋子小心地放置于沸水中并且留在其中30分钟,确保所有袋子在整个沸腾过程期间始终浸没于水中。当完成时,记录隧穿、分层或泄漏的程度,与预先存在的缺陷进行比较。通过测试的样品将展示无超出任何预先存在的热封或层压缺陷的隧穿、分层或泄漏迹象。随后打开袋子,清空袋子并且使其冷却下来,随后切成15mm宽的条带,以使用InstronTM5943机器在25cm/min速度下测试T-剥离粘合强度。
测试结果如下。“Ex”是实例,“Comp”是比较,并且“nt”意指未测试。其中未展示失效模式,失效模式是粘着剂失效(当一个衬底上的粘着剂之间的粘合失效或粘着剂分裂时,样品失效,其中粘着剂层分裂)
粘合强度(牛顿和失效模式)
第一衬底 | 第二衬底 | Ex.1 | Ex.2 | Ex.3 | Ex.4 | Ex.5 | Comp.Ex.10 |
PET | PE | 2.7 | 3.2FF | 8.5FF | 3.95FF | 7.38FF | 9.21FF |
Ny | PE | 3.1 | 10.7FF | 11.83FF | 10.32FF | 11.57FF | 14.31FT |
箔片 | PE | 2.2 | 11.7FF | 3.5 | 3.2 | 2.5 | 1.67 |
PET | 箔片 | 1.1 | 1.6 | 2.3 | 1.5 | 1.56 | 1.55 |
箔片 | PET | nt | 4FF | 4.8FF | Nt | nt | nt |
袋中沸腾(牛顿和失效模式)
第一衬底 | 第二衬底 | Ex.1 | Ex.2 | Ex.3 | Ex.4 | Ex.5 | Comp.Ex.10 |
PET | PE | nt | 6FF | 6.5FF | Nt | 4.9FF | 8FF |
Ny | PE | nt | 5 | 7.3 | Nt | 8.7 | 12.1FT |
箔片 | PE | nt | 11FF | 6.6 | 5 | 3.3 | 2.2 |
粘合强度(牛顿和失效模式)
第一衬底 | 第二衬底 | Ex.6 | Ex.7 | Ex.8 | Comp.Ex.9 | Comp.Ex.11 |
PET | PE | 3.6FF | 4FF | 3.4FF | 3.54FF | 4.5FF |
Ny | PE | 4.7 | 5.3 | 6.6 | 3.28 | 7.8FF |
箔片 | PE | 4.3 | 3.82 | 4 | 2.6 | 11 |
PET | 箔片 | 2.1 | 1.61 | 1.78 | 1.25 | 4.2FF |
箔片 | PET | 3.4FF | 3.42FF | 3.51 | 2.1 | 4FF |
袋中沸腾(牛顿和失效模式)
第一衬底 | 第二衬底 | Ex.6 | Ex.7 | Ex.8 | Comp.Ex.9 | Comp.Ex.11 |
PET | PE | 4.5FF | 3.6FF | 3.7FF | 3.4FF | 3.4FF |
Ny | PE | 4.7 | 4.5 | 4.8 | 1.9 | 5 |
箔片 | PE | 4.9 | 4.8 | 4.8 | 2.3 | 6 |
尤其重要的是针对第一衬底是箔片并且第二衬底是PE的层压物的结果。本发明实例均比水性比较实例进行地更好。测试溶剂型比较实例(comp.Ex.11)以提供关于不为水性的粘着剂能力的信息。
对于所有其它衬底,本发明实例表明粘着强度的适用等级。
Claims (4)
1.一种水性粘着剂组合物,其包含
(i)含水介质
(ii)一种或多种分散于所述含水介质中的异氰酸酯化合物,和
(iii)一或多种分散于所述含水介质中的官能性硅烷化合物,
其中所述异氰酸酯化合物选自由以下组成的群组:
(a)一种或多种亲水改性的寡异氰酸酯,
(b)一种或多种异氰酸酯-官能性聚氨基甲酸酯,其中所述聚氨基甲酸酯包含一种或多种聚醚多元醇、一种或多种聚酯多元醇或其混合物与一种或多种聚异氰酸酯的反应产物,和
(c)(a)与(b)的混合物;
其中所述粘着剂组合物不含着色剂。
2.根据权利要求1所述的组合物,其中所述一种或多种异氰酸酯化合物包含一种或多种氨基甲酸酯预聚物,其中所述氨基甲酸酯预聚物包含4,4′-MDI与一种或多种多元醇的反应产物。
3.根据权利要求1所述的组合物,其中所述一种或多种异氰酸酯化合物包含一种或多种亲水改性的异氰酸酯三聚体。
4.根据权利要求1所述的组合物,其中所述组合物另外包含一种或多种非氨基甲酸酯聚合物,所述非氨基甲酸酯聚合物呈悬浮于所述含水介质中的粒子的形式。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2013/085205 WO2015054822A1 (en) | 2013-10-15 | 2013-10-15 | Method of bonding to foil |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105612234A true CN105612234A (zh) | 2016-05-25 |
CN105612234B CN105612234B (zh) | 2019-10-25 |
Family
ID=52827529
