CN103666094B - A kind of printing-ink and its preparation method - Google Patents
A kind of printing-ink and its preparation method Download PDFInfo
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- CN103666094B CN103666094B CN201310574961.9A CN201310574961A CN103666094B CN 103666094 B CN103666094 B CN 103666094B CN 201310574961 A CN201310574961 A CN 201310574961A CN 103666094 B CN103666094 B CN 103666094B
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Abstract
A kind of printing-ink, is made up of the raw material of following weight part: bismuth oxide 3-4, boron oxide 2-3, zinc oxide 3-4, silicon sol 4-6, ethyl acetate 5-8, tetrapropyl ammonium borofluoride 1-2,2-butoxy-ethanol 3-4, Virahol 6-8, ethoxylated trimethylolpropane triacrylate 10-12, vinylformic acid-4-hydroxybutyl 12-14, polyethylene glycol acrylate 6-9, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5. Ink of the present invention has that glossiness is good, bright in luster, firmness height, has the advantages such as good water-fast, resistance to molten, wear resisting property; The preparation method of ink, preparation process is simple and direct, is suitable for suitability for industrialized production. Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, prevents the surface of water and other molecules corrosion ink and painting objects in air, anti-oxidant, makes color bright-coloured lastingly, and improves slickness.
Description
Technical field
The invention belongs to printing ink paint field, particularly relate to a kind of printing-ink and its preparation method.
Background technology
The color (form and aspect) of ink, body bone (rheological property such as rare thick, degree of mobilization) and drying property are three performances the most important of ink. Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare. What have makes low-melting ink vehicle with vegetables oil; What have makes low-melting ink vehicle with resin and solvent or water etc. These are all that the object according to printing and stock, printing process, the type of printing plate and drying means etc. determine.
Production efficiency, quality product are had huge impact by the rate of drying of ink, thixotropy, skeleton property, and human body is had impact by the composition of ink, how to study to human body harm as far as possible ink little, that production efficiency height, environmental friendliness, cost are low have far-reaching meaning.
Summary of the invention
It is an object of the invention to provide a kind of printing-ink and its preparation method, this ink is water-fast, resistance to molten, wear-resisting.
The technical scheme of the present invention is as follows:
A kind of printing-ink, it is characterised in that be made up of the raw material of following weight part: bismuth oxide 3-4, boron oxide 2-3, zinc oxide 3-4, silicon sol 4-6, ethyl acetate 5-8, tetrapropyl ammonium borofluoride 1-2,2-butoxy-ethanol 3-4, Virahol 6-8, ethoxylated trimethylolpropane triacrylate 10-12, vinylformic acid-4-hydroxybutyl 12-14, polyethylene glycol acrylate 6-9, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4, Kathon 1-2,2-amino-2-methyl-1-propanol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 10351-2, linking agent TAC1-2, ethanol 20-24; Preparation method is by Silane coupling reagent KH-570, ricinolic acid, ethanol mixing, is heated to 60-70 DEG C, stirs after 20-30 minute, then add other remaining component, be warming up to 80-85 DEG C, stirs 30 40 minutes, to obtain final product.
The preparation method of described refractoriness printing-ink, it is characterized in that comprising the following steps: by bismuth oxide, boron oxide, zinc oxide, silicon sol, ethyl acetate, tetrapropyl ammonium borofluoride, 2-butoxy-ethanol, Virahol, ethoxylated trimethylolpropane triacrylate mixes, under stirring at 1000-1400 rev/min, add the peroxidation trimethylacetic acid tert-butyl ester, it is heated to 70-90 DEG C with the speed of 5-8 DEG C/minute, add vinylformic acid-4-hydroxybutyl, polyethylene glycol acrylate, continue stirring reaction 30-40 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μm, obtain.
The useful effect of the present invention
Ink of the present invention has that glossiness is good, bright in luster, firmness height, has the advantages such as good water-fast, resistance to molten, wear resisting property; The preparation method of ink, preparation process is simple and direct, is suitable for suitability for industrialized production. Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, prevents the surface of water and other molecules corrosion ink and painting objects in air, anti-oxidant, makes color bright-coloured lastingly, and improves slickness, wear resistance, extends working time.
Embodiment
A kind of printing-ink, is made up of the raw material of following weight part (kilogram): bismuth oxide 3.5, boron oxide 2.5, zinc oxide 3.5, silicon sol 5, ethyl acetate 6, tetrapropyl ammonium borofluoride 1.5,2-butoxy-ethanol 3.5, Virahol 7, ethoxylated trimethylolpropane triacrylate 11, vinylformic acid-4-hydroxybutyl 13, polyethylene glycol acrylate 8, the peroxidation trimethylacetic acid tert-butyl ester 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): Silane coupling reagent KH-570 2.5, Viscoat 295 3.5, Kathon 1.5,2-amino-2-methyl-1-propanol 1.5, polyoxyethylene sorbitan monooleate 2.5, ricinolic acid 1.5, oxidation inhibitor 10351.5, linking agent TAC1.5, ethanol 22; Preparation method is by Silane coupling reagent KH-570, ricinolic acid, ethanol mixing, is heated to 65 DEG C, stirs after 26 minutes, then add other remaining component, be warming up to 83 DEG C, stirs 34 minutes, to obtain final product.
