CN105008595B - 通过直拉法制造铟掺杂硅 - Google Patents
通过直拉法制造铟掺杂硅 Download PDFInfo
- Publication number
- CN105008595B CN105008595B CN201380074084.7A CN201380074084A CN105008595B CN 105008595 B CN105008595 B CN 105008595B CN 201380074084 A CN201380074084 A CN 201380074084A CN 105008595 B CN105008595 B CN 105008595B
- Authority
- CN
- China
- Prior art keywords
- indium
- silicon
- dopant
- melt
- mrow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B15/00—Single-crystal growth by pulling from a melt, e.g. Czochralski method
- C30B15/02—Single-crystal growth by pulling from a melt, e.g. Czochralski method adding crystallising materials or reactants forming it in situ to the melt
- C30B15/04—Single-crystal growth by pulling from a melt, e.g. Czochralski method adding crystallising materials or reactants forming it in situ to the melt adding doping materials, e.g. for n-p-junction
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B15/00—Single-crystal growth by pulling from a melt, e.g. Czochralski method
- C30B15/20—Controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/02—Elements
- C30B29/06—Silicon
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/12—Active materials
- H10F77/122—Active materials comprising only Group IV materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/12—Active materials
- H10F77/122—Active materials comprising only Group IV materials
- H10F77/1223—Active materials comprising only Group IV materials characterised by the dopants
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/16—Material structures, e.g. crystalline structures, film structures or crystal plane orientations
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/70—Surface textures, e.g. pyramid structures
- H10F77/703—Surface textures, e.g. pyramid structures of the semiconductor bodies, e.g. textured active layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/547—Monocrystalline silicon PV cells
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Photovoltaic Devices (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITTO2012A001175 | 2012-12-31 | ||
| ITTO20121175 | 2012-12-31 | ||
| EP2013054878 | 2013-03-11 | ||
| EPPCT/EP2013/054875 | 2013-03-11 | ||
| EPPCT/EP2013/054878 | 2013-03-11 | ||
| EP2013054875 | 2013-03-11 | ||
| US201361838660P | 2013-06-24 | 2013-06-24 | |
| US61/838,660 | 2013-06-24 | ||
| PCT/US2013/078046 WO2014106080A1 (en) | 2012-12-31 | 2013-12-27 | Fabrication of indium-doped silicon by the czochralski method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105008595A CN105008595A (zh) | 2015-10-28 |
| CN105008595B true CN105008595B (zh) | 2018-04-13 |
Family
ID=51022087
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380074084.7A Active CN105008595B (zh) | 2012-12-31 | 2013-12-27 | 通过直拉法制造铟掺杂硅 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US10060045B2 (enExample) |
| JP (1) | JP2016503964A (enExample) |
| KR (1) | KR20150103703A (enExample) |
| CN (1) | CN105008595B (enExample) |
| TW (2) | TWI596240B (enExample) |
| WO (2) | WO2014106086A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104213185B (zh) * | 2014-08-20 | 2017-01-25 | 浙江晶盛机电股份有限公司 | 一种用于单晶硅生长炉的氩气分流装置 |
| CN108138354B (zh) * | 2015-05-01 | 2021-05-28 | 各星有限公司 | 生产被挥发性掺杂剂掺杂的单晶锭的方法 |
| US10184193B2 (en) | 2015-05-18 | 2019-01-22 | Globalwafers Co., Ltd. | Epitaxy reactor and susceptor system for improved epitaxial wafer flatness |
