CN106634717A - Anti-corrosive high-viscosity binder and preparation method thereof - Google Patents
Anti-corrosive high-viscosity binder and preparation method thereof Download PDFInfo
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- CN106634717A CN106634717A CN201610818873.2A CN201610818873A CN106634717A CN 106634717 A CN106634717 A CN 106634717A CN 201610818873 A CN201610818873 A CN 201610818873A CN 106634717 A CN106634717 A CN 106634717A
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- acrylic resin
- resin
- binding agent
- ethyoxyl
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an anti-corrosive high-viscosity binder and a preparation method thereof. The anti-corrosive high-viscosity binder is composed of, by weight part, 22-27 parts of epoxy-modified hydroxy-acrylic resin, 22-28 parts of thermoplastic acrylic resin, 18-23 parts of organosilicone-modified acrylic resin, 8-12 parts of 6-ethyoxyl-2,2,4-trimethyl-1,2-dihydroquinoline, 7-11 parts of melamine resin, 5-9 parts of phenyl trichlorosilane, 8-12 parts of 2,4-dichlorobenzoyl peroxide, 2-7 parts of vinyl trimethoxy silane, 5-8 parts of titanium dioxide and 3-6 parts of attapulgite powder. The anti-corrosive high-viscosity binder obtained through the preparation method is high in strength and good in stability and achieves a cross-linked structure excellent in heat resistance and corrosion resistance and high in binding and mechanical performance and the like, thereby greatly improving the anti-aging performance and widening the thermal adapting range.
Description
Technical field
The present invention relates to industrial materials field, more particularly to a kind of high binding agent of anticorrosive viscosity and preparation method thereof.
Background technology
Binding agent is the guarantee of adhesion strength between abrasive material and matrix.With the development of chemical engineering industry, various novel bondings
Agent enters coated abrasive tool field, improves the performance of coated abrasive tool, promotes coated abrasive tool industrial expansion.Binding agent except
Outside sizing material, also including auxiliary elements such as solvent, curing agent, toughener, preservative, colouring agent, defoamers.Binding agent is except most normal
Outside animal glue, also including synthetic resin, rubber and paint.
Thermoplastic resin modified epoxy resin has preferable heat resistance.It is presently used for the heat of flexibilizing epoxy adhesive
Plastic resin mainly has Pioloform, polyvinyl acetal, poly- carbonic acid vinegar, nylon, poly- maple etc..Pioloform, polyvinyl acetal is thermoplastic linear's high score
Son, it is good with the compatibility of epoxy resin.Due to there is Jing bases in its molecule, etherification reaction can be carried out with epoxy resin, so as to
Play the effect of toughness reinforcing.Have in prior art with Pioloform, polyvinyl acetal as " framework material ", be made up of sizing with E5 epoxy resin
A kind of new structure glue.Also prepared with organic siliconresin and the composite modified epoxy E-42 of polyvinyl butyral resin in prior art
Go out a kind of new epoxy structural rubber.But existing above-mentioned binding agent has that Acclimation temperature scope is little, shear strength is low, resistance to
Long property is poor, the shortcoming of poor toughness.
The content of the invention
For above-mentioned problems of the prior art, it is an object of the invention to provide a kind of anticorrosive viscosity is high gluing
Knot agent and preparation method thereof.
A kind of high binding agent of anticorrosive viscosity, raw material are constituted according to following portion rate：
Epoxy modified hydroxyl acrylic resin 22-27 parts, thermoplastic acrylic resin 22-28 parts, organosilicon-modified acrylic tree
Fat 18-23 parts, 6- ethyoxyl -2,2,4- trimethyl -1,2- dihyaroquinoline 8-12 parts, melmac 7-11 parts, phenyl
Trichlorosilane 5-9 parts, 2,4- dichlorobenzoperoxide 8-12 parts, vinyltrimethoxy silane 2-7 parts, titanium dioxide 5-8 parts,
Attapulgite 3-6 parts, dichlorotetra-fluoroethane 2-5 parts, ethylene glycol monobutyl ether 17-21 parts, sodium carboxymethylcellulose 9-16 parts, phenolic aldehyde
Resin 17-21 parts, sodium bentonite 46-57 parts, yellow starch gum 10-20 parts and polyacrylamide 6-15 parts.
