CN1042435C - 制备可再分散的核－壳聚合物粉末的方法 - Google Patents
制备可再分散的核－壳聚合物粉末的方法 Download PDFInfo
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- CN1042435C CN1042435C CN92105647A CN92105647A CN1042435C CN 1042435 C CN1042435 C CN 1042435C CN 92105647 A CN92105647 A CN 92105647A CN 92105647 A CN92105647 A CN 92105647A CN 1042435 C CN1042435 C CN 1042435C
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- acid
- shell
- gram
- methacrylic
- ester
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- 229920000642 polymer Polymers 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 42
- 239000000843 powder Substances 0.000 title claims abstract description 42
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- 230000008569 process Effects 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title description 14
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 239000000178 monomer Substances 0.000 claims description 50
- 238000006116 polymerization reaction Methods 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- 239000000126 substance Substances 0.000 claims description 28
- -1 2-EHA Chemical compound 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 27
- 239000002253 acid Substances 0.000 claims description 24
- 150000002148 esters Chemical class 0.000 claims description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 18
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 16
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 16
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 16
- 101150114104 CROT gene Proteins 0.000 claims description 15
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- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 12
- 238000013459 approach Methods 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 9
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 9
- 239000001530 fumaric acid Substances 0.000 claims description 9
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 9
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 9
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 8
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 6
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- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 6
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 4
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 claims description 4
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 4
- 125000005907 alkyl ester group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
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- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 claims description 3
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- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 claims description 3
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- XJRIDJAGAYGJCK-UHFFFAOYSA-N (1-acetyl-5-bromoindol-3-yl) acetate Chemical compound C1=C(Br)C=C2C(OC(=O)C)=CN(C(C)=O)C2=C1 XJRIDJAGAYGJCK-UHFFFAOYSA-N 0.000 claims description 2
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- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
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- 150000008065 acid anhydrides Chemical class 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
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- 238000006386 neutralization reaction Methods 0.000 claims description 2
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- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 2