| US10145023B2 (en) * | 2015-07-17 | 2018-12-04 | Corner Star Limited | Methods for reducing deposits in ingot puller exhaust systems |
| US9640450B1 (en) * | 2015-10-23 | 2017-05-02 | Motech Industries Inc. | Method for reducing light-induced-degradation in manufacturing solar cell |
| US10487418B2 (en) | 2016-01-06 | 2019-11-26 | Globalwafers Co., Ltd. | Seed chuck assemblies and crystal pulling systems for reducing deposit build-up during crystal growth process |
| CN105821474B (zh) * | 2016-04-13 | 2018-01-09 | 江西赛维Ldk太阳能高科技有限公司 | 一种晶体硅的制备方法及晶体硅 |
| US20180087179A1 (en) * | 2016-09-28 | 2018-03-29 | Corner Star Limited | Single crystal silicon ingots having doped axial regions with different resistivity and methods for producing such ingots |
| KR102626492B1 (ko) * | 2016-11-14 | 2024-01-17 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 고광전변환효율 태양전지의 제조 방법 및 고광전변환효율 태양전지 |
| US10920337B2 (en) * | 2016-12-28 | 2021-02-16 | Globalwafers Co., Ltd. | Methods for forming single crystal silicon ingots with improved resistivity control |
| JP6699797B2 (ja) * | 2017-02-28 | 2020-05-27 | 株式会社Sumco | シリコン単結晶インゴットの製造方法およびシリコン単結晶インゴット |
| JP6862916B2 (ja) * | 2017-02-28 | 2021-04-21 | 株式会社Sumco | シリコン単結晶インゴットの製造方法およびシリコン単結晶育成装置 |
| DE102017220352B4 (de) | 2017-11-15 | 2023-02-02 | Siltronic Ag | Verfahren zum Überprüfen einer Vorrichtung zum Ziehen eines Einkristalls und Vorrichtung zum Ziehen eines Einkristalls |
| DE102018210317A1 (de) * | 2018-06-25 | 2020-01-02 | Siltronic Ag | Verfahren zur Herstellung eines Einkristalls aus Halbleitermaterial gemäß der FZ-Methode, Vorrichtung zur Durchführung des Verfahrens und Halbleiterscheibe aus Silizium |
| US11047066B2 (en) * | 2018-06-27 | 2021-06-29 | Globalwafers Co., Ltd. | Growth of plural sample rods to determine impurity build-up during production of single crystal silicon ingots |
| EP3864197B1 (en) * | 2018-10-12 | 2022-08-03 | GlobalWafers Co., Ltd. | Dopant concentration control in silicon melt to enhance the ingot quality |
| WO2020210129A1 (en) | 2019-04-11 | 2020-10-15 | Globalwafers Co., Ltd. | Process for preparing ingot having reduced distortion at late body length |
| JP2022529451A (ja) | 2019-04-18 | 2022-06-22 | グローバルウェーハズ カンパニー リミテッド | 連続チョクラルスキー法を用いる単結晶シリコンインゴットの成長方法 |
| CN110255863B (zh) * | 2019-07-22 | 2023-04-25 | 山东柔光新材料有限公司 | 一种柔性玻璃板根控制系统及其控制方法 |
| US11111597B2 (en) | 2019-09-13 | 2021-09-07 | Globalwafers Co., Ltd. | Methods for growing a nitrogen doped single crystal silicon ingot using continuous Czochralski method |
| US11111596B2 (en) | 2019-09-13 | 2021-09-07 | Globalwafers Co., Ltd. | Single crystal silicon ingot having axial uniformity |
| JP7285197B2 (ja) * | 2019-11-06 | 2023-06-01 | グローバルウェーハズ・ジャパン株式会社 | 単結晶引上方法及び単結晶引上装置 |
| CN113355739B (zh) * | 2021-05-12 | 2023-01-24 | 晶澳太阳能有限公司 | 单晶硅及其制备方法 |
| CN115491751A (zh) * | 2021-06-17 | 2022-12-20 | 内蒙古中环协鑫光伏材料有限公司 | 一种根据保护气体流量控制掺镓单晶电阻率的拉制工艺 |
| US11866845B2 (en) | 2022-01-06 | 2024-01-09 | Globalwafers Co., Ltd. | Methods for growing single crystal silicon ingots that involve silicon feed tube inert gas control |
| US12037698B2 (en) | 2022-01-06 | 2024-07-16 | Globalwafers Co., Ltd | Ingot puller apparatus having a flange that extends from the funnel or from the silicon feed tube |