Further illustrate, the high binding agent of described a kind of anticorrosive viscosity, raw material are constituted according to following portion rate：
27 parts of epoxy modified hydroxyl acrylic resin, 26 parts of thermoplastic acrylic resin, 19 parts of organosilicon modified crylic acid resin,
6- ethyoxyl -2,2,4- trimethyl -1,9 parts of 2- dihyaroquinolines, 10 parts of melmac, 7 parts of phenyl trichlorosilane, 2,4-
9 parts of dichlorobenzoperoxide, 6 parts of vinyltrimethoxy silane, 7 parts of titanium dioxide, 5 parts of attapulgite, dichlorotetra-fluoroethane 4
Part, 19 parts of ethylene glycol monobutyl ether, 12 parts of sodium carboxymethylcellulose, 19 parts of phenolic resin, 47 parts of sodium bentonite, 12 parts of yellow starch gum
With 8 parts of polyacrylamide.
Further illustrate, the preparation method of the high binding agent of described a kind of anticorrosive viscosity comprises the steps：
(1) epoxy modified hydroxyl acrylic resin is weighed respectively, thermoplastic acrylic resin, organosilicon modified crylic acid resin,
In sequentially adding agitator tank, with the speed of 100rpm 40 minutes are sufficiently stirred for；
(2) 6- ethyoxyl -2,2,4- trimethyl -1,2- dihyaroquinolines, melmac, phenyl trichlorine silicon are continuously added
Alkane, 2,4- dichlorobenzoperoxides, vinyltrimethoxy silane is sufficiently stirred for 60 minutes with the speed of 100rpm, stirring
Temperature is 25 DEG C；
(3) titanium dioxide is continuously added in the mixture of step (2), attapulgite, dichlorotetra-fluoroethane, ethylene glycol monobutyl ether,
Sodium carboxymethylcellulose, phenolic resin, sodium bentonite, dextrin and polyacrylamide, with the speed of 100rpm 60 are sufficiently stirred for
Minute, obtain binder product.
Beneficial effects of the present invention are as follows：
The adhesive strength that preparation in accordance with the present invention is prepared is high, good stability, with excellent high temperature resistant, anti-corruption
The cross-linked structure of the performances such as erosion, high-adhesion, mechanicalness, greatly improves the ageing resistace of binding agent, improves binding agent
Acclimation temperature scope.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based on the reality in the present invention
Example is applied, the every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made is belonged to
The scope of protection of the invention.
Embodiment 1
A kind of high binding agent of anticorrosive viscosity, raw material are constituted according to following portion rate：
22 parts of epoxy modified hydroxyl acrylic resin, 22 parts of thermoplastic acrylic resin, 18 parts of organosilicon modified crylic acid resin,
6- ethyoxyl -2,2,4- trimethyl -1,8 parts of 2- dihyaroquinolines, 7 parts of melmac, 5 parts of phenyl trichlorosilane, 2,4-
8 parts of dichlorobenzoperoxide, 2 parts of vinyltrimethoxy silane, 5 parts of titanium dioxide, 3 parts of attapulgite, dichlorotetra-fluoroethane 2
Part, 17 parts of ethylene glycol monobutyl ether, 9 parts of sodium carboxymethylcellulose, 17 parts of phenolic resin, 46 parts of sodium bentonite, 10 parts of yellow starch gum
With 6 parts of polyacrylamide.
The preparation method of the high binding agent of described a kind of anticorrosive viscosity, comprises the steps：
(1) epoxy modified hydroxyl acrylic resin is weighed respectively, thermoplastic acrylic resin, organosilicon modified crylic acid resin,
In sequentially adding agitator tank, with the speed of 100rpm 40 minutes are sufficiently stirred for；
(2) 6- ethyoxyl -2,2,4- trimethyl -1,2- dihyaroquinolines, melmac, phenyl trichlorine silicon are continuously added
Alkane, 2,4- dichlorobenzoperoxides, vinyltrimethoxy silane is sufficiently stirred for 60 minutes with the speed of 100rpm, stirring
Temperature is 25 DEG C；
(3) titanium dioxide is continuously added in the mixture of step (2), attapulgite, dichlorotetra-fluoroethane, ethylene glycol monobutyl ether,
Sodium carboxymethylcellulose, phenolic resin, sodium bentonite, dextrin and polyacrylamide, with the speed of 100rpm 60 are sufficiently stirred for
Minute, obtain binder product.