- 150000005690 diesters Chemical class 0.000 claims 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- ZMARGGQEAJXRFP-UHFFFAOYSA-N 1-hydroxypropan-2-yl 2-methylprop-2-enoate Chemical compound OCC(C)OC(=O)C(C)=C ZMARGGQEAJXRFP-UHFFFAOYSA-N 0.000 claims 2
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims 2
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims 2
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims 2
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 claims 2
- 125000000746 allylic group Chemical group 0.000 claims 1
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- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 125000001844 prenyl group Chemical group [H]C([*])([H])C([H])=C(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000002769 thiazolinyl group Chemical group 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- UIYCHXAGWOYNNA-UHFFFAOYSA-N vinyl sulfide Chemical compound C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/902—Core-shell
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Developing Agents For Electrophotography (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Polymerisation Methods In General (AREA)
- Polyesters Or Polycarbonates (AREA)
- Medicinal Preparation (AREA)
- Dental Preparations (AREA)
- Liquid Crystal (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/728,398 US5403894A (en) | 1991-07-11 | 1991-07-11 | A redispersible core-shell polymer powder |
| US728,398 | 1991-07-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1068337A CN1068337A (zh) | 1993-01-27 |
| CN1042435C true CN1042435C (zh) | 1999-03-10 |
Family
ID=24926690
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92105647A Expired - Fee Related CN1042435C (zh) | 1991-07-11 | 1992-07-11 | 制备可再分散的核－壳聚合物粉末的方法 |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US5403894A (enExample) |
| EP (1) | EP0522791B1 (enExample) |
| JP (1) | JPH05194681A (enExample) |
| KR (1) | KR0149877B1 (enExample) |
| CN (1) | CN1042435C (enExample) |
| AT (1) | ATE135019T1 (enExample) |
| AU (1) | AU657965B2 (enExample) |
| BR (1) | BR9202580A (enExample) |
| CA (1) | CA2073154A1 (enExample) |
| CZ (1) | CZ217092A3 (enExample) |
| DE (1) | DE69208754T2 (enExample) |
| ES (1) | ES2086657T3 (enExample) |
| FI (1) | FI923192L (enExample) |
| HK (1) | HK160996A (enExample) |
| HU (1) | HU214105B (enExample) |
| IE (1) | IE922267A1 (enExample) |
| IL (1) | IL102469A (enExample) |
| MX (1) | MX9204036A (enExample) |
| NO (1) | NO922664L (enExample) |
| NZ (1) | NZ243439A (enExample) |
| PL (1) | PL171898B1 (enExample) |
| SI (1) | SI9200144A (enExample) |
| SK (1) | SK217092A3 (enExample) |
| TW (1) | TW219367B (enExample) |
| ZA (1) | ZA924957B (enExample) |
Families Citing this family (87)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5212251A (en) * | 1990-09-24 | 1993-05-18 | Rohm And Haas Company | Alkali-resistant core-shell polymers |
| US5328952A (en) * | 1992-02-14 | 1994-07-12 | Rohm And Haas Company | Multi-stage polymer latex cement modifier and process of making |
| WO1994004581A1 (en) * | 1992-08-13 | 1994-03-03 | Ppg Industries, Inc. | Waterborne latices adapted for spray application |
| EP0695339A4 (en) * | 1993-04-21 | 1997-05-07 | Copytele Inc | BLACK AND WHITE ELECTROPHORETIC PARTICLES AND THEIR MANUFACTURING METHOD |
| GB9316221D0 (en) * | 1993-08-05 | 1993-09-22 | Zeneca Ltd | Production of polymer emulsions |