| CN114808112B (zh) * | 2022-03-31 | 2024-09-20 | 上海新昇半导体科技有限公司 | 一种单晶生长方法及晶圆 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040069214A1 (en) * | 2002-10-15 | 2004-04-15 | Ill Soo Choi | Silicon single crystal growing furnace supplemented with low melting point dopant feeding instrument and a low melting point dopant feeding method thereof |
| CN1498988A (zh) * | 2002-10-31 | 2004-05-26 | �����ɷ� | 制造掺杂高挥发性异物的硅单晶的方法 |
| US20100071612A1 (en) * | 2007-05-10 | 2010-03-25 | Yasuhito Narushima | Method for manufacturing single crystal |
| CN101805925A (zh) * | 2010-02-20 | 2010-08-18 | 西安隆基硅材料股份有限公司 | 太阳能电池用掺镓铟单晶硅材料及其制备方法 |
| WO2012031136A2 (en) * | 2010-09-03 | 2012-03-08 | Gt Advanced Cz Llc | Silicon single crystal doped with gallium, indium, or aluminum |
Family Cites Families (21)
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|---|---|---|---|---|
| US4547258A (en) | 1982-12-22 | 1985-10-15 | Texas Instruments Incorporated | Deposition of silicon at temperatures above its melting point |
| JPS59156993A (ja) | 1983-02-23 | 1984-09-06 | Komatsu Denshi Kinzoku Kk | Cz単結晶のド−プ方法およびその装置 |
| DE4106589C2 (de) | 1991-03-01 | 1997-04-24 | Wacker Siltronic Halbleitermat | Kontinuierliches Nachchargierverfahren mit flüssigem Silicium beim Tiegelziehen nach Czochralski |
| US5406905A (en) | 1993-05-28 | 1995-04-18 | Simco/Ramic Corporation | Cast dopant for crystal growing |
| JPH08119787A (ja) | 1994-10-14 | 1996-05-14 | Komatsu Electron Metals Co Ltd | 連続チャージ法におけるドーパント供給方法およびドーパント組成物 |
| US6063188A (en) | 1998-05-20 | 2000-05-16 | Seh-America. Inc. | Crucible with differentially expanding release mechanism |
| DE10006589A1 (de) * | 1999-05-26 | 2000-12-07 | Samsung Electronics Co Ltd | Czochralski-Zugvorrichtungen und Zugverfahren zum Herstellen von monokristallinen Siliziumblöcken |
| US6815605B1 (en) * | 1999-05-28 | 2004-11-09 | Shin-Etsu Handotai Co., Ltd. | Silicon single crystal and wafer doped with gallium and method for producing them |
| DE19961126A1 (de) | 1999-12-17 | 2001-06-21 | Siemens Solar Gmbh | Siliziumkristall, insbesondere für Solarzellen, und Verfahren zur Herstellung |
| DE10007179B4 (de) | 2000-02-17 | 2004-08-19 | Siltronic Ag | Verfahren und Vorrichtung zum Dotieren einer Schmelze mit einem Dotierstoff |
| JP2001267610A (ja) * | 2000-03-17 | 2001-09-28 | Hitachi Ltd | 太陽電池 |
| JP2002057351A (ja) | 2000-08-15 | 2002-02-22 | Shin Etsu Handotai Co Ltd | 太陽電池セルの製造方法および太陽電池セル |
| JP2005272265A (ja) | 2004-03-26 | 2005-10-06 | Toshiba Ceramics Co Ltd | 単結晶引上装置 |
| JP4356517B2 (ja) | 2004-05-28 | 2009-11-04 | 株式会社Sumco | シリコン単結晶引上装置およびシリコン単結晶の製造方法 |
| EP1777753B1 (en) | 2005-10-21 | 2011-07-13 | Sumco Solar Corporation | SiGe Solar-cell single-crystal silicon substrate, SiGe solar cell element, and method for producing the same |
| US20090039478A1 (en) | 2007-03-10 | 2009-02-12 | Bucher Charles E | Method For Utilizing Heavily Doped Silicon Feedstock To Produce Substrates For Photovoltaic Applications By Dopant Compensation During Crystal Growth |
| JP5074826B2 (ja) | 2007-05-31 | 2012-11-14 | Sumco Techxiv株式会社 | ドーパントの注入方法、及びドーピング装置 |
| FR2929960B1 (fr) * | 2008-04-11 | 2011-05-13 | Apollon Solar | Procede de fabrication de silicium cristallin de qualite photovoltaique par ajout d'impuretes dopantes |
| DE102009034317A1 (de) | 2009-07-23 | 2011-02-03 | Q-Cells Se | Verfahren zur Herstellung durchbruchsicherer p-Typ Solarzellen aus umg-Silizium |