Embodiment 2
A kind of high binding agent of anticorrosive viscosity, raw material are constituted according to following portion rate：
27 parts of epoxy modified hydroxyl acrylic resin, 28 parts of thermoplastic acrylic resin, 23 parts of organosilicon modified crylic acid resin,
6- ethyoxyl -2,2,4- trimethyl -1,12 parts of 2- dihyaroquinolines, 11 parts of melmac, 9 parts of phenyl trichlorosilane, 2,
12 parts of 4- dichlorobenzoperoxides, 7 parts of vinyltrimethoxy silane, 8 parts of titanium dioxide, 6 parts of attapulgite, dichloro-tetrafluoro second
5 parts of alkane, 21 parts of ethylene glycol monobutyl ether, 16 parts of sodium carboxymethylcellulose, 21 parts of phenolic resin, 57 parts of sodium bentonite, yellow starch gum
20 parts and 15 parts of polyacrylamide.
The preparation method of the high binding agent of described a kind of anticorrosive viscosity, comprises the steps：
(1) epoxy modified hydroxyl acrylic resin is weighed respectively, thermoplastic acrylic resin, organosilicon modified crylic acid resin,
In sequentially adding agitator tank, with the speed of 100rpm 40 minutes are sufficiently stirred for；
(2) 6- ethyoxyl -2,2,4- trimethyl -1,2- dihyaroquinolines, melmac, phenyl trichlorine silicon are continuously added
Alkane, 2,4- dichlorobenzoperoxides, vinyltrimethoxy silane is sufficiently stirred for 60 minutes with the speed of 100rpm, stirring
Temperature is 25 DEG C；
(3) titanium dioxide is continuously added in the mixture of step (2), attapulgite, dichlorotetra-fluoroethane, ethylene glycol monobutyl ether,
Sodium carboxymethylcellulose, phenolic resin, sodium bentonite, dextrin and polyacrylamide, with the speed of 100rpm 60 are sufficiently stirred for
Minute, obtain binder product.
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention not by above-described embodiment
Limit, other any Spirit Essences without departing from the present invention and the change, modification, replacement made under principle, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (3)
1. the high binding agent of a kind of anticorrosive viscosity, it is characterised in that raw material are constituted according to following portion rate：
Epoxy modified hydroxyl acrylic resin 22-27 parts, thermoplastic acrylic resin 22-28 parts, organosilicon-modified acrylic tree
Fat 18-23 parts, 6- ethyoxyl -2,2,4- trimethyl -1,2- dihyaroquinoline 8-12 parts, melmac 7-11 parts, phenyl
Trichlorosilane 5-9 parts, 2,4- dichlorobenzoperoxide 8-12 parts, vinyltrimethoxy silane 2-7 parts, titanium dioxide 5-8 parts,
Attapulgite 3-6 parts, dichlorotetra-fluoroethane 2-5 parts, ethylene glycol monobutyl ether 17-21 parts, sodium carboxymethylcellulose 9-16 parts, phenolic aldehyde
Resin 17-21 parts, sodium bentonite 46-57 parts, yellow starch gum 10-20 parts and polyacrylamide 6-15 parts.
2. the high binding agent of a kind of anticorrosive viscosity according to claim 1, it is characterised in that raw material are according to following part
Number is than composition：
27 parts of epoxy modified hydroxyl acrylic resin, 26 parts of thermoplastic acrylic resin, 19 parts of organosilicon modified crylic acid resin,
6- ethyoxyl -2,2,4- trimethyl -1,9 parts of 2- dihyaroquinolines, 10 parts of melmac, 7 parts of phenyl trichlorosilane, 2,4-
9 parts of dichlorobenzoperoxide, 6 parts of vinyltrimethoxy silane, 7 parts of titanium dioxide, 5 parts of attapulgite, dichlorotetra-fluoroethane 4
Part, 19 parts of ethylene glycol monobutyl ether, 12 parts of sodium carboxymethylcellulose, 19 parts of phenolic resin, 47 parts of sodium bentonite, 12 parts of yellow starch gum
With 8 parts of polyacrylamide.