The preparation method of described printing-ink, comprise the following steps: by bismuth oxide, boron oxide, zinc oxide, silicon sol, ethyl acetate, tetrapropyl ammonium borofluoride, 2-butoxy-ethanol, Virahol, ethoxylated trimethylolpropane triacrylate mixes, under stirring at 1200 revs/min, add the peroxidation trimethylacetic acid tert-butyl ester, it is heated to 80 DEG C with the speed of 7 DEG C/minute, add vinylformic acid-4-hydroxybutyl, polyethylene glycol acrylate, continue stirring reaction 35 minutes, add other remaining components, continue stirring reaction 1.8 hours, grinding distribution becomes the slurry of 30 μm, obtain.
Ink quality equal one of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances reach the requirement of QB/T2024-94 standard.
Claims (2)
1. a printing-ink, it is characterised in that be made up of the raw material of following weight part: bismuth oxide 3-4, boron oxide 2-3, zinc oxide 3-4, silicon sol 4-6, ethyl acetate 5-8, tetrapropyl ammonium borofluoride 1-2,2-butoxy-ethanol 3-4, Virahol 6-8, ethoxylated trimethylolpropane triacrylate 10-12, vinylformic acid-4-hydroxybutyl 12-14, polyethylene glycol acrylate 6-9, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4, Kathon 1-2,2-amino-2-methyl-1-propanol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 10351-2, linking agent TAC1-2, ethanol 20-24; Preparation method is by Silane coupling reagent KH-570, ricinolic acid, ethanol mixing, is heated to 60-70 DEG C, stirs after 20-30 minute, then add other remaining component, be warming up to 80-85 DEG C, stirs 30 40 minutes, to obtain final product.
2. the preparation method of printing-ink according to claim 1, it is characterized in that comprising the following steps: by bismuth oxide, boron oxide, zinc oxide, silicon sol, ethyl acetate, tetrapropyl ammonium borofluoride, 2-butoxy-ethanol, Virahol, ethoxylated trimethylolpropane triacrylate mixes, under stirring at 1000-1400 rev/min, add the peroxidation trimethylacetic acid tert-butyl ester, it is heated to 70-90 DEG C with the speed of 5-8 DEG C/minute, add vinylformic acid-4-hydroxybutyl, polyethylene glycol acrylate, continue stirring reaction 30-40 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μm, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574961.9A CN103666094B (en) | 2013-11-18 | 2013-11-18 | A kind of printing-ink and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574961.9A CN103666094B (en) | 2013-11-18 | 2013-11-18 | A kind of printing-ink and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666094A CN103666094A (en) | 2014-03-26 |
| CN103666094B true CN103666094B (en) | 2016-06-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310574961.9A Expired - Fee Related CN103666094B (en) | 2013-11-18 | 2013-11-18 | A kind of printing-ink and its preparation method |
Country Status (1)
| Country | Link |
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| CN (1) | CN103666094B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194471B (en) * | 2014-07-28 | 2016-06-15 | 蚌埠首创滤清器有限公司 | A kind of printing-ink being modifiied preparation by wasted ink powder |
| CN106084998A (en) * | 2016-08-10 | 2016-11-09 | 苏州中亚油墨有限公司 | White waterproof ink |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60248711A (en) * | 1984-05-25 | 1985-12-09 | Ricoh Co Ltd | Nonaqueous resin dispersion |
| CN102627028A (en) * | 2012-03-29 | 2012-08-08 | 中国科学院化学研究所 | Method for preparing high-resolution pattern based on self-infiltration-removal of ink droplet |
| CN103374260A (en) * | 2013-07-31 | 2013-10-30 | 中国科学院化学研究所 | Superhydrophobic ink and application thereof to printing plate material for offset print |
-
2013
- 2013-11-18 CN CN201310574961.9A patent/CN103666094B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60248711A (en) * | 1984-05-25 | 1985-12-09 | Ricoh Co Ltd | Nonaqueous resin dispersion |
| CN102627028A (en) * | 2012-03-29 | 2012-08-08 | 中国科学院化学研究所 | Method for preparing high-resolution pattern based on self-infiltration-removal of ink droplet |
| CN103374260A (en) * | 2013-07-31 | 2013-10-30 | 中国科学院化学研究所 | Superhydrophobic ink and application thereof to printing plate material for offset print |
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| Publication number | Publication date |
|---|---|
| CN103666094A (en) | 2014-03-26 |
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Granted publication date: 20160615 Termination date: 20181118 |
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