| JP2012066965A (ja) | 2010-09-24 | 2012-04-05 | Covalent Materials Corp | シリコン単結晶引上装置 |
| FI126401B (fi) | 2011-09-30 | 2016-11-15 | Aalto-Korkeakoulusäätiö | Menetelmä valon indusoiman degradaation vähentämiseksi piisubstraatissa sekä piisubstraattirakenne ja laite, jotka käsittävät piisubstraatin |
-
2013
- 2013-12-27 CN CN201380074084.7A patent/CN105008595B/zh active Active
- 2013-12-27 KR KR1020157020520A patent/KR20150103703A/ko not_active Ceased
- 2013-12-27 US US14/758,471 patent/US10060045B2/en active Active
- 2013-12-27 JP JP2015550811A patent/JP2016503964A/ja active Pending
- 2013-12-27 US US14/758,467 patent/US20150333193A1/en not_active Abandoned
- 2013-12-27 WO PCT/US2013/078056 patent/WO2014106086A1/en not_active Ceased
- 2013-12-27 WO PCT/US2013/078046 patent/WO2014106080A1/en not_active Ceased
- 2013-12-31 TW TW102149292A patent/TWI596240B/zh active
- 2013-12-31 TW TW102149294A patent/TW201438262A/zh unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040069214A1 (en) * | 2002-10-15 | 2004-04-15 | Ill Soo Choi | Silicon single crystal growing furnace supplemented with low melting point dopant feeding instrument and a low melting point dopant feeding method thereof |
| CN1498988A (zh) * | 2002-10-31 | 2004-05-26 | �����ɷ� | 制造掺杂高挥发性异物的硅单晶的方法 |
| US20100071612A1 (en) * | 2007-05-10 | 2010-03-25 | Yasuhito Narushima | Method for manufacturing single crystal |
| CN101805925A (zh) * | 2010-02-20 | 2010-08-18 | 西安隆基硅材料股份有限公司 | 太阳能电池用掺镓铟单晶硅材料及其制备方法 |
| WO2012031136A2 (en) * | 2010-09-03 | 2012-03-08 | Gt Advanced Cz Llc | Silicon single crystal doped with gallium, indium, or aluminum |
Non-Patent Citations (1)
| Title |
|---|
| An Improved Model for Analyzing Hole Mobility and Resistivity in p-Type Silicon Doped with Boron, Gallium, and Indium;L. C. Linares,et al.;《Journal of the electrochemical society》;19811231;第128卷(第3期);第601-608页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201432101A (zh) | 2014-08-16 |
| TW201438262A (zh) | 2014-10-01 |
| WO2014106080A1 (en) | 2014-07-03 |
| WO2014106086A1 (en) | 2014-07-03 |
| US20160215413A1 (en) | 2016-07-28 |
| CN105008595A (zh) | 2015-10-28 |
| KR20150103703A (ko) | 2015-09-11 |
| US20150333193A1 (en) | 2015-11-19 |
| JP2016503964A (ja) | 2016-02-08 |
| TWI596240B (zh) | 2017-08-21 |
| US10060045B2 (en) | 2018-08-28 |
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Address after: American Missouri Patentee after: SUNEDISON, Inc. Address before: Italy Novara Patentee before: MEMC Electronic Materials, Inc. |
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Effective date of registration: 20190315 Address after: 1703B-1706, 17th Floor, Global Trade Plaza, 1 West Austin Road, Kowloon, China Patentee after: SUNEDISON, Inc. Address before: American Missouri Patentee before: SUNEDISON, Inc. |
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Effective date of registration: 20230811 Address after: Room 205, West Zone, 2nd Floor, No. 707 Zhangyang Road, China (Shanghai) Pilot Free Trade Zone, Pudong New Area, Shanghai Patentee after: GCL New (Shanghai) Photovoltaic Technology Co.,Ltd. Address before: World Trade Plaza No. 1 Hongkong Kowloon Chinese Austin Road West 17 floor 1703B-1706 Patentee before: SUNEDISON, Inc. |
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