| US5714539A (en) * | 1993-10-04 | 1998-02-03 | Ppg Industries, Inc. | Polymeric surfactant and latex made therefrom |
| KR0177182B1 (ko) * | 1993-10-20 | 1999-05-15 | 최근선 | 중공구조를 갖는 유화중합체의 제조방법 |
| EP0654454A1 (en) * | 1993-11-22 | 1995-05-24 | Rohm And Haas Company | A core-shell polymer powder |
| GB9408725D0 (en) * | 1994-05-03 | 1994-06-22 | Zeneca Resins Bv | Production of aqueous polymer compositions |
| US5476897A (en) * | 1994-10-17 | 1995-12-19 | The Goodyear Tire & Rubber Company | Process for the production of high solids latex |
| FR2726828A1 (fr) * | 1994-11-10 | 1996-05-15 | Rohm & Haas France | Additifs dispersants ameliorant l'indice de viscosite pour huiles lubrifiantes |
| FR2729150A1 (fr) * | 1995-01-06 | 1996-07-12 | Rhone Poulenc Chimie | Poudres redispersables dans l'eau de polymeres filmogenes a structure "coeur/ecorce" |
| DE69520423T2 (de) * | 1995-01-06 | 2001-10-18 | Rohm And Haas Co., Philadelphia | Wasserdispergierbare Pulverzusammensetzung für wasserbeständige Überzugsmittel |
| EP0725092A3 (de) * | 1995-02-06 | 1997-08-27 | Chemie Linz Gmbh | Redispergierbare, pulverförmige Kern-Mantel-Polymere, deren Herstellung und Verwendung |
| US5606015A (en) * | 1995-02-16 | 1997-02-25 | Rohm And Haas Company | Polymer powder stability |
| US5563187A (en) * | 1995-02-16 | 1996-10-08 | Rohm And Haas Company | Grafted polymer composition |
| DE19506331A1 (de) * | 1995-02-23 | 1996-08-29 | Chemie Linz Deutschland Gmbh I | Redispergierbare, pulverförmige Kern-Mantel-Polymere, deren Herstellung und Verwendung |
| US6090892A (en) * | 1995-07-17 | 2000-07-18 | Mitsui Toatsu Chemicals, Inc. | Redispersible polymer and production process thereof |
| US5739196A (en) * | 1995-11-30 | 1998-04-14 | Union Carbide Chemicals & Plastics Technology Corporation | Latex compositions having wet adhesion and other improved rheological properties and methods of producing same |
| US5776651A (en) * | 1996-01-31 | 1998-07-07 | Minnesota Mining & Manufacturing Company | Laminable proofing elements |
| DE19614844A1 (de) * | 1996-04-15 | 1997-10-16 | Basf Ag | Formmassen zur Herstellung von Formteilen mit vermindertem Oberflächenglanz |
| DE19644309A1 (de) * | 1996-10-24 | 1998-04-30 | Basf Ag | Pulverförmiger Klebstoff |
| DE19710109A1 (de) * | 1997-03-12 | 1998-09-17 | Clariant Gmbh | Heißsiegelklebstoff |
| DE19710382A1 (de) * | 1997-03-13 | 1998-09-17 | Buna Sow Leuna Olefinverb Gmbh | Radispergierbare Dispersionspulver auf Basis von Polyacrylaten |
| DE19710381A1 (de) * | 1997-03-13 | 1998-09-17 | Buna Sow Leuna Olefinverb Gmbh | Redispergierbare Dispersionspulver auf Basis von Polyacrylaten |
| US5782972A (en) * | 1997-03-21 | 1998-07-21 | W.R. Grace & Co.-Conn. | Additive for production of highly workable mortar cement |
| US6147165A (en) | 1997-03-31 | 2000-11-14 | Avery Dennison Corporation | Pressure-sensitive adhesives for marking films |
| US5895801A (en) * | 1997-03-31 | 1999-04-20 | Avery Dennison Corporation | Pressure-sensitive adhesives for marking films |
| US6107382A (en) * | 1997-07-31 | 2000-08-22 | Avery Dennison Corporation | Process for the production of improved PSA's |
| US6306982B1 (en) | 1997-07-31 | 2001-10-23 | Avery Dennison Corporation | Process for the production of general purpose PSA's |
| FR2767835B1 (fr) * | 1997-08-28 | 2003-09-12 | Atochem Elf Sa | Latex ne contenant ni composes organiques volatils ni agents de coalescence et pouvant former un film a basse temperature |
| DE19741184A1 (de) | 1997-09-18 | 1999-03-25 | Basf Ag | Verfahren zur Verminderung von Restmonomeren in Flüssigsystemen unter Zugabe eines Redoxinitiatorsystems |
| US5932515A (en) * | 1997-11-25 | 1999-08-03 | The Mead Corporation | Recording paper incorporating hollow spherical plastic pigment |
| DE19756474A1 (de) * | 1997-12-18 | 1999-06-24 | Buna Sow Leuna Olefinverb Gmbh | Redispergierbare Polymerisatpulver |
| DE19824650A1 (de) * | 1998-05-24 | 1999-11-25 | Bodmeier Roland | Redispergierbare Polymerpulver |
| US6020438A (en) * | 1998-06-09 | 2000-02-01 | The B. F. Goodrich Company | Supported vinyl chloride emulsion (co) polymers and process for making the same |
| DE19833062A1 (de) * | 1998-07-22 | 2000-02-03 | Elotex Ag Sempach Station | Redispergierbares Pulver und dessen wäßrige Dispersion, Verfahren zur Herstellung sowie Verwendung |
| DE19833066A1 (de) * | 1998-07-22 | 2000-02-03 | Elotex Ag Sempach Station | Verfahren zur Herstellung wäßriger Dispersionen von (Co-)Polymerisaten, die danach erhältlichen Dispersionen, aus den Dispersionen erhältliche redispergierbare Pulver sowie deren Verwendung |
| DE69943379D1 (de) | 1998-11-23 | 2011-06-01 | Grace W R & Co | Verbesserte verarbeitung und lebensdauer von mörtelplatten aus maurermörtel und verfahren zu dessen herstellung |
| AU771383B2 (en) | 1998-12-08 | 2004-03-18 | Rohm And Haas Company | Dirt pickup resistant coating binder and coatings |
| JP2002534540A (ja) * | 1998-12-30 | 2002-10-15 | ザ ビー．エフ．グッドリッチ カンパニー | ケラチン質基質処理用分岐状／ブロックコポリマー |
| DE19929008A1 (de) * | 1999-06-24 | 2001-01-11 | Wacker Polymer Systems Gmbh | Verfahren zur Herstellung von in Wasser redispergierbaren Vinylaromat-Mischpolymerisat- Redispersionspulvern |
| US6531183B1 (en) * | 1999-07-28 | 2003-03-11 | Meadwestvaco Corporation | Method of producing high gloss paper |
| GB9919304D0 (en) | 1999-08-17 | 1999-10-20 | Ici Plc | Acrylic composition |
| US7008901B2 (en) | 2000-01-19 | 2006-03-07 | Mitsui Chemicals, Inc. | Emulsion for thermal recording material and thermal recording materials made by using the same |
| CN1195642C (zh) * | 2000-01-19 | 2005-04-06 | 三井化学株式会社 | 感热记录材料用的乳液和用它制得的感热记录材料 |
| GB0001752D0 (en) * | 2000-01-27 | 2000-03-15 | Ciba Spec Chem Water Treat Ltd | Particulate compositions and their manufacture |
| US6410005B1 (en) | 2000-06-15 | 2002-06-25 | Pmd Holdings Corp. | Branched/block copolymers for treatment of keratinous substrates |
| US6391973B1 (en) * | 2000-07-24 | 2002-05-21 | Basf Corporation | Curable coating composition with improved stability |
| TWI231305B (en) * | 2000-10-25 | 2005-04-21 | Rohm & Haas | High rubber impact modifier powders |
| US20030225190A1 (en) * | 2002-04-26 | 2003-12-04 | Janos Borbely | Polymeric product for film formation |
| WO2004099261A1 (en) * | 2003-05-06 | 2004-11-18 | Nuplex Resins B.V. | Emulsion polymerization process, polymer dispersion and film-forming composition |
| US7825173B2 (en) * | 2005-04-29 | 2010-11-02 | E.I. Du Pont De Nemours And Company | Process for the production of aqueous binder latices |
| DE102006009840A1 (de) * | 2006-03-01 | 2007-09-06 | Röhm Gmbh | Additive Baustoffmischungen mit Mikrovollpartikeln |
| KR100864007B1 (ko) * | 2006-03-07 | 2008-10-16 | 주식회사 엘지화학 | 아크릴계 재유화형 수지, 그 제조방법, 및 이를 포함하는시멘트 조성물 |
| US8529694B2 (en) | 2006-10-26 | 2013-09-10 | Air Products And Chemicals, Inc. | Powdered acetylenic surfactants and compositions containing them |
| CN101168584B (zh) * | 2007-09-28 | 2010-10-06 | 上海东升新材料有限公司 | 可再分散乳胶粉乳液和可再分散乳胶粉及其制备方法 |
| US8726580B1 (en) * | 2007-10-15 | 2014-05-20 | Christopher M. Hunt | Standing seam cementitious roof |
| US20090098345A1 (en) * | 2007-10-15 | 2009-04-16 | Brasher Jon H | Polymer-coated construction component and method |
| US20100047553A1 (en) * | 2008-08-20 | 2010-02-25 | Brasher Jon H | Coating Reinforcement Apparatus and Method |
| CN101550218B (zh) * | 2009-04-03 | 2012-08-08 | 江苏工业学院 | 一种聚合物乳液及制备方法和可再分散乳胶粉 |
| TWI483953B (zh) | 2009-06-30 | 2015-05-11 | Lubrizol Advanced Mat Inc | 複合聚合物乳化液 |
| US9200155B2 (en) | 2011-06-23 | 2015-12-01 | Dow Global Technologies Llc | Water redispersible epoxy polymer powder and method for making the same |
| PL2791077T3 (pl) | 2011-12-15 | 2019-09-30 | Dow Global Technologies Llc | Formulacje suchej mieszanki zawierające redyspergowalne proszki karboksylowanego polimeru styren-butadien i cementy zawierające duże ilości tlenku glinu |
| US9169382B2 (en) | 2012-03-09 | 2015-10-27 | Dow Global Technologies Llc | Carboxyl group containing acrylic RDP and dry mix cement formulations containing them |
| US10150008B1 (en) | 2017-11-15 | 2018-12-11 | Acushnet Company | Golf balls incorporating mixtures of a thermoplastic polymer and polymethyl methacrylate-based polymers |
| US10814180B2 (en) | 2017-11-15 | 2020-10-27 | Acushnet Company | Golf balls incorporating thermoplastic blend(s) of ionomer(s), thermoplastic polymer(s), and polymethyl methacrylate-based polymer(s) |
| US10500444B2 (en) | 2012-04-20 | 2019-12-10 | Acushnet Company | Golf balls incorporating thermoplastic blend(s) of ionomer(s), thermoplastic polymer(s), and PEPA |
| KR101301736B1 (ko) * | 2012-06-20 | 2013-08-29 | 장수관 | 폴리머 시멘트, 그 제조방법 및 그 폴리머 시멘트를 이용한 복합 방수 시공 방법 |
| CN103665776A (zh) * | 2012-09-06 | 2014-03-26 | 杜邦公司 | 阻燃剂共聚醚酯组合物和包含其的物品 |
| CN104703941B (zh) * | 2012-09-28 | 2017-03-08 | 罗门哈斯公司 | 适用于具有改进特性的干式混合配制品的可再分散聚合物粉末混合物 |
| EP2882804B1 (en) * | 2012-09-28 | 2016-08-31 | Rohm and Haas Company | Redispersible polymer powder mixtures for use in dry-mix formulations |
| CN104822734B (zh) | 2012-10-03 | 2017-06-20 | 陶氏环球技术有限公司 | 展现改进的存放稳定性的碱溶性树脂(asr)壳环氧树脂rdp |
| JP6291507B2 (ja) * | 2012-12-18 | 2018-03-14 | ダウ グローバル テクノロジーズ エルエルシー | 非セメント系外装仕上げ組成物のためのアクリル再分散可能なポリマー粉体 |
| WO2014111292A1 (en) | 2013-01-18 | 2014-07-24 | Basf Se | Acrylic dispersion-based coating compositions |
| JP6506012B2 (ja) | 2013-12-09 | 2019-04-24 | ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ | 改善された加工性を有する非セメント系有機下塗材配合物 |
| IN2014DE03244A (enExample) | 2013-12-10 | 2015-07-17 | Dow Global Technologies Llc | |
| US9688800B2 (en) | 2014-07-07 | 2017-06-27 | Columbia Insurance Company | Sequentially polymerized hybrid latex |
| KR102027935B1 (ko) * | 2017-01-20 | 2019-11-04 | 한화케미칼 주식회사 | 알칼리 수용성 수지, 이의 제조 방법 및 알칼리 수용성 수지를 포함하는 에멀젼 중합체 |
| US10493326B2 (en) | 2017-11-15 | 2019-12-03 | Acushnet Company | Golf balls incorporating thermoplastic blend(s) of ionomer(s), thermoplastic polymer(s), and ABS and/or ASA |
| US10427004B2 (en) | 2017-11-15 | 2019-10-01 | Acushnet Company | Golf balls incorporating thermoplastic blends(s) of ionomer(s), thermoplastic polymer(s), PGM reactive crosslinker(s), and catalyst(s) |
| CN110872367B (zh) * | 2018-09-04 | 2023-10-03 | 罗门哈斯公司 | 多级聚合物颗粒的水分散体 |
| WO2020198343A1 (en) * | 2019-03-26 | 2020-10-01 | Dow Global Technologies Llc | Cement modifier compositions |
| CN112573885A (zh) * | 2020-12-12 | 2021-03-30 | 南京霄祥工程技术有限公司 | 一种自流平砂浆及其制备方法 |
| KR20250121009A (ko) * | 2021-12-16 | 2025-08-11 | 오가닉 킴야 사나이 베 틱. 에이.에스. | 수분산 중합체 조성물 및 이의 제조 방법 |
| CN116554608A (zh) * | 2023-05-04 | 2023-08-08 | 博特尔包装(江苏)有限公司 | 一种可降解聚苯乙烯包装材料的制备工艺 |
| CN119775501A (zh) * | 2025-01-02 | 2025-04-08 | 万华化学集团股份有限公司 | 一种热塑性树脂改性剂的制备方法与应用 |
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|---|---|---|---|---|
| JPS5443285A (en) * | 1977-09-13 | 1979-04-05 | Asahi Chem Ind Co Ltd | Production of synthetic resin emulsion for cement |
| US4876313A (en) * | 1986-08-29 | 1989-10-24 | Rohm And Haas Company | Grafted core-shell polymer compositions using polyfunctional compounds |
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|---|---|---|---|---|
| JPS5339387A (en) * | 1976-09-24 | 1978-04-11 | Nippon Jiyunyaku Kk | Method of making aquaous emulsion polymer |
| JPS53117033A (en) * | 1977-03-23 | 1978-10-13 | Toyo Ink Mfg Co Ltd | Adhesive composition |
| US4468498A (en) * | 1980-06-12 | 1984-08-28 | Rohm And Haas Company | Sequential heteropolymer dispersion and a particulate materal obtainable therefrom, useful in coating compositions as a thickening and/or opacifying agent |
| US4916171A (en) * | 1984-07-25 | 1990-04-10 | Rohm And Haas Company | Polymers comprising alkali-insoluble core/alkali-soluble shell and copositions thereof |
| US4894397A (en) * | 1988-04-21 | 1990-01-16 | S. C. Johnson & Son, Inc. | Stable emulsion polymers and methods of preparing same |
-
1991
- 1991-07-11 US US07/728,398 patent/US5403894A/en not_active Expired - Lifetime
-
1992
- 1992-06-30 AU AU18693/92A patent/AU657965B2/en not_active Ceased
- 1992-07-01 AT AT92306097T patent/ATE135019T1/de not_active IP Right Cessation
- 1992-07-01 DE DE69208754T patent/DE69208754T2/de not_active Expired - Fee Related
- 1992-07-01 ES ES92306097T patent/ES2086657T3/es not_active Expired - Lifetime
- 1992-07-01 EP EP92306097A patent/EP0522791B1/en not_active Expired - Lifetime
- 1992-07-03 NZ NZ243439A patent/NZ243439A/en unknown
- 1992-07-03 ZA ZA924957A patent/ZA924957B/xx unknown
- 1992-07-03 CA CA002073154A patent/CA2073154A1/en not_active Abandoned
- 1992-07-07 NO NO92922664A patent/NO922664L/no unknown
- 1992-07-09 MX MX9204036A patent/MX9204036A/es not_active IP Right Cessation
- 1992-07-10 PL PL92295245A patent/PL171898B1/pl unknown
- 1992-07-10 IL IL10246992A patent/IL102469A/en not_active IP Right Cessation
- 1992-07-10 SK SK2170-92A patent/SK217092A3/sk unknown
- 1992-07-10 HU HU9202284A patent/HU214105B/hu not_active IP Right Cessation
- 1992-07-10 BR BR929202580A patent/BR9202580A/pt not_active IP Right Cessation
- 1992-07-10 CZ CS922170A patent/CZ217092A3/cs unknown
- 1992-07-10 FI FI923192A patent/FI923192L/fi not_active Application Discontinuation
- 1992-07-10 KR KR1019920012262A patent/KR0149877B1/ko not_active Expired - Fee Related
- 1992-07-10 JP JP4184088A patent/JPH05194681A/ja active Pending
- 1992-07-10 SI SI19929200144A patent/SI9200144A/sl unknown
- 1992-07-10 IE IE226792A patent/IE922267A1/en not_active Application Discontinuation
- 1992-07-11 CN CN92105647A patent/CN1042435C/zh not_active Expired - Fee Related
- 1992-08-15 TW TW081106460A patent/TW219367B/zh active
-
1996
- 1996-08-29 HK HK160996A patent/HK160996A/en not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5443285A (en) * | 1977-09-13 | 1979-04-05 | Asahi Chem Ind Co Ltd | Production of synthetic resin emulsion for cement |
| US4876313A (en) * | 1986-08-29 | 1989-10-24 | Rohm And Haas Company | Grafted core-shell polymer compositions using polyfunctional compounds |
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