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201380080186.XA Active CN105612234B (zh) | 2013-10-15 | 2013-10-15 | 粘合到箔片的方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US10138401B2 (zh) |
EP (1) | EP3030622B1 (zh) |
JP (1) | JP6307601B2 (zh) |
CN (1) | CN105612234B (zh) |
AR (1) | AR097872A1 (zh) |
BR (1) | BR112016008007B1 (zh) |
MX (1) | MX2016004543A (zh) |
RU (1) | RU2660031C2 (zh) |
TW (1) | TWI573851B (zh) |
WO (1) | WO2015054822A1 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111269686A (zh) * | 2020-04-03 | 2020-06-12 | 山东奥德美高分子材料有限公司 | 胶印用高牢度水性聚氨酯转移胶水 |
US11485886B2 (en) | 2019-03-07 | 2022-11-01 | Dow Global Technologies Llc | Formaldehyde free adhesive composition |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6404977B2 (ja) * | 2016-03-31 | 2018-10-17 | Jfeスチール株式会社 | 耐熱接着性絶縁被膜用組成物および絶縁被膜付き電磁鋼板 |
WO2018209483A1 (en) * | 2017-05-15 | 2018-11-22 | Dow Global Technologies Llc | Water-based adhesive compositions |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993023490A1 (de) * | 1992-05-13 | 1993-11-25 | Henkel Kommanditgesellschaft Auf Aktien | Lagerstabiler kontaktklebstoff auf basis einer wässrigen dispersion oder lösung eines polyurethans |
JP2000198920A (ja) * | 1999-01-06 | 2000-07-18 | Nippon Nsc Ltd | 水に分散が容易な新規なポリイソシアネ―ト組成物 |
JP2002256048A (ja) * | 2001-03-01 | 2002-09-11 | Asahi Denka Kogyo Kk | ノニオン性水分散型ポリウレタン組成物 |
CN1854165A (zh) * | 2005-04-20 | 2006-11-01 | 广州宏昌胶粘带厂 | 有机硅改性水性聚氨酯 |
CN101490197A (zh) * | 2006-07-12 | 2009-07-22 | 巴斯夫欧洲公司 | 含硅烷化合物作为添加剂的聚氨酯粘合剂 |
CN103059258A (zh) * | 2012-12-07 | 2013-04-24 | 青岛文创科技有限公司 | 一种有机硅改性水性聚氨酯乳液 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60255877A (ja) * | 1984-05-31 | 1985-12-17 | Nippon Urethane Service:Kk | 接着剤組成物 |
DE4136618A1 (de) * | 1991-11-07 | 1993-05-13 | Bayer Ag | Wasserdispergierbare polyisocyanatgemische |
JPH10198920A (ja) * | 1996-12-27 | 1998-07-31 | Victor Co Of Japan Ltd | 薄膜磁気ヘッドの摺動幅加工方法 |
US5861470A (en) | 1997-03-07 | 1999-01-19 | H. B. Fuller Licensing & Financing, Inc. | Two component water-based adhesives for use in dry-bond laminating |
JPH1160939A (ja) | 1997-08-18 | 1999-03-05 | Nippon Nsc Ltd | ポリウレタン水性分散液およびその製造方法 |
US5919860A (en) * | 1997-12-17 | 1999-07-06 | Bayer Corporation | Aqueous polyurethane/urea dispersions containing alkoxysilane groups |