3. the preparation method of the high binding agent of a kind of anticorrosive viscosity according to claim 1, it is characterised in that include as
Lower step：
(1) epoxy modified hydroxyl acrylic resin is weighed respectively, thermoplastic acrylic resin, organosilicon modified crylic acid resin,
In sequentially adding agitator tank, with the speed of 100rpm 40 minutes are sufficiently stirred for；
(2) 6- ethyoxyl -2,2,4- trimethyl -1,2- dihyaroquinolines, melmac, phenyl trichlorine silicon are continuously added
Alkane, 2,4- dichlorobenzoperoxides, vinyltrimethoxy silane is sufficiently stirred for 60 minutes with the speed of 100rpm, stirring
Temperature is 25 DEG C；
(3) titanium dioxide is continuously added in the mixture of step (2), attapulgite, dichlorotetra-fluoroethane, ethylene glycol monobutyl ether,
Sodium carboxymethylcellulose, phenolic resin, sodium bentonite, dextrin and polyacrylamide, with the speed of 100rpm 60 are sufficiently stirred for
Minute, obtain binder product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610818873.2A CN106634717A (en) | 2016-09-13 | 2016-09-13 | Anti-corrosive high-viscosity binder and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610818873.2A CN106634717A (en) | 2016-09-13 | 2016-09-13 | Anti-corrosive high-viscosity binder and preparation method thereof |
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| CN106634717A true CN106634717A (en) | 2017-05-10 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107739586A (en) * | 2017-10-25 | 2018-02-27 | 浙江星丰科技有限公司 | A kind of moisture-proof adhesive and preparation method thereof |
| CN108086082A (en) * | 2017-12-22 | 2018-05-29 | 河南城建学院 | A kind of construction technology of cement emulsified asphalt mortar penetration type semi-rigid pavement |
| CN109357107A (en) * | 2018-11-01 | 2019-02-19 | 中山科邦化工材料技术有限公司 | A kind of composite insulation boards and preparation method thereof |
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| CN104356978A (en) * | 2014-12-03 | 2015-02-18 | 张亦彬 | Preparation method of adhesive |
| CN105176448A (en) * | 2015-07-24 | 2015-12-23 | 中山市伯伦克专用化学产品有限公司 | Protective elastic peelable blue glue and preparation method therefor |
| CN105602484A (en) * | 2015-12-31 | 2016-05-25 | 东莞市卓艺印刷制品有限公司 | Transfer printing film special for ceramics and preparation method of transfer printing film |
-
2016
- 2016-09-13 CN CN201610818873.2A patent/CN106634717A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289611A (en) * | 2013-05-23 | 2013-09-11 | 安徽溢彩玻璃器皿有限公司 | Acrylic resin thermal transfer glue and preparation method thereof |
| CN103600020A (en) * | 2013-12-03 | 2014-02-26 | 巩义市晶辉耐火材料有限公司 | Binder and preparation method thereof |
| CN104356978A (en) * | 2014-12-03 | 2015-02-18 | 张亦彬 | Preparation method of adhesive |
| CN105176448A (en) * | 2015-07-24 | 2015-12-23 | 中山市伯伦克专用化学产品有限公司 | Protective elastic peelable blue glue and preparation method therefor |
| CN105602484A (en) * | 2015-12-31 | 2016-05-25 | 东莞市卓艺印刷制品有限公司 | Transfer printing film special for ceramics and preparation method of transfer printing film |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107739586A (en) * | 2017-10-25 | 2018-02-27 | 浙江星丰科技有限公司 | A kind of moisture-proof adhesive and preparation method thereof |
| CN108086082A (en) * | 2017-12-22 | 2018-05-29 | 河南城建学院 | A kind of construction technology of cement emulsified asphalt mortar penetration type semi-rigid pavement |
| CN109357107A (en) * | 2018-11-01 | 2019-02-19 | 中山科邦化工材料技术有限公司 | A kind of composite insulation boards and preparation method thereof |
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Application publication date: 20170510 |