CN103804988A - Heat-resistant and oxidation-resistant printing ink and preparation method thereof - Google Patents
Heat-resistant and oxidation-resistant printing ink and preparation method thereof Download PDFInfo
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- CN103804988A CN103804988A CN201310523633.6A CN201310523633A CN103804988A CN 103804988 A CN103804988 A CN 103804988A CN 201310523633 A CN201310523633 A CN 201310523633A CN 103804988 A CN103804988 A CN 103804988A
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Abstract
The invention discloses a heat-resistant and oxidation-resistant printing ink prepared from the following raw materials in parts by weight: 12-15 parts of sec-butyl acetate, 12-14 parts of polyketone resin, 5-9 parts of propylene glycol, 1-3 parts of fluorescent powder, 3-4 parts of microcrystalline wax, 34-40 parts of long oil alkyd resin, 10-12 parts of tripropylene glycol diacrylate, 1-2 parts of europium trifluoro-2,4-pentanedionate, 1-3 parts of tetrahydrofuran, 10-12 parts of trimethylolpropane triacrylate, 8-10 parts of dipentaerythritol hexaacrylate, 10-15 parts of aluminum nitride, 1-2 parts of dibutyltin dilaurate, 1-2 parts of tert-butyl peroxypivalate, 3-4 parts of organic pigment and 4-5 parts of auxiliaries. The printing ink disclosed by the invention has strong adhesive force for a plastic film; in addition, due to the addition of europium trifluoro-2,4-pentanedionate and tetrahydrofuran, the printing ink also has the characteristics of flame retardance, corrosion resistance, high glossiness, oil resistance, wear resistance and good low temperature performance; the polyketone resin is polymerized with various monomers, so that the chemicals resistance, light resistance and weather resistance of the printing ink are improved. The printing ink is a preferable printing ink for a high-grade plastic film.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of heat-resistant oxidized printing-ink and preparation method thereof.
Background technology
The color (form and aspect) of ink, body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely make low-melting ink vehicle with resin and solvent or water etc.These are all that the type and the drying means etc. that are stock, printing process, printing plate according to the object of printing decide.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of heat-resistant oxidized printing-ink and preparation method thereof, this ink adhesion power is strong, fast light, weather, low-temperature performance are good.
Technical scheme of the present invention is as follows:
A kind of plastics film fluorescent ink, is characterized in that being made up of the raw material of following weight part: sec-butyl acetate 12-15, polyketone resin 12-14, propylene glycol 5-9, fluorescent material 1-3, microcrystalline wax 3-4, long oil alkyd 34-40, tri (propylene glycol) diacrylate 10-12, trifluoroacetylacetone europium 1-2, tetrahydrofuran (THF) 1-3, Viscoat 295 10-12, double pentaerythritol methacrylate 8-10, aluminium nitride 10-15, dibutyl tin laurate 1-2, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, tri (propylene glycol) diacrylate 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, to obtain final product.
The preparation method of described heat-resistant oxidized printing-ink, it is characterized in that comprising the following steps: by sec-butyl acetate, polyketone resin, propylene glycol, microcrystalline wax, long oil alkyd mixes, under 1000-1400 rev/min of stirring, speed with 5-8 ℃/point is heated to 60-80 ℃, add dibutyl tin laurate, the peroxidation trimethylacetic acid tert-butyl ester, stirring reaction 10-20 minute, add tri (propylene glycol) diacrylate, trifluoroacetylacetone europium, Viscoat 295, double pentaerythritol methacrylate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
Ink of the present invention has very strong adhesive power to plastics film, and by using trifluoroacetylacetone europium, tetrahydrofuran (THF), and that this ink also has is fire-retardant, corrosion-resistant, glossiness is high, oil resistant, the feature that wear-resisting, low-temperature performance is good; By using polyketone resin and various of monomer polymerization, make the chemicals-resistant of ink, fast light, weathering resistance increase, be the preferred ink of high-grade plastics film.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A kind of plastics film fluorescent ink, by following weight part (kilogram) raw material make: sec-butyl acetate 14, polyketone resin 13, propylene glycol 7, fluorescent material 2, microcrystalline wax 3.5, long oil alkyd 37, tri (propylene glycol) diacrylate 11, trifluoroacetylacetone europium 1.5, tetrahydrofuran (THF) 2, Viscoat 295 11, double pentaerythritol methacrylate 9, aluminium nitride 13, dibutyl tin laurate 1.5, the peroxidation trimethylacetic acid tert-butyl ester 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, tri (propylene glycol) diacrylate 2.5, methacrylic acid-2-hydroxy methacrylate 2.5, tea-polyphenol 2.5, glyceryl monostearate 4.6, p-tert-butyl benzoic acid 1.4, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.4, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 26 minutes, then adds other remaining component, is warming up to 84 ℃, stirs 38 minutes, to obtain final product.
The preparation method of described heat-resistant oxidized printing-ink, comprise the following steps: by sec-butyl acetate, polyketone resin, propylene glycol, microcrystalline wax, long oil alkyd mixes, under 1300 revs/min of stirrings, be heated to 70 ℃ with the speed of 7 ℃/point, add dibutyl tin laurate, the peroxidation trimethylacetic acid tert-butyl ester, stirring reaction 15 minutes, add tri (propylene glycol) diacrylate, trifluoroacetylacetone europium, Viscoat 295, double pentaerythritol methacrylate, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.8 hours, grinding distribution becomes the slurry of 30 μ m, obtain.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a plastics film fluorescent ink, is characterized in that being made up of the raw material of following weight part: sec-butyl acetate 12-15, polyketone resin 12-14, propylene glycol 5-9, fluorescent material 1-3, microcrystalline wax 3-4, long oil alkyd 34-40, tri (propylene glycol) diacrylate 10-12, trifluoroacetylacetone europium 1-2, tetrahydrofuran (THF) 1-3, Viscoat 295 10-12, double pentaerythritol methacrylate 8-10, aluminium nitride 10-15, dibutyl tin laurate 1-2, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, tri (propylene glycol) diacrylate 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, to obtain final product.
2. the preparation method of heat-resistant oxidized printing-ink according to claim 1, it is characterized in that comprising the following steps: by sec-butyl acetate, polyketone resin, propylene glycol, microcrystalline wax, long oil alkyd mixes, under 1000-1400 rev/min of stirring, speed with 5-8 ℃/point is heated to 60-80 ℃, add dibutyl tin laurate, the peroxidation trimethylacetic acid tert-butyl ester, stirring reaction 10-20 minute, add tri (propylene glycol) diacrylate, trifluoroacetylacetone europium, Viscoat 295, double pentaerythritol methacrylate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310523633.6A CN103804988A (en) | 2013-10-30 | 2013-10-30 | Heat-resistant and oxidation-resistant printing ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310523633.6A CN103804988A (en) | 2013-10-30 | 2013-10-30 | Heat-resistant and oxidation-resistant printing ink and preparation method thereof |
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| CN103804988A true CN103804988A (en) | 2014-05-21 |
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| CN201310523633.6A Pending CN103804988A (en) | 2013-10-30 | 2013-10-30 | Heat-resistant and oxidation-resistant printing ink and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194470A (en) * | 2014-07-28 | 2014-12-10 | 蚌埠德美过滤技术有限公司 | Anti-abrasive plant printing ink |
| CN104877435A (en) * | 2015-04-27 | 2015-09-02 | 安徽宏洋包装集团有限公司 | green tea seed powder-containing flame-retardant low-odor printing ink |
| CN105273488A (en) * | 2014-07-23 | 2016-01-27 | 天津恒和包装印刷有限公司 | Antibacterial printing ink and preparation method thereof |
| CN106046929A (en) * | 2016-08-02 | 2016-10-26 | 安徽美翔塑业有限公司 | Printing ink for plastic film |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002188026A (en) * | 2000-10-11 | 2002-07-05 | Hitachi Maxell Ltd | Aqueous fluorescent ink composition |
| JP2003201425A (en) * | 2000-10-11 | 2003-07-18 | Hitachi Maxell Ltd | Water-based fluorescent ink composition |
| CN1454947A (en) * | 2002-04-30 | 2003-11-12 | 大日本油墨化学工业株式会社 | Ultraviolet-ray solidified ink and printed matter using same |
| CN103319941A (en) * | 2013-06-05 | 2013-09-25 | 苏州凹凸彩印厂 | Ink for plastic films and preparation method thereof |
-
2013
- 2013-10-30 CN CN201310523633.6A patent/CN103804988A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002188026A (en) * | 2000-10-11 | 2002-07-05 | Hitachi Maxell Ltd | Aqueous fluorescent ink composition |
| JP2003201425A (en) * | 2000-10-11 | 2003-07-18 | Hitachi Maxell Ltd | Water-based fluorescent ink composition |
| CN1454947A (en) * | 2002-04-30 | 2003-11-12 | 大日本油墨化学工业株式会社 | Ultraviolet-ray solidified ink and printed matter using same |
| CN103319941A (en) * | 2013-06-05 | 2013-09-25 | 苏州凹凸彩印厂 | Ink for plastic films and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273488A (en) * | 2014-07-23 | 2016-01-27 | 天津恒和包装印刷有限公司 | Antibacterial printing ink and preparation method thereof |
| CN104194470A (en) * | 2014-07-28 | 2014-12-10 | 蚌埠德美过滤技术有限公司 | Anti-abrasive plant printing ink |
| CN104877435A (en) * | 2015-04-27 | 2015-09-02 | 安徽宏洋包装集团有限公司 | green tea seed powder-containing flame-retardant low-odor printing ink |
| CN106046929A (en) * | 2016-08-02 | 2016-10-26 | 安徽美翔塑业有限公司 | Printing ink for plastic film |
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Application publication date: 20140521 |
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