DE19908562A1 (de) | 1998-03-25 | 1999-10-07 | Henkel Kgaa | Polyurethan und polyurethanhaltige Zubereitung |
BR9916355A (pt) | 1998-12-18 | 2001-09-11 | Eastman Chem Co | Composição de copoliéster, artigo conformado, e, processo para a manufatura de uma composição de poliéster |
TW510916B (en) * | 1998-12-21 | 2002-11-21 | Bayer Ag | Aqueous reacitve filler compositions |
CN1330681C (zh) * | 2003-03-20 | 2007-08-08 | 科尼希株式会社 | 硅烷化聚氨酯类水性组合物、和水性包封用粘接剂以及水性接触型粘接剂 |
JP4737923B2 (ja) | 2003-03-20 | 2011-08-03 | コニシ株式会社 | シリル化ウレタン系水性組成物、および水性ラッピング用接着剤並びに水性コンタクト型接着剤 |
JP4771276B2 (ja) | 2005-03-31 | 2011-09-14 | 日本ポリウレタン工業株式会社 | ラミネート用接着剤 |
JP4455472B2 (ja) | 2005-09-28 | 2010-04-21 | ローム アンド ハース カンパニー | 二成分アクリル‐ウレタン接着剤 |
WO2008112946A1 (en) | 2007-03-14 | 2008-09-18 | Sun Chemical Corporation | Water-based polyurethane pigmented coating |
EP2103648A1 (de) | 2008-03-20 | 2009-09-23 | Sika Technology AG | Feuchtigkeitshärtende Zusammensetzung mit guter Lagerstabilität und geringem Volumenschwund |
CN102504185A (zh) | 2011-11-01 | 2012-06-20 | 吴江市北厍盛源纺织品助剂厂 | 有机硅改性阴离子型水性聚氨酯涂层剂的制备方法 |
-
2013
- 2013-10-15 MX MX2016004543A patent/MX2016004543A/es unknown
- 2013-10-15 CN CN201380080186.XA patent/CN105612234B/zh active Active
- 2013-10-15 BR BR112016008007-6A patent/BR112016008007B1/pt active IP Right Grant
- 2013-10-15 JP JP2016521299A patent/JP6307601B2/ja active Active
- 2013-10-15 EP EP13895474.8A patent/EP3030622B1/en active Active
- 2013-10-15 US US15/029,055 patent/US10138401B2/en active Active
- 2013-10-15 WO PCT/CN2013/085205 patent/WO2015054822A1/en active Application Filing
- 2013-10-15 RU RU2016118663A patent/RU2660031C2/ru active
-
2014
- 2014-10-01 TW TW103134171A patent/TWI573851B/zh active
- 2014-10-01 AR ARP140103646A patent/AR097872A1/es active IP Right Grant
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993023490A1 (de) * | 1992-05-13 | 1993-11-25 | Henkel Kommanditgesellschaft Auf Aktien | Lagerstabiler kontaktklebstoff auf basis einer wässrigen dispersion oder lösung eines polyurethans |
JP2000198920A (ja) * | 1999-01-06 | 2000-07-18 | Nippon Nsc Ltd | 水に分散が容易な新規なポリイソシアネ―ト組成物 |
JP2002256048A (ja) * | 2001-03-01 | 2002-09-11 | Asahi Denka Kogyo Kk | ノニオン性水分散型ポリウレタン組成物 |
CN1854165A (zh) * | 2005-04-20 | 2006-11-01 | 广州宏昌胶粘带厂 | 有机硅改性水性聚氨酯 |
CN101490197A (zh) * | 2006-07-12 | 2009-07-22 | 巴斯夫欧洲公司 | 含硅烷化合物作为添加剂的聚氨酯粘合剂 |
CN103059258A (zh) * | 2012-12-07 | 2013-04-24 | 青岛文创科技有限公司 | 一种有机硅改性水性聚氨酯乳液 |
Non-Patent Citations (1)
Title |
---|
项尚林等: ""硅烷偶联剂对层压复合用WPU胶粘剂的改性研究"", 《粘接》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11485886B2 (en) | 2019-03-07 | 2022-11-01 | Dow Global Technologies Llc | Formaldehyde free adhesive composition |
CN111269686A (zh) * | 2020-04-03 | 2020-06-12 | 山东奥德美高分子材料有限公司 | 胶印用高牢度水性聚氨酯转移胶水 |
Also Published As
Publication number | Publication date |
---|---|
EP3030622A4 (en) | 2017-05-10 |
JP2016539205A (ja) | 2016-12-15 |
EP3030622A1 (en) | 2016-06-15 |
WO2015054822A1 (en) | 2015-04-23 |
TWI573851B (zh) | 2017-03-11 |
BR112016008007A8 (pt) | 2020-03-17 |
EP3030622B1 (en) | 2024-04-17 |
CN105612234B (zh) | 2019-10-25 |
BR112016008007A2 (pt) | 2017-08-01 |
US10138401B2 (en) | 2018-11-27 |
BR112016008007B1 (pt) | 2021-07-27 |
RU2016118663A (ru) | 2017-11-21 |
US20160257866A1 (en) | 2016-09-08 |
MX2016004543A (es) | 2016-08-03 |
JP6307601B2 (ja) | 2018-04-04 |
TW201529783A (zh) | 2015-08-01 |
AR097872A1 (es) | 2016-04-20 |
RU2660031C2 (ru) | 2018-07-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0606532B1 (en) | Silicone polyelectrolyte aqueous coating solution | |
KR102132308B1 (ko) | 열성형성 미소구체 물품 | |
CN104583353B (zh) | 脲基和聚氨基甲酸酯基压敏粘合剂共混物 | |
US20150183544A1 (en) | Label Application System | |
BR112019015345B1 (pt) | Composição adesiva sem solvente de dois componentes, estrutura de laminado e método para formar uma estrutura de laminado | |
CN105612234A (zh) | 粘合到箔片的方法 | |
JP2022119938A (ja) | アミン開始ポリオールを含む二成分無溶剤接着剤組成物を含む積層体を形成するための方法 | |
CN102026808A (zh) | 漆膜复合物及其制备和使用方法 | |
CN104789140A (zh) | 具有泡沫载体的自粘性制品 | |
JP2013539493A5 (zh) | ||
CN105891924B (zh) | 具有高温稳定性的柔性微球制品 | |
CN110945048B (zh) | 酸性指示剂系统 | |
EP3092130B1 (en) | Methods for marking substrates | |
CN105637049A (zh) | 粘合到箔片的方法 | |
TW201934711A (zh) | 用於黏附至聚合物阻隔基材之雙組分無溶劑黏著劑組合物 | |
TR201815449T4 (tr) | Sulu poliüretan dağılımlar. | |
JP2020045442A (ja) | 粘着剤および粘着シート | |
TWI792909B (zh) | 二液硬化型接著劑、積層膜、積層膜製造裝置、積層膜